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Trimethyl Borate

    • Product Name Trimethyl Borate
    • Alias Trimethoxyborane
    • Einecs 203-742-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales6@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    920172

    Chemicalname Trimethyl Borate
    Casnumber 121-43-7
    Molecularformula B(OCH3)3
    Molarmass 103.93 g/mol
    Appearance Colorless liquid
    Odor Mild, alcohol-like
    Density 0.935 g/cm³
    Boilingpoint 68.7 °C
    Meltingpoint -34.6 °C
    Solubilityinwater Reacts with water
    Flashpoint 11 °C (closed cup)
    Refractiveindex 1.369 at 20 °C
    Vaporpressure 108 mmHg (20 °C)

    As an accredited Trimethyl Borate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Trimethyl Borate is packaged in a 500 mL amber glass bottle with a secure screw cap and labeled with hazard warnings.
    Shipping Trimethyl Borate should be shipped in tightly sealed containers, away from moisture and sources of ignition, as it is highly flammable. It must be handled as a hazardous material under proper labeling and transport regulations (UN 1993, Class 3). Store and ship in cool, well-ventilated areas, following all relevant safety guidelines.
    Storage Trimethyl borate should be stored in a cool, dry, and well-ventilated area, away from heat, sparks, open flames, and incompatible substances such as strong oxidizers and moisture. Keep the container tightly closed and properly labeled. Use approved safety containers and store in a flammable liquids cabinet. Protect from direct sunlight and static discharge to prevent fire or explosion hazards.
    Application of Trimethyl Borate

    Applications of Trimethyl Borate in Industrial Manufacturing

    As the direct manufacturer of Trimethyl Borate, we supply this compound to specialized sectors where it fulfills precise roles throughout various production processes. Below, we outline real-world downstream applications in which Trimethyl Borate contributes unique value, describing compliance requirements, working concentrations, process integration points, and actual finished goods.

    1. Boron-Based Optical Glass Production

    Specialty glassmakers use Trimethyl Borate to introduce boron oxide into the glass matrix during the melt process. Its high purity supports optical clarity and thermal shock resistance for advanced glass types, including borosilicate and high refractive index glasses. By using it as a boron source, manufacturers achieve precise control over final optical and mechanical properties essential for laboratory, photonics, and instrument glass.

    Industry compliance standards

    • DIN ISO 3585 (Borosilicate glass)
    • ASTM C162 (Standard terminology of glass and glass products)
    • ISO 9001:2015 Quality Management Systems

    Typical usage ratio

    • 2–12% by weight of total silica input, adjusted for boron oxide equivalency depending on glass formulation and target specifications

    Downstream process integration

    • Added directly to the glass furnace batch step, often dissolved in other batch-forming agents to ensure homogeneous boron distribution before melting at 1200–1600°C

    Final product types

    • Borosilicate laboratory glassware
    • Optical glass blanks
    • Glass fiber for high-performance composites
    • Specialty flat glass for electronics and displays

    2. Catalyst Synthesis for Olefin Polymerization

    Chemical producers employ Trimethyl Borate in the synthesis of boron-containing co-catalysts for olefin and diene polymerization. It functions as a methylating agent or boron precursor during the preparation of metallocene and Ziegler-Natta catalysts, enabling controlled catalyst morphology and activity. This improves polymer attributes like melt index, transparency, and toughness in finished product lines.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • REACH Regulation (EC 1907/2006) for catalyst ingredients
    • 21 CFR 177.1520 for polymer food contact compliance (end-use dependency)

    Typical usage ratio

    • 0.5–5 mol% relative to main transition metal catalyst, tuned for catalyst support type and monomer feedstock

    Downstream process integration

    • Reacted in situ with alumoxanes, silanes, or metallocene precursors prior to reactor charging stage of polymer production

    Final product types

    • Polyethylene and polypropylene resins
    • Thermoplastic elastomers
    • High-clarity polyolefin films
    • Impact-modified plastics for automotive and packaging

    3. Flame Retardant Additive Synthesis

    Formulators of flame-retardant chemicals use Trimethyl Borate as a boron-donor in reactions that yield borate esters and other organoboron compounds. These intermediates serve in the compounding of halogen-free flame retardants for thermoplastics, coatings, and insulation foams. The resulting additives offer thermal stability and low-smoke performance for electronics and construction systems.

    Industry compliance standards

    • UL 94 (Flammability testing of plastic materials)
    • IEC 60695 (Fire hazard testing for electrical equipment)
    • RoHS Directive 2011/65/EU for substances in electronics (exclusion of prohibited elements)

    Typical usage ratio

    • 10–25% by weight in intermediate synthesis, ratio determined by target phosphorus/boron balance in additive products

    Downstream process integration

    • Reacted with diols or polyols in the esterification step to form borate esters prior to compounding with host polymers

    Final product types

    • Halogen-free flame-retardant masterbatches
    • PC/ABS fire-retardant compounds
    • Coating additives for wire & cable
    • Rigid PU foam insulation panels

    4. Boron Source in Sintered Advanced Ceramics

    Sintered materials manufacturers use Trimethyl Borate as a boron feedstock in the preparation of boron carbide and boron nitride ceramics. It is favored for its clean volatility and minimal residual impurities during high-temperature processing. This supports controlled grain growth and improved densification, which are crucial in producing high-hardness, wear-resistant components for defense, tooling, and electronics sectors.

    Industry compliance standards

    • ASTM C1326 (Boron carbide test methods)
    • ISO 9001:2015 Quality Management Systems
    • ISO 20507 (Powder metallurgy — ceramics terminology)

    Typical usage ratio

    • As boron oxide equivalent, 2–8% by weight of total ceramic powder blend, adjusted for target boron/carbon or BN ratios in the sintered matrix

    Downstream process integration

    • Introduced during powder mixing step, followed by pre-calcination or directly into sintering ovens at 1600–2000°C

    Final product types

    • Boron carbide armor plates
    • Hot-pressed boron nitride crucibles
    • Abrasion-resistant ceramic seals
    • High-temperature electrical insulators

    5. Reagent in Organic Synthesis of Boronic Esters

    Pharmaceutical and agrochemical manufacturers use Trimethyl Borate in a key reagent role for the preparation of aryl boronic esters and acids. It reacts with Grignard reagents or organolithiums to deliver boronic group transfer, essential for subsequent Suzuki-Miyaura cross-coupling reactions. This pathway produces high-purity intermediates required for complex active ingredients and specialty organics.

    Industry compliance standards

    • GMP (Good Manufacturing Practice) for pharma actives (ICH Q7, FDA 21 CFR Parts 210/211)
    • ISO 9001:2015 Quality Management Systems
    • REACH registration compliance for intermediates

    Typical usage ratio

    • Stoichiometric or slight excess to Grignard or organolithium reagent (1–1.2 equivalents), depending on substrate reactivity

    Downstream process integration

    • Added during halide/metalation step in air-free organic synthesis; excess is typically distilled off in workup before subsequent coupling

    Final product types

    • Aryl boronic acids and esters
    • Bifunctional intermediates for Suzuki coupling
    • Pharmaceutical drug intermediates
    • Agrochemical synthesis building blocks
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