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Trichloro(3,3,3-Trifluoropropyl)Silane

    • Product Name Trichloro(3,3,3-Trifluoropropyl)Silane
    • Alias TFPS
    • Einecs 213-026-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    349718

    Cas Number 429-60-7
    Molecular Formula C3H4Cl3F3Si
    Molecular Weight 233.51 g/mol
    Appearance Colorless to pale yellow liquid
    Boiling Point 144-146 °C
    Density 1.386 g/mL at 25 °C
    Refractive Index 1.386 at 20 °C
    Purity Typically ≥97%
    Flash Point 59 °C (closed cup)
    Solubility Decomposes in water; soluble in organic solvents
    Vapor Pressure 9 mmHg at 25 °C
    Smiles C(C(F)(F)F)[Si](Cl)(Cl)Cl

    As an accredited Trichloro(3,3,3-Trifluoropropyl)Silane factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 500g of Trichloro(3,3,3-Trifluoropropyl)Silane, securely sealed in a dark amber glass bottle with a tamper-evident cap.
    Shipping Trichloro(3,3,3-trifluoropropyl)silane should be shipped in tightly sealed, corrosion-resistant containers under dry, inert conditions. As a moisture-sensitive, corrosive, and volatile liquid, it must be properly labeled as hazardous material. Transport should comply with all relevant regulations for dangerous goods, avoiding exposure to heat, flame, or humidity during transit.
    Storage Trichloro(3,3,3-trifluoropropyl)silane should be stored in a cool, dry, well-ventilated area, away from moisture, heat, and sources of ignition. Keep container tightly closed and store under an inert atmosphere, such as nitrogen or argon. Avoid exposure to air and water, as it reacts with moisture to release corrosive hydrogen chloride gas. Use compatible, corrosion-resistant containers.
    Application of Trichloro(3,3,3-Trifluoropropyl)Silane

    Applications of Trichloro(3,3,3-Trifluoropropyl)Silane in Industrial Manufacturing

    Trichloro(3,3,3-Trifluoropropyl)Silane serves as a specialized organosilicon coupling agent and surface modifier in several advanced material industries. The following application scenarios provide detailed insights into compliant use, processing integration, recommended dosage, and the genuine end products created by downstream manufacturers.

    1. Silicone Rubber Formulations for High-Performance Insulation

    Major elastomer producers incorporate this silane to improve heat, chemical, and tracking resistance in high-grade silicone rubber, including fluorosilicone types used for wire cables and aerospace seals. This additive introduces trifluoropropyl functional groups through co-polymerization or as a post-treatment, enhancing the finished rubber's performance in demanding service environments.

    Industry compliance standards

    • IEC 60811-404: Test methods for insulating and sheathing materials of electric cables
    • UL 94: Flammability Standards for Plastics
    • RoHS 2011/65/EU: Restriction of Hazardous Substances Directive
    • ISO 1629: Classification of rubber types

    Typical usage ratio

    • 0.5–2.0 wt% in base silicone rubber compounds, adjusted based on filler surface area and desired dielectric properties

    Downstream process integration

    • Introduced during the masterbatch mixing stage, prior to vulcanization; either directly reacted with fillers or blended with base polymers

    Final product types

    • Fluorosilicone wire insulation for high-voltage cables
    • Aerospace-grade O-rings and gaskets
    • Automotive spark plug boots and seals
    • Electrical connectors and cable coatings

    2. Glass Fiber Surface Treatment for Advanced Composites

    This material modifies the hydrophobicity and chemical interaction of glass fiber surfaces, ensuring better resin wettability and adhesion in composite applications. Producers apply it as a sizing agent or as a component in multi-functional silane blends, supporting robust fiber-matrix bonds in high-performance structural parts.

    Industry compliance standards

    • ISO 1268: Glass fiber-reinforced plastics—production of laminate test plates
    • ASTM D2344: Short-Beam Strength of Polymer Matrix Composite Materials
    • REACH Regulation (EC) No 1907/2006
    • RoHS 2011/65/EU

    Typical usage ratio

    • 0.1–0.8 wt% relative to glass fiber mass, with exact loading based on type of resin and end-use environmental requirements

    Downstream process integration

    • Applied via aqueous or solvent-based dip-coating onto glass fibers before drying and bundling, as a component in fiber sizing formulations

    Final product types

    • Epoxy glass fiber laminates for printed circuit boards (PCBs)
    • Structural components for automotive and aerospace industries
    • Chemical-resistant composite storage tanks
    • Wind turbine blade reinforcements

    3. Surface Modification in Precision Electronic Encapsulation

    Electronics manufacturers employ this silane for modifying filler particles in encapsulation compounds, targeting improved moisture resistance and adhesion balance in sensitive device packages. Its unique fluorinated moiety makes it suitable for semiconductor sealing and sensor encapsulation where long-term reliability is critical under high humidity and temperature cycling.

    Industry compliance standards

    • IPC/JEDEC J-STD-033: Handling, Packing, Shipping and Use of Moisture/Reflow Sensitive Devices
    • JIS C 5010: Moisture Resistance Standards for Electronic Components
    • IEC 60068-2: Environmental Testing Procedures
    • RoHS 2011/65/EU

    Typical usage ratio

    • 0.2–1.5 wt% relative to total inorganic filler; formulation can be tailored based on encapsulant viscosity and device miniaturization constraints

    Downstream process integration

    • Treated onto silica, alumina, or magnesium oxide fillers prior to their introduction to silicone or epoxy matrices used in potting and encapsulation

    Final product types

    • Chip-level encapsulants for integrated circuits
    • Optoelectronic module sealants
    • MEMS sensor housing encapsulation
    • Automotive and satellite electronics potting compounds

    4. Anti-Graffiti and Stain-Resistant Coating Formulations

    Coatings and paints manufacturers use this silane as a reactive modifier in creating anti-graffiti and non-stick coatings for commercial facades, transport infrastructure, and food processing equipment. The trifluoropropyl group imparts low surface energy, improving release properties and long-term color retention under UV exposure, all while meeting strict compliance expectations.

    Industry compliance standards

    • EN 1062-1: Paints and varnishes—Coating materials and coating systems for exterior masonry and concrete
    • ISO 2812-4: Paints and varnishes—Determination of resistance to liquids
    • REACH Regulation (EC) No 1907/2006
    • ASTM D6578: Standard Practice for Determination of Graffiti Resistance

    Typical usage ratio

    • 0.3–1.2 wt% on total resin solids; dosage optimized for target surface slip and chemical durability without reducing adhesion

    Downstream process integration

    • Dosed into polyurethane, epoxy, or acrylic resin preblends at the pigment dispersion or clearcoat formulation stage

    Final product types

    • Permanent anti-graffiti architectural coatings
    • Food contact-approved kitchen worktop coatings (where permitted)
    • Transport infrastructure protection paints
    • High-durability exteriors for commercial real estate

    5. Specialized Silane Crosslinkers in Fluoropolymer Synthesis

    Producers of specialty elastomers and plastics for niche industrial use co-polymerize this silane into fluoropolymer chains, imparting enhanced chemical resistance and flexibility required in critical service hoses and diaphragms. The raw material acts as a functional comonomer or as a grafting reactant depending on desired molecular weight distribution and product certification demands.

    Industry compliance standards

    • ASTM D2000: Classification System for Rubber Products in Automotive Applications
    • ISO 1043-1: Plastics—Symbols and abbreviated terms
    • FDA 21 CFR 177.2600: Rubber Articles Intended for Repeated Use (in permitted applications)
    • REACH Regulation (EC) No 1907/2006

    Typical usage ratio

    • 0.8–3.0 mol% relative to total monomer feed; higher levels favored in critical chemical delivery or extreme temperature environments

    Downstream process integration

    • Introduced during copolymerization in solution or emulsion polymerization reactors, or via melt-grafting to modify existing polymer backbones

    Final product types

    • Flexible fluoropolymer hoses for chemical transport
    • Resilient seals and gaskets for hydraulic equipment
    • Diaphragm materials used in analytical instrumentation
    • High-purity tubing for pharmaceutical and semiconductor use
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    Certification & Compliance
    More Introduction

    Introducing Trichloro(3,3,3-Trifluoropropyl)Silane: Versatile Surface Modifier from an Experienced Manufacturer

    In the field of organosilicon production, few compounds draw as much consistent attention as trichloro(3,3,3-trifluoropropyl)silane. Over several decades of manufacturing specialty silanes, this molecule has shown itself as a reliable performer for applications where enhanced stability and unique surface characteristics are required. Our journey with this compound comes from years of practical synthesis, fine-tuning purity, and working alongside industrial formulators to solve real-world surface problems.

    Understanding the Molecular Advantage

    Trichloro(3,3,3-trifluoropropyl)silane offers a structure that stands apart from most common silane coupling agents. The presence of the trifluoropropyl group bonded to silicon, along with three reactive chlorine atoms, isn’t just clever chemistry on paper; it directly impacts how the molecule behaves during real processing. Fluorinated silanes like this were never designed for everyday adhesion. Where standard methyl-, ethyl-, or phenyl-substituted silanes stop, this trifluoropropyl variant continues. The highly electronegative fluorine atoms imbue the resulting bonded surfaces with notable hydrophobicity and resistance to many harsh organic solvents and acids. That unique value keeps this silane in demand among our customers in surface treatment, polymer modification, and electronics.

    From the perspective of someone who has handled the raw material, watched it react, and troubleshot the downstream issues, a few things become evident. The boiling point, volatility, and sensitivity to moisture all signal a need for solid handling protocols and reliable equipment. In our plant, extra care during synthesis and purification pays off once you see the clarity and stability of the finished product.

    Ideal Applications Shaped by Practice

    Industrial use drives most technical development in specialty silanes. Trichloro(3,3,3-trifluoropropyl)silane has been consistently adopted by manufacturers who need more than just "surface modification." Its main appeal begins with glass, silica, and metal oxides. These surfaces, whether in fiber-reinforced plastics, electronics, or chemical sensors, demand coatings and coupling agents that can survive both environmental exposure and aggressive processing media.

    Standard silanes like methyltrichlorosilane or vinyltrichlorosilane struggle to provide long-term repellency or chemical inertness, particularly against water, oils, and aggressive acids. In contrast, the presence of fluorinated carbon within trichloro(3,3,3-trifluoropropyl)silane pushes repellency to another level. We see formulators at industrial scale using this molecule to render glass superhydrophobic and oleophobic in a single treatment—yielding coatings that last through extended wash cycles or continuous flow applications. Electronics makers rely on the improved dielectric stability, a benefit you quickly learn to appreciate after seeing fewer device failures during qualification testing.

    Differences Based on Real-World Results

    Our perspective as a manufacturer means we don’t just see specifications on a data sheet, but outcomes after extended production runs. Compared to standard chlorosilanes, introducing the trifluoropropyl tail profoundly shifts the dynamic between substrate and environment. For instance, methyl- and ethyl-functional silanes tend to produce films that limit water, but their organic end groups degrade under ultraviolet light and hot-wet conditions. The trifluoropropyl group, with its compact and robust fluorocarbon backbone, keeps coatings from losing performance even after repeated exposure to boiling water or corrosive acids.

    Users often highlight how trichloro(3,3,3-trifluoropropyl)silane simplifies some notoriously tricky problems, such as anti-graffiti coatings, corrosion-resistant glassware, and microfluidic devices. These benefits don’t emerge from marketing promises—they come from years of comparative testing, where conventional silanes left measurable residue or failed to deliver repellency after months in the field. In surface energy measurements, contact angles routinely exceed what’s achievable using non-fluorinated analogs. The compound has also offered lasting anti-fog and anti-stain treatment for technical glass in scientific and architectural applications.

    Usability in Real Plant and Laboratory Environments

    Plant chemists quickly learn that chlorosilanes present challenges—moisture sensitivity can turn transfers into messy reactions, generating hydrochloric acid vapors and possible cross-contamination. Storage tanks and drum valves require dry nitrogen blankets, and production lines can’t cut corners on inert gas purging. Over time, we’ve refined our own material handling to keep hydrolysis at bay, boosting both shelf life and performance consistency.

    In the hands of customers, trichloro(3,3,3-trifluoropropyl)silane tolerates standard silanization techniques, from vapor deposition to solution-based treatment. Some clients spray dilute ethanol or hydrocarbon solutions onto glass or polyester fabric, while others use vapor-phase application in controlled chambers. The highly reactive Si–Cl bonds allow efficient grafting onto hydroxylated surfaces, sustaining durable aromatic or alkyl surface groups for long-term performance.

    This silane can also act as a valuable intermediate for downstream fluorosilane synthesis. The trifluoropropyl group facilitates a smooth reaction path towards more complex silicone polymers or coatings, expanding the flexibility for custom product development. As demand for low-surface-energy coatings rises in emerging electronics and sensor technologies, the ability to offer scalable, reproducible batches has set this compound apart from lower-value alternatives.

    Safety and Environmental Experience

    In the chemical industry, worker safety and environmental control form the bedrock of daily operations. Chlorosilanes react vigorously with water and alcohols, evolving heat and hydrochloric acid. Our manufacturing teams have faced and solved these issues from process design onward. Closed-loop systems, thorough moisture exclusion, and real-time monitoring of emissions have all helped us keep plant safety on track. That hard-earned experience translates directly into stable, predictable shipments for downstream processors, cutting downtime and waste.

    Regulatory questions about perfluorinated compounds or persistent organic pollutants often arise. Trichloro(3,3,3-trifluoropropyl)silane sits outside the family of persistent perfluorooctanoic compounds, owing to its partially fluorinated propyl group. It remains broadly compliant for use in technical and industrial settings, especially where direct consumer exposure is not anticipated. Product stewardship means tracking evolving legislation and helping customers make informed decisions, whether they are working on manufacturing specialty glassware or new generations of flexible electronics.

    Examples from the Factory and Beyond

    Years of direct observation help fill the blanks left by academic literature. Every batch from our reactor is scrutinized for clarity, color, and volatility. Moisture and acid content get checked using established Karl Fischer and titration methods. Small amounts of unreacted chlorosilane can throw off downstream polymerization or cause haze in clear coatings. There's no substitute for this level of attention, as most problems in application trace right back to issues in synthesis or purification.

    Maintenance technicians and process chemists both contribute to refining production. Sticky residues in pumps and transfer lines, arising from trace hydrolysis, motivated us to rethink how we dry intermediate streams. Strategic use of molecular sieves and pressurized transfer piping keeps everything moving. Over time, we learned that higher-purity trichloro(3,3,3-trifluoropropyl)silane opens possibilities for more sensitive electronics coatings, where early adopters reported greater yield and fewer device returns.

    On the customer’s side, end-of-line tests often focus on water and oil contact angles or accelerated exposure to acids. One client in the fiber optics sector reported a dramatic reduction in micro-cracking and fogging after shifting from a commodity silane to our high-specification trichloro(3,3,3-trifluoropropyl)silane. Another, working with silicone elastomer modification, noted improved flexibility without sacrificing chemical resistance. These reports come without prodding; as a manufacturer, you hear the difference when end users reach back for long-term supply.

    Balancing Cost and Value

    In specialty chemical production, many buyers weigh price against long-term benefit. For trichloro(3,3,3-trifluoropropyl)silane, the balance comes down to application needs. Routine water repellency can use more commonplace silanes, but many formulators return to the trifluoropropyl group after seeing conventional coatings fail stress testing. For instance, sports eyewear makers reported much lower returns due to ghosting or delamination, while architectural glass installers cited easier maintenance and cleaning.

    Running the reactors and distillation units, you watch how batch process controls affect product cost. Minor improvements in yield and purity directly benefit both the factory and the customer. Extensive cleaning between product runs helps prevent cross-contamination, but it also means longer turnaround time, which can elevate per-kilo pricing. Over time, stable demand and close partnership with high-tech users have justified continued investment in better manufacturing equipment and quality control systems.

    Some companies new to using this silane may underestimate the initial challenges. Precise dosing and the right curing temperature determine whether you get a robust surface or spotty repellency. Our technical support has walked customers through test protocols, transferred best practices in post-application drying, and even revised recommendations after learning about previously undocumented interactions. A solid supply relationship grows from this collaboration, not just a shipment of drums.

    The Future of Fluorosilane Technology

    With growing pressure for advanced coatings and functional surfaces that survive tough environments, trichloro(3,3,3-trifluoropropyl)silane stands as a core ingredient in multiple technological trends. Flexible displays, medical diagnostic surfaces, and next-generation insulation all challenge formulators to unite durability with new kinds of chemistry. The compactness and precision manufacturing that this compound delivers make it an attractive choice as demands increase for reliability over longer service lives.

    Our ongoing investments follow market signals, but also draw on feedback from scientists and engineers who push coatings harder every year. For several clients proof-of-concept experiments didn’t reveal the full story; real innovation happened after scaling up, where minute impurities or subtle protocol changes impacted large-area glass treatments or electronics. As a manufacturer, we keep our ear close to those stories, using field insights to revise and improve our processes.

    It would be misleading to claim that any one molecule answers every surface challenge, but our experience tells us the trifluoropropyl silane solves problems that competitors cannot. The balance of chemical robustness, hydrophobicity, and adhesion sits right for markets that require something more than commodity adhesion promoters.

    Summary of Practical Knowledge and Choices

    The story of trichloro(3,3,3-trifluoropropyl)silane—from synthetic starting materials in the reactor to specialized glass on a lab bench—follows a direct line shaped by practice, investigation, and troubleshooting. Each successful use case reinforces the compound’s reputation among those who need lasting results, not just theoretical performance.

    Our team has guided many customers as they moved toward more rigorous process controls, supporting installations and even modifying our product specifications in response to changing equipment on their side. If a better recipe or handling protocol results in fewer product failures or shorter maintenance shutdowns, those become our new standard operating procedure. It's in this messy, iterative, and ultimately rewarding cycle of production and feedback that we see the real value of what we make.

    By matching technical innovation with cautious stewardship and strong partnerships across industries, our factory continues to expand what's possible with trichloro(3,3,3-trifluoropropyl)silane. Users who care about reliable outcomes, custom solutions, and lasting surface effects find this silane delivers, not because it is flawless, but because continuous improvement has made its strengths clear in the places where it matters most. For anyone serious about advancing surface science or industrial reliability, choosing the right fluoroalkyl silane makes all the difference—a difference we witness with each new batch and every satisfied partner.