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Tris(4-Nitrophenyl)Amine

    • Product Name Tris(4-Nitrophenyl)Amine
    • Alias TPA-NO2
    • Einecs 212-763-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    887115

    Chemical Name Tris(4-Nitrophenyl)Amine
    Cas Number 37634-87-8
    Molecular Formula C18H12N4O6
    Molecular Weight 380.31
    Appearance Yellow solid
    Melting Point 201-203 °C
    Boiling Point Decomposes before boiling
    Solubility Slightly soluble in organic solvents
    Density 1.47 g/cm3 (estimated)
    Purity Typically ≥98%
    Smiles C1=CC(=CC=C1N(NC2=CC=C(C=C2)[N+](=O)[O-])C3=CC=C(C=C3)[N+](=O)[O-])[N+](=O)[O-]
    Inchi InChI=1S/C18H12N4O6/c23-21(24)13-1-7-16(8-2-13)20(17-9-3-14(4-10-17)22(25)26)18-11-5-15(6-12-18)19(27)28/h1-12H
    Storage Conditions Store at room temperature, away from light and moisture

    As an accredited Tris(4-Nitrophenyl)Amine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 5-gram Tris(4-Nitrophenyl)Amine comes in a sealed amber glass bottle with a white screw cap, labeled for laboratory use.
    Shipping Tris(4-Nitrophenyl)Amine is shipped in tightly sealed containers, protected from light, moisture, and heat. The packaging complies with chemical transport regulations to prevent leaks or contamination. During shipping, it is labeled as a hazardous material and handled with care to ensure the safety of personnel and the integrity of the product.
    Storage Tris(4-Nitrophenyl)Amine should be stored in a tightly sealed container, protected from light, moisture, and air. Keep it in a cool, dry, well-ventilated area, ideally at room temperature. Avoid storing near strong acids, bases, or oxidizing agents. Ensure clear labeling and limit access to trained personnel. Follow all relevant safety and regulatory guidelines for chemical storage.
    Application of Tris(4-Nitrophenyl)Amine

    Applications of Tris(4-Nitrophenyl)Amine in Industrial Manufacturing

    Tris(4-Nitrophenyl)Amine is an advanced specialty chemical used as a key intermediate, functional additive, and building block in niche, value-added downstream sectors. We support large-scale, consistent manufacturing supply for global OEMs requiring high-purity input in optimized formulations. Below, we outline the primary industrial applications validated by customer usage and market data.

    1. Organic Electronic Materials: Hole Transport Layer in OLED Displays

    Display manufacturers deploy this amine derivative as a high-performance hole transport material for multi-layer organic light-emitting diode (OLED) assemblies. Its electron-rich core, nitro group configuration, and thermal stability enable precise tuning for energy level alignment and improved layer interface contact. Producers integrate the material directly into solution-processable or vapor deposition stacks for both small molecule and polymer OLED fabrication lines.

    Industry compliance standards

    • IEC 62341 (OLED panel safety and performance requirements)
    • RoHS Directive (2011/65/EU) hazardous substances restrictions
    • REACH Registration (EC 1907/2006) raw material conformity
    • Display device manufacturers' internal quality control protocols

    Typical usage ratio

    • 1.5–3.0% by weight in hole transport mixture; precise percentage adjusted per device stack design, film thickness, and desired current density

    Downstream process integration

    • Dissolved in organic solvent, deposited as thin film by spin-coating, inkjet printing, or thermal evaporation at designated stage in OLED stack assembly

    Final product types

    • High-resolution OLED TV panels
    • Flexible smartphone displays
    • Wearable AMOLED screens
    • Automotive digital dashboards

    2. Synthesis of Electron Transport Compounds in Organic Photovoltaics

    The nitrophenyl-substituted triamine structure serves as a key intermediate for industrial organic photovoltaic (OPV) material synthesis. Formulators utilize it as a precursor in multi-step reactions for manufacturing custom small-molecule or polymeric electron transport layers, which enhance charge mobility and device efficiency. The precision reactivity of the nitro groups supports functionalization routes required by leading OPV integrators.

    Industry compliance standards

    • IEC 61215 (Crystalline silicon terrestrial PV modules – Design qualification and type approval)
    • ISO 9001:2015 (Quality Management for specialty synthesis)
    • REACH/TSCA inventory compliance for electronic-grade intermediates

    Typical usage ratio

    • Acts as a step-wise precursor, used stoichiometrically in 1:1 to 1:3 molar ratios depending on the synthetic pathway and final ETL compound design

    Downstream process integration

    • Introduced during electron transport compound synthesis via nucleophilic or electrophilic aromatic substitution, with subsequent purification for device integration

    Final product types

    • Large-area organic solar cell modules
    • Lightweight flexible PV films
    • Building-integrated photovoltaic panels

    3. Advanced Dye and Pigment Manufacturing for Specialty Printing

    Industrial dye producers employ this compound as a core structure in high-performance, nitro-functionalized azo and triarylamine dye synthesis for inkjet and security printing applications. It provides a stable aromatic backbone that delivers high chroma, improved resistance to fading, and compatibility with microdispersion ink systems. This functionality is critical for anti-counterfeiting inks and specialty graphic formulations where custom molecular tuning is required.

    Industry compliance standards

    • ISO 2846-1 (Color and transparency standards for printing inks)
    • EN 71-3 (Toy Safety: migration of certain elements, for ink safety in relevant markets)
    • REACH Annex XVII (Limitation of hazardous substances such as arylamines in dyes)

    Typical usage ratio

    • 5–15% by weight of dye precursor mixture; loading adjusted to optimize color strength, solubility, and dispersion stability

    Downstream process integration

    • Utilized in the condensation or coupling reaction stage of azo or triarylamine dye synthesis, followed by pigment purification, milling, and formulation into ink systems

    Final product types

    • Security printing inks for currency and documents
    • UV-cured digital inkjet printing inks
    • Specialty colorants for plastics-brand protection applications

    4. Precursor for Redox-Active Components in Energy Storage Devices

    Producers of next-generation organic batteries and flow batteries leverage this trinitroaniline compound as a key intermediate for synthesizing electron-donating molecules designed for redox flow systems and organic electrode materials. The aromatic backbone supports modifications yielding tunable voltage profiles and enhanced cycle stability, essential for advanced large-scale energy storage integrators.

    Industry compliance standards

    • IEC 62932-2 (Flow battery safety and performance standards)
    • IEEE 1679.5 (Guide for the Characterization and Evaluation of Sodium-based Batteries)
    • ISO 14001 (Environmental Management for chemical supply chain)

    Typical usage ratio

    • 0.8–2.5% by weight as precursor in conductive polymer or small molecule synthesis, tailored to redox potential and solubility requirements for electrode formulation

    Downstream process integration

    • Introduced at the initial organic synthesis stage for active material, followed by formulation into battery electrodes or electrolyte blends and processed via coating or infusion into cell stack

    Final product types

    • Organic redox flow battery electrolyte solutions
    • Organic radical polymer electrodes
    • Grid-scale stationary energy storage modules

    5. Building Block in High-Temperature Epoxy and Polyimide Resins

    Resin formulators employ this trifunctional aromatic amine in custom syntheses for polymers that require elevated glass transition temperatures and enhanced rigidity. Its well-defined reactivity enables precise crosslinking during polyimide or specialty epoxy resin manufacturing, especially for electrical insulation and aerospace composite prepreg systems where stable nitrophenyl functionality is required under demanding processing environments.

    Industry compliance standards

    • ASTM D5213 (Polyimide resin for electrical insulation)
    • UL 94 (Flammability standards for resin systems)
    • Federal Aviation Regulation 25.853 (Aerospace material flammability)

    Typical usage ratio

    • 2–6% by weight in total resin or hardener/crosslinker phase; percentage determined by Tg target, modulus requirements, and degree of cure

    Downstream process integration

    • Charged during the resin pre-polymerization stage, reacted at controlled temperature and atmosphere, then compounded as part of final resin matrix or composite prepreg system

    Final product types

    • High-performance aerospace composite laminates
    • Insulating varnishes for electrical rotors
    • Printed circuit board base materials (polyimide PI and epoxy laminates)
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    Certification & Compliance
    More Introduction

    Tris(4-Nitrophenyl)Amine: Reliable Performance from a Manufacturer’s Perspective

    Consistent Quality Built on Practical Experience

    Every kilogram of Tris(4-nitrophenyl)amine we produce represents years of hands-on laboratory work and a constant drive to deliver dependable batch-to-batch quality. Our process grew from bench testing and customer partnerships, as research labs and industrial users shared their frustrations about inconsistent materials from resellers. We’ve learned the crucial markers to control—impurity thresholds, moisture content, particle size—because researchers face setbacks when these vary. Our production team tracks every stage, from anisole-based nitration onward, verifying identity and purity at multiple points. When we talk about reliability, we mean it in concrete terms: a melting point that holds within spec, color that doesn’t shift unexpectedly, and the absence of extraneous byproducts that might compromise sensitive synthesis work. Chemists should not have to second-guess material origins or batch history. Through internal QA checkpoints, our focus lands on delivering a product that supports confident formulation, not drawing attention to itself through failed tests or inconsistent results.

    What Matters in Tris(4-Nitrophenyl)Amine Manufacturing

    From the start, we learned that end-users need clarity above all. In academic research, a novel organic semiconductor or charge-transport material often relies on this precise amine. Customers told us early on how a minor deviation in residue or a misreported melting point undermined weeks of progress. We addressed that by expanding analytical verification—routinely running HPLC, NMR, and mass spectrometry—on both raw inputs and final lots. No shortcuts or pooled lots from unknown origins cross our lines; we maintain dedicated vessels and cleaning protocols. The product emerges as a pale yellow solid with deliberately monitored purity above 99%. Researchers select it for synthesis of custom push-pull dye molecules, high-voltage electronic switches, redox mediators, and a host of custom ligands where nitrophenyl substitution patterns control reactivity and electron flow. We measure not only what’s present, but what must not be: residual acid, trace metals, unreacted aniline.

    Our technicians rely on real-world feedback. A complaint about slow dissolution led us to modify drying conditions, helping customers speed up their own process. Large-scale electronic device makers need kilogram lots without batch-to-batch surprises; our approach guarantees that calculated yields and performance values remain steady, even in long development cycles or manufacturing runs. Customers notice the difference when sellers without manufacturing oversight cut corners—adulterants sneak in, spectra don’t match, or poor handling spoils reactivity. We built internal systems for double-sealing, desiccant inclusion, and tamper-indicating packaging to prevent these recurring issues. Lab and production staff review documentation with every shipment, so the chain of custody remains clear. We commit to keeping chain-of-evidence intact, because one ignored error in a batch can derail a larger project or delay patent submissions.

    Specifications Backed by Transparency

    Our Tris(4-nitrophenyl)amine holds the CAS number 2457-80-9, with a molecular formula of C18H12N4O6 and a molecular weight of 380.31 g/mol. During manufacture, particle size distribution is not only monitored but also tailored for direct application in both solution-based and solid-state processes. The melting point consistently falls in the 217–220°C range. We avoid blended or reprocessed material. Final batch certificates detail each analytical finding alongside individual batch history, because our clients routinely cite traceability as an essential part of any purchase decision. We trace origins of all key raw materials, never substituting to cut costs when purities or regulatory status matter.

    Technicians who scale processes from milligram flasks all the way to bulk reactors bring a craftsman’s mentality. Packing this amine for air shipment presents a real-world challenge—any trace of moisture alters its shelf life or complicates mass transfer. We use layered containment and run Karl Fischer titrations by default to check for water content. Spectral fingerprinting (NMR, FTIR) guarantees molecular identity before and after shipping. In our experience, researchers focusing on optoelectronic applications appreciate tight controls on nitro group orientation and amine purity, as these factors determine charge transport and light emission efficiency. A lab technician commented, “It feels like this batch came right out of my own lab.” We take that as affirmation the process works.

    Field Applications—Connecting Lab and Industry

    Few specialty chemicals travel as far from basic synthesis to direct application as Tris(4-nitrophenyl)amine. In organic electronics, experimental OLED and sensor manufacturers count on the consistent energy levels this compound supports. One university group published a breakthrough on donor-acceptor frameworks, acknowledging that performance drifted with other suppliers’ inconsistent batches. Our material, in contrast, enabled them to reproduce published device efficiency—even years after initial trials—because we respected the underlying synthetic needs. Device manufacturers testing new blends in small-run displays or redox catalysis depend on this reproducibility to iterate designs and scale prototypes.

    Polymers, dye intermediates, and photochemical switches also draw on the electron-donating profile of this amine core. A dye chemist described running high-pressure couplings and seeing batchwise stability improve only after switching to our amine. Customers in surface functionalization specify this material when building highly conjugated organic networks for photonic materials, citing the clean profile and minimized background absorbance. This illustrates why chemical manufacturers, not traders, must maintain full process transparency: minute changes in byproducts or contaminants alter device function, absorbance, or mechanical properties in ways difficult to detect until final products fail. With our approach, research leads confidently submit new findings and patent filings, reducing unplanned delays and data variability.

    Comparing Our Product to Alternatives

    We’ve examined samples from so-called premium inventories—sources promising high assay values, but who lack a real-time link to analytical or process history. A head-to-head NMR or FTIR assessment tells the story quickly: lines broaden, unknown impurities arise, or moisture enters undercutting the shelf-stability critical for demanding synthesis. With many resellers, the origin is unclear; batches may have come through many intermediaries or had prior exposure to improper storage. Analytical data sheets rarely provide the granularity needed to confirm lot traceability. We often see non-uniform color or the faint presence of nitro-aniline byproducts, evidence of undeclared or mixed-materials. This is not a minor difference—the resulting downstream reactions stall, yields sink, or new catalysts fail to meet literature expectations.

    We began direct delivery after seeing researchers invest in excess purification steps just to overcome low-purity starting points. Our regular users report cutting hours off their workflow and reducing wasted reagents once they switched to our material. Notably, the customer support line fields fewer complaints regarding reactivity hang-ups or unexplained TLC bands than when resellers formed the bulk of the market. As a direct producer, we stand behind the composition—and remain open to custom specifications for those with more rigorous needs than regular catalog options permit.

    Key Uses Driven by Practical Feedback

    No single use defines this compound. In synthesis for organic electronics and semiconductors, the electron-donating and nitro-bearing structure confers unique reactivity, making it invaluable in developing new photoactive materials and charge carriers. In cross-coupling reactions, polymerizations, or advanced organic frameworks, chemists cite predictable yield and purity as the difference between wasting resources and progressing. Specialty pigment makers and sensors research teams benefit from low-variability batches that shorten troubleshooting times when scaling from bench to pilot.

    Our own partnerships with battery researchers brought forward specific purity demands—trace metals needed explicit tracking, so we built ICP-AES testing into our workflow. In dye-sensitized applications, slight changes in molecular profile shift the response spectrum. By working directly with end-users during scale-up runs, we observed that minor variations in handling after synthesis could induce unwanted crystallization or introduce isomeric impurities. We answered by adjusting cooling profiles, not just standardizing but optimizing them based on post-delivery storage findings from customer labs.

    Handling, Safety, and Direct Manufacturer Insight

    While vendors may reference standard handling protocols, as the manufacturer we incorporate practical experience on safe and efficient handling. Tris(4-nitrophenyl)amine forms airborne dust easily—specialized packaging prevents product loss and air contamination, and we educate our logistics partners on careful transfer. Warehouse teams use custom-designed scoops and anti-static controls to avoid spills, loss, or static discharge. We proactively ship in small-batch containers with clear batch numbering traced back to our enterprise resource system.

    Our team fields frequent questions about shelf life and recommended storage. Years of experience show that vacuum-sealed, low-humidity storage at controlled room temperature extends usability and avoids clumping or caking common to lesser packed products. By maintaining rigorous supplier qualification standards on raw materials, we cut down on variability at the outset. Technicians benefit from direct support—not just a vague datasheet—when transitioning from bench to process scale, and long-running projects rarely see disruption stemming from material inconsistencies.

    Partnering With Real End-Users to Find Solutions

    Our front-line technical staff often works alongside development chemists, especially when troubleshooting purification bottlenecks or reactivity issues not captured in the literature. Feedback loops run both ways: a complaint about slow evaporation in a chromophore build prompted us to re-examine drying mechanisms and packaging material. In more than one case, a novel device functioned as expected only after the user switched away from generic resold amine blends to a high-purity, single-vendor batch. Traceability, direct manufacturing control, and open communication move the product from commodity chemical to precision tool.

    We routinely adapt processes for custom requirements, such as finer particle fractions for thin-film applications, or ultra-low water content for glovebox chemistry. These modifications don’t just follow ISO checklists; they result from real-world problem reports, developmental failures, and customer successes. Transparency in documentation and a willingness to engage at each stage of the project build trust with users inventing the next generation of photoactive or catalytic compounds.

    The Value of Going Direct

    Having full control of the synthetic route gives us flexibility to tighten parameters or adapt to new industry requirements without passing along unanticipated problems. For projects involving regulated intermediates, or nuanced redox behavior, confidence grows when a direct manufacturer can demonstrate every prior step, document tight impurity ranges, and field technical questions about process history. Users cite this openness as pivotal during regulatory filings, grant reports, or patent submissions involving specialty compounds. By continuously iterating with active researchers, we ensure our Tris(4-nitrophenyl)amine not only matches analytical benchmarks but also supports industry innovation, research reproducibility, and upscaled productivity.

    Documented Improvements Rooted in User Collaboration

    In practice, we address not just the analytical parameters, but the holistic experience users encounter. This means covering everything from bottle labeling—large-format barcodes for easy traceability during audits—to reformulating outer packaging after users reported excessive bottle breakage in overseas shipments. Data exchanges between our support staff and customer labs clarify whether a batch fits a unique synthetic pathway, or if specialty documentation aids in regulatory or grant compliance. Problems such as batch settling, unexpected byproduct formation, or recurrent moisture ingress seldom arise when feedback is incorporated directly into every operational step.

    We measure the success of our Tris(4-nitrophenyl)amine not simply in analytical numbers, but by whether users achieve their goals efficiently: turning around successful device trials, publishing in reputable journals, or scaling processes with minimal material waste. Every improvement—be it drying, purity, or documentation clarity—comes about through this direct feedback loop, never as afterthoughts or generic upgrades.

    Trust Built on Track Record and Technical Depth

    Our reputation in manufacturing Tris(4-nitrophenyl)amine developed through more than just technical excellence; it follows from our willingness to engage with complex use cases, respond to time-sensitive problems, and evolve as user needs shift. Technical staff regularly consult with both industrial and university partners, sharing application-specific insights—such as the downstream effects of micro-impurity profiles, light stability, or mechanical blending behavior. New project proposals often begin with a dialog, not just a purchase order, so each unique synthesis or process innovation includes material support matched to its intended use.

    As long as research groups and commercial enterprises continue expanding the fields of organic electronics, advanced catalysis, sensor chemistry, and custom organic synthesis, we remain committed to delivering an amine product defined not solely by purity scores, but by a proven ability to deliver results in demanding real-world conditions. A strong manufacturing backbone, direct engagement, and openness to user feedback distinguish the material and the service supporting it from lesser-known channels or indirect sources.

    Direct Dialogue Shapes Product Evolution

    Each improvement in our production pipeline can be traced back to a collaboration or a frank report from an end-user. We believe chemical manufacture evolves fastest at points of direct connection—chemist to chemist—instead of through layers of distribution or detached reselling. Solutions to complications such as variable dissolution, unexpected contamination, or preparation failures emerge not from abstract best practices, but from relentless adaptation and willingness to revisit every process step. Our Tris(4-nitrophenyl)amine stands as a case study for what direct manufacturing means: a quality profile grounded in technical rigor, guided by transparent communication, and improved through shared problem-solving.