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Tetrahydrofurfuryl Acrylate

    • Product Name Tetrahydrofurfuryl Acrylate
    • Alias THFA
    • Einecs 257-743-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    107589

    Cas Number 2399-48-6
    Molecular Formula C8H12O3
    Molecular Weight 156.18 g/mol
    Appearance Colorless to pale yellow liquid
    Odor Mild characteristic odor
    Boiling Point 90-92°C at 13 mmHg
    Density 1.10 g/cm3 at 25°C
    Refractive Index 1.448-1.451 at 20°C
    Flash Point 107°C (Closed cup)
    Solubility Miscible with most organic solvents; slightly soluble in water
    Purity Typically ≥ 98%
    Storage Temperature Store at 2-8°C, protected from light and moisture

    As an accredited Tetrahydrofurfuryl Acrylate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Tetrahydrofurfuryl Acrylate is packaged in a 25-liter blue HDPE drum with tamper-evident seal and clear hazard labeling.
    Shipping Tetrahydrofurfuryl Acrylate is shipped in tightly sealed, corrosion-resistant containers to prevent leakage and moisture ingress. It should be stored and transported in a cool, well-ventilated area, away from heat, ignition sources, and incompatible substances. Standard shipping regulations classify it as a hazardous material due to its flammability and potential health hazards.
    Storage Tetrahydrofurfuryl Acrylate should be stored in a cool, dry, well-ventilated area away from heat, ignition sources, and direct sunlight. Keep the container tightly closed and away from incompatible materials such as oxidizers, acids, and bases. Store in approved, labeled containers and protect from moisture. Proper grounding and bonding are essential to prevent static discharge during handling and storage.
    Application of Tetrahydrofurfuryl Acrylate

    Applications of Tetrahydrofurfuryl Acrylate in Industrial Manufacturing

    Tetrahydrofurfuryl Acrylate (THFA) is a specialty monomer valued for its reactivity, hydrophilicity, and low volatility, supporting performance and processing advantages in selected high-performance coatings, adhesives, inks, and specialty polymer applications. As the actual manufacturer, we support process engineers and formulation chemists with application-focused expertise and technical transparency for compliant, efficient downstream integration.

    1. UV-Curable Industrial Coatings

    Formulators use THFA as a reactive diluent to enhance flexibility and reduce VOC content in UV-cured coatings for wood, plastics, and metal substrates. Its molecular structure provides a balance of hardness and elongation, supporting abrasion and chemical resistance required in demanding end uses. Its compatibility allows technicians to fine-tune viscosity in high-solid UV systems, aligning with sustainability targets and rapid curing processes.

    Industry compliance standards

    • REACH (EC) No. 1907/2006
    • EN 71-3:2019 (Safety of Toys - Migration of certain elements, relevant to furniture coatings)
    • RoHS Directive 2011/65/EU (Restriction of Hazardous Substances)
    • ISO 16000-9 (Indoor Air VOC Emission Requirements)

    Typical usage ratio

    • 8%–20% of total monomer content; higher ratios for flexibility, lower for hard coat requirements. Adjustments based on viscosity target and reactivity needed for cure speed.

    Downstream process integration

    • Blend into oligomer and monomer phase during pre-mix; incorporate before photoinitiator addition; disperse under nitrogen or inert gas to avoid premature polymerization; filter prior to UV curing application (roller, spray, or curtain coaters).

    Final product types

    • Floor varnishes for wood and parquet
    • Industrial metal clear coats
    • Plastic component topcoats (e.g., electronics casings)
    • Decorative and protective finishes for engineered wood

    2. Acrylate-Based Pressure-Sensitive Adhesives

    THFA serves as a functional monomer incorporated in the synthesis of acrylic pressure-sensitive adhesives (PSA), promoting cohesive strength and humidity resistance. Its contribution to polymer backbone flexibility and tack properties ensures high-performance bonding on both polar and non-polar surfaces, enhancing label retention and tape durability in diverse environments, including automotive and electronics assembly.

    Industry compliance standards

    • FDA 21 CFR 175.105 (Adhesives for indirect food contact, for compliant product types)
    • ISO 9001:2015 (Quality Management for adhesives manufacturing)
    • ISO 8510-1&2 (Adhesives - Peel strength testing)
    • ASTM D3330 (Peel adhesion testing of PSAs)

    Typical usage ratio

    • 2%–10% of the acrylate monomer blend depending on flexibility and tack requirements. Higher ranges in tapes exposed to low-temperature environments or requiring water resistance.

    Downstream process integration

    • Co-polymerize with main backbone monomers (e.g., n-butyl acrylate, 2-ethylhexyl acrylate) via emulsion or solution polymerization; introduce during the charge-in phase alongside surfactants and initiators; monitor polymerization kinetics and adjust pH to optimize conversion.

    Final product types

    • Label stock adhesives (permanent and removable)
    • Double-sided industrial tapes
    • Protective films for electronic displays
    • Circuit assembly masking tapes

    3. Printing Ink Binders (UV and Waterborne Systems)

    Manufacturers employ THFA in the production of UV- and waterborne acrylic ink binders to improve pigment dispersion, gloss retention, and substrate adhesion in packaging and commercial printing. Its hydrophilic character aids in formulating low-migration inks for food and pharmaceutical packaging, where balanced flexibility and safety compliance are essential.

    Industry compliance standards

    • EuPIA Exclusion Policy for Printing Inks
    • Swiss Ordinance SR 817.023.21 (Printing inks for food packaging)
    • EC Regulation No. 1935/2004 (Materials and articles intended for food contact)
    • ISO 2846-1 (Color and binder specifications)

    Typical usage ratio

    • 3%–12% of binder formulation; increased proportion in inks for flexible packaging, lower for rigid substrate inks. Formulator determines level based on flow and curing profile.

    Downstream process integration

    • Add to acrylate/oligomer backbone during binder synthesis or pigment pre-dispersion; combine prior to emulsification or UV-curable monomer addition; verify pigment wetting and crosslink density before final letdown.

    Final product types

    • Flexographic and gravure packaging inks
    • Low-odor food wrap inks
    • Coldset label and security printing inks
    • Pharmaceutical blister pack overprint varnishes

    4. Specialty Acrylic Polymers for Waterborne Floor Sealers

    THFA acts as a key monomer introducing hydrophilicity and toughening in the synthesis of high-solids waterborne acrylic polymers utilized in floor sealers and heavy-duty finishes. Its chemical structure enhances the coalescence properties while maintaining film clarity and resistance to black heel mark and scrub cycles in commercial and institutional applications, responding to environmental and indoor air quality demands.

    Industry compliance standards

    • Green Seal GS-11 (Environmental standards for paints and coatings)
    • LEED v4 (Low-emitting materials requirements, for finished sealers used indoors)
    • ISO 11998 (Determination of wet-scrub resistance)
    • ASTM D2486 (Scrub resistance of wall paints)

    Typical usage ratio

    • 5%–15% by weight of the total monomer feed. Higher end of range supports enhanced water-resistance and flow; adjusted according to the desired level of film flexibility and performance testing protocol.

    Downstream process integration

    • Introduce into pre-emulsion or seed latex phase of acrylic polymerization; co-polymerize with methyl methacrylate, butyl acrylate, and crosslinker under controlled temperature; integrate in bead-mill pigment grind if additional flow is desired.

    Final product types

    • Commercial wood and laminate floor polishes
    • High-traffic polyurethane-acrylic hybrid sealers
    • Concrete surface waterborne finishes
    • Slip-resistant floor coatings for healthcare and education facilities

    5. Radiation-Curable Fiber Optic Cable Coatings

    Specialty formulators select THFA for use in acrylate-based UV-curable coating systems shielding optical fiber cores. Its chemical structure contributes to low modulus and high adhesion, addressing micro-bend performance and solvent resistance requirements during optical cable manufacturing and subsequent cable drawing processes. THFA maintains process window for rapid UV cure under high line speed, supporting throughput targets in fiber cable plants.

    Industry compliance standards

    • Telcordia GR-20-CORE (Generic requirements for optical fiber and cable)
    • IEC 60794-1-2 (Cable test procedures for mechanical and environmental properties)
    • ISO 9001:2015 (Process quality for cable production)
    • RoHS Directive 2011/65/EU (for coated cable products)

    Typical usage ratio

    • 12%–25% in primary and secondary coating formulations, with proportion tailored based on modulus, adhesion to glass, and cure speed optimization; higher amounts in soft tube and buffer coatings.

    Downstream process integration

    • Blend into acrylate oligomer premix before photoinitiator; apply directly via die coating to fiber during draw process; instant UV cure post-application on continuous draw lines; check crosslink density and transmission loss post-cure.

    Final product types

    • Core and cladding coatings for single-mode and multi-mode fiber
    • Primary and secondary fiber buffer coatings
    • UV-cured jacketing for high-speed telecom cables
    • Specialty data and sensor fiber cable coatings
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    Certification & Compliance
    More Introduction

    Tetrahydrofurfuryl Acrylate: A Closer Look From the Manufacturing Floor

    An Insider’s Introduction to THFA

    We have spent years working hands-on with Tetrahydrofurfuryl Acrylate, and few chemicals have shaped our workshop quite like this one. Known among our team as THFA, this specialty acrylate with the formula C9H12O3 finds its main place in advanced coatings, adhesives, and polymerizations. We see requests ramp up every season from partners building UV-curable coatings and inks, who demand a product that can take on high-performance jobs where standard acrylates break under pressure. The product we send out never leaves our doors until it matches strict tests for purity, color, and reactivity.

    Getting Down to Quality and Model

    Our Tetrahydrofurfuryl Acrylate runs under the model THFA-98, signifying a minimum purity of 98%. We keep color less than 50 APHA in every batch. Moisture level stays below 0.1%. Sometimes customers ask why these details matter if other acrylates contain similar basic groups. In our experience, customers working with UV formulations come to regret any cut in purity. Even slight contaminants or higher water levels can slow reaction rates or leave unwanted by-products in the cured matrix. We retain lab analysis records going years back showing that even small upticks in acidity or color change the final gloss and adhesion profile of a coating, especially under challenging sunlight or vibration.

    Why Formulators Keep Coming Back to THFA

    Our applications team on the production line gets calls from formulators in coatings, adhesives, and specialty paints. Some days, adhesive specialists working on glass and metal assembly projects track us down for THFA because of its flexible molecule. After discussions with technicians on their end, we often hear a common pattern: where typical acrylates offer a brittle, rigid film, Tetrahydrofurfuryl Acrylate adds elasticity and impact resilience.

    The ring structure in our THFA model unlocks superior compatibility with both polar and non-polar monomers. Epoxy acrylate and urethane acrylate systems gain impressive results for weathering and heat resistance when mixed with our product. We have watched teams in flooring applications solve adhesion failures on unusual substrates by simply adding 15% THFA to their usual blends. That brings improvements in both flexibility and adhesion, along with reduced risk of yellowing after prolonged UV exposure.

    Differences from Standard Acrylates: Experience at Scale

    Many incoming customers have years with butyl acrylate, methyl methacrylate, or hydroxyethyl acrylate. From the process side, the switch to THFA brings familiarities and surprises. Handling characteristics are close – clear liquid, mild odor, typical acrylate viscosity. Differences emerge once the reaction runs. Where traditional acrylates give a hard, sometimes glassy product, THFA’s unique structure provides a softer, tougher cured layer and superior adhesion to metals and engineering plastics.

    Many of our clients in the 3D printing sector have reported that swapping in THFA in photopolymer formulations delivers better print accuracy and reduced warping under stress. The difference comes down to molecular structure: the tetrahydrofurfuryl ring softens internal stresses and adds resilience at a molecular level. We work closely with formulators to dial in an optimal balance, and the results lead to smoother, longer-lasting parts.

    Our View on Reliable Production

    Quality control is not a catchphrase in our plant. Team members oversee every step, from distillation to storage of raw THF-derived feedstock. Over the years, we have upgraded our distillation columns to pull residual aldehyde and water below threshold levels, since even a small departure can change how the acrylate crosslinks. Storage drums remain inert, and shipment happens under nitrogen blanket as standard. Our shipping crew notes that THFA needs gentle handling, but it transports and flows much like conventional acrylates, so customers with regular handling protocols never face equipment surprises.

    Practical Use: What Actually Works in the Real World

    Our partners often push THFA harder than conventional monomers, stretching it across solventless and solvent-based chemistries. Large-scale UV-curing facilities like it because the product flows well at room temperature and reacts quickly under mercury or LED lighting. It slots perfectly into existing lines for paints, inks, flooring systems, and fiber-reinforced plastics. From personal visits to customer plants, we see setups ranging from roll-to-roll paper coating lines to small batch operations making artisanal adhesives. Teams working with reactive hot-melt adhesives come back telling us that THFA’s low glass transition temp keeps finished products from turning brittle in winter climates.

    In some high-end architectural coatings, researchers collaborate directly with us to chase zero-VOC goals and meet updated indoor air quality standards. THFA’s low volatility fits right into those requirements, with less worker exposure than more traditional acrylate monomers. In these projects, our THFA forms the backbone for high-durability waterborne resins with almost no trade-off on viscosity or cure speed.

    Performance Under Pressure: Stress, UV, and Moisture

    Real life can make or break any material. We often run weathering trials in partnership with test centers. Over an 18-month trial in a South China test yard, THFA-containing coatings resisted chalking and loss of adhesion under salt spray and subtropical sun, outliving standard BA/HEA mixes by several seasons. Our on-site researchers followed gloss and adhesion data and made repeated field visits. No desk-bound analysis beats seeing panels up on a roof in a monsoon, holding color and grip.

    The molecular structure allows the finished resin to breathe and flex with temperature shifts, while resisting whitening or gross yellowing—pain points we encountered often in the early days with methacrylate-based coatings. Automotive suppliers from Germany and the United States now turn to us for custom resin packages designed around THFA, chasing resilience under engine heat, oil splash, and freeze-thaw cycles. On their test benches, our blends stayed intact after months of engine exposure where standard acrylate films began crazing and delaminating.

    Balancing Cost and Benefit: A Manufacturer’s Perspective

    Customers rightly ask about cost-per-kilo, and our approach stands out for keeping overheads low and value high. THFA is more involved to make than common linear acrylates, owing to its ring structure and the need to watch purity and storage. Buyers using our THFA for years balance this by pointing to the reduced scrap rate, fewer product recalls, and less downtime from coating failure. In some flooring installations, we have seen lifetime extension of 3-4 years versus a standard BA/HEA base—worth more than the incremental cost.

    We take pride in repeat orders from OEMs and specialty resin formulators. They build their budgets on the fact that THFA blends last longer and save on labor or warranty costs down the road. That difference has proven itself beyond the lab, in the hands of our clients who have run side-by-side field trials.

    Meeting the Needs of the Present: Sustainability and Safety

    Over the last decade, regulatory demands have shifted. Our chemists have retooled processes to reduce residuals at source, and THFA aligns well with expectations for low-tox, high-performance building blocks. Customers integrating THFA into flooring and interior products benefit from a VOC profile lower than traditional acrylates, giving them an edge in bids for schools and hospitals.

    We follow developments from global bodies on monomer toxicity and manufacture our THFA to align with strict guidelines. Our investment in storage and transport limits worker exposure and supports safer downstream handling. Regular audits and process upgrades keep us ahead. Large buyers tour our site annually, and their feedback informs our next steps.

    Production Experience: Lessons from the Line

    We started with small reactors, batching a ton per week, and scaled up after seeing solid demand from coatings companies and adhesive houses. Most production challenges have centered on protecting the acrylate double bond during synthesis—without aggressive purification and stable temperatures, unwanted polymerization shuts down yield. We added double-scrubbers and batch-specific peroxide inhibitors to cut that risk.

    Operators keep careful control records. Every time we tweak a process, such as trying a new catalytic system or adjusting feed temperature, we run pilot batches and test finished material in-house. Lowering the moisture content gains us performance up the line—smaller surface bubbles, stronger interlayer adhesion. We pass those findings directly to our larger customers so they see real-world gains.

    Supporting Formulators: Living the Details

    We employ a technical support staff who have run production lines themselves. Their feedback often drives our process choices. Calls come in about blending, side reactions, polymerization speed, and cure uniformity. Technical workshops on our site help clients solve formulation hurdles. Our role extends past shipping from the warehouse—we spend days troubleshooting with chemists and line supervisors when a formulation changeover or a new substrate challenge arises.

    Success has come through sharing case studies and hands-on troubleshooting, not handing out generic specification sheets. We help set up equipment to handle THFA safely, avoiding exposure and minimizing evaporative losses through correct blanketing and temperature control. We listen for bottlenecks in downstream mixing, flow, or UV cure, suggesting tweaks that cut rejection and boost throughput.

    Case Examples: THFA in Action

    Our coatings team recently worked with a wood-finish specialist striking out in the Chinese high-end furniture market. Their prior formulations cracked and turned cloudy after export to a humid Southeast Asian climate. By redesigning with THFA, they shipped batches that kept their original gloss through humidity swings, earning expanded orders and less warranty claim volume.

    In another case, an electronics potting resin supplier struggled to balance flexibility and dielectric strength. Incorporating THFA solved premature cracking and improved electrical insulation under repeated flexing, without giving up cure speed. Customers stayed with the new product after independent test centers validated its long-term durability.

    During the early days of the pandemic, a soap dispenser OEM found themselves in a scramble, needing rapidly cured and durable coatings that resisted the constant chemical attack of sanitizers. Their prior base fell apart after repeated exposure. Our THFA-based UV-curable system sailed through the trials, keeping the finish clear and tough under alcohol sprays. Such feedback continues to guide our product evolution.

    The Future of Tetrahydrofurfuryl Acrylate: What We Are Learning

    Research in functional polymers puts pressure on us to innovate beyond commodity layouts. We work with partners in additive manufacturing, medical adhesives, and flexible electronics to push the boundaries of what THFA can do. Lab teams tell us the unique ring structure opens up crosslinking paths not possible with methyl acrylate or butyl acrylate. Development work in biocompatible coatings and smart hydrogels uses THFA as a critical monomer for backbone flexibility and tunable swelling—far from everyday paints and coatings.

    THFA stands out in these high-spec sectors for its ability to bridge the rigid and flexible, and for its performance in both clarity and resistance to yellowing. Our lab team continues to publish results from in-progress work using THFA in specialty membranes and waterborne dispersions. The potential extends into greener manufacturing, as THFA allows more effective resin systems without traditional solvents or plasticizers.

    Challenges and Solutions: The Manufacturer’s Side

    We see ongoing challenges in sourcing consistent feedstocks, maintaining batch purity, and supporting evolving safety standards. Solutions come from tighter upstream vetting, more robust in-process analysis, and field feedback from downstream users. Our investments in process automation and analytics have trimmed variation and improved reliability.

    We face requests for ever-greater customization, and we respond by adding capability rather than squeezing customers into one mold. Some need THFA with even tighter moisture or acidity specs; others require custom packaging or inhibitor tweaks for local conditions. By making these changes at our end, we spare our customers reengineering costs and keep the supply chain smooth.

    Conclusion: Built on Practical Experience

    Our manufacturing crew sees Tetrahydrofurfuryl Acrylate not as a commodity, but as a specialty tool that makes high-performance coatings, adhesives, and resins possible. Every drum that leaves here carries years of attention to detail, hard-won improvements, and close ties with the technologists who build better products. Whether you operate a large-scale UV-curable coating line or an innovation lab running new blends, THFA offers a unique route to performance and reliability, proven through rigorous testing and real-world feedback.