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Tris(2-Aminoethyl)Amine

    • Product Name Tris(2-Aminoethyl)Amine
    • Alias TREN
    • Einecs 203-928-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    521532

    Chemical Name Tris(2-Aminoethyl)Amine
    Synonyms TREN, Trien, Tris(2-aminoethyl)amine
    Cas Number 4097-89-6
    Molecular Formula C6H18N4
    Molecular Weight 146.24 g/mol
    Appearance Colorless to pale yellow liquid
    Density 0.985 g/mL at 25°C
    Boiling Point 285 °C
    Melting Point -39 °C
    Solubility In Water Very soluble
    Ph 1 Solution 12 (alkaline)
    Vapor Pressure 0.000369 mmHg at 25°C
    Flash Point 157 °C (closed cup)
    Refractive Index 1.525 at 20°C
    Smiles NCCN(CCN)CCN

    As an accredited Tris(2-Aminoethyl)Amine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 500 mL amber glass bottle with a secure screw cap, labeled "Tris(2-Aminoethyl)Amine, analytical grade, 500 mL."
    Shipping Tris(2-Aminoethyl)Amine should be shipped in tightly sealed containers made of compatible materials, protected from moisture and extreme temperatures. It is classified as a corrosive substance; therefore, proper labeling and packaging according to local and international regulations (e.g., DOT, IATA, IMDG) are required. Handle with gloves and eye protection.
    Storage Tris(2-Aminoethyl)Amine should be stored in a cool, dry, well-ventilated area, tightly sealed in its original container. Keep it away from incompatible substances such as acids, oxidizing agents, and strong bases. Protect from moisture and direct sunlight. Clearly label the container and store at room temperature to prevent degradation. Follow all relevant safety regulations and chemical hygiene protocols.
    Application of Tris(2-Aminoethyl)Amine

    Applications of Tris(2-Aminoethyl)Amine in Industrial Manufacturing

    Tris(2-Aminoethyl)Amine (TREN), with its strong chelating ability and multi-functional amine structure, is a key raw material in advanced industrial processes. As a direct manufacturer, we support industrial partners globally with traceable production batches, technical data, and consistent supply tailored for process-critical integration. Below we present focused scenarios illustrating where TREN enters core manufacturing chains and how professional formulators deploy it to achieve quality and performance objectives under regulated frameworks.

    1. Epoxy Curing Agents for High-Performance Composites

    TREN functions as a curing agent and crosslinker in the formulation of advanced epoxy systems for wind turbine blades, aerospace laminates, and marine applications. Its low molecular weight and high amine functionality enable thorough network formation during thermoset processing to achieve high glass transition temperatures, chemical resistance, and structural strength, demanded by composite manufacturers for critical components subjected to fatigue and weathering.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • EN 13938-2: Determination of gel time for epoxy resin systems
    • ASTM D1652: Epoxy Resin Application Procedures
    • REACH Regulation (EC 1907/2006)

    Typical usage ratio

    • 8–18 parts by weight per 100 parts epoxy resin, adjusted for required crosslink density and work life; precise ratio set according to resin type and target mechanical properties.

    Downstream process integration

    • Added directly into epoxy resin mix during compounding; thorough mixing and degassing precede lay-up, casting, or filament winding. Cure parameters and ratio selection verified by in-plant thermal cycle testing and viscosity monitoring for process repeatability.

    Final product types

    • Aerospace structural laminates
    • Wind turbine rotor blades
    • Marine hull and deck assemblies
    • Electrical encapsulants and insulators

    2. Chelating and Sequestering Agents in Industrial Water Treatment

    TREN serves as an effective tertiary amine chelating agent in industrial water treatment plants, targeting removal and stabilization of heavy metals such as copper, zinc, and nickel. Power stations, chemical refineries, and textile dyeing facilities rely on TREN-based formulations to maintain clean effluent and protect critical equipment from scale, fouling, and regulatory violations, where stable complex formation ensures downstream water meets discharge limits on trace metals.

    Industry compliance standards

    • ISO 14001:2015 Environmental Management Systems
    • US EPA Clean Water Act (40 CFR Part 401, 423)
    • EN ISO 15586: Water Quality—Determination of Trace Metals
    • China GB 8978-1996: Integrated Wastewater Discharge Standard

    Typical usage ratio

    • 0.02–0.10% by volume in circulation or batch systems, with the exact ratio set by inlet heavy metal concentration, pH, and residence time; dosing controlled by inline ion-specific electrode probes.

    Downstream process integration

    • Metered into recirculation lines before sedimentation, flotation, or filtration units; field operators adjust dosing based on real-time trace metal analysis. Compatibility with other treatment agents confirmed to avoid downstream precipitation or re-release phenomena.

    Final product types

    • Industrial process water for reuse
    • Discharged wastewater meeting targeted heavy metal limits
    • Demineralized water for boiler and cooling towers
    • Remediated groundwater for site restoration

    3. Polyamide and Polyurea Catalyst in Coatings Formulation

    In commercial anticorrosion and protective coatings, TREN acts as a highly reactive amine catalyst and chain extender, accelerating polyamide and polyurea polymerization during ambient or forced-cure processes. It allows paint and coating manufacturers to tune pot life, film formation speed, and final hardness to meet end-user requirements for pipeline, storage tank, and marine structure coatings, especially where rapid overcoating and hardness development are prioritized for project throughput.

    Industry compliance standards

    • ISO 12944: Paints and Varnishes—Corrosion Protection of Steel Structures
    • ASTM D823: Practice for Producing Films of Uniform Thickness
    • China GB/T 25251: Polyurea Waterproof Coating Standard
    • REACH SVHC compliance for supplied amine ingredients

    Typical usage ratio

    • 0.5–3.5% by total binder weight for ambient-cured polyamide coatings; increased up to 6% in rapid-setting polyurea spray systems, adjusted by ambient temperature and desired gel time.

    Downstream process integration

    • Introduced during resin pre-mix stage in blending tanks, with close monitoring of batch temperature and resin viscosity. End-use film performance validated via accelerated corrosion and adhesion tests on coated panels.

    Final product types

    • Pipelining and tank lining coatings
    • Industrial floor coatings
    • Waterproofing membrane coatings
    • Protective marine paints

    4. Cationic Surfactant Synthesis for Oilfield and Mining

    TREN forms the backbone of cationic surfactant manufacture, where it undergoes quaternization to deliver strong wetting, emulsifying, and clay inhibition properties in oil and gas drilling fluids, as well as mineral processing aids. The chemical’s reactivity supports tailored surfactant production for field-specific requirements, including well stimulation, emulsion stabilization, and tailings management, giving operators greater control over extraction efficiency and site compliance targets.

    Industry compliance standards

    • API RP 13B-1: Recommended Practice for Field Testing of Drilling Fluids
    • OECD 301B: Ready Biodegradability (Surfactants for Oilfield Use)
    • SAE-J161-02: Additives for Mining Industry
    • EU CLP Regulation (EC) No 1272/2008 for hazard classification

    Typical usage ratio

    • 0.5–2.0% active surfactant (typically supplied as a 40–60% solution) based on base mud or aqueous phase; adjusted according to drilling fluid rheology and field-specific downhole conditions.

    Downstream process integration

    • Produced by quaternizing TREN with alkylating agents in closed reactors, followed by downstream blending with other additives. Drilling fluid engineers inject the finished surfactant concentrate in dosed increments during active drilling, monitored for mud stability and formation interaction.

    Final product types

    • Clay inhibitors for water-based drilling fluids
    • Demulsifiers and emulsion breakers
    • Flocculants and floating aids in ore beneficiation
    • Tailings dewatering agents

    5. Metal Ion Scavenger in Electroplating Bath Maintenance

    TREN is implemented in the electroplating industry as an efficient scavenger for rogue metal ions, extending plating bath operational life and minimizing rejection rates on plated workpieces. Direct plant use involves periodic or continuous dosing in nickel, copper, and precious metal lines to control metallic contaminants and improve deposit uniformity, key for electronics, automotive, and decorative plating operations where thin film properties and visual appearance demand stringent quality assurance.

    Industry compliance standards

    • ISO 4527:2003—Nickel Plating for Industrial Use
    • RoHS Directive 2011/65/EU (Restriction of Hazardous Substances)
    • ASTM B567: Thickness of Metallic Coatings by X-Ray Spectrometry
    • China GB/T 10125: Salt Spray Testing of Plated Metal

    Typical usage ratio

    • 0.01–0.05% relative to total bath volume; dose set by inline spectral analysis or periodic wet chemical titrations, with adjustment based on plating throughput and metal loading profiles.

    Downstream process integration

    • Dosed directly into recirculated plating @ bath holding tanks under agitation; system engineers monitor the impact via deposit test panels and by real-time conductivity measurements to prevent interference with intentional metal deposition rates.

    Final product types

    • Connector and circuit board coatings
    • Automotive trim and hardware
    • Jewelry and wear-resistant metal finishes
    • Equipment and enclosure corrosion protection coatings

    6. Intermediary for Potting and Encapsulation Resin Production

    TREN is utilized in the synthesis of high-grade potting and encapsulation resins, especially those requiring rigid chemical structures and low outgassing for electrical and electronics protection. Its highly reactive primary and secondary amine sites support the creation of tough, impact-resistant polymer networks for applications where dimensional stability and long-term mechanical strength are essential under dynamic loading or temperature variation.

    Industry compliance standards

    • UL 94: Flammability Testing of Plastic Materials
    • IEC 60695-2-10: Glowing/hot-wire based test methods
    • IPC-CC-830: Qualification and Performance of Electrical Insulating Compounds
    • China GB/T 19212: Safety Requirements for Electrical Insulating Materials

    Typical usage ratio

    • 12–30 phr (parts per hundred resin) as dedicated crosslinker in epoxy/amine or polyurethane potting systems; chosen based on filler content and dielectric requirements.

    Downstream process integration

    • Incorporated in the pre-polymer or hardener blend, using controlled temperature reactors with vacuum degassing. Producers qualify resultant resins for low shrinkage, electrical insulation, and flame retardancy per equipment supplier protocols.

    Final product types

    • LED module encapsulants
    • Transformer and coil potting compounds
    • Printed circuit board protective resins
    • Sensor and cable sealing gels
    Free Quote

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    Certification & Compliance
    More Introduction

    Our Perspective on Tris(2-Aminoethyl)Amine: Reliable Chemistry, Practical Results

    Building Experience Into Every Batch

    Producing Tris(2-Aminoethyl)Amine, which many in the business call TREN, has taught our team a few things about consistency, handling, and honest feedback. Over the years, our facility has moved from small reactors to larger, more robust systems. Every time we scale up, we find new quirks in the process—whether it’s fine-tuning reaction conditions or managing the purity challenges inherent in amine chemistry. Our engineers and operators have come to recognize the subtle signs of a good batch: clarity, sharp ammonia odor, and reliable analysis numbers that match our experience as much as the equipment.

    Model, Grade, and Batch Quality by Real Experience

    We manufacture what the market refers to as TREN, C6H18N4. The product leaves our lines as a clear, pale yellow liquid. Measuring by assay, our typical batches return 98-99% purity, which meets the requirements for epoxy curing, chelation, and resin crosslinking. Side components sometimes creep in—related polyamines and minor color bodies—but over time, we’ve learned to watch for these, adapt the distillation, and turn out the consistent quality that industrial users can rely on.

    Standard packaging is chosen for practicality, not just compliance. We offer steel drums lined for amine resistance or IBCs depending on application volumes, with each shipment tested for water content, color, and purity. Packing lines are set up to minimize headspace and water ingress, which protects both the product and customer downstream processes.

    Hands-On Use From Day One

    TREN finds its way onto the plant floor wherever strong, branched amines are needed. Years ago, our clients in resin manufacturing struggled with inconsistent curing when using linear ethyleneamines. Our teams worked together, ran small batches, and saw firsthand how the branching in TREN allowed for more crosslinking points compared to diethylenetriamine (DETA) or even triethylenetetramine (TETA). A modest increase in crosslink density improved hardness, sped up cure times, and changed how coatings held up to abrasion and moisture. The hardware can be adapted to run thinner films on rollers or thicker masses in potting compounds without a major overhaul.

    Another strong use case comes from the water treatment sector. Over the past decade, scale prevention and heavy metal capture have required amines with defined structures. TREN’s tri-branched skeleton and four nitrogens offer multiple binding sites, which leads to a more efficient capture-molecule than monoamines or linear versions. Our technical staff has run trials with local clients, helping them move from EDTA or DETA blends to more selective capture, lowering the required dose and simplifying downstream regeneration. Real data comes from gallons pumped, not just calculated binding constants on paper.

    From Our Operations to Your Production

    There’s no guesswork in storage and handling recommendations. TREN absorbs water and carbon dioxide from the air. Decades of refilling drums in humid coastal regions have shown us the importance of keeping seals tight and using nitrogen blankets where ambient humidity runs high. End users have saved hours—sometimes days—of rework just by switching to lined containers we recommend and using desiccant packs we provide upon request.

    On the plant floor, operators appreciate that TREN runs through most positive-displacement pumps without significant wear, thanks to its relatively low viscosity and chemical compatibility with standard seals. Spills, on the other hand, always attract attention due to the strong amine odor. We work closely with our customers to improve ventilation and recommend personal protective equipment based on practical experience, not just regulatory minimums. It’s much easier to set up a dedicated amine-handling cell for blending or reacting than to retrofit safety controls after complaints arise.

    Product Differences: Why Structure Matters

    Many ask us, “Why TREN instead of the usual DETA or TETA?” Years back, we ran comparative batches both for our internal development and for several regular clients. Linear polyamines form fairly straight chains, and their crosslinking ability in polymers or chelates is limited by molecular geometry. In contrast, our TREN features three arms radiating from a central nitrogen, making more efficient use of each molecule in building a 3D network.

    This difference shows up in the finished resin: denser curing, higher glass transition, and a firmer feel under mechanical stress. In chelation, customers report increased selectivity when binding specific metals, paving the way for finer separation or easier reclamation steps. Some large users in adhesives and thermosets report changing only the hardener and seeing marked improvements in bond line appearance and durability. When we deliver TREN, we can often cut down overall amine loading by up to 15% compared to using DETA-based curatives, reducing side reactions and minimizing odor issues.

    Customer Communication: Fielding the Hard Questions

    Most customers we’ve worked with over the years appreciate a straight answer about shelf-stability and limitations. TREN, like all aliphatic amines, is prone to yellowing in contact with air and will form carbamates on standing in the open. We encourage storage under dry nitrogen if repeated openings can’t be avoided, and we track all returns and reports of off-spec materials. More than one lab request has led to us retooling a drying line or boosting distillation vacuum, because we see ourselves as part of our customers’ trouble-shooting chain, not just a supplier.

    We rarely hear complaints about purity outside of specific optical, electronics, or pharmaceutical applications. In those cases, we can discuss running a special fractionation or polishing step, but for the bulk of industrial customers, 98-99% is robust, and any minor components are low enough not to interfere with downstream formulations. Keeping analytical data open and providing retained samples on request have built a reputation grounded in accessibility. Our technical directors make it a point to pick up the phone to sort out complaints, and feedback gets logged directly to our line operators.

    Regulatory and Environmental Considerations in Manufacturing

    Operating in the amine manufacturing space for years has given us firsthand insight into both regulatory and environmental issues. Our site has adjusted handling, worker exposure, and waste management policies as the landscape changes. Modern synthesis requires tight air emissions, so we invest in scrubber upgrades and use closed reactor systems to capture off-gassed ammonia and amine vapors. It hasn’t always been this way—older plants vented off chemicals that would now trigger shutdowns. Now, every solvent stream and amine residue gets analyzed and documented before disposal, with most waste fractions reprocessed into secondary chemical streams, lowering our overall environmental load.

    Customers have started asking about the carbon footprint not just of the product, but of our operations. In the last three years, we’ve moved towards both energy efficiency and raw material traceability. A significant portion of our ethyleneamines are sourced from domestic partners to reduce transit miles, and synthetic efficiencies have dropped process energy per ton by roughly 20%. Our engineering team manages these changes not only to meet government mandates but also to answer detailed buyer questionnaires about sourcing and sustainability.

    Improving Downstream Flexibility

    Resin plants, formulators, and blenders who use TREN often look for flexibility in formulation. Our clients in adhesives, particularly those serving the construction market, have found that TREN’s reactivity allows for lower curing temperatures and shorter press cycles, especially compared to linear amine blends. On a typical production line, this translates to faster exports, more shifts per day, and less downtime waiting for the product to set. Increased throughput can mean the difference between meeting tight project deadlines and dealing with project overruns.

    On the formulation side, the strong basicity and unique geometry allow our technical partners to dial in performance—ranging from rapid snap-cures to longer open times by blending with lower reactivity co-curing agents. The difference goes beyond what’s described in technical bulletins. We have worked with customers who refined their formulations so precisely that changes in TREN content as small as a few tenths of a percent created measurable advances in weatherability and cure profile.

    Safety in Use: Beyond the Data Sheet

    Even with all of TREN’s performance benefits, we have always recognized its handling hazards. Amine burns and respiratory irritation are more than just a warning label—these are realities we’ve directly observed on the shop floor when procedures weren’t followed. Our plant’s experience guides field recommendations: always wear gloves and goggles in splash zones, and run proper local exhaust whenever opening containers or pumping.

    We stress close communication with industrial safety officers. Over years of bulk delivery, we’ve refined procedures so transfer lines remain sealed until the final drop, and we offer training sessions to customers who wish to reduce odor emissions or avoid contamination between runs. Even after decades, new employees or visitors sometimes underestimate the volatility and odor of TREN. Our experience proves there’s no substitute for a thorough introduction and hands-on demonstration.

    Collaborative Product Development and Real-World Testing

    One of the most rewarding aspects of operating a TREN manufacturing line is working directly with engineers, formulators, and plant managers from partner companies. Each season brings a new set of challenges: tighter cure windows, new regulatory lists, or boards demanding more sustainable sourcing. We often support pilot studies—sending out custom lots, tweaking purity or color, and listening closely for feedback. Some of our most effective improvements sprang from direct feedback in messy, real-world environments, not lab bench theory.

    One of our recent projects involved moving a client from a solvent-based hardener to nearly solventless TREN-based formulations. Their blending tanks required less cleanout, their operators handled fewer hazardous spills, and the community around the plant noted a measurable drop in ambient odors. It wasn’t a textbook solution; it required persistent tweaking from both sides and the willingness to re-run batches until the parameters worked for both quality control and cost targets. We don’t claim every problem has a silver bullet, but over time, focused, collaborative development leads to better choices for everyone involved.

    Looking Forward: Sustainability, Traceability, and Future Directions

    As the industry shifts towards responsible chemistry, we expect tighter controls and more attention from regulators, end-users, and the public. For TREN, this means maintaining robust purity while searching out alternative feedstocks, minimizing impact at each step, and tracing materials from raw input through finished package. New markets, especially those outside traditional resins and water treatment, are asking about lifecycle analyses and “green” chemistry claims. In our experience, the only credible approach is open communication about current capabilities and realistic pathways for improvement.

    We have begun pilot work on bio-derived amines, but as with all chemical manufacturing, balance must be struck between cost, scalability, and downstream performance. Every new route introduces its own variations in impurity profile and process behavior. To those in the market for TREN or similar polyamines, our advice remains: test real samples, run full-scale trials, and ask for transparency at every step. Over time, iterative improvement, shared lessons, and clear expectations move progress further than flashy but unproven claims.

    Supporting Your Manufacturing Journey

    Clients who visit our facility often remark on the practical mindset of our production and QC staff. From the start, we’ve focused on turning out reliable TREN shipments without pretending that chemical manufacturing is without its complications. Each client brings a new set of requirements, whether that’s tighter color standards, adapted handling, or alternate packaging. Over the years, we’ve built partnerships based on open dialogue, upfront troubleshooting, and thorough documentation. Troubles aren’t something to be hidden—they’re an opportunity for real improvement.

    Our advice to those entering or scaling up in polyamine use: value a supplier as a true partner, not just a box on the procurement list. Reliability comes from a willingness to show the process, prove the results, and take ownership of both successes and failures. We believe that our commitment to safe, sustainable, and transparent production of Tris(2-Aminoethyl)Amine has earned us a foundation of trust with our customers. Together, we are building better and safer products for industries that demand more from every molecule.