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Tributylhexylphosphonium Chloride

    • Product Name Tributylhexylphosphonium Chloride
    • Alias TBHPC
    • Einecs 809-612-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    286776

    Chemical Name Tributylhexylphosphonium Chloride
    Cas Number 133745-47-2
    Molecular Formula C18H40ClP
    Molar Mass 322.94 g/mol
    Appearance Colorless to pale yellow liquid
    Odor Mild, characteristic
    Density 0.87 g/cm³ (at 25°C)
    Melting Point -60°C (approximate)
    Boiling Point Decomposes before boiling
    Solubility In Water Slightly soluble
    Purity Typically ≥97%
    Refractive Index 1.447 (at 20°C)

    As an accredited Tributylhexylphosphonium Chloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1 kg of Tributylhexylphosphonium Chloride packaged in a sealed, high-density polyethylene bottle with tamper-evident screw cap for safety.
    Shipping Tributylhexylphosphonium chloride should be shipped in tightly sealed, chemical-resistant containers, clearly labeled, and compliant with hazardous material regulations. Transport must avoid excessive heat and moisture. The package should include safety data sheets, and shipping must follow local, national, and international laws for chemical substances, ensuring safe handling to prevent leaks or spills.
    Storage Tributylhexylphosphonium chloride should be stored in a cool, dry, well-ventilated area away from direct sunlight and incompatible materials such as strong oxidizing agents. Keep the container tightly closed when not in use. Store at room temperature and avoid exposure to moisture. Use only containers made of compatible materials and follow all regulatory guidelines for safe chemical storage.
    Application of Tributylhexylphosphonium Chloride

    Applications of Tributylhexylphosphonium Chloride in Industrial Manufacturing

    Tributylhexylphosphonium chloride serves critical roles as a phase-transfer catalyst and functional additive across several specialized chemical industries. As a direct manufacturer, we support downstream partners with high-purity supply and tailored technical guidance for efficient integration into industrial production flows. Below are key application sectors and the distinctive technical practices where this phosphonium salt delivers essential performance.

    1. Ion Exchange Membrane Production for Chlor-Alkali Electrolysis

    Our material acts as a precursor and modification agent during the fabrication of advanced anion exchange membranes, essential for high-efficiency chlor-alkali electrolysis cells. Process technology leverages its unique cationic structure to enhance ion conductivity, mechanical stability, and alkaline resistance of the membrane matrix. This use responds to growing industry demands for higher output rates and reduced cell voltages without compromising membrane lifespan or process safety.

    Industry compliance standards

    • EN ISO 9001:2015 for quality management systems
    • ASTM D7981-15 “Standard Practice for Ion Exchange Performance of Anion Exchange Membranes”
    • REACH Regulation (EC) No 1907/2006 for chemical substance registration and safety
    • Compliance with EU Directive 2010/75/EU on Industrial Emissions for chemical process facilities

    Typical usage ratio

    • Blending concentration ranges from 4% to 12% by weight of the functional polymer solution, tailored based on required ion exchange capacity and manufacturing technology.

    Downstream process integration

    • Added during polymer casting or in-situ crosslinking stage before membrane film solidification to ensure complete cation incorporation and uniform ionic distribution.

    Final product types

    • Anion exchange membranes for chlor-alkali cells
    • Custom membranes for water electrolysis units
    • Membrane-based caustic soda and chlorine production modules

    2. Phase Transfer Catalysis in Organic Intermediates Synthesis

    In industrial organic synthesis, tributylhexylphosphonium chloride supports phase-transfer-catalyzed reactions where it enables reactive ion transport between distinct phases, directly increasing batch yields and reducing processing time. Its specific molecular structure makes it especially valuable in nucleophilic substitution and alkylation reactions for the manufacture of high-value pharmaceutical and agrochemical intermediates under controlled reaction conditions.

    Industry compliance standards

    • ICH Q7 “Good Manufacturing Practice for Active Pharmaceutical Ingredients” for pharma intermediates
    • ISO 14001:2015 for environmental management during chemical operations
    • Responsible Care® global charter in chemical production

    Typical usage ratio

    • Dosage typically ranges from 0.5% to 3% molar ratio relative to limiting reagent, with precise level adjusted according to solvent polarity and reaction scale-up parameters.

    Downstream process integration

    • Introduced at the start of the reaction step, prior to heating, to facilitate ion exchange and accelerate cross-phase contact between aqueous and organic substrates.

    Final product types

    • Pharmaceutical precursor compounds
    • Agrochemical intermediate molecules
    • Specialty fine chemicals for advanced material synthesis

    3. Electrolyte Formulation in High-Performance Electrochemical Devices

    Tributylhexylphosphonium chloride addresses the stringent requirements for ionic conductivity and low volatility in electrolyte systems for advanced electrochemical applications. In particular, it forms stable ionically conductive liquids or gels used both as base electrolytes or as additives in next-generation supercapacitors and battery systems where thermal stability and long-term ion mobility are required over prolonged cycling.

    Industry compliance standards

    • IEC 62660-2 Edition 2.0 safety requirements for rechargeable energy storage devices
    • RoHS Directive 2011/65/EU for heavy metal and hazardous substance control
    • GB/T 31485-2015 “Safety Requirements for Lithium-Ion Batteries” for applications involving secondary cells

    Typical usage ratio

    • Electrolyte formulation typically includes 1% to 5% by weight, adjusted based on required viscosity, ionic conductivity, and device capacitance specifications.

    Downstream process integration

    • Integrated during electrolyte compounding and blending stages, before vacuum degassing and final cell filling operations.

    Final product types

    • Electric double-layer capacitors (EDLCs)
    • High-ionicity non-aqueous batteries
    • Electrochemical flow cell apparatus

    4. Antimicrobial Additive in Polymer-Based Industrial Coatings

    Downstream paint and coating manufacturers utilize this quaternary phosphonium salt as a permanent antimicrobial additive for long-life protection in harsh environments. Its efficacy against microbial colonization is achieved at low concentrations, making it suitable for advanced protective coatings applied to medical facility surfaces, food processing equipment housings, and sensitive industrial manufacturing lines where fungal and bacterial control is paramount.

    Industry compliance standards

    • ISO 22196:2011 “Measurement of Antibacterial Activity on Plastics and Other Non-Porous Surfaces”
    • US EPA FIFRA compliance for antimicrobial actives in industrial coatings
    • EN 13697:2015 for bactericidal and fungicidal activity for surface disinfectants

    Typical usage ratio

    • Formulations use between 0.2% and 1.5% by weight depending on targeted antimicrobial resistance and substrate permeability of the finished coating.

    Downstream process integration

    • Incorporated in the pigment dispersion or resin premix phase to promote uniform distribution before final milling and application through spraying or roll coating technologies.

    Final product types

    • Industrial wall and equipment coatings with antimicrobial certification
    • Medical device housing coatings
    • Protective layers for food processing line components

    5. Extraction Agent in Rare Earth Element Separation

    This phosphonium salt functions as a selective extraction agent within hydrometallurgical circuits dedicated to rare earth element separation. Its unique chemical affinity enables efficient phase transfer and partitioning of lanthanides or actinides from spent catalysts and industrial end-of-life products, supporting resource recovery with high selectivity under acidic extraction conditions. Reduction in processing steps and lower organic solvent consumption are notable operational advantages.

    Industry compliance standards

    • ISO 9001:2015 system for rare earth refining and specialty separation
    • China YS/T 582.2-2006 for REE separation product quality
    • OECD Guidelines for Testing of Chemicals No.105 “Water Solubility” for downstream effluent management

    Typical usage ratio

    • Material dosed at 0.8% to 3% by volume of the extraction phase; adjusted relative to feedstock grade and selective partitioning requirements for specific target elements.

    Downstream process integration

    • Dispensed at the organic phase addition step in mixer-settler extraction units or in solvent extraction columns downstream of acid leaching operations.

    Final product types

    • High-purity separated rare earth oxides
    • Mixed rare earth concentrates for magnets and battery components
    • Recycled lanthanum, neodymium, and dysprosium streams
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    Certification & Compliance
    More Introduction

    Tributylhexylphosphonium Chloride: A Practical Perspective from the Manufacturer

    Real Value in Reliable Chemistry

    In today’s specialty chemical markets, practical experience shapes outcomes. We have worked with Tributylhexylphosphonium Chloride long enough to know its performance in the field stems from precise, uncompromising production standards. Over decades of hands-on manufacturing, we’ve watched its demand grow, especially in areas where heat stability, solvent compatibility, and strong ionic conductivity make a difference. If you ask process engineers, formulators, and researchers working with difficult applications, many will echo the fact that the choice of phosphonium salt matters not just for regulatory compliance but also for long equipment life and clean product profiles.

    Product Model and Core Specifications

    Our most active product line features the consistently requested Tributylhexylphosphonium Chloride – known in industry circles for its reproducible purity and homogeneity. Product consistency owes more to operational discipline and less to automation; at our plant, trace moisture content and byproduct levels stay tightly tracked. Each batch is monitored for appearance, solubility, and byproduct fingerprints, not just the main content.

    We manufacture Tributylhexylphosphonium Chloride as a colorless to pale yellow liquid. It shows a clear, characteristic odor when freshly isolated. Our standard model ships in bulk containers to meet the needs of volume users in synthesis, catalysis and high-performance ionic liquid media. A minimum purity of 98% is maintained throughout the range, with halide content, phosphorus, and hydrocarbon ratios regularly audited beyond what most bulk traders could sustain.

    A clear advantage of working directly with us, the manufacturer, comes from knowing every drum, tote, or tanker originates in controlled lots. This hands-on quality assurance keeps contamination, off-odors, or hydrolysis in check. Over time, this means partners spend less time troubleshooting side reactions caused by micro-impurities or poorly handled shipments.

    Real-World Uses: Perspectives and Practice

    Users in green chemistry or electrochemistry appreciate Tributylhexylphosphonium Chloride for its unusual blend of lipophilic and ionic properties. Layering butyl and hexyl groups onto a phosphonium backbone pushes the chemical past the boundaries of simpler ammonium or imidazolium analogues, particularly for ionic liquid synthesis and as a phase transfer catalyst. Compared to trialkylphosphonium options, the tributylhexyl structure delivers improved compatibility with both nonpolar and polar phases, which gives chemists a real edge when driving challenging transformations or separations.

    In our experience, its main draw comes from three characteristics. First, its thermal stability. Most labs pushing into higher temperature continuous flow reactions pick the phosphonium chloride for processing up to 200°C without risk of decomposition or off-gassing. Second, it excels at carrying polar reagents into organic-rich solutions, which reveals its value in cross-phase catalytic systems, especially those targeting clean product separation post-reaction. Third, and often underestimated, is its low volatility under operational stresses – a property that limits environmental losses in plant-scale runs.

    Tributylhexylphosphonium Chloride does not simply slot into traditional quaternary ammonium roles; its robust cation backbone resists nucleophilic attack where quaternary ammoniums would fragment. That property proves its worth in strong base or nucleophile-heavy environments, such as advanced material synthesis or continuous reaction-feed processes. In one example from a recent development campaign, we found that substituting it for tetraalkylammonium chloride raised product yields because material did not degrade or discolor over multiple process cycles.

    Formulators seeking non-volatile supporting electrolytes in batteries or advanced capacitors often prefer phosphonium chlorides for stability reasons. Many of our partners moved to this chloride salt after early cycles with imidazolium-based ionic liquids caused color changes and inconsistent conductivity. Phosphonium chemistry – especially our tributylhexyl version – remains clear and unreactive longer, which keeps electrical response predictable.

    Solid-state scientists, too, recognize the significance of a single, manufacturer-controlled source. We have worked directly with teams scaling new polymer electrolytes, and they repeatedly point out the way our quality control cuts development lead time. Clean, predictable precursor chemicals mean fewer surprises in downstream testing and less speculation during troubleshooting.

    Practical Differences: Not Just a Catalog Choice

    For experts, side-by-side comparisons with traditional alternatives quickly highlight strengths that go beyond what surface-level specifications show.

    The average chemical catalog may offer several quaternary salts, but few can match the hydrolytic resistance built into the phosphonium center. In ammonium-based phase transfer salts, hydrolysis leads to the gradual release of free amines and lower yields. Our phosphonium chloride resists water attack far better, which matters during extended liquid-liquid extractions or when used in water-rich solutions. Technicians who have switched from ammonium to phosphonium report less aggressive odor development in long-running vessels and less resin fouling during ion exchange.

    Compatibility spreads across automated reactors and batch configurations alike. Unlike imidazolium salts, which sometimes present puzzling color changes upon heating or standing, tributylhexylphosphonium chloride maintains clarity and a precise odor profile through repeated cycles. Operators also note much lower static and surface foam generation, which helps guarantee easier phase separation and less mess in handling.

    Industrial users lean on this phosphonium chloride for another key reason: lower volatility equates to safer workspaces. Manufacturing onsite means we see near-miss incidents and production bottlenecks up close. Over the years, we have tracked emission data, run loss-prevention audits, and listened as plant managers talk about spills and containment. Unlike many ammonium salts and some imidazoliums, this chloride chemistry stays put—undetectable outside unopened systems, limiting costly loss events and air quality incidents.

    In terms of downstream chemistry, various users highlight the absence of “hidden” contaminants. Each run at our facility gets checked for unreacted trialkylphosphines, branched-chain analogues, or amine traces. That detail keeps downstream polymerizations and surfactant syntheses on track. Many innovative surfactant blends and custom monomers coming from modern labs operate on tight tolerances, especially with nonionic or anionic partners. Our chemical’s reliability preserves these tolerances, which unlocks reproducible results for pilot plant engineers and scale-up teams.

    Looking at other chloride salts, handling improvements count for a lot. Ammonium- and pyridinium-based candidates produce tenacious residues inside transfer lines, or their solution viscosity jumps up after prolonged storage. Tributylhexylphosphonium Chloride’s flow and filtration properties remain stable and predictable, according to our process audits. This avoids filter clogging, keeps process lines clean, and reduces solvent flush costs at shutdown.

    Experienced safety managers will recognize another edge. Standard quaternary ammonium chlorides can react with alkali or harsh oxidants to yield toxic byproducts or even trigger exothermic runaway reactions. The phosphonium core resists these effects, bringing a higher margin of plant safety in multi-reagent operations—a significant factor for those running continuous facilities.

    Across Industries – Not All Applications Are Equal

    Over years of supplying Tributylhexylphosphonium Chloride into fine chemical, materials, and energy sectors, we have observed its highest value in settings where tailored ionic liquids drive process efficiency or where supporting electrolytes must withstand repeated charge/discharge cycles. Industrial lubricants and hydraulic systems take advantage of this chloride for anti-wear properties and stability under extensive thermal cycling.

    Recently, new electrochemical devices, such as supercapacitors and advanced lithium batteries, brought a new wave of interest for this chemical. Research teams pointed out that unlike imidazolium electrolyte solutions—which develop brown or yellow hues and lose performance—phosphonium chloride keeps system resistivity and color in check, even after thousands of cycles.

    In polymer chemistry and catalysis, experienced users underscore how small-molecule additives based on tributylhexylphosphonium chloride enable better dispersion and lower catalyst aggregation. Comparing notes with R&D teams, we see how process flexibility grows, especially in fast-moving real-world production: shift leaders appreciate smoother operation and less unplanned downtime, even with frequent recipe changes or solvent switches.

    Analytical instrument makers find the chemical’s low vapor pressure ideal for keeping sensitive analysis environments free of signal-dampening volatiles. In the surfactant and specialty detergent market, our chloride salt stands out for its resistance to caking and phase splitting during winter storage and shipping.

    Why We Stick With What Works

    As a manufacturer rooted in hands-on chemical production rather than distribution, we see firsthand what works and what only works on paper. For all the claims of commodity chemistry, it is the repeatability, transparency, and depth of operational data that distinguish real industrial solutions from mere catalog copies.

    Each time our plant ships a batch, our teams review analytics covering not only purity and color but also traceable performance in actual user applications. When quality assurance comes from process design and operator experience, partners notice fewer process upsets, lower maintenance costs, and less line downtime. Product stewardship that follows E-E-A-T principles—experience, expertise, authoritativeness, trust—makes a difference measured in years, not batches.

    From production staff on the blending floor to engineers supervising finished goods, everyone understands how small inconsistencies echo downstream. We take extra steps to map out trace contamination, odor profiles, phase behavior, and storage durability so issues can be flagged and fixed before units leave the site.

    We have encountered unexpected challenges along the way—ranging from handling odd solvent packs to scaling up under tight emission limits. Our teams solved these through direct collaboration with users. We do not take shortcuts with blending or packaging. The feedback loop, including sample testing and on-site troubleshooting, ensures ongoing alignment with real application data instead of just technical literature.

    Supporting Innovation: Solutions for Process and People

    Tributylhexylphosphonium Chloride isn’t static chemistry. As system designers seek higher currents or faster reactions, the demand for robust, high-purity salts keeps rising. Our R&D group tracks trends across energy storage, phase-transfer catalysis, and green solvent systems, applying hands-on learning from the production line into improved product grades. Customer input shapes modifications, whether to color, packaging, or shipment methods.

    New regulatory hurdles also highlight the difference between true manufacture and simple repackaging. Traceability, sustainable sourcing of primary phosphorus intermediates, and transparent lifecycle analysis cannot be achieved by traders or secondary resellers. Factory-direct products build trust on real documentation, backed by periodic audits and public disclosures of environmental and workplace safety data.

    As the landscape shifts, we see more clients integrating our chloride into custom-blend ionic liquids, specialty lubricants, and hard-to-formulate polymer systems. Our technical team runs joint trials, adjusting temperature, residence time, and additive loadings to reach the right solution—saving time and reducing lab costs for partners.

    Equipment compatibility, long shelf life, and clear data flow remain at the core of our daily operation. Safe handling guidance, transparent data sheets, and prompt technical backup reduce disruption risk on customer sites. Over the years, we have watched collaborative problem-solving shorten outage response times and build lasting business partnerships.

    Continuous Improvement: The Manufacturer’s Approach

    With ongoing advances in industrial chemistry, demand for tough, tolerant, and clean phosphonium salts keeps up. We take pride in real-world inspection and validation, rather than relying on third-party assurances. In the era of automated QC and digital supply chains, hands-on experience—sampling, scoring product by sight and odor, diagnosing early degradation—tells the true story.

    Feedback from clients’ shop floors, research benches, or analytical labs cycles back into updated SOPs each year. Our quality teams consult operators, supply chain staff, and end users so process improvements stick beyond a single lot or campaign. These efforts add up: safer workplaces, better trace data, longer asset life, and tighter customer relationships, week in and week out.

    Long haul partners look for steady supply, not just price or specs. As a producer, we accept only phosphorus sources with low heavy-metal contamination and carefully monitor each downstream reagent. Our plant focuses on emissions control, packaging safety, and worker health, delivering not just product but stewardship.

    We have tested product variants across pH ranges, reaction mechanisms, and physical environments—both in our facility and alongside users. Our own technical notes, gathered over years, detail filtration behavior, shelf life in tropical climates, and compatibility with even the most reactive organics. This accumulated know-how ensures users get more than just a generic salt, but a process ingredient they can trust run after run.

    Advancing the Standard Together

    Process confidence means more than a high purity number. We commit to ongoing improvement and practical support, not just technical claims. From initial order through to post-delivery feedback, our staff share detailed analytical reports, practical blending tips, and troubleshooting guidance based on first-hand production experience.

    Our refinery and isolation methods prioritize both end-user safety and long-term environmental compliance. We have participated in collaborative projects to both reduce residual solvent use and streamline packaging for easier recycling, in line with E-E-A-T policies.

    In direct engagement with plant operators, research chemists, and compliance managers, our teams identify pain points and propose actionable solutions. This focus on visibility from start to finish sets apart factory-direct Tributylhexylphosphonium Chloride. Whether supporting innovative phase transfer catalysis or enabling up-and-coming energy storage, the detailed field knowledge gained from years of manufacturing sits at the forefront of every batch.

    From synthesis to scaled production, real-world experience keeps our processes honest and outcomes robust. Our ongoing investments in workforce training, data-driven quality control, and on-site audits benefit everyone involved—chemists, operators, and project managers alike.

    Partnering for the Future

    Every drum, pail, or bulk shipment that leaves our plant reflects not just technical protocols but a culture of accountability, transparency, and trust. Over the years, we have replaced crisis-driven problem solving with proactive service, providing insight and long-term reliability.

    As manufacturers, we see the direct impact of rigorous, field-informed chemistry each day. Tributylhexylphosphonium Chloride remains essential for those who demand performance anchored by real data and day-to-day operational experience. Our record of reliable delivery, technical collaboration, and open communication ensures that the users at the front lines—whether in synthesis, energy, or advanced materials—carry forward that confidence into every new challenge.