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Tributyl(Vinyl)Tin

    • Product Name Tributyl(Vinyl)Tin
    • Alias Vinyltributyltin
    • Einecs 212-029-3
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    400991

    Chemicalname Tributyl(vinyl)tin
    Casnumber 1116-70-7
    Molecularformula C14H30Sn
    Molecularweight 317.10
    Appearance Colorless to pale yellow liquid
    Boilingpoint 123-124 °C at 10 mmHg
    Density 1.114 g/mL at 25 °C
    Refractiveindex 1.490-1.494 at 20 °C
    Meltingpoint -70 °C
    Purity Typically ≥ 97%
    Flashpoint 115 °C
    Solubility Insoluble in water, soluble in organic solvents

    As an accredited Tributyl(Vinyl)Tin factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 250 mL amber glass bottle with screw cap, labeled "Tributyl(Vinyl)Tin." Chemical hazard symbols, lot number, and manufacturer details present.
    Shipping Tributyl(Vinyl)Tin should be shipped in tightly sealed containers, protected from light, moisture, heat, and incompatible substances. It is typically transported as a hazardous material according to IATA, IMDG, or DOT regulations, requiring appropriate labeling and documentation. Ensure handling by trained personnel with suitable protective equipment to prevent leaks or spills during transit.
    Storage Tributyl(vinyl)tin should be stored in a tightly sealed container under an inert atmosphere, such as nitrogen or argon, to prevent moisture and air exposure. Store in a cool, dry, and well-ventilated area, away from heat, sparks, or open flames. Keep separate from acids, oxidizing agents, and incompatible substances. Use appropriate safety measures to avoid spills and contamination.
    Application of Tributyl(Vinyl)Tin

    Applications of Tributyl(Vinyl)Tin in Industrial Manufacturing

    Tributyl(vinyl)tin plays a specialized role in multiple chemical manufacturing sectors, especially in high-value polymer synthesis, advanced electronics, and pharmaceutical intermediates. As the direct producer, we ensure compliance with industry-specific regulations and provide technical integration support for downstream partners. This application section highlights key industrial segments where this organotin compound drives performance and process efficiency.

    1. Conductive Polymer Synthesis (Polythiophenes and Polyvinyl-Systems)

    This compound acts as a precise vinylation agent in the synthesis of conductive polymers like poly(3-hexylthiophene), widely used in organic electronics. It participates as a stannyl precursor in palladium-catalyzed coupling reactions, such as the Stille reaction, critical for controlled molecular structures and optimized charge transport. Carefully managed process conditions control the molecular weight and electronic properties of the downstream polymer, with the presence of vinyl groups enabling further post-polymerization modifications by end users.

    Industry compliance standards

    • REACH Regulation (EC 1907/2006) for organotin intermediates
    • RoHS Directive 2011/65/EU for electronic component manufacturing
    • IEC 62474 material declaration for electronics
    • ISO 9001:2015 for polymer supply chain quality management

    Typical usage ratio

    • Monomer to stannane molar ratios of 1:1–1:2; adjusted by catalyst loading and target polymer chain length
    • Stille coupling utilizes 3–7% of the total monomer mass as tributyl(vinyl)tin input

    Downstream process integration

    • Added during Grignard metathesis (GRIM) or direct Stille coupling synthesis
    • Controls vinyl functionality for side-chain engineering; introduced during the monomer functionalization stage
    • Final treatment includes solvent purification to remove tin residues before pelletization

    Final product types

    • Organic semiconductors for OLED displays
    • Photovoltaic active layers in flexible solar cells
    • Printed electronic sensor films
    • Electrochromic device coatings

    2. Pharmaceutical Intermediate Synthesis (Vinylation Step for API Building Blocks)

    Downstream API manufacturers employ this material for vinyl group introduction during the preparation of complex heterocyclic compounds. It finds significant use in advanced pharmaceutical process routes relying on Stille coupling to construct carbon–carbon bonds in the core structure of antimicrobial agents and oncology candidates. Reaction selectivity and low impurity levels in this route directly support tight regulatory submissions and minimize downstream purification burden for customers.

    Industry compliance standards

    • ICH Q7 GMP Guidelines for active pharmaceutical ingredient production
    • European Pharmacopoeia and USP monograph compliance during clinical batch preparation
    • FDA 21 CFR Part 211 for finished pharmaceuticals
    • Certificate of Suitability (CEP) process for exported bulk drugs

    Typical usage ratio

    • Vinylation step utilizes 1.0–1.3 molar equivalents relative to halide starting materials
    • Adjusted for substrate reactivity and scale: typical input 10–50 g per 1 mol API substrate

    Downstream process integration

    • Introduced after initial heterocycle assembly as a coupling partner
    • Stille coupling under strict oxygen-free, anhydrous conditions
    • Spin filtration and liquid-liquid extraction steps ensure removal of tin by-products

    Final product types

    • Intermediate building blocks for antiviral APIs
    • Key fragments for anticancer active substances
    • Specialty agrochemical intermediates
    • Advanced organic molecules for contract synthesis

    3. Specialty Silicones and RTV Additives

    The vinyl functionality enables downstream manufacturers to apply this compound for modifying silicone formulation, especially in room-temperature vulcanizing (RTV) systems. Here, it acts as a crosslinking agent or functional coupling partner, boosting adhesion and durability in elastomers. Its role extends to controlling cure rates and imparting specialized surface properties to cured silicone rubbers, essential for automotive and electrical insulation applications.

    Industry compliance standards

    • ISO 9001:2015 for quality assurance in silicones
    • UL 94 Standards for safety in electrical components
    • ASTM D412 and D624 for elastomer physical properties
    • RoHS Directive 2011/65/EU for restricted substances

    Typical usage ratio

    • 0.2–1.0 phr (parts per hundred rubber) depending on required end-use flexibility and cure profile
    • Cure package adjustment by end user based on substrate and thickness

    Downstream process integration

    • Blended into base polymers with platinum or tin catalyst systems
    • Enables post-cure functionalization for specific adhesion requirements
    • Participates in in-situ crosslinking before mold casting or extrusion

    Final product types

    • Encapsulating materials for electronic devices
    • High-clarity silicone lenses
    • Industrial RTV gasket materials
    • Specialized automotive sealants

    4. OLED & OPV Material Manufacturing

    Producers of organic light-emitting diodes (OLEDs) and organic photovoltaic (OPV) elements depend on high-purity vinyl-functionalized tin reagents to build complex conjugated donor-acceptor systems. In this sector, strict material traceability and ultra-low metal contamination guide raw material specification. The compound supports synthesis of advanced emitter and electron-transport layers, ensuring reliable luminance, voltage stability, and photo-conversion efficiency in downstream device fabrication.

    Industry compliance standards

    • IEC 62684/Ed1 for OLED material composition
    • IPC-1752A material declaration for electronics
    • RoHS Directive 2011/65/EU for device safety
    • ISO 14001:2015 for environmental management in materials processing

    Typical usage ratio

    • Conjugated polymer syntheses: 1–3 mol% reagent relative to key monomer units
    • Adjusted depending on functional group density and end-layer thickness

    Downstream process integration

    • Employed during synthesis of heteroaromatic monomers and pre-polymer stages
    • Enables tailored incorporation of vinyl groups for further device functionalization
    • Followed by high-vacuum purification and solution processing into thin films

    Final product types

    • OLED emitter and transport layers
    • Photoactive donor materials in OPV modules
    • Thin-film organic sensors
    • Flexible light-emitting foils

    5. Industrial Adhesive and Resin Modifier

    This stannylvinyl compound modifies certain high-performance adhesives and UV-curable resins by acting as a grafting and crosslinking agent. The vinyl groups integrate into polymer chains, increasing mechanical strength and surface reactivity. Coatings producers use it for structural adhesives in electronics assembly and high-strength industrial laminates, with process protocols focusing on low residual tin and balanced flexibility.

    Industry compliance standards

    • UL 746C for polymeric adhesives in electrical devices
    • ASTM D1002 for lap shear strength testing
    • ISO 10993 for limited biocompatibility in non-implantable devices
    • ISO 14001 for safe process management

    Typical usage ratio

    • 0.5–2.5% by weight in adhesive formulations, depending on matrix chemistry
    • Adjustment based on film thickness and target cure speed

    Downstream process integration

    • Incorporated during pre-polymer resin synthesis
    • Reacted under UV or thermal cure with peroxide initiators
    • Final adhesive films produced by extrusion or solvent casting

    Final product types

    • Assemblage adhesives for electric and automotive industries
    • UV-cured electronic coatings
    • Industrial laminating resins
    • Structural films for component bonding
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    Certification & Compliance
    More Introduction

    Tributyl(Vinyl)Tin: Real-World Production and Practical Uses

    Understanding Tributyl(Vinyl)Tin from Our Production Floor

    The reality of long-chain organotin chemistry often gets overlooked amidst technical jargon and distant product brochures. Tributyl(Vinyl)Tin never arrives as a mere commodity in our plant at sunrise; every drum begins with a series of tightly monitored reactions and batch tests. Over the years, our team has realized why certain industries keep calling for this compound. We’ve seen its direct link to successful manufacturing runs, especially in vinyl polymers and specialty chemical synthesis.

    As a manufacturer, we stand in boots covered in the dust and faint odor of stannous residues. Every liter of Tributyl(Vinyl)Tin tells a story far removed from a catalog description. It isn’t just another segment in the lineup of organotin derivatives. This compound reflects precise control in organometallic synthesis—a vinyl group extended onto a tributyl platform, offering a producer-friendly entry point for further vinyl transfer or catalysis.

    What Sets Tributyl(Vinyl)Tin Apart in Actual Use?

    Tributyl(Vinyl)Tin carries a reputation for high selectivity in vinyl transfer reactions. Decades back, while tuning our reactors away from trialkyls without vinyl, we found that introducing this specific vinyl-tin moiety created new opportunities in organic intermediates. Where many organotins clog reactors with side reactions, this compound consistently gives clean, sharp outputs in several Stille coupling reactions—making complex molecule synthesis more efficient.

    Our batches usually reach the market at greater than 98% purity, because anything less tends to generate complications further down in user processes. By monitoring every cooling curve and every bubbling inch in the glass reactor, we have learned to avoid side-product formation, which older, more generic tributylstannane variants often produce. Modern analytical tools confirm what our experienced hands already suspect; with tributyl(vinyl)tin, predictable outcomes mean fewer stops and greater confidence on the production line.

    Usage—What We Witness in Industrial and Laboratory Squares

    Witnessing Tributyl(Vinyl)Tin in action on a production scale, we’ve seen its strongest demand in the synthesis of specialty vinyl compounds. One of our longstanding partners in the pharmaceutical sector relies on our material as an essential building block for synthesizing key molecular frameworks. Unlike bulkier or more amorphous organotin species, this vinyl-substituted compound offers a neatly controlled pathway for carbon-carbon bond formation using palladium-catalyzed processes. Several generations of synthetic chemists from different companies have spent nights in our labs confirming that this organotin delivers vinyl groups to aromatic halides with minimal complication.

    Researchers sometimes gravitate toward cheaper analogues, thinking all organotins deliver similar results. The reality in our reactors, especially after years perfecting filtration, is different. Many of those alternatives introduce unwanted alkanes or generate unstable byproducts in cross-couplings. But the clean, almost predictable behavior of Tributyl(Vinyl)Tin allows downstream users to concentrate on their unique chemistry, not on cleaning up residual messes. These outcomes don’t come from marketing claims. They come from the heat of our reaction vessels and the results on our NMR spectra.

    Sizing and Specifications—How Manufacturing Decisions Matter

    The way we size our batches and set our controls stems from years of direct customer feedback and process troubleshooting. Most clients ask for volumes ranging from several liters to metric tons. We build every batch to stringent specifications because our users—in plastics, pharmaceuticals, and advanced materials—cannot afford surprises.

    Our standard output features a clear, colorless to pale yellow liquid, with a boiling point high enough to support a range of processing temperatures yet volatile enough for easy distillation when purity matters most. Each drum carries a consistent molecular weight, optimal stannane content, and controlled moisture levels. While some smaller labs prioritize immediate stock, larger buyers often value detailed certificates of analysis and reliable lot conformity; both preferences stem from how critical downstream reaction reliability has become in today’s competitive manufacturing environment.

    What Everyday Production Taught Us About Quality and Safety

    It’s one thing to list purity percentages; it’s another to live with these products everyday. Every member on our production team spends at least a portion of the week cross-verifying batches since marginal impurities readily complicate things. We learned quickly that neglecting proper storage can generate toxic byproducts or unpredictable reactivity—even before shipment leaves the facility.

    The chemistry on our floor remains hands-on. Regular audits from internal and external teams, coupled with 30+ years of synthesis, keep our output aligned with the real requirements of high-stakes industries. Routine handling of organotins demands a tight grip on safety. Rigorous fume extraction, proper PPE, and strict containment form the baseline in our workflow—not post-script warnings in the fine print.

    Tributyl(Vinyl)Tin Compared to Other Organotin Compounds

    Many buyers have tried switching between tributyl-based organotins, triphenyl derivatives, or simple trialkyl homologues. Each has its own reactivity profile and risk regime. A few years back, several customers attempted to substitute tributyl(vinyl)tin with standard tributylstannane or tributyltin chloride in Stille couplings—hoping to minimize costs or tackle process bottlenecks. We observed increased byproduct formation, extended purification cycles, and unwanted rearrangements.

    The difference boils down to selectivity and downstream purification. The vinyl group on tributyl(vinyl)tin introduces a greater degree of versatility for C–C bond building. While triphenyltin and similar products excel elsewhere—such as in polymer stabilizers or agricultural biocides—they lack the functional flexibility of this compound during direct synthetic modification of aromatic rings. Our experience, alongside customer case studies shared directly in our QC meetings, points to fewer headaches and real savings once switching to this product.

    Many newer producers enter the market with scaled-up organotin products targeting bulk segments, prioritizing throughput over precision. This shift often results in inconsistent performance. As we’ve learned, the difference emerges not during procurement, but as the product enters the reaction flask—where reagent stability, transfer reactivity, and side reactions matter more than marketing promises.

    Real Challenges—And How We Overcame Them in the Plant

    Tributyl(Vinyl)Tin production presented early hurdles. Not every raw material supplier met our expectations. At times, minor shifts in butyl chloride or vinyl halide source placed entire batches in jeopardy. Some years back, a newly sourced vinyl halide—advertised as comparable—introduced trace metals that contaminated the stannane, triggering downstream failures in pharmaceutical syntheses.

    To solve these headaches, our team reinforced batch sampling and broadened analytical screens. Every incoming raw is checked beyond supplier COA claims. We realized over time that the integrity of this compound starts far upstream. So we keep close working relationships with feedstock suppliers. Where possible, we backwards-trace raw materials—sometimes well beyond what regulations request, driven by hands-on necessity more than compliance.

    Further down the line, we automated distillation cut controls in-house. The result: colorless, stable product regardless of feed fluctuation. Our spectroscopist tracks each batch using state-of-the-art NMR and trace metal analysis so that our customers never deal with unwelcome surprises. These routines didn’t arise from regulatory pressure, but from dozens of batch failures that cost us plenty in time, materials, and reputation over the years.

    Supporting User Processes—From Synthesis to Waste Stream

    Every buyer of organotins faces the tough questions of waste management and regulatory scrutiny. As manufacturers, we don’t look away from these issues. Our labs spend significant time mapping out product fate in user settings. Tributyl(Vinyl)Tin, like most organotins, demands care in both process design and post-synthesis cleanup.

    Several years back, one customer flagged compliance risks after transitioning from trialkyl homologues—a reminder that downstream regulatory requirements keep evolving. Our technical support teams guide users with insights from our real-world application lab, providing first-hand data on decomposition, side-reaction profiles, and workup strategies. This hands-on know-how allows users to clear hurdles before they escalate to larger process or compliance headaches.

    We also monitor active legislation targeting organotin compounds. Given tightening limits in waste water and workplace standards worldwide, we roll out in-house improvements—like enhanced vapor recovery and solvent recycling—long before directives land on the local regulator’s desk. This isn’t about ticking boxes; it reflects the practical realities of working every week with these substances and wanting to future-proof both our output and user safety.

    Looking Forward—Engineering Value Beyond a Single Molecule

    Every year, new methods surface in synthetic chemistry journals. New ligands, advanced catalysts, green alternatives all vie for attention. Still, Tributyl(Vinyl)Tin keeps a firm place in the toolkit of many advanced material and pharmaceutical producers. The reliability of this molecule, built on the steel and glassware of our factory, is more than tradition. It evolves as user needs shift and as regulatory standards rise.

    Our technical team works directly with some of the largest R&D labs in the world. From one-off gram-scale evaluations to multi-ton runs, our focus lands on proactive problem-solving rather than simple order fulfillment. Every new project is a chance to test the resilience of our process and learn where both chemistry and operations can move next. Every failed coupling, every flagged impurity, pushes us to keep refining—not just the product, but its broader lifecycle.

    Why Direct Dialogue with Manufacturers Still Matters

    Modern markets overflow with intermediaries: traders, brokers, anonymous resellers with similar claims. Over decades, though, producers and users at the sharp edge of chemistry learn the importance of direct dialogue. Every time a downstream user consults with us about process hiccups—yellowing in polymer runs, trace impurities causing downstream polymer failure—they gain from the hundreds of trials, errors, and insights that only come from manufacturing every batch in-house.

    Some clients return, year after year, with new challenges. The specificity of questions grows deeper, reflecting a familiarity with both the molecule and the people behind it. We’ve spent late evenings troubleshooting purification tedium, adjusting shipping protocols in response to weather delays, and tweaking storage guidelines to meet GMP requirements. These problems and solutions rarely fit neatly into a typical product data sheet, but make the difference in actual production fidelity.

    Continuous Improvement—A Way of Work, Not a Slogan

    The chemical sector rewards those willing to revisit old assumptions. Our process for manufacturing Tributyl(Vinyl)Tin shifts incrementally with each batch, guided by post-market feedback, upstream improvements, and advances in both process control and analytical scrutiny. Our workflow never sits still.

    One year, we identified recurring issues with moisture content during winter; our response wasn’t a one-time fix, but a full overhaul of raw material pre-drying. Another season, a run of inconsistent product color led us to reformulate our filtration steps and audit every piece of glassware. Incremental changes, often based on after-hours feedback from industrial users and in-plant engineers, ensure that we honor every commitment made at the order desk with results on the plant floor.

    From Our Factory to Your Reaction

    Tributyl(Vinyl)Tin exists for us not as a bulk good, but as a sequence of real decisions, batch tests, and working stories. As manufacturers, our knowledge doesn’t rest in abstract purity guarantees; it comes from the hands-on reality of synthesizing this organotin, batch after batch, every season. For the users out there—whether facing routine syntheses or pushing into new chemical territory—our production floor remains as open to feedback and collaboration as it did decades ago. The chemistry grows stronger, safer, and more predictable with every cycle, and we look forward to seeing this molecule enable even more ambitious chemistry in years ahead.