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Tris(4-Bromophenyl)Amine

    • Product Name Tris(4-Bromophenyl)Amine
    • Alias TPA-Br
    • Einecs 251-971-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    781890

    Chemical Name Tris(4-Bromophenyl)Amine
    Molecular Formula C18H12Br3N
    Cas Number 87146-45-0
    Appearance Pale yellow to off-white solid
    Melting Point 245-247°C
    Purity Typically ≥98%
    Solubility Slightly soluble in common organic solvents
    Density 1.98 g/cm³ (estimated)
    Boiling Point Decomposes before boiling
    Storage Conditions Store at room temperature, away from moisture and light

    As an accredited Tris(4-Bromophenyl)Amine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging for 5 grams of Tris(4-Bromophenyl)Amine is a sealed amber glass bottle with a secure screw cap and hazard labeling.
    Shipping **Shipping Description for Tris(4-Bromophenyl)Amine:** Tris(4-Bromophenyl)Amine is typically packaged in tightly sealed containers to prevent moisture and contamination. It should be shipped at ambient temperature as a non-hazardous solid, clearly labeled, and in compliance with local regulations. Handle with appropriate personal protective equipment (PPE) and avoid exposure to heat, sparks, or open flame.
    Storage Tris(4-Bromophenyl)Amine should be stored in a tightly sealed container under a dry, inert atmosphere, such as nitrogen or argon, to prevent moisture and air exposure. Keep it in a cool, well-ventilated area away from direct sunlight, heat sources, and incompatible materials like strong oxidizers. Properly label the container and follow all relevant safety and handling protocols.
    Application of Tris(4-Bromophenyl)Amine

    Applications of Tris(4-Bromophenyl)Amine in Industrial Manufacturing

    As a direct manufacturer of Tris(4-Bromophenyl)Amine, we closely support key industrial segments that demand high purity intermediates for advanced material and electronics applications. Our production aligns with the precise specification and compliance requirements of downstream industries, ensuring material consistency for reliable integration into end product manufacturing. Below we outline the principal application fields for this compound, segmented by function, regulatory adherence, blending recommendations, process stage, and resulting final goods.

    1. Organic Light-Emitting Diode (OLED) Materials

    Display panel manufacturers use this amine derivative as a core hole-transport and emissive layer additive in the fabrication of OLED devices. Its superior charge-transport characteristics and film-forming ability allow device engineers to optimize luminance and operational lifetime in both rigid and flexible display assemblies. Tris(4-Bromophenyl)Amine is dissolved or co-evaporated with other monomers and dopants directly onto the ITO substrate during device stack construction.

    Industry compliance standards

    • IEC 62341 (OLED Panel Performance Requirements)
    • RoHS Directive 2011/65/EU (Hazardous Substance Restriction)
    • ISO 9001:2015 (Quality Management for Electronic Materials)
    • REACH Regulation (EC) No 1907/2006 (Substance Registration)

    Typical usage ratio

    • 2–8% by weight in hole transport layers, tuned according to targeted voltage and color coordinates

    Downstream process integration

    • Introduced by vacuum deposition (co-evaporation) or solution spin-coating at the organic materials deposition step, prior to cathode sealing

    Final product types

    • AMOLED smartphone and television panels
    • Flexible OLED lighting sheets
    • Wearable electronics displays
    • Automotive dashboard screens

    2. Organic Photovoltaic (OPV) Active Layer Additive

    In solar cell R&D and pilot manufacturing, this compound functions as an electron donor component in the bulk heterojunction structure of new-generation OPV devices. Its aromatic amine skeleton enables efficient charge separation and transport, improving device efficiency and energy conversion rates through molecular-level compatibility with non-fullerene acceptors. Downstream users value its controlled reactivity profile during solution processing at ambient temperatures.

    Industry compliance standards

    • IEC 61215 (Photovoltaic Module Testing)
    • UL 1703 (Safety Standards for Flat-Plate Photovoltaics)
    • ISO 14001:2015 (Environmental Management for Solar Materials)
    • Restriction of PBT/vPvB substances (REACH Annex XIII)

    Typical usage ratio

    • 5–12% by mass in donor:acceptor blends, selected for target photon absorption profiles and film morphology

    Downstream process integration

    • Blended with solvent and co-monomers in the ink formulation prior to blade-coating or roll-to-roll slot-die application during active layer formation

    Final product types

    • Flexible organic photovoltaic modules
    • BIPV (Building-Integrated Photovoltaics) laminates
    • Compact portable energy harvesters

    3. Hole Transport Layer Modifier in Perovskite Solar Cells

    Cell fabricators use Tris(4-Bromophenyl)Amine as a high-performance additive in the hole transport layer for perovskite solar cells, aiming to increase charge mobility and operational stability. Its molecular design allows for enhanced interfacial contact, minimizing recombination and maximizing device performance in commercial module assemblies. Stable supply is crucial for scaling from cell prototyping to GWh-scale manufacturing lines.

    Industry compliance standards

    • IEC 61215 and IEC 61730 (Photovoltaic Module Performance and Safety)
    • CQC Mark (China Quality Certification for PV Components)
    • RoHS 2015/863/EU Annex II
    • ISO 14001:2015

    Typical usage ratio

    • 1.5–3% by weight in spiro-OMeTAD or alternative hole-transport matrices, adjusted for layer conductivity and film clarity

    Downstream process integration

    • Dispersed in chlorobenzene solution with dopants and spin-coated directly after perovskite layer deposition, prior to electrode assembly

    Final product types

    • Perovskite solar cell mini-modules
    • High-efficiency perovskite tandem modules

    4. Advanced Polymeric Semiconductor Synthesis

    Materials science innovation teams employ Tris(4-Bromophenyl)Amine as a functional monomer during the synthesis of semiconducting and electroactive polymers. Its brominated structure provides versatile cross-linking sites, supporting scalable chain growth in Suzuki or Buchwald–Hartwig coupling reactions. This application is essential for manufacturing next-generation polymers for transistor arrays and advanced memory embedded devices.

    Industry compliance standards

    • RoHS Directive 2011/65/EU
    • ISO/TS 80004 (Nanotechnology Polymer Materials)
    • REACH Pre-registration
    • Internal QC under IATF 16949 for automotive-grade electronics

    Typical usage ratio

    • 10–30 mol% in co-polymerization feed, set by target molecular weight, material glass transition, and electronic performance criteria

    Downstream process integration

    • Reacted via step-growth or chain-growth polymerization in bulk or solvent media with controlled temperature and catalyst conditions, yielding functionalized high molecular weight intermediates

    Final product types

    • Organic field-effect transistor (OFET) substrates
    • Flexible sensor circuit boards
    • Low-voltage memory elements

    5. Specialty Photoresist Intermediate for Lithography

    Wafer fabrication plants rely on Tris(4-Bromophenyl)Amine as a specialty intermediate for synthesizing custom photoresist precursors, required for high-resolution photolithography. The material’s photo-oxidative response and molecular stability influence resist sensitivity and patterning precision in the sub-10-nm node device etching. Sourcing from a direct producer secures reliable batch consistency and traceability necessary for yield optimization.

    Industry compliance standards

    • SEMI C39 (Photoresist Material Quality Standards)
    • ISO 14644-1 (Cleanroom Particle Control for Device Fabrication)
    • IATF 16949:2016 (Automotive Integrated Circuit Manufacturing)
    • REACH Annex XVII (Restriction on Hazardous Substances in Lithography Chemicals)

    Typical usage ratio

    • 4–15% by mass in photoresist precursor formulation, set by desired photosensitivity and molecular weight control

    Downstream process integration

    • Introduced at the photoresist resin synthesis stage by solution polymerization, followed by blending with diazonaphthoquinone sulfonate systems for spin-coating onto silicon wafers

    Final product types

    • Advanced positive/negative photoresists for VLSI and ULSI semiconductor devices
    • Micro-patterned IC wafers (logic, memory, MEMS)
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