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Tert-Butyl 2-Fluoroacrylate

    • Product Name Tert-Butyl 2-Fluoroacrylate
    • Alias 2-Fluoroacrylic acid tert-butyl ester
    • Einecs 629-678-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales7@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    136069

    Product Name Tert-Butyl 2-Fluoroacrylate
    Cas Number 111128-12-2
    Molecular Formula C7H11FO2
    Molecular Weight 146.16 g/mol
    Appearance Colorless liquid
    Boiling Point 66 °C at 14 mmHg
    Density 1.025 g/mL at 25 °C
    Purity Typically ≥98%
    Synonyms 2-Fluoroacrylic acid tert-butyl ester
    Storage Conditions Store at 2-8 °C
    Refractive Index 1.420-1.424
    Smiles CC(C)(C)OC(=O)C=C(F)

    As an accredited Tert-Butyl 2-Fluoroacrylate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 250g amber glass bottle with a sealed cap, labeled “Tert-Butyl 2-Fluoroacrylate,” including hazard symbols and batch information.
    Shipping Tert-Butyl 2-Fluoroacrylate should be shipped in tightly sealed containers, protected from moisture, heat, and direct sunlight. It should be packed in accordance with hazardous material regulations, clearly labeled, and transported under appropriate temperature conditions. Ensure compliance with local, national, and international shipping guidelines for chemicals, including required documentation and safety data sheets.
    Storage Tert-Butyl 2-Fluoroacrylate should be stored in a tightly sealed container, away from moisture, heat, and direct sunlight. Keep it in a cool, well-ventilated area, separate from incompatible substances such as strong acids, bases, and oxidizers. Storage should ideally be at temperatures below 25°C to prevent polymerization or degradation. Use proper chemical storage protocols and ensure containers are appropriately labeled.
    Application of Tert-Butyl 2-Fluoroacrylate

    Applications of Tert-Butyl 2-Fluoroacrylate in Industrial Manufacturing

    Tert-Butyl 2-Fluoroacrylate serves as a specialized monomer for various industrial polymerization processes, contributing distinct chemical features to downstream products. As a manufacturer, we focus on supplying this high-purity acrylate monomer directly to sectors where its fluorinated and tert-butyl-modified backbone enables the creation of functional materials and end-products that meet demanding market and regulatory expectations.

    1. High-Performance UV-Curable Coatings

    Formulators in the coatings sector utilize Tert-Butyl 2-Fluoroacrylate to impart chemical resistance, low surface energy, and durability to UV-cured finishes used on electronics, automotive interior parts, and high-wear plastic components. Its unique structure enables UV-initiated copolymerization, boosting coating longevity and cleanability. Application rates depend on viscosity and adhesion targets for specific substrates.

    Industry compliance standards

    • ISO 12944 (Corrosion protection of steel structures by protective paint systems)
    • REACH Annex XVII and RoHS 2011/65/EU substance restrictions
    • DIN EN 71-3 (Safety of toys - migration of certain elements) for coated toy surfaces
    • US EPA VOC 40 CFR Part 59 (VOC limits for architectural coatings)

    Typical usage ratio

    • Usually incorporated at 1–6% w/w of total monomer mix, adjustable by resin reactivity, desired film properties, and end-use mechanical requirements.

    Downstream process integration

    • Added during prepolymer mixing before photoinitiator charging; dispersed thoroughly into acrylate base formulations ahead of UV exposure line.

    Final product types

    • UV-cured protective coatings for automotive panels
    • Scratch-resistant finishes on consumer electronics casings
    • High-gloss varnishes for cosmetic packaging
    • Touchscreen protective layers

    2. Specialty Pressure-Sensitive Adhesives

    Adhesive manufacturers integrate Tert-Butyl 2-Fluoroacrylate into their acrylate co-polymer blends to produce specialty tapes and label adhesives with improved humidity resistance, low peel forces, and minimal residue transfer. The fluorine atom modification reduces tack and enhances removal characteristics for specialty surface protection films and reworkable applications.

    Industry compliance standards

    • ASTM D3330 (Standard Test Method for Peel Adhesion of Pressure-Sensitive Tape)
    • FDA 21 CFR 175.105 (Adhesives for food packaging, indirect contact)
    • ISO 9001:2015 (Quality management for adhesive production)
    • Directive 94/62/EC (Packaging and packaging waste safety)

    Typical usage ratio

    • Used at 0.5–4% w/w in acrylate monomer blends; ratio fine-tuned for target peel and shear properties, as well as end-use environmental resistance.

    Downstream process integration

    • Included in bulk monomer feed for copolymerization via emulsion or solution processes, followed by crosslinker and antioxidant addition ahead of coating onto film substrates.

    Final product types

    • Electronics component protection films
    • Removable masking tapes for automotive refinishing
    • Repositionable industrial labels
    • Protective films for display panels

    3. Fluorinated Acrylic Resins for Anti-Graffiti Paints

    Protective coating manufacturers employ Tert-Butyl 2-Fluoroacrylate as a copolymer ingredient for anti-graffiti systems. Its fluorinated vinyl structure facilitates the creation of acrylic polymers with high hydrophobicity and oleophobicity, reducing pigment and ink anchoring while enhancing substrate release profiles. This enables repeated cleaning of urban structures and transit surfaces without film degradation.

    Industry compliance standards

    • ISO 11998 (Wet-scrub resistance for paints and varnishes)
    • LEED EQ Credit (Low-emitting materials for public buildings)
    • ASTM D6578 / D6578M (Graffiti resistance of paint films)
    • EN 1504-2 (Protection systems for concrete surfaces)

    Typical usage ratio

    • Incorporated at 2–8% of the total monomer mass, adjusted for balance between graffiti-release performance and film hardness.

    Downstream process integration

    • Charged directly into emulsion or solution polymerization reactors alongside main acrylates before pigment dispersion and resin let-down stages.

    Final product types

    • Permanent anti-graffiti wall coatings
    • Barrier films for public transport interiors
    • Anti-marking clear coats for commercial restrooms
    • Maintenance-friendly architectural topcoats

    4. Functional Additive for Medical Device Polymer Components

    The medical polymer sector leverages the fluorinated and tert-butyl structure of this acrylate for hydrophobic coatings on device housings and microstructured components, where low-surface-energy is critical to reduce contamination and facilitate sterilization cycles. In catheter and diagnostic consumable manufacturing, formulators employ it to fine-tune surface friction and resistance against biofouling.

    Industry compliance standards

    • ISO 10993-5 (Cytotoxicity testing of medical device materials)
    • USP Class VI (Plastics for medical device use)
    • ISO 13485 (Quality management for medical device manufacturing)
    • FDA 21 CFR 820 (Medical device quality system regulation)

    Typical usage ratio

    • Formulated at 0.2–1.5% of total polymer content, calibrated for target migration, coating uniformity, and biocompatibility validations.

    Downstream process integration

    • Blended into acrylate copolymer resin batches prior to extrusion or injection molding stages, or dissolved into surface-cure coatings applied post-molding.

    Final product types

    • Hydrophobic catheter coatings
    • Low-friction diagnostic device covers
    • Reusable surgical instrument grips
    • Protective films for laboratory consumables

    5. Surface Modification Agent in Optical Polymer Films

    Producers of specialty optical films for solar, display, and LED applications utilize this acrylate monomer to customize refractive indices and lower surface energy, minimizing static charge and dust attraction. Its controlled copolymerization produces transparent, non-tacky surfaces that retain high light transmission and extended UV stability demanded in advanced display technologies and light guides.

    Industry compliance standards

    • IEC 61215 (Performance for photovoltaic modules)
    • ISO 14644-1 (Cleanroom manufacturing for optical film handling)
    • RoHS 2011/65/EU (Restriction of hazardous substances)
    • VDE 0126 (Components for solar power modules)

    Typical usage ratio

    • Dosed at 1–3% in the acrylate polymer matrix, depending on target haze, contact angle, and mechanical retention criteria.

    Downstream process integration

    • Fed into solvent or water-based acrylate cast film lines ahead of polymerization and tensioning sections, or into coating solutions for in-line surface functionalization.

    Final product types

    • Anti-reflective display protection sheets
    • Solar cell encapsulation films
    • Optical light guide plates
    • Low-static covers for touch panels

    6. Chemical-Resistant Polymer Flooring Systems

    Industrial flooring producers incorporate this specialty acrylate to increase chemical inertness and cleanability in polymer-based floor coatings and overlays for factories and laboratories. Its unique side groups help formulators meet customer requirements for acid, alkali, and solvent resistance in high-traffic zones. The monomer enhances overall flooring longevity under harsh sanitation cycles.

    Industry compliance standards

    • EN 13813 (Floor screeds and materials for use in internal flooring)
    • ISO 2812-1 (Determination of resistance to chemicals, spot test for coatings)
    • ASTM F3010 (Moisture vapor barriers for flooring)
    • SCAQMD Rule 1113 (Architectural coatings VOC compliance, US)

    Typical usage ratio

    • Added at 2–5% of total resin weight, depending on required solvent resistance and gloss retention outcomes under industrial cleaning cycles.

    Downstream process integration

    • Introduced during resin kettle pre-mix before final blending with fillers and curing agents; can also be co-dispersed in 2K floor coating systems for reinforced chemical barriers.

    Final product types

    • Seamless industrial flooring coatings
    • Chemical-resistant laboratory floor sealants
    • Electrostatic discharge (ESD) protected surface coatings
    • Heavy-duty cleanroom floor overlays
    Free Quote

    Competitive Tert-Butyl 2-Fluoroacrylate prices that fit your budget—flexible terms and customized quotes for every order.

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    Email: sales7@sinochem-nanjing.com

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    Certification & Compliance
    More Introduction

    Tert-Butyl 2-Fluoroacrylate: Reliable Chemistry from the Source

    Our Commitment to Consistency and Performance

    Working in the field of specialty acrylate monomers for several decades, few products have generated as much steady feedback from our partners as our Tert-Butyl 2-Fluoroacrylate. Here at our plant, the process behind each drum starts with the right selection of raw feedstock and tight control of every reaction stage. We take pride not just in high assay and purity, but in a supply chain that keeps laboratories and production floors moving without costly interruptions.

    Every batch receives our full attention from synthesis through distillation and quality checks. We ship Tert-Butyl 2-Fluoroacrylate according to the needs of researchers refining advanced polymer architectures and manufacturers who require scale for coatings, adhesives, or electronics. Over years and thousands of batches, that attention to detail has survived shifts in cost structures, changing regulations, and supply shocks in the broader chemicals market. Our customers count on steady, predictable product delivered when promised.

    Getting to Know Tert-Butyl 2-Fluoroacrylate: Structure and Benefits

    Tert-Butyl 2-Fluoroacrylate draws attention because the tert-butyl ester offers more hydrolysis stability than methyl or ethyl variants, while the fluorine atom at the 2-position gives distinct reactivity and property effects in downstream polymers. Most research teams tell us they chose this molecule for its contribution to thermal and chemical resistance once incorporated into copolymers, especially in demanding end-uses such as automotive topcoats, specialty films, and medical devices. Formulators see an opportunity for lower surface energy, which translates into anti-fouling, non-stick, or easy-clean functions without extensive recipe changes.

    Comparing it with standard acrylate esters, the blend of fluorine and bulky tert-butyl group prevents rapid backbone degradation and improves weathering resistance. We see customers using it not only as a main monomer but also as a performance modifier—a small dose at the right spot in a resin composition breaks through limits of adhesion or flexibility. Our production process avoids residual acid, so the material goes cleanly into radical polymerizations. Customers often note how much more predictable cure profiles become as they swap in our product after using cheaper alternatives sourced from traders.

    From Bulk Drums to Fine Bottles: How We Support Users

    Many users start their journey with a few grams in the laboratory glass reactor, but scale rapidly once results prove out. From the synthesis line, we offer Tert-Butyl 2-Fluoroacrylate in a spectrum of packaging, starting at small bottles suitable for reference standards, scaling to drum lots destined for production sites. In practice, our customers describe our product as “plug and play”—no haze in solution, no sediment on standing, no color darkening in storage up to a year under ambient conditions. That performance is the result of real controls rather than luck. Side-products and high-boiling impurities are scrubbed both during process optimization and real-time distillation adjustments tailored to specific runs.

    Logistics matter as much as synthesis. We found early on that partnering with tank-cleaning stations and certified warehouses prevents cross-contamination, especially when handling sensitive fluorinated monomers. In-house drum washing, nitrogen blanketing, and on-request stockpiling cut the incidence of moisture uptake or exposure in transit. It’s easy to promise delivery, but we deliver on those promises even in times of container shortages and freight rerouting.

    Feedback Informs Refinement: Listening to End Users

    Each new batch of Tert-Butyl 2-Fluoroacrylate is influenced by the ongoing stream of practical reports and inquiries from customers around the globe. Some clients focus on the need for extremely low residual acid; others require clear documentation for regulatory filings, especially if their finished polymers are heading into contact applications or strict environmental frameworks. We compile this feedback to guide both quality assurance priorities and the documentation we provide.

    For users in the EU or jurisdictions with demanding REACH or GHS documentation standards, we keep up with current guidelines—not just PDFs and paperwork, but actual pre-registrations, updates, and compatibility checks for third-party audits. Our on-site compliance officer reviews each new guideline and translates it into daily practice on the plant floor. That means less friction for you, the chemical user, as you focus on performance data, not regulatory surprises. Our batch records reflect exact lot traceability, so any possible issue can be backtracked to its source for full transparency.

    Differences from Other Fluoroacrylates and Related Acrylates

    Across the acrylate family, small changes at the molecular level take on outsized roles in specific applications. Adding a tert-butyl group versus a methyl or ethyl ester dramatically increases the hydrophobicity and lowers water sensitivity. Drop in a fluorine atom at the 2-position, and you extend solvent resistance and lower the surface energy in cured films.

    Compared to methyl 2-fluoroacrylate, Tert-Butyl 2-Fluoroacrylate builds in a higher glass transition point due to restricted chain mobility and benefits from decreased volatility during processing. In contrast, linear or secondary alkyl esters often lead to tackiness or poor shelf life, especially outside temperature-controlled storage. The combined presence of the tert-butyl and fluoro groups means that our product resists both spontaneous polymerization in storage and hydrolysis in the presence of trace water.

    Researchers investigating copolymerization with vinylidene fluoride or similar specialty monomers report that Tert-Butyl 2-Fluoroacrylate delivers greater control over molecular weight distribution, resulting in more consistent mechanical properties. For industrial clients looking to push boundaries around corrosion protection or biocompatibility, tiny chemical changes have enabled new formulas for high-durability lacquers and medical films free from plasticizer migration. Our product gives this flexibility while cutting cleanup hassle or unwanted reactivity at the end-use stage.

    Making Quality Transparent from Synthesis to Delivery

    All operations relating to Tert-Butyl 2-Fluoroacrylate happen in-house at our manufacturing site. We don’t leave third-party tollers or resellers to dictate quality. By owning the process from sourcing to shipment, our team can set and hold specifications beyond what is simply “good enough.” Each operator is cross-trained to respond to changing production variables, preventing deviations that cause slips in color, odor, or reactivity.

    From pilot batches to full production runs, we document every change to feed ratios, catalyst cuts, and distillation profiles. That’s not a marketing point, it reflects decades of practicing continuous improvement while the global regulatory scene keeps moving. Our documentation system links laboratory analysis with shipping records, so your own internal teams can check and verify against your requirements. Any time our clients detect unexpected results, a full record lets us retrace and resolve root causes quickly.

    Addressing Field Issues: Common Challenges and Solutions

    It’s no secret that acrylate esters are vulnerable to excessive storage heat, light, or oxygen exposure. With Tert-Butyl 2-Fluoroacrylate, we encountered fewer issues arising from premature polymerization—thanks to our purification approach and robust inhibitor monitoring. Still, we recommend storing in original sealed containers, under cool, dry conditions, far from peroxides or strong acid/base contaminants. Our technical support team helps customers interpret any color formation or viscosity drift if it appears, and offers tailored advice to get the material back on spec.

    Another real pain point in the field is blending with other monomers where variable reactivity leads to erratic final product results. Where competitors offer minimum-spec or untested lots, we maintain a strict upper and lower limit for inhibitor (MEHQ or BHT) content, keeping your recipes reproducible from year to year. If your formulators find troubles with reactivity ratios or poor conversion in emulsion polymerizations, contact us for tailored guidance based on our own blend histories. We’ve supported many process engineers through the learning curve of switching from commodity esters to specialty fluoroacrylate variants.

    Keeping the Focus on Safety and Environment

    We produce Tert-Butyl 2-Fluoroacrylate using processes that minimize volatile organic compound losses and cut hazardous waste. Our environmental management system assures compliance with national and international standards, and each year we reinvest in emission controls and solvent recovery. We encourage buyers to adopt closed transfer systems and personal protective equipment matching the same high bar we enforce in our own plant. Any time there’s a question about skin or inhalation hazards, our technical sheets walk you through dosage, limiting exposure, and best practice ventilation. We work directly with downstream users on waste minimization, solvent recycling, and safe end-of-life disposal for containers.

    Applications: Success Stories and Industry Shifts

    Tert-Butyl 2-Fluoroacrylate found its early market groove in the automotive sector, especially where topcoats faced both corrosion and UV exposure. As shifts in environmental requirements forced formulators to ditch heavy metal additives and high-VOC resins, our fluoroacrylate offered a path to smarter durability. In the electronics sector, our partners now use it to create anti-fouling protective films for circuit boards and screens—helping protect sensitive devices against moisture, fingerprinting, and dust adhesion.

    Medical device developers use small quantities in specialty films and adhesives, where trace extractables and low toxicity are non-negotiable. Our team has responded to questions about leachables, confirming full traceability of every raw input. We’re capable of short-turnaround reformulations too, supporting teams who want a tweak in inhibitor dose or lower particle counts for cleanroom applications.

    Waterborne coatings and adhesives sectors have steadily increased their reliance on Tert-Butyl 2-Fluoroacrylate since their customers began demanding both stain resistance and lower emissions. We supply these materials in drum quantities large enough for pilot lines, but clean enough for stages where any contamination means lost production time or failed product launches.

    Production Integrity: Making Innovation Reliable

    Our shift supervisors and chemical operators know Tert-Butyl 2-Fluoroacrylate inside out, not because it’s effortless, but because care counts. Every specification you read on a data sheet comes from hours of process optimization, troubleshooting, and listening to the field about real performance shortfalls. We invest in advanced analytical equipment so results don’t vary batch to batch. Our staff meets regularly to review non-conforming events, even if the batch left the plant intact, to improve methods and avoid recurrences.

    As a primary manufacturer, we see firsthand where short-term cost savings from cut corners rebound as lost reputations or recalls down the road. That’s why our own values center on traceability, operator training, and being transparent whenever things don’t go exactly as planned. These aren’t empty promises—just people working diligently to support innovators, coating formulators, and polymer scientists as they push materials performance forward.

    Your Real-World Partner

    Tert-Butyl 2-Fluoroacrylate stands out among acrylate monomers for its stability, easy handling, and unique performance in challenging polymer environments. We’re available not just as a source but as a resource, addressing specific needs in formulation, processing, and regulatory compliance. Reliability, not just supply, is what makes our customers keep coming back each season.

    We encourage you to reach out with application challenges and formulation goals. Our team works closely with your chemists, engineers, and quality staff to solve problems drawn from years of experience in both the lab and the plant. Our perspective comes from real production—not abstract claims or brokered lots, but firsthand knowledge in making each batch right. Tert-Butyl 2-Fluoroacrylate, produced under a watchful eye and delivered with integrity, is ready to meet your next challenge.