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Sodium Sulfide Nonahydrate

    • Product Name Sodium Sulfide Nonahydrate
    • Alias Sodium Sulfide 9H2O
    • Einecs 215-211-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    257459

    Chemical Name Sodium Sulfide Nonahydrate
    Chemical Formula Na2S·9H2O
    Molar Mass 240.18 g/mol
    Cas Number 1313-84-4
    Appearance Colorless to yellowish crystalline solid
    Solubility In Water Very soluble
    Melting Point Approximately 60 °C (140 °F)
    Odor Rotten egg (hydrogen sulfide odor)
    Density 1.43 g/cm³
    Ph Aqueous Solution Alkaline, typically around 12
    Stability Stable under recommended storage conditions
    Main Uses Textile industry, water treatment, ore flotation, chemical manufacturing

    As an accredited Sodium Sulfide Nonahydrate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Packed in a 500g white HDPE bottle with a yellow hazard label, tightly sealed to prevent moisture absorption.
    Shipping **Sodium Sulfide Nonahydrate** should be shipped in tightly sealed containers made of compatible materials, away from moisture, acids, and oxidizers. It is classified as a hazardous material (UN 1849), requiring labeling and documentation per transportation regulations. Handle with care to avoid leaks or spills, using appropriate protective equipment.
    Storage Sodium Sulfide Nonahydrate should be stored in a cool, dry, and well-ventilated area, away from moisture, acids, and oxidizing agents. Keep the container tightly closed and properly labeled. Avoid exposure to air, as it is hygroscopic and may release toxic hydrogen sulfide gas upon contact with acids. Store in corrosion-resistant containers, away from incompatible materials.
    Application of Sodium Sulfide Nonahydrate

    Applications of Sodium Sulfide Nonahydrate in Industrial Manufacturing

    Sodium sulfide nonahydrate serves a decisive role as an industrial processing aid and chemical intermediate across several mature downstream sectors. Below, we detail application scenarios where this raw material enters critical production processes, supported by established compliance protocols, verified incorporation parameters, clear onsite integration steps, and links to recognizable finished products.

    1. Leather Tanning and Unhairing Operations

    Sodium sulfide nonahydrate acts as a main depilatory in the pre-tanning beamhouse stage, enabling rapid and complete removal of hair, epidermis, and unwanted proteins from hides and skins. Tanneries require efficient and reproducible outcomes across hair sheep, goat, and bovine hides to meet strict physical quality benchmarks specified by downstream footwear, garment, and upholstery sectors. Manufacturers incorporate the sulfide in aqueous liming baths, integrating precise dosing based on hide origin, thickness, and required surface characteristics.

    Industry compliance standards

    • ISO 5397:2020 (Leather — Determination of sulphide)
    • REACH Regulations (Annex XVII restrictions on tanning chemicals)
    • Leather Working Group (LWG) Environmental Protocols
    • ZDHC Manufacturing Restricted Substances List (MRSL)

    Typical usage ratio

    • 2–6% of the limed pelt weight, adjusted for hair type, seasonal hide variation, and targeted grain preservation

    Downstream process integration

    • Sulfide enters directly in the liming drum after soaking and unhairing pre-wash, where it breaks keratin-peptide bonds; subsequent addition of lime controls pH and reaction kinetics.

    Final product types

    • Upholstery leather for the automotive and furniture sectors
    • Shoe upper and lining leather
    • Garment-grade nappa and nubuck leather

    2. Pulp and Paper Kraft Process (Chemical Pulping)

    Sodium sulfide nonahydrate forms one of the vital alkali agents during the Kraft pulping process, contributing to lignin breakdown and separation from cellulose fibers in wood chips. This application demands rigorous control of sulfidity levels to prevent fiber degradation while ensuring sufficient removal of non-cellulosic components for strength-critical paper grades. The chemical enters black liquor cycles and undergoes closed-loop recovery within the pulp mill ecosystem, requiring close coordination with process control and environmental compliance teams.

    Industry compliance standards

    • TAPPI T650 (Chemical analysis of pulping liquors)
    • EN 643 (European List of Standard Grades of Paper and Board for Recycling)
    • ISO 14001 (Environmental Management System for pulp/paper mills)
    • Best Available Techniques (BAT) for the Pulp and Paper Industry (EU BREF)

    Typical usage ratio

    • 15–25% of total cooking liquor active alkali content, calculated based on desired pulp Kappa number and wood species

    Downstream process integration

    • Added to white liquor preparation tanks; participates in digestion of wood chips within continuous or batch digesters, followed by counter-current washing and chemical recovery loops.

    Final product types

    • Bleached Kraft pulp for printing and writing papers
    • Sack and bag paper base stock
    • Dissolving pulp for viscose rayon manufacturing

    3. Ore Flotation in Non-Ferrous Metal Mining

    During sulphidic ore flotation, sodium sulfide nonahydrate selectively modifies mineral surfaces and acts as a sulfidizing agent, particularly in the beneficiation of oxide copper, lead, and zinc ores. It transforms oxide minerals into their respective sulfide forms, thus rendering them floatable for separation via xanthate or other collectors. Quantifying correct sulfide dosages depending on ore mineralogy and flotation cell residence time is critical for maximizing recovery and minimizing reagent consumption.

    Industry compliance standards

    • OECD Guidelines for Testing of Chemicals (as referenced in mining effluent protocols)
    • ISO 14001 (Site-specific Environmental Management in mining)
    • NI 43-101 (Canadian National Instrument for Mineral Projects, reagent traceability section)
    • MSHA/CFR Surface Mining Regulations for hazardous reagents

    Typical usage ratio

    • 0.1–1.5 kg per metric ton of ore, adjusted after bench-scale and pilot testing based on oxide/sulfide content and local process water chemistry

    Downstream process integration

    • Metered addition ahead of conditioning tanks or directly to flotation cells preceding collector introduction, with inline pH and redox monitoring

    Final product types

    • Copper concentrate for smelting
    • Zinc and lead sulfide concentrates
    • Byproduct precious metal (gold/silver) concentrates

    4. Sulfur Dye Synthesis in Textile Applications

    Sodium sulfide nonahydrate provides both the reduction potential and sulfur source during sulfur dye synthesis, including vatting and solubilization steps for vat and leuco dyes used on cotton and regenerated cellulosics. Dye manufacturers must ensure full reduction to achieve high color strength and fastness while suppressing the formation of insoluble side products, which requires precise reagent quality and batch control under managed temperature and agitation profiles.

    Industry compliance standards

    • OEKO-TEX Standard 100 (for dyestuffs not to exceed allocated impurity limits)
    • ZDHC MRSL (applicable to dyehouse raw material traceability)
    • ISO 105-C06 (Textiles — Tests for color fastness)
    • REACH Registration requirements for sulfur dye intermediates

    Typical usage ratio

    • 1–4 moles per mole of dye precursor, optimized through pilot vatting to balance solubility and exhaust efficiency

    Downstream process integration

    • Charged in dye synthesis reactors or dyeing machines during the reduction-vatting stage, followed by controlled oxidation during dye fixation and rinse-off

    Final product types

    • Direct sulfur dyes for denim, workwear, and decorative textiles
    • Leuco sulfur dye intermediates for on-site dilution at textile mills

    5. Chemical Intermediates Manufacturing (Sulfur Compounds)

    Sodium sulfide nonahydrate acts as a key intermediate for synthesizing a broad range of downstream sulfur-based chemicals, notably including thio-organic compounds, thiols, polysulfide elastomers, and other specialty fine chemistries. Chemical processing plants demand high-purity, controlled hydrate content to avoid batch inconsistency in multi-step synthesis and to comply with rigorous quality assurance protocols for intermediate and technical-grade end users in polymer, crop protection, and specialty chemical segments.

    Industry compliance standards

    • ISO 9001:2015 for quality management in chemical synthesis
    • Responsible Care® Guiding Principles (global chemical industry initiative)
    • Chemical Facility Anti-Terrorism Standards (CFATS, in the US)
    • National Chemical Inventory (China IECSC, US TSCA, EU REACH registration)

    Typical usage ratio

    • Adjusted stoichiometrically as 1–2.2 equivalents relative to target substrate, depending on desired conversion rate and side reaction minimization

    Downstream process integration

    • Fed in batch or continuous reactor trains for nucleophilic substitution, reduction, or precipitation steps, followed by separation and purification of thiolated intermediates

    Final product types

    • Alkali thioglycolates for haircare chemical suppliers
    • Mercaptans and thiols for polymer modification
    • Polysulfide sealants for construction and aerospace applications
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    Certification & Compliance
    More Introduction

    Sodium Sulfide Nonahydrate: Our Experience with a Reliable Industrial Workhorse

    What Makes Sodium Sulfide Nonahydrate Stand Out in Real-World Applications?

    Sodium sulfide nonahydrate has become a necessary tool in our production lineup for decades. Every bag and crate leaving our warehouse reflects years of detailed process control and hands-on monitoring. The product we send out under the name Sodium Sulfide Nonahydrate—model Na2S·9H2O, a solid with a pale yellow to reddish tint—traces its strength back to the consistency of our raw materials and the know-how involved in hydration control. Our customers in leather processing plants, pulp and paper mills, textiles, and mining operations value this grade for the reliability it offers step after step, batch after batch. Every time a drum of this compound gets opened, someone is trusting our understanding of both chemistry and real-life factory requirements.

    Our workers don't see sodium sulfide nonahydrate as just another chemical. They recognize its sharp, distinct odor and crystalline form as hallmarks of safety and predictability in large-scale processing. In our own experience, careful attention to the ratio of sodium sulfide to water creates a product that responds immediately in downstream applications, whether it is in the removal of hair from animal hides or the flotation of precious metal ores.

    Other sodium sulfide forms, such as the pentahydrate or anhydrous types, offer their own advantages but often come with increased handling risks or storage considerations. The nonahydrate version holds moisture at a level that prevents unnecessary dust formation, reducing the chance of airborne contamination. The water content also helps to moderate the product’s exothermic reactions, giving users a safer experience at the mixing stage.

    Experience-Driven Quality Control: Setting the Standard for Sodium Sulfide Nonahydrate

    Quality doesn’t come only from technical sheets and inspection reports. For us, it begins with maintaining the right temperatures and timing during crystallization. We keep tight control on the purity of inputs and make regular checks for iron, insoluble matter, and sodium thiosulfate. What actually matters to our crew is catching any sign of contamination that could affect a customer’s hide processing or pulp bleaching. Knowing what's at stake—yield losses, off-odor, or ruined production runs—puts a firm responsibility on our backs.

    We watch for the telltale red tinge that signals excess iron, and we track the clarity of mother liquors to ensure low levels of insolubles. Over the years, we have found that keeping free alkaline levels within narrow parameters allows customers to dial in dosages without risking waste or underperformance. Our testing reveals a sodium sulfide concentration ranging from 56% to 60%, with minimal byproduct content. This value translates directly into control over reaction times and final product yield across user industries.

    Why Leather, Pulp, and Metal Processors Stick with Nonahydrate

    Traditional leather businesses rely on sodium sulfide nonahydrate for its predictable efficacy in removing hair and fat from animal hides without cause for corrosive accidents. We have visited tanneries where operators could tell the difference between our product and less controlled alternatives, only by the time it takes for the chemical to react or the completeness of the unhairing process. Fast dissolving, low-fume, and mild on equipment, nonahydrate allows them to optimize water consumption and time in drum operation.

    In paper production, mills use sodium sulfide nonahydrate to digest wood chips and separate lignin from cellulose during the Kraft process. The water of hydration acts almost as an internal buffer, preventing sudden spikes in temperature or reaction speed when the flakes are added to liquor tanks. Operators of continuous processes mention fewer stoppages, less need for manual adjustments, and less equipment wear over months of use. This performance links directly to purity and sustainable handling—outcomes that can only arise when every production run is checked, batch by batch.

    The mining sector uses sodium sulfide nonahydrate in mineral flotation, especially for copper, lead, zinc, and molybdenum. Process engineers told us that excessive dust from drier grades stresses air filtration and raises risks for workers. The hydrated product has just enough moisture to reduce airborne particulates, with no compromise on performance. Reliability in ore separation depends on both purity and particle size, which we fine-tune through sieving and post-crystallization sampling. That level of attention arose not from a single directive, but from years spent listening to customer feedback.

    Handling and Storage: What Matters Beyond the Lab

    Sodium sulfide nonahydrate needs appropriate packaging and storage environment to maintain its chemical integrity. Our own shipping and receiving teams always store product in cool, dry, well-ventilated spaces, using lined bags and sealed drums to prevent moisture fluctuation. The nonahydrate form resists caking much better than anhydrous or pentahydrate versions, holding granule integrity over long shelf times. This trait simplifies both warehouse management and worker protection onsite.

    Everyone who’s had to handle sodium sulfide in bulk environments knows that product stability and minimal dust carry a lot of weight on real production floors. The nonahydrate type, thanks to its water content, sits firmly in a sweet spot—neither too damp to clog nor so dry as to create clouds of irritating dust. That translates to easier handling, cleaner mixing vessels, and fewer gloves lost to unnecessary degradation.

    Our warehouses never underestimate the smell or the risk of H2S gas evolving from open containers, so we rely on proper venting and work rotation. The crystalline nonahydrate structure makes spills less powdery, so cleanup happens faster and exposure stays lower. These may sound like small advantages, but over tens of thousands of tons shipped every year, every improvement adds up.

    Production Insights: Why Hydration Level Is the Key Difference

    Many who haven’t experienced the difference between nonahydrate and other sodium sulfide grades may think it comes down to water content alone. The reality runs deeper. The extra water molecules reduce the rate of heat release on dissolution, creating an extra margin of safety for workers. Since the nonahydrate dissolves predictably, customers avoid the risk of thermal spikes or burning during batch preparation.

    We’ve experimented with pentahydrate and anhydrous sodium sulfide when customer requirements called for tighter moisture control or low-temperature applications. These grades can crank up risk levels if not managed properly, generating more fumes or triggering exothermic reactions that threaten personnel safety and equipment integrity. Our practice shows that the nonahydrate bridges these gaps for most large-scale users who demand repeatable, safe results with minimal downtime.

    Supporting Customer Outcomes Through Direct Feedback

    Our technical support teams spend more time on customer sites than in offices. This direct communication reveals obstacles that never make it onto standard usage guides. Tannery owners prefer our product because it dissolves quickly and fully without creating excessive scum on wastewater systems. Pulp mills noted that with our tighter iron control, their white liquor tanks stay cleaner, and they recover more usable cellulose. Many mining operations have cut their downtime in half since switching to our carefully screened nonahydrate batches.

    One customer in the textile dye industry mentioned that using more volatile grades wrecks color consistency, leading to expensive reworks and chemical overdoses. With nonahydrate, process staff have managed their color baths predictably, lowering both error rates and overall chemical consumption. That result comes back to our consistent control over both moisture and impurity elimination, right from the earliest production stages.

    Industrial wastewater treatment plants also use sodium sulfide nonahydrate to precipitate heavy metals. Operators value the manageable reaction rates—less risk of sudden precipitation that could overwhelm their clarifiers or degrade effluent quality. Our response to feedback has included designing packaging that resists condensation and using moisture monitors to test every shipment.

    Environmental and Regulatory Realities

    All sodium sulfide products draw attention from regulatory authorities due to their toxicity and potential for H2S gas release. Over the years, our compliance staff and production line supervisors have built documented procedures that track every step of manufacture through transportation. The nonahydrate product, by its nature, presents a slightly lower risk profile compared to more concentrated forms. Still, our team enforces strict personal protective equipment use, air quality checks, and emergency ventilation equipment wherever the compound is handled onsite.

    We have worked with clients to set up Secondary Containment practices and to design spill response strategies. By choosing the nonahydrate grade, many facilities report fewer incidents where airborne irritants affect workers or lead to accidental overexposure. Prevention controls and routine environmental audits keep the handling of the material well within regulatory bounds. These routines emerged from deep experience, close listening, and a willingness to revisit methods after every significant incident or product recall—never simply in response to paperwork.

    What Sets Our Sodium Sulfide Nonahydrate Apart?

    Make a single batch of sodium sulfide nonahydrate, and you’ll see that it isn’t a plug-and-play operation. Our senior operators know that cooling rates, purity of soda ash, and careful addition of hydrogen sulfide gas create the groundwork for years of dependable downstream use. The product rarely varies from season to season—no easy task in some climates. Years of minor tweaks, repair, and operator training help achieve a level of control that buyers in aggressive, high-throughput industries depend on without thinking twice.

    Sodium sulfide nonahydrate from our facility arrives in a range of particle sizes. We adapt our crystallizer controls to meet specification requests—whether for rapid solubility in batch-dyeing operations or for easier measurement in larger bulk settings. Each shipment ships out with real feedback from our own line workers, checked and logged after equipment cleaning, filter changes, and sample testing. That process creates a trust chain from the back of our plant to the back gate of a customer’s own operation.

    While new entrants might look at sodium sulfide supply as a matter of meeting codes, those handling it daily notice every subtlety—humidity levels, bulk density, free-flowing characteristics, and even shifts in odor strength. The nonahydrate, by virtue of its water content and balanced preparation, crosses some of industry’s biggest chemical hurdles with less risk and fewer production detours. Stabilized sacks translate to more predictable bursts of productivity on shop floors, with much less downtime caused by unpredictable chemical behavior.

    Lessons Learned in Field Use and What’s Next

    Over forty years, our teams have learned to look for more than just purity metrics. Process engineers flag issues such as cake formation, waste tank scaling, or harsh residue in finished products. With these reports, our plant managers adjust process variables and, when warranted, share best practice updates directly with end users. This style of feedback loop, augmented by years of incident records and user success stories, has helped shape a sodium sulfide nonahydrate that performs above basic expectations.

    The trend among industrial users is toward process automation, lower chemical waste, and better air quality in plants. Sodium sulfide nonahydrate, thanks to both its chemistry and our manufacturing adjustments, provides a foundation for these improvements. We’ve seen tanneries raise throughput by optimizing sodium sulfide dissolution parameters. Mining operations have used our nonahydrate to replace less predictable in-house mixed sulfide solutions, cutting process variability and lowering risk to workers and equipment.

    Pulping mills, wrestling with increasingly strict emissions limits, report that our tighter contaminant control reduces their environmental liabilities. Reducing iron and thiosulfate to trace levels means their own downstream chemicals function better, creating a more stable cycle from chip to finished paper.

    Potential Solutions for Common User Challenges

    It’s not always smooth sailing. Some customers deal with caking during long transit or high humidity, particularly when storing in coastal ports or equatorial regions. We address this by improving inner bag materials, adjusting crystal size in our drying phase, and keeping logistics teams updated about shipping timelines and storage instructions. User sites that experience rapid product consumption get more frequent deliveries and smaller batch packing for easier inventory rotation.

    Odor management remains a constant challenge, especially in confined sites or places where air exchange is difficult. Our crews recommend and help design dedicated storage spaces with active ventilation, and—in cases where regulatory limits are strict—install local exhaust and air scrubbers to keep worker exposure to hydrogen sulfide gases at comfortable minimums.

    Worker safety training has also featured for us as a growing priority. Many mishaps in chemical use stem from lack of knowledge rather than pure product defect. We share training guides, walkthroughs, and hands-on sessions with partner plants, ensuring they can recognize physical hazards and implement effective emergency procedures. Keeping this information current draws from both regulation changes and our own experience responding to onsite accidents.

    Looking Ahead: Continuous Improvement from Factory to Field

    Every year introduces new challenges—changing weather, raw material supply interruptions, or spikes in demand from the metallurgy or water treatment sectors. We invest in new technologies, process analytics, and operator retraining with a single goal in mind: to keep our sodium sulfide nonahydrate consistent and fit for the actual ways people use it. While some see these as overhead costs, we recognize that customers notice the difference during every hour of smooth, predictable operation.

    The nonahydrate’s flexibility allows us to respond to emerging industrial approaches—cleaner processing, tighter emissions controls, digital process monitoring. We actively solicit reports from user sites, incorporating their data points and criticism into our own process audits. Each improvement in handling, storage, or packaging reflects hours of trial, error, and in-plant verification. The end result is a sodium sulfide nonahydrate product that matches both the letter and spirit of demanding chemical applications in a wide range of sectors.

    Our commitment is built on real-world results, industry trust, and the ongoing exchange between laboratory and production floor. Every drum, bag, and shipment combines detailed chemical science with the daily realities of worker safety, predictable performance, and sustainable industrial growth. Sodium sulfide nonahydrate stands as more than a commodity—it becomes a proven partner in getting work done, meeting challenges head-on, and enabling growth for users old and new.