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Tungsten(VI) Chloride

    • Product Name Tungsten(VI) Chloride
    • Alias tungsten hexachloride
    • Einecs 233-022-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    195604

    Name Tungsten(VI) Chloride
    Other Names Tungsten hexachloride
    Chemical Formula WCl6
    Molar Mass 396.47 g/mol
    Appearance Dark violet-blue crystalline solid
    Melting Point 275 °C
    Boiling Point 346 °C (decomposes)
    Density 3.68 g/cm³
    Solubility In Water Reacts, decomposes
    Solubility In Other Solvents Soluble in carbon disulfide, chloroform, carbon tetrachloride
    Cas Number 13283-01-7
    Oxidation State +6
    Hazard Statements Corrosive, harmful if inhaled or swallowed

    As an accredited Tungsten(VI) Chloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Tungsten(VI) Chloride is packaged in a sealed, amber glass bottle, 100 grams, with hazard labeling and moisture-resistant protective outer box.
    Shipping Tungsten(VI) Chloride should be shipped in tightly sealed, corrosion-resistant containers under a dry, inert atmosphere to prevent moisture absorption and hydrolysis. Package and label according to hazardous material transport regulations. Handle with care, avoiding contact with skin or eyes. Store and ship in cool, well-ventilated conditions away from incompatible substances.
    Storage Tungsten(VI) chloride should be stored in a tightly sealed container, under an inert atmosphere such as dry nitrogen or argon. It must be kept in a cool, dry, and well-ventilated area, away from moisture and incompatible materials like strong bases and oxidizers. Protect from light and sources of ignition. Proper labeling and secure, corrosion-resistant containers are necessary to prevent leaks and contamination.
    Application of Tungsten(VI) Chloride

    Applications of Tungsten(VI) Chloride in Industrial Manufacturing

    As a direct manufacturer, we supply Tungsten(VI) Chloride to specialized downstream sectors that demand precise integration of high-purity tungsten compounds. Below, we detail its main industrial applications, each with unique process requirements and compliance needs.

    1. Organotungsten Synthesis for Advanced Catalysts

    Leading catalyst producers use Tungsten(VI) Chloride as a base material to synthesize organotungsten intermediates required in polymerization catalysts and specialty chemical processes. During these syntheses, precise moisture control, inert gas handling, and high-purity feedstocks are essential for achieving homogeneous molecular complexes and minimizing trace impurities. Industry partners typically demand consistent batch quality to meet performance benchmarks in high-efficiency catalysts for olefin polymerization or for selective oxidation in petrochemical refining.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • ASTM D6304-00 (water content control)
    • REACH (EC No 1907/2006, SVHC compliance)
    • Responsible Care® Global Charter

    Typical usage ratio

    • 0.5–5 wt% of Tungsten(VI) Chloride relative to organic ligand substrates; adjusted based on target catalyst loadings and efficiency requirements

    Downstream process integration

    • Direct addition in inert atmosphere reactors for ligand coordination
    • Batched during controlled solvent reflux for transition metal complexation
    • Used for in situ chlorination during alkylation or arylation reactions

    Final product types

    • Alkyl tungsten complexes for Ziegler-Natta catalyst systems
    • Tungsten-based metathesis catalysts for polyolefin production
    • Organotungsten intermediates for electronic chemical applications

    2. Precursor for Tungsten Oxide Coatings

    Glass coating manufacturers utilize Tungsten(VI) Chloride as a volatile precursor to deposit tungsten oxide films via chemical vapor deposition (CVD) and sol-gel routes. The controlled hydrolysis and oxidation during application ensure even deposition vital for electrochromic and thermal control glass technologies. Each stage, from precursor distillation to substrate reaction, is tightly monitored to maintain film thickness and functional performance.

    Industry compliance standards

    • ISO 14001 Environmental Management Systems
    • EN 1096-1:2012 (glass with coatings for building)
    • RoHS (2011/65/EU, for architectural glass components)
    • Occupational exposure limits for chlorine and tungsten under OSHA 29 CFR 1910.1000

    Typical usage ratio

    • Stoichiometric precursor:substrate ratio typically 1:20–1:100, depending on substrate area and desired film thickness

    Downstream process integration

    • Vaporized in controlled reaction chambers for CVD glass coating
    • Hydrolyzed in solution for sol-gel and dip-coating processes
    • Used as a dopant or additive for mixed oxide films (e.g., tungsten-molybdenum oxides)

    Final product types

    • Electrochromic windows for energy-efficient buildings
    • Low-emissivity (Low-E) architectural glazing
    • Photocatalytic and self-cleaning glass panels

    3. Metal Halide Lamp Manufacturing

    Manufacturers of high-intensity discharge (HID) and specialty lighting systems employ Tungsten(VI) Chloride as an intermediate to produce volatile tungsten species incorporated inside lamp bulbs. The compound’s volatility under moderate heat allows even doping and consistent vapor phase tungsten distribution, supporting sustained emission characteristics and lamp longevity. This process benefits from high-group purity and trace-level impurity screening.

    Industry compliance standards

    • IEC 62035:2014 (discharge lamps - safety requirements)
    • EN 62471:2008 (lamp photobiological safety)
    • ISO 9001:2015 for lighting manufacturing QA/QC
    • EU Directive 2012/19/EU (WEEE – waste electrical and electronic equipment)

    Typical usage ratio

    • Doping ratio of 1–8 mg per lamp unit, depends on lamp wattage and emission spectrum requirements

    Downstream process integration

    • Metered addition into lamp ampule during fill and seal operations
    • Processed under vacuum or inert atmosphere to prevent premature hydrolysis
    • Combined with halide salts for tailored emission color temperatures

    Final product types

    • Metal halide lamps for streetlighting
    • Projection and stage lighting bulbs
    • Specialized UV-C lamps for industrial sterilization

    4. Tungsten Thin Film Deposition in Semiconductor Device Fabrication

    Semiconductor and integrated circuit manufacturers deploy Tungsten(VI) Chloride as a chemical vapor deposition precursor for tungsten metal thin films. These films serve as gate electrodes, interconnects, and contact layers in high-reliability electronic devices. Deposition processes require ultra-high purity starting material, precise flow modulation, and integration with high-temperature metallization steps, all essential to achieving uniform film morphology and low electrical resistivity.

    Industry compliance standards

    • SEMI C74 (purity standards for tungsten compounds)
    • JEDEC JESD22-A103 (IC reliability - high temperature storage)
    • ISO 14644-1 cleanroom classification
    • RoHS 2011/65/EU (for electronic devices)

    Typical usage ratio

    • Controlled vapor flow rates, typically 0.01–0.1 mol/h per chamber, scaled based on wafer size and deposition target thickness

    Downstream process integration

    • Introduced to CVD chamber with reductants for direct metal film formation
    • Integrated in ALD (Atomic Layer Deposition) cycles for sub-10nm feature sizes
    • Used after dielectric etch for contact plug fill processes

    Final product types

    • VLSI and ULSI devices (logic and memory ICs)
    • Semiconductor wafers with tungsten interconnects
    • MEMS (Micro-Electro-Mechanical Systems) components

    5. Inorganic Synthesis of Tungstic Acid and Tungstate Salts

    Producers of analytical reagents and specialty tungsten salts start with Tungsten(VI) Chloride for direct hydrolysis into tungstic acid, which forms the base for manufacturing high-purity tungstate compounds. The conversion processes require precise pH control, staged addition of chlorides, and post-synthesis purification to eliminate unwanted metallic contaminants. These preparations are critical for laboratories, ceramics, and pigment industries demanding exacting purity and analytical performance.

    Industry compliance standards

    • ACS Reagent Chemical Standards (American Chemical Society)
    • ISO/IEC 17025 Analytical Laboratory Accreditation
    • REACH and CLP compliance for downstream sales within EEA
    • UN 3260 DG requirements for transport until conversion is complete

    Typical usage ratio

    • Reactant ratios: 1 mol Tungsten(VI) Chloride per 6 mol water for tungstic acid formation, adjusted during upscaling and purity optimization

    Downstream process integration

    • Hydrolysis reactors for tungstic acid generation
    • Neutralization and filtration steps for crude salt precipitation
    • Final recrystallization for high-purity analytical grade salts

    Final product types

    • Sodium tungstate and ammonium paratungstate for analytical chemistry
    • Ceramic-grade tungstic acid for electronic component production
    • Tungsten pigments for specialty colorants

    6. Chlorination Agent in High-Performance Alloy Synthesis

    Producers of specialty superalloys and high-strength steels rely on Tungsten(VI) Chloride as a source of reactive tungsten in metallurgical chlorination processes. Direct chlorination modifies the metal matrix, introducing tungsten homogeneously at the atomic level, which enhances the alloy’s corrosion, wear, and thermal resistance. Operations prioritize closed system handling, atmospheric controls, and high-temperature profiles to optimize conversion efficiency and minimize reactive by-products.

    Industry compliance standards

    • ISO 4948-1:1982 (classification of steel and alloy composition)
    • AMS 5692 (aerospace-grade high-temperature alloys)
    • CFR Title 29, Subpart Z (hazardous materials and occupational exposure)
    • IATF 16949 for automotive-quality alloys

    Typical usage ratio

    • Chlorination loadings: 0.1–2% by weight of total alloy charge, optimized based on target alloy microstructure

    Downstream process integration

    • Introduced during molten alloy handling for in-situ metal chlorination
    • Reactive gas phase addition in vacuum induction melting or argon arc processes
    • Used in powder metallurgy for fine alloy control

    Final product types

    • Tungsten-modified nickel-based superalloys
    • High-strength tool steels for cutting and forming applications
    • Corrosion-resistant cast components for aerospace and marine use
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    Certification & Compliance
    More Introduction

    Tungsten(VI) Chloride: Practical Insight from the Manufacturing Floor

    Understanding Tungsten(VI) Chloride in the Real World

    In chemical manufacturing, the reality behind Tungsten(VI) Chloride—often listed as WCl6—goes well beyond simple formulas or textbook diagrams. Behind every flask or drum stands a production process embedded in practical experience. Unlike resellers, our warehouse floors witness the exact points where WCl6 behaves as more than just a rare transition metal halide. We start with high-purity tungsten, fuse it with chlorine under carefully controlled heat, and see a deep purple crystalline powder emerge, rich with chemical promise.

    Model, Size, and Consistency: Beyond the Label

    Batch numbers and grade markings tell only part of the story. Each lot of Tungsten(VI) Chloride carries its own minor fingerprint, yet every shipment must align with the core spec—above 99.9% purity, little to no visible contamination, and no clumping from poor packaging or exposure to moisture. Early in our operation, we learned that even a hint of water sets off WCl6 hydrolysis, throwing off yield and safety alike. Maintaining crystal integrity means forming and funneling the product under a dry, controlled atmosphere, and using double-seal packaging so air remains out and the payload stays true to quoted molarity.

    Putting WCl6 to Work: Applications Backed by Direct Experience

    Most chemists approach Tungsten(VI) Chloride with respect mixed with caution. Over the years, customers working in organic chemistry, materials research, and even advanced electronics have come looking for dependable WCl6—not just by the gram, but by the kilo or even pallet. It forms the backbone for synthesizing other tungsten-based compounds, feeding directly into the creation of tungsten oxides, clusters, and many organotungsten complexes.

    Custom alloy makers use our WCl6 to tweak metal grain boundaries and enhance corrosion resistance. In thin film and nanotechnology labs, its volatility at moderate temperatures makes it especially useful for chemical vapor deposition (CVD), depositing uniform tungsten layers in semiconductors and glass coatings. Consistency between batches remains critical for predictable film thickness and resistance; a slight variation in raw powder can turn into performance headaches at the device level. Having manufactured and shipped hundreds of tons, we know the pressure.

    Other industries use WCl6 for catalysis, especially when developing reagents tailored for site-specific chemical transformations. Pharmaceutical studies sometimes reach for tungsten clusters formed directly from chloride precursors, leveraging unique redox properties for highly selective reactions. Customers on the research side often mention how they rely on stable supplies so each experiment can repeat with confidence, and every variable stays visible.

    What Sets This Product Apart: Differences Born from Manufacture, Not Brochure Copy

    It's tempting to stack brochures with promises. Actual experience with WCl6 shows that not all products calling themselves "high purity" live up to those claims where it matters. Too many shipments sourced through vague supply chains show up off-color or with suspiciously gritty texture. Our shop floor has rejected attempts at cost-cutting through cheaper tungsten feedstock: even a trace of transition metal or lighter halide, introduced early, migrates through the product line and sabotages later use.

    Critical differences between manufacturers show up in simple gravimetric tests and even more in real-world application. The translucent violet, deep crystalline shine of a fresh batch reveals more than spectrographs alone. We've noticed that competitors sometimes cut steps in drying or skip post-fusion conditioning, which leaves their WCl6 prone to caking and less reactive in key organic syntheses. Even slight exposure to air between pour-off and packaging can create a grayish crust, leading to frustrating downtime or poor yields on the customer side.

    Our experience also informs safe handling guidance. Some knowledge comes only from hours cleaning equipment or troubleshooting blocked transfer lines. Moisture and residual acid vapor represent constant risks in both storage and application settings. We've seen the chaos of a poorly sealed container: corrosion on shelves, wasted material, and staff safety compromised. Addressing this starts at procurement—investing in the right desiccants and foil layer packaging means the product lands at your bench as we made it, not degraded in transit.

    Differences extend into batch tracking and responsiveness: when a customer raises a concern, we can trace every step of production and packaging, find potential issues, and fix them for future runs. Trace metals require more than a data sheet; they call for regular mass spectrometry and in-process sampling. Cheaper suppliers often miss this—at best, the customer faces extra purification steps; at worst, entire projects go on hold while material goes back and forth across borders.

    Sourcing Tungsten(VI) Chloride in the Era of Supply Chain Turbulence

    Price and availability depend on global tungsten ore supply—fragile under unpredictable mining regimes and periodic trade policy shifts. We've seen demand for WCl6 spike with each leap forward in battery research or as new semiconductor fabrication processes emerge. Years ago, extensive outsourcing of tungsten processing to distant sites brought low prices but raised inconsistency and trace contamination. Rebuilding local refining capacity and locking in diversified supply sources brought back control over quality, at the cost of thicker compliance paperwork and more logistics oversight.

    Global customers increasingly scrutinize raw material sourcing, whether it's the European Union or North American firms bound by responsible minerals standards. Our plant team goes beyond minimum regulatory declarations: regular third-party audits, fully documented chain-of-custody, and transparent test records ensure shipments meet expectations. This isn't empty compliance; we've seen customers launch new product lines with our WCl6 precisely because they could guarantee full regulatory traceability from ore to packaged batch, down to the drum.

    Even routine restocking cycles become complicated by global shipping constraints and environmental regulatory changes. Shipments that sailed with little fuss a decade ago now require detailed hazard documentation and proof of secondary containment. We maintain direct relationships with shipping partners who understand how to minimize transit time and environmental risk—more than once, that's saved a consignment from climate-induced delays or mishandling at border storage.

    Problems and the Path Forward: Practical Solutions Through Experience

    In manufacturing, even small failures compound quickly. We learned early that ignoring small water leaks in the transfer system allowed chlorides to react prematurely, costing time and raw material. We redesigned valves, switched to higher-grade fluoropolymer seals, and introduced regular atmospheric monitoring in key transfer zones. The investment paid off: improved yields, fewer waste incidents, and safer staff working conditions.

    Some problems show up only after scale-up. Lab-scale synthesis can hide issues like phase separation, but scaling to hundreds of kilograms brings heat management, exhaust handling, and packaging design to the fore. For Tungsten(VI) Chloride, poor cooling protocols allow microcrystallization, trapping unreacted tungsten that pulls purity below spec. We built our quality procedures through actual failures—wasted runs, recalibrated temperature curves, new chiller systems, and staff retraining.

    Logistics sometimes confound the best-made plans. One winter, an overlooked shipment sat for hours on a freezing airport tarmac, leading to partial hydrolysis and several tense days tracing lost raw value. Today, we flag winter routes in our logistics system, coordinate with shippers on climate-controlled transit, and include real-time tracking so even sensitive packages reach their destination intact. Product traceability and shipment resilience matter as much as technical specification in this business.

    Industry Trends and Customer Needs: Evolving Together

    Applications for Tungsten(VI) Chloride evolve with end-user innovation. In recent years, semiconductor research called for WCl6 of ever-higher purity with tighter controls over trace silicon and aluminum, contaminants that can sabotage thin-film deposition. Responding to this shift, our labs doubled the frequency of impurity testing; we invested in new plasma emission spectrometers, ensuring customers facing ever-mounting regulatory and process scrutiny could base their next project on trustworthy data.

    Research into catalytic transformations pushes formulation purity further: small shifts in trace transition metals or residual organic contamination can dramatically change reaction pathways. Our process engineers take feedback from these advanced users to refine filtration and separation steps, sometimes working alongside customer labs to troubleshoot unexpected results or investigate possible production artifacts. We've adjusted batch sizes, cleaning protocols, and even re-engineered packaging lines to reduce particle contamination.

    Communication shapes daily improvements. Technical support doesn't just solve problems after the fact; regular conversations with process engineers, lab managers, and even academic researchers reveal real-world changes in expectations around packing size, material format, and delivery frequency. Not every request fits into standard production runs, but our years of experience allow for quick turnarounds and custom packaging solutions. Flexibility grows out of firsthand knowledge of both the chemistry and the challenges faced by end users.

    Why Consistent Product Matters: Lessons That Built Our Process

    Far from abstract, the importance of quality and consistency in Tungsten(VI) Chloride hits hardest during scale-up or in mission-critical research. A kilo of contaminated reagent can halt days of device manufacturing, cost tens of thousands in wasted effort, or undermine scientific conclusions. We learned these lessons through post-mortems on failed batches—tracking back to supply issues, packing faults, or cleaning oversights that were only caught by lucky observant operators.

    It takes recurring collaboration to align product output with strict academic or industrial needs. For high-purity electronics labs, surface oxidation or trace contaminants present the greatest challenges. We've modified finishing steps to cut down on extraneous surface layers and brought in automated sifting under inert atmosphere, helping labs maximize reproducibility. For research teams exploring new catalytic chemistries, a steady supply and predictable chemical behavior count for as much as the listed grade—every failed run wastes precious time and resources.

    Built on direct conversations and post-delivery support, our product stewardship program means customers speak with the same personnel who physically handled their batch. This matters when troubleshooting rare performance issues or verifying compliance with industry regulations. Real answers replace jargon because our staff has handled the product from start to final pack, not read it off a datasheet.

    Environmental, Health, and Safety Commitments: Not Optional Add-ons

    Handling reactive halides like Tungsten(VI) Chloride carries real safety and environmental risks, so our production line incorporates both traditional safeguards and modern monitoring. During synthesis, operators use closed lines, local ventilation, and real-time atmosphere sensors calibrated to the product’s specific hazards. In training sessions, our older operators share hard-earned lessons about avoiding release points and recognizing subtle signs of leaks or unplanned reaction. Stop-work authority sits with every team member, and incident reviews become another tool for operational improvement rather than mere paperwork.

    Disposal and waste minimization remain key points of attention. By recovering and purifying side streams of tungsten and chlorine byproducts, we reduce both landfill impact and inbound raw requirements. Customers increasingly look for proof of closed-cycle management, especially those supplying sectors governed by green procurement standards. Transparent reporting on emissions and effluents reassures industrial partners; regular external audits keep us accountable and tuned to changing community standards.

    Health and safety protocols don't just check regulatory boxes—they protect the people keeping our process running. We've seen the difference from inside: regular drills, sharp emergency response, and a company culture that values clarity over shortcuts. No one learns from a spreadsheet alone; practical walkthroughs, hands-on training, and active participation in incident reviews shape a safer, more resilient shop.

    Looking Ahead: Responding to a Changing Market

    Future demand for Tungsten(VI) Chloride will only increase as manufacturing processes move toward more energy-efficient electronics, new catalytic routes, and advanced manufacturing that needs predictable, high-performance metal halides. Our outlook relies on strengthening what has worked—investing in staff and equipment, preserving institutional memory, and staying directly connected to changes in regulation and technology. This hands-on approach came from years of adapting to shifting industry priorities, new environmental standards, and the hard realities of global logistics.

    Manufacturing excellence does not rest on isolated innovation. It builds on every powder, every drum filled and tracked, every email cleared up between our team and the customer’s bench. Our Tungsten(VI) Chloride stands apart because every improvement, every problem solved, and every lesson learned comes from years of direct, on-the-ground production experience. As regulations shift and industries innovate, we stay focused on the fundamentals, delivering stable, reliable material that meets the highest standards—and adjusting as those standards rise. The work will not end, but neither does our commitment.