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Tetraallyltin

    • Product Name Tetraallyltin
    • Alias TAS
    • Einecs 215-694-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    193357

    Chemical Name Tetraallyltin
    Molecular Formula C12H20Sn
    Molar Mass 323.00 g/mol
    Cas Number 2143-19-5
    Appearance Colorless to pale yellow liquid
    Density 1.22 g/cm³
    Boiling Point 135 °C at 1 mmHg
    Melting Point -80 °C (approximate)
    Solubility Insoluble in water, soluble in organic solvents
    Refractive Index 1.536
    Pubchem Cid 66235
    Structure Sn(CH2CH=CH2)4
    Synonyms Tetraprop-2-enyltin, Tetraallyl tin

    As an accredited Tetraallyltin factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Tetraallyltin is packaged in a 500 mL amber glass bottle, sealed, labeled with hazard symbols, and secured in protective cushioning.
    Shipping Tetraallyltin should be shipped in tightly sealed containers, protected from moisture and incompatible substances. It is classified as a hazardous material and must be handled according to relevant regulations (UN number 3281, Class 6.1 toxic substance). Transport in well-ventilated vehicles, with appropriate labeling and documentation, ensuring compliance with local and international shipping standards.
    Storage Tetraallyltin should be stored in a tightly sealed container under an inert atmosphere, such as nitrogen or argon, to prevent oxidation and hydrolysis. Keep it in a cool, dry, well-ventilated area away from heat sources, ignition sources, and incompatible materials like acids or oxidizing agents. Store in accordance with relevant chemical safety guidelines, avoiding exposure to moisture and direct sunlight.
    Application of Tetraallyltin

    Applications of Tetraallyltin in Industrial Manufacturing

    Tetraallyltin is a specialty organotin compound manufactured in high purity for catalyst, polymer, and specialty chemical producers. Below, we detail its established roles in downstream processing, focusing on authentic industrial use cases across several value chains. Each scenario addresses industry compliance, dosage, process positioning, and key finished product types relevant to today’s global markets.

    1. Organotin Catalysts in Polyurethane Production

    As a raw material for organotin catalysts, tetraallyltin is applied in synthesizing stannous and organotin derivatives used to accelerate the production of flexible, rigid, and microcellular polyurethane foams. Downstream manufacturers introduce it during catalyst synthesis, controlling reactivity profiles for product consistency in mass and continuous processes. The purity and reactivity of the material must align tightly with manufacturing specifications to avoid side reactions impacting molding and expansion characteristics. Careful dosing based on polyol and isocyanate ratios delivers fine-tuned curing behavior in product lines ranging from insulation panels to automotive seats.

    Industry compliance standards

    • ISO 9001 Quality Management Systems
    • REACH (EC) No 1907/2006 Registration for catalyst components
    • UL 94 Flammability Standards for foam products
    • EN 14315-1:2013 for thermal insulation products

    Typical usage ratio

    • 0.05%–0.2% by weight in catalyst formulation, further diluted to 0.001%–0.03% in final polyurethane resin depending on required polymerization speed and product density

    Downstream process integration

    • Added to the catalyst manufacturing stage, then introduced into polyurethane resin blending and foaming operations

    Final product types

    • Flexible and rigid polyurethane foams for automotive interiors
    • Thermal and acoustic insulation boards
    • Furniture cushioning
    • Structural foam cores for construction

    2. Crosslinking Agent in Silicone Rubber Manufacturing

    Tetraallyltin serves as a crosslinking intermediate for specialty silicone elastomers and RTV (room-temperature vulcanizing) rubbers. In this sector, its allyl functionalities promote efficient bridging between polysiloxane backbones under controlled addition. Downstream production relies on precise mixing times and homogeneous dispersal to achieve desired tensile strength and elongation without compromising transparency or flexibility. The input proportion typically requires recalibration based on molecular weight distributions of silicone precursors and customer-specified mechanical properties.

    Industry compliance standards

    • FDA 21 CFR 177.2600 for rubber articles for repeated use
    • RoHS Directive 2011/65/EU for restrict substances
    • ASTM D412 for vulcanized rubber tensile properties
    • ISO 10993 biological evaluation for medical silicones

    Typical usage ratio

    • 0.2%–0.6% by weight in silicone rubber compounds; adjustments based on desired network density and processing parameters

    Downstream process integration

    • Generally incorporated during the silicone polymer compounding stage before curing, either batch-wise or via continuous kneading/extrusion

    Final product types

    • RTV and HTV silicone gasket materials
    • Food-grade sealing rings
    • Medical device housing and tubing
    • Automotive silicone elastomeric components

    3. Functional Intermediate for Specialty Polymer Synthesis

    Leading polymer manufacturers employ tetraallyltin as a structure-directing agent or reactive intermediate in synthesizing organotin-modified polymers and copolymers. It facilitates the introduction of tin centers and allylic branching in specialty plastics for electronic encapsulation or advanced coatings. Integration occurs under controlled temperature and inert atmosphere to manage tin-oxygen/crosslink formation and ensure consistent electrical properties in final polymers. Stringent quantitative control influences molecular weight, solubility, and dielectric strength, especially in applications demanding long-term electrical reliability.

    Industry compliance standards

    • IEC 60695-11-10 Fire Hazard Testing for plastics
    • RoHS and WEEE guidelines for electronic materials
    • UL 746B Polymeric materials test methods
    • ISO 1043-1 Polymer base resin characterization

    Typical usage ratio

    • 0.1%–0.5% by weight in polymerization feed, with final loading tailored to electrical or mechanical property targets

    Downstream process integration

    • Metered addition during in-reactor polymerization, or late-stage post-polymer modification with specialized organotin reactants

    Final product types

    • Electronic encapsulant resins
    • High-performance anti-corrosive coatings
    • Specialty engineering copolymers
    • Industrial adhesive films with organometallic functionality

    4. Intermediate for Agrochemical Formulations

    In agrochemical active ingredient synthesis, tetraallyltin acts as a functionalized tin transfer reagent to introduce organotin motifs into biocidal molecules or synthetic intermediates. It is applied in strictly controlled batch syntheses, with all processing steps occurring in closed systems to avoid organotin emissions or contamination. The exact charge based on the stoichiometry of desired agrochemical derivatives ensures efficient use without excess tin content, aligning with global regulatory limits for residual tin in crop protection agents. This material is cleared for use only where local and international guidelines permit organotin intermediates in synthesis but not as direct actives.

    Industry compliance standards

    • FAO/WHO JMPR Guidelines for agrochemical manufacturing
    • Regulation (EC) No 1107/2009 on plant protection product approval
    • China GB 2763-2023 (Maximum Residue Limits)
    • OECD Good Laboratory Practice (GLP)

    Typical usage ratio

    • 0.05–0.15 equivalents relative to the active ingredient backbone, with charge adjusted by mole-to-mole conversion targeting minimal tin residues

    Downstream process integration

    • Fed into controlled organotin coupling or allylation stages during fine chemical synthesis of agrochemical active or intermediates

    Final product types

    • Organotin-derived fungicide intermediates
    • Fine chemical building blocks for pesticide actives
    • Precursor stock solutions for downstream biocidal synthesis

    5. Precursor for Organotin-Stabilized PVC Additives

    PVC processor supply chains use tetraallyltin as a precursor material for synthesizing organotin-based stabilizers, which protect polyvinyl chloride against thermal and UV degradation during compounding and molding. These stabilizer intermediates find application in wire insulation, transparent sheets, and potable water pipe systems where both clarity and stability are mandatory. The downstream synthesis step typically involves controlled reaction with mercaptans or carboxylic acids, delivering stabilizers with tightly regulated tin content and compatibility. Formulation engineers specify feed ratios according to the stabilizer’s final dose in PVC, which varies with finished product requirements and compliance obligations.

    Industry compliance standards

    • EN ISO 9001 for stabilizer manufacturing
    • EN 61010-1 for safety in electrical PVC components
    • ANSI/NSF 61 for organotin additives in potable water contact materials
    • REACH Annex XVII organotin restrictions

    Typical usage ratio

    • 0.05%–0.3% in stabilizer intermediate synthesis, corresponding to 0.5–2.5 parts per hundred resin (phr) in final PVC compounds; adjustment depends on end-use exposure rating

    Downstream process integration

    • Reacted during synthesis of mercapto-organotin stabilizers, which are then dosed into PVC compounding blends before extrusion or molding

    Final product types

    • Clear and flexible PVC sheets
    • Potable water pipe linings
    • Insulated wire and cable coatings
    • Technical films requiring heat and light stability
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    Certification & Compliance
    More Introduction

    Tetraallyltin: A Look Inside Our Process and Product Value

    Those of us in chemical manufacturing know what it takes to bring a specialty organotin into the world—not just in terms of formula but also attention to detail. Tetraallyltin has become essential on benches and in lines where selectivity and reactivity drive progress. From our side, handling Tetraallyltin stands out not just because it’s a rare organotin, but because its unique structure delivers performance few others match. We’ve put in the hours, faced the practical challenges, and scaled up with both safety and outcome front-of-mind.

    The Chemical Model

    Tetraallyltin stands tall as a fourfold-allyl substituted tin compound. Each atom of tin bonds to four allyl groups, giving it a distinctive molecular framework: Sn(C3H5)4. No other tin derivative we produce shows this precise arrangement, and that matters for both reactivity and control. In labs, workers often choose Tetraallyltin for reactions where those distinct allyl groups do the heavy lifting—either as transfer agents or to generate tailored organometallic complexes.

    Our batches of Tetraallyltin display excellent purity levels that we regularly confirm by both gas chromatography and NMR. Typical purity exceeds 98%. Specifications like density and boiling point hold steady too. From an appearance perspective, it comes out as a colorless to light yellow liquid, humidity-sensitive and with a characteristic odor. Colleagues value how consistent our finished product remains between runs—a result of our focus on inert atmosphere synthesis and controlled storage.

    Understanding the Applications

    There’s no question about the role Tetraallyltin plays in organic synthesis, industrial catalyst systems, and the development of new materials. Its standout value shows up where selective tin-allyl transfer opens up possibilities. Polymer chemists put it to work forming novel tin-containing polymers. Synthetic researchers rely on its predictable reactivity in the preparation of metal-organic frameworks, or for introducing allyl groups with precision in cross-coupling reactions. Few other tin reagents match its flexibility for these niche but essential processes.

    We often consult with end users who require this compound at varying scales. In silicone and rubber industries, catalysis applications depend on its ability to participate in coupling and cross-linking processes. Its performance as a precursor stands apart, especially where other tin compounds trigger side reactions or don’t release allyl moieties as cleanly. The demands of pharma and electronics routes—where compound purity and structure bear heavily on end use—have shaped the way we produce and handle Tetraallyltin in our plant, from the storage drum to the line transfer connection.

    Safety and Material Handling Insights

    Having worked with a wide range of organotins, we appreciate the respect they command in daily use. In our experience, Tetraallyltin’s volatility and moisture-sensitivity call for special handling. All filling, sampling, and drumming takes place under nitrogen. Our storage tanks steer clear of air and water—one stray leak and you’re looking at rapid hydrolysis. We encourage customers to use compatible PTFE-lined closures and to store containers away from heat or sunlight. Every facility gets explicit guidance from our technical team before their first order.

    Don’t overlook the importance of well-ventilated transfer spaces and personal protective measures. We learned this the hard way years ago as we scaled from bench to pilot: early errors showed how even small vapor escapes could lead to strong tin odors and persistent residue. Each packing—whether in steel drums, ampoules, or stainless kegs—shows deliberate care, since exposure to air rapidly degrades it and erodes the value our clients count on. We’ve adjusted workflows, introduced better vessel purging, and created procedures that help both us and our customers avoid unnecessary downtime or loss.

    How Tetraallyltin Differs from Related Organotins

    The tin world is broad. We work with all sorts—from tetramethyltin to tributyltin derivatives. Tetraallyltin is unique not just for its structure but for its chemical behavior. Many other tin organics remain stable in air and show less reactivity. Our Tetraallyltin offers a balance: it delivers active allyl groups but refuses to linger unreacted. For researchers, that means less risk of unintended tin contamination and more control over conversion rates. In polymer chemistry, where alternative tin-based agents like tin octoate or dialkyltins often struggle with side chain migration or poor activation, Tetraallyltin remains predictable throughout the process.

    We’ve seen formulators try other organotins for similar applications, only to return to us with reports of inferior product color, incomplete conversion, or variation in end properties. Structural differences drive these outcomes: the four available allyl groups in Tetraallyltin open new doors for selective reaction—especially compared to those with only two or three allyl sites. Customers in specialty elastomer and adhesives spaces report that substituting alternative tin sources almost always leads to loss of mechanical performance or increased processing times. This aligns with what we observe with routine batch testing and downstream trials.

    Production: Design, Consistency, and Challenges

    Scaling Tetraallyltin production remains a careful balance of art and science. From the earliest days, we faced hurdles uncommon with other organotins. Raw material purity matters more here than in butyltin production, since trace contaminants quickly poison the delicate tin-allyl bonds. Reaction times require close monitoring. Our engineers developed batch reactors equipped for thorough inert purging, jacketed control, and robust containment. Small tweaks in reaction temperature lead to visible differences in product color, so we keep continuous vigilance during every critical step.

    For years, we stuck by traditional distillation but have since adopted advanced fractionation setups. These let us separate side-products and delivers the lot-to-lot purity that downstream users depend on. We invested heavily in detection gear—GC-MS and multi-nuclear NMR—proving invaluable for rapid checkups and trouble-tracing if output ever drifts. Those who use our tetraallyltin receive not just a chemical, but the results of hundreds of hours of development and consecutive improvement. Our own R&D team works side-by-side with operations—an approach that’s paid off whenever a process adjustment is needed to hit a tighter product limit or meet a complex use-case for a loyal customer.

    Environmental Footprint and Waste Handling Lessons

    All organotins require diligence beyond just industrial performance. Disposal and environmental safety weigh on everyone’s mind in this industry. Learning from earlier decades, our facility upgraded all vent and liquid waste abatement for Tetraallyltin lines. Solvent and product residues see neutralization before any discharge; spent drums are handled as hazardous until cleared. Each batch run includes built-in waste capture streams, so operatives stay clear of exposed lines or uncontrolled vapor. City and national audits shaped not only our physical layout, but also our staff training and records. This focus helps assure both our team and our customers that compliance and safety underpin every shipment.

    We bring customers into the process: they receive material-by-material guidance about safe use and post-use treatment that follows both their local laws and our own experiences. The days of sending off universal advice ended long ago—each downstream workflow carries unique risks and requirements. We adapt advice to their processes, whether it’s a one-off R&D run or full-scale plant operation. No two bulk users face exactly the same risk profile, and our job remains to help them get the result without putting people or the environment at risk. Years in business have taught us to never take shortcuts—upstream mistakes only multiply costs and headaches down the line.

    What End Users Say: Working With Tetraallyltin in the Field

    The most useful feedback comes once Tetraallyltin hits production environments, not just test tubes. Over twenty years, feedback from production chemists, R&D managers, and plant operators guides how we handle the product. They value consistency above all. It’s common to hear that a plug-and-play approach leaves no surprises. Customers dedicated to continuous runs report minimal equipment fouling. When downtimes happen, it’s usually from mechanical issues outside of the chemical streams—a testament to the product’s dependability when handled right.

    We often support scale-up activities. Tetraallyltin moves from bench top testing into pilot plants, often with only minor changes. Our customers value early samples shipped for process risk evaluation; this “try before full order” support identifies compatibility issues before larger investments. Users have commented that switching from trial drum to isocontainer has proven smooth given our product’s batch-to-batch reliability. Any rare deviation gets corrected quickly—one feature that separates chemical manufacturers from resellers or distributors less in touch with process reality.

    Handling Issues and Solutions: Real Experiences

    Real manufacturing brings real challenges, and Tetraallyltin is no exception. Tank leaks, transfer system clogs, or contamination incidents demand rapid response. Our years in the field led us to install redundant level controls and deploy mobile vapor suppression equipment. During an emergency years ago, rapid drum passivation and secondary containment proved effective at protecting both assets and personnel. It came from preparedness, routine practice, and a willingness to review every incident for lessons. As a result, we adjusted bulk transfer methods and retrained workforce, preventing recurrence. Every real incident toughened our protocols and improved our partners’ comfort in handling the product themselves. Learning from accidents rather than ignoring them has become embedded in our company culture.

    The humidity-sensitive nature of Tetraallyltin led us to design snap-seal transfer lines and heated delivery systems, limiting moisture ingress regardless of weather conditions. Full traceability for each drum or container helps in identifying any sources of unusual impurity or degradation—much more efficient than the generic lot blending some competitors choose. The shift has saved our customers time and headache when troubleshooting batch deviations in their own process setups.

    Supporting Research and Industrial Evolution

    Our technical team keeps up with advances in both academic and industrial chemistry where Tetraallyltin finds new life. University labs push our product further into synthesis, seeking new compounds no other tin reacts with as easily. Collaborations with industrial customers have explored advanced cross-linking of thermoplastics or targeted modification of specialty rubbers. In each case, our product’s stability and reactivity play a direct part in making new materials with improved strength, thermal resistance, or electrical properties.

    Users in the electronics and pharmaceuticals space look for ever-tighter purity and documentation. We’ve stepped up by integrating in-line analytical checks, robust labeling, and digital batch tracking. Trace metals, water content, and volatile residue checks all contribute to the confidence our partners seek. These steps help unlock applications where a single contaminant could ruin an entire line or batch.

    Challenges In Sourcing Raw Materials

    Global events have increased hurdles for raw material logistics. In the past, steady supply chains meant little worry over base tin or allyl reagents. In recent years, shipping delays and export restrictions meant our procurement team needed backup sources and greater flexibility. Direct relationships with verified suppliers allow us to maintain stocks and avoid running our lines dry, even during tight markets. We never break continuity even if the cost of reserve inventories rises. Over decades, we learned that a missed shipment means lost customer trust — something far more costly than any temporary dip in profit margin.

    We also look out for impurities that sometimes crop up in raw materials. Even minor upstream slip-ups can lead to downstream headaches: off-color product, aberrant reaction behavior, or unplanned downtime. Careful incoming inspection and on-site testing give us control before raw materials ever see the reactor. These steps separate an experienced chemical manufacturer from those who merely blend, repackage, or sell on behalf of others—an important lesson for both us and our customers as specialization and complexity rise each year.

    Trust Built Over Time

    Few chemical stories involve such a blend of technical complexity and practical know-how. Our experience delivering Tetraallyltin in quantity has shaped our operational focus, safety mindset, and customer relationships. The trust customers place in our ability to deliver the right material—on time, on spec, with all risks and details disclosed—didn’t appear overnight. Years of honest feedback, open problem solving, and attention to what makes each plant or bench unique shaped how we work.

    We remain committed to ongoing improvement. Technical feedback, better process controls, and shared data all feed our drive to keep Tetraallyltin consistent and reliable. Real people worked to make every drum and sample safe, traceable, and up to spec before it went out the door. That’s the story behind every batch of Tetraallyltin we send out. Our team stands behind that with experience forged in every run, test, trial, and challenge along the way.