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Sodium 5-Hydroxynaphthalene-1-Sulphonate

    • Product Name Sodium 5-Hydroxynaphthalene-1-Sulphonate
    • Alias Sodium 5-hydroxy-1-naphthalenesulfonate
    • Einecs 208-070-3
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    143577

    Chemical Name Sodium 5-Hydroxynaphthalene-1-Sulphonate
    Molecular Formula C10H7NaO4S
    Molar Mass 246.22 g/mol
    Appearance White to off-white powder
    Solubility In Water Soluble
    Melting Point Decomposes
    Cas Number 130-13-2
    Ph Of 1 Solution Approximately 6-8
    Odor Odorless
    Stability Stable under normal conditions
    Storage Conditions Store in a cool, dry place
    Synonyms Sodium 5-hydroxy-1-naphthalenesulfonate

    As an accredited Sodium 5-Hydroxynaphthalene-1-Sulphonate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging is a sealed, labeled 500g amber plastic bottle, featuring hazard warnings, lot number, and manufacturer information for laboratory use.
    Shipping Sodium 5-Hydroxynaphthalene-1-Sulphonate is shipped in tightly sealed containers, protected from moisture and incompatible substances. Store in a cool, dry place away from strong oxidizers. Handle with proper safety equipment. Ensure containers are properly labeled during transport. Comply with local, national, and international regulations regarding chemical shipping and hazard classification.
    Storage **Storage of Sodium 5-Hydroxynaphthalene-1-Sulphonate:** Store in a tightly closed container in a cool, dry, and well-ventilated area away from incompatible substances, such as strong oxidizing agents and acids. Protect from moisture and direct sunlight. Use appropriate personal protective equipment when handling. Ensure proper labeling and avoid sources of ignition. Follow all relevant safety guidelines and regulations for chemical storage.
    Application of Sodium 5-Hydroxynaphthalene-1-Sulphonate

    Applications of Sodium 5-Hydroxynaphthalene-1-Sulphonate in Industrial Manufacturing

    Sodium 5-Hydroxynaphthalene-1-Sulphonate serves as a specialized intermediate across a restricted set of chemical processes due to its molecular structure and reactivity. As the direct manufacturer, we supply this compound for industrial customers engaged in proven downstream transformation steps, which require stringent quality and application-specific compliance. The following scenarios detail established B2B applications verified through long-standing industry practice and customer implementation.

    1. Azo Dye Synthesis for Textile and Paper Colorants

    In colorant production, downstream manufacturers use this compound as a diazo coupling component in the synthesis of direct and acid azo dyes. The aromatic sulfonate group assures good solubility and interaction with diazonium salts, enabling controlled coupling reactions for finely tuned dye shades. Its purity and isomeric consistency are critical for reproducible color properties in the final dye batches.

    Industry compliance standards

    • OEKO-TEX® STANDARD 100 chemical safety restrictions
    • ZDHC MRSL (Zero Discharge of Hazardous Chemicals) V3.1 requirements
    • EU REACH Annex XVII for dye intermediates
    • ISO 9001:2015 certified process control

    Typical usage ratio

    • 0.8–1.2 molar equivalents per 1.0 molar equivalent of diazonium salt, adjusted by required dye shade and purity of raw materials

    Downstream process integration

    • Post-sulphonation work-up followed by direct coupling in aqueous medium with diazotized aromatic amines; used at the dye synthesis stage before isolation and formulation

    Final product types

    • Direct azo dyes for cellulose fiber fabrics
    • Acid azo dyes for protein fibers and nylon
    • Water-soluble dyestuff concentrates for paper tinting

    2. Naphthol AS-Type Pigment Manufacturing

    This material forms the primary naphthol component in the preparation of Naphthol AS pigments, valued for their heat resistance and color stability in plastics and coatings. Its sulphonate group improves pigment particle size control during synthesis, letting downstream processors achieve brilliant hues and high dispersion for polymer coloration.

    Industry compliance standards

    • EN 71-3:2019 for pigment safety in toys
    • DIN 55945 for colorant and pigment quality
    • FDA CFR Title 21, §178.3297 for colorants in polymers (where applicable for indirect food contact)
    • ISO 1248 for pigment quality assurance

    Typical usage ratio

    • Varies between 0.9–1.1 equivalents to the diazonium reactant, optimized for target color strength and purity; process water content and milling conditions may further influence ratio adjustments

    Downstream process integration

    • Introduced during the naphtholization step, followed by precipitation and washing to obtain pigment lakes; used prior to pigment finishing and compounding with dispersants

    Final product types

    • Naphthol AS-based red and orange pigments for plastics coloration
    • Pigment dispersions for waterborne and solventborne paints
    • Masterbatches for injection molding and extrusion

    3. Intermediate for Optical Brighteners

    Sodium 5-Hydroxynaphthalene-1-Sulphonate acts as a building block in the multistep synthesis of certain naphthalene-derived optical brightening agents (OBAs), used in laundry detergents and paper coatings. The material’s sulphonated structure enables efficient subsequent alkylation or condensation reactions critical to OBA chromophore development, impacting final fluorescence intensity.

    Industry compliance standards

    • EU Regulation (EC) No 648/2004 on detergents
    • FDA 21 CFR § 176.170 for paper and paperboard in contact with aqueous and fatty foods (OBA component limits)
    • EN 648 for migration limits in paper for food contact
    • ISO 14021 for environmental declaration of OBAs

    Typical usage ratio

    • 1.0 equivalent per targeted benzoxazole or stilbene moiety in the OBA synthesis route; exact ratio depends on subsequent reaction yield and wastewater management considerations

    Downstream process integration

    • Fed into the initial condensation or sulphonation stage of OBA production, participating in cyclization or linkage reactions before purification and formulation

    Final product types

    • Fluorescent whitening agents for paper, cotton, and synthetics
    • Laundry detergent optical brightener additives
    • Paper coating and calendering OBAs

    4. Synthesis of Pharmaceutical Intermediates (Sulfonated Naphthalene Derivatives)

    Certain pharmaceutical manufacturers utilize this compound for large-scale production of sulfonated naphthalene intermediates. The sulphonate and hydroxyl substitution provide essential reactivity for selective coupling and further transformation, delivering key building blocks for active ingredients, with full traceability and GMP process oversight.

    Industry compliance standards

    • ICH Q7 GMP for active pharmaceutical ingredient (API) manufacturing
    • USP–NF for intermediate traceability and impurity profiling
    • EU cGMP EudraLex Volume 4 for API and excipient production
    • ISO 9001:2015 quality documentation

    Typical usage ratio

    • Normalized as 1.0–1.3 molar equivalents per subsequent activation or coupling step, refined according to stoichiometry, reaction kinetics, and API route efficiency

    Downstream process integration

    • Dosed into the early-stage aromatic sulfonation or coupling reactions; intermediates formed enter further synthetic elaboration or purification en route to final APIs

    Final product types

    • Sulfonated naphthalene API intermediates
    • Specialty precursors for anti-infective and cardiovascular pharmaceuticals
    • Regulated bulk intermediates for further conversion

    5. Dispersant Synthesis for Industrial Dyeing Processes

    This compound functions as a precursor in the manufacture of naphthalene sulfonate-based dispersants. These dispersants enhance particle stability and dye bath homogeneity in textile, leather, and paper dyeing, with sulphonate purity and degree of substitution directly affecting dispersant activity and compatibility in the customer’s final process.

    Industry compliance standards

    • EU Ecolabel for textile and leather processing agents
    • ZDHC MRSL for auxiliary chemicals in wet processing
    • ISO 14001 for environmental management of production
    • REACH registration for surfactant intermediates

    Typical usage ratio

    • In dispersant synthesis, typically 1.0 equivalent as a core aromatic unit per formaldehyde or condensation counterpart, fine-tuned by reaction yield and dispersant type

    Downstream process integration

    • Enters the condensation and sulphonation stage to yield finished dispersing agents, which are post-processed, neutralized, and standardized for activity

    Final product types

    • Sulfonated naphthalene-based dispersants for textile and leather dyeing
    • Anionic dispersing agents for industrial dye baths
    • Dye formulation additives for dispersion and leveling enhancement
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    Certification & Compliance
    More Introduction

    Sodium 5-Hydroxynaphthalene-1-Sulphonate: A Practical Perspective From the Manufacturer

    Our Experience Manufacturing Sodium 5-Hydroxynaphthalene-1-Sulphonate

    Producing chemicals like Sodium 5-Hydroxynaphthalene-1-Sulphonate always calls for care at every stage. Operating our own facilities, we handle the full process from raw naphthols through sulfonation, purification, crystallization, and drying. This lets us keep an eye on quality and address any variation early. Over decades, demand from dyestuff and pigment makers has guided our standards for purity and performance, both in the physical characteristics and the underlying chemistry.

    Physical Qualities and Lab Standards

    For our batches, Sodium 5-Hydroxynaphthalene-1-Sulphonate appears as pale grayish-white powder or small granules, neither sticky nor prone to caking under room conditions. Particle form stays consistent for years in proper storage, even through seasonal humidity. Assay frequently runs 85% or above (as sodium salt), with trace metals checked down to just a few ppm. Moisture typically tests at less than 3%, as high water throws off downstream blending and slows dissolving. We ship out bags sealed tight after sieving, so the granules stay free flowing on arrival for all customers.

    Standards That End Users Rely On

    Our clients' orders come from a range of industries, but textile dye formulation leads by volume. In that trade, dyers rely on total sulfonate value for water solubility and efficient dispersal in vats. Low residue and high assay mean less rework for them, faster batch prep, and fewer complaints about filter clogging. Paper mills appreciate absence of visible color, as their optical brightener synthesis reacts poorly with dark or yellowish contaminants. The buyers making developers for photo chemistry spot strict density and solution clarity, since cloudiness during dilution can cause interference in sensitive reactions.

    Differences From Other Aromatic Sulfonates

    Over the years, we have made series of naphthalenesulfonate salts, both as straight substituents and in combo with further hydroxy or amine groups. Not all perform equally. For example, Sodium 1-Naphthalenesulfonate and Sodium 2-Naphthalenesulfonate attract requests due to cost, but struggle to match the solubilizing strength or dye coupling reactivity. In some reactions, their lack of a hydroxy group prevents integration into more complex molecular designs. In contrast, our Sodium 5-Hydroxynaphthalene-1-Sulphonate bridges the gap with both the surfactant value of the sulfonate and the fast-reacting hydroxy function—this versatility has made it an industry standard for azo dye coupling intermediates.

    Many customers ask about switching to products like Sodium 6-Hydroxynaphthalene-2-Sulphonate or Sodium 4-Hydroxynaphthalene-1-Sulphonate, but each comes with differences in position around the naphthalene ring. Even a simple swap can shift reactivity, and this shows up often when dyehouses troubleshoot shade mismatches or inconsistent light fastness. Our team deals directly with their lab managers, troubleshooting with trial batches. This hands-on support lets us see what even minor batch differences can do to the final product and why our standard naphthalenesulfonates have earned a specific role batch after batch.

    Key Uses Grounded in Industry Practice

    Across our chemical plant, demand for Sodium 5-Hydroxynaphthalene-1-Sulphonate comes mostly from coloring, especially in vat and reactive dyestuffs. This intermediate links well with diazo compounds, forming chromophores that yield rich reds and oranges—difficult to produce with other hydroxy- or aminosulfonate salts. Dyes built from this intermediate resist fading, even in harsh bleach or under sunlight, which is crucial for garment makers exporting to strict buyers.

    Another large group includes optical brightener producers. Here, purity rules, since clouding or yellowing in the optical spectrum can harm huge runs of paper or textile. We apply multi-stage recrystallization and additional filtration steps on these lots. Our partners report up to 5% gain in their brightener yield simply by specifying our highest clarity sodium 5-hydroxynaphthalene-1-sulphonate, compared to technical alternatives offered in open markets.

    Many newer users come from analytical labs, using our product for pH indicator manufacturing, as well as for reagents in photographic developers and some pharmaceutical derivatives. The hydroxy-sulfonic structure plays a dual role—keeping the molecules water soluble while participating in clean, predictable reactions, which makes method development simpler for synthetic chemists working at bench scale.

    The Manufacturing Difference: Factory Floor Knowledge

    Our team sees firsthand how raw ingredient quality influences every stage downstream. We source naphthalene from local refineries with track records for low polycyclic contamination. Our reactors maintain stable temperatures for uniform sulfonation; overheating risks dark byproducts, and underheating leaves too much unreacted base. Technicians monitor color change and pH drop during addition—every one of those signals triggers a process adjustment, not an after-the-fact fix.

    Filtration systems in our plant filter out solid traces, but if the parent naphthalene batch carries too much tar or if the reactor runs at wrong speeds, clarity drops. We avoid chemical waste by recapturing excess sodium sulfate, washing crystals repeatedly, and drying under controlled airflow, which prevents the lumpiness seen from simple drum driers. Each bag out the door carries a batch number traceable to every process condition, and regular staff training means most process improvements come straight from experience, not from manuals.

    Challenges We See and How We Address Them

    Local regulations grow stricter every year, and our field sees new environmental limits for sulfonated effluent. We installed closed water loops and run chemical recovery units to bring wastewater down well below legal thresholds before discharge. Periodic external sampling and surprise audits keep operators honest, but the big improvements come from teamwork with our suppliers. By tightening specs at the naphthalene step, we avoid off-color and bad-smelling charge that otherwise ends up as effluent after multiple re-runs, costing time and money.

    On packaging, we dealt with complaints about caking and loss during shipment. Over the years we moved from multi-layer paper to high-strength polyethylene lined bags with induction sealed closures. Tracking records show scrap from torn bags dropped by over 90%, and we see much less customer dissatisfaction from spillage.

    Handling fine organic powders sometimes creates static, so we installed humidifiers and antistatic controls in packing and loading bays to cut fire incidents and dust inhalation. Employee turnover fell once the plant grew cleaner and safer, which in turn preserved key skills for troubleshooting old problems with modern equipment.

    Why This Product Retains Its Place in the Chemical Trade

    A consistent physical look—clean color, right powder texture—matters but does not finish the story. The heart of the value lies in consistent assay, batch repeatability, ready solvency, and reactivity in the customer’s reactions. Our product runs cleaner in both small batch glassware and large steel reactors. Technical teams at our clients' sites tell us they switched to our sodium 5-hydroxynaphthalene-1-sulphonate after repeated issues with trace contaminants from non-integrated manufacturers—odd odors in final dyestuffs, abnormal reactivity rates, or off-spec color in test production.

    Direct engagement with textile chemists, dyehouse technologists, and materials scientists helps us adapt specs over time. One example: a major European user requested testing for a broader range of organic bases in our intermediate. Their concern stemmed from sporadic yellowing seen on high-luminance paper. We ran side pilot test lines, adjusted one purification step, and retested several shipped containers at their location to confirm improvements before rolling out the change. That approach only works for a company with both technical transparency and willingness to listen to the end user, and we measure progress by such partnerships, not by chasing after every fleeting market trend.

    Improvements That Have Actually Made a Difference

    Some process tweaks over the years have let us drive up purity and lower waste—not quick fixes, but practical process goals. Early on, several production lines relied on open crystallizers, which made for variable batch consistency in rainy months. Upgrading to jacketed vacuum crystallizers let us recover product faster, produce less off-grade material, and build more steady output all year long. Extra fume management improved product color, so technical grade product looked more like advanced grades from global competitors; this won several batches of new export business.

    One less visible area runs in our quality control lab. Near-infrared spectroscopy cuts down lab time for moisture and purity tests over manual titration, letting us test every drum and send out results same day. Any outlier can be flagged before it ships, avoiding costly downstream recalls. We invested in smaller test reactors so our scientists can mirror real user conditions—not just batch purity but actual performance in typical end uses. When an R&D partner approaches us with a need for a higher assay product, or lower metal content for a specialized photographic developer, our technical team has the means and the knowhow to run these trials in weeks, not months.

    The Value of Listening to End Users

    Our direct access to customers’ production lines offers insights that lab work alone doesn’t provide. Some users blend our sodium 5-hydroxynaphthalene-1-sulphonate into complex dye mixtures needing more than just straight solubility—it has to work in tandem with several sulfonate intermediates. Consistency in reaction times, as well as ability to predict downstream viscosity changes, means their planning and machine settings can stay fixed across long runs, reducing downtime. One Indian paper mill told our team in person that after switching to our batches, the need for labor-intensive pre-dissolving tanks and agitators fell by over half, with impact seen in daily payroll and energy bills, not just lab numbers on paper.

    We sometimes modify our process to fit entirely new uses. Collaborations with polymer additive companies, seeking water solubility and heat stability in the same molecule, led our chemical engineers to run test trials on blending this compound with newer acrylics. The batch feedback loop—shipping test kilos direct to their pilot lines, reviewing results, adjusting sulfonation temperature or post-treatment until the best blend emerged—lets our clients capture new revenue using familiar raw materials.

    Technical Support, Documentation, and Regulatory Oversight

    Even simple compounds must now satisfy regulatory needs that grow each year. Our technical documentation covers heavy metal content, residual solvents, potential side product profiles, and full traceability back through supply chain audits. Clients moving product across borders ask us for analysis data, environmental compliance, and certificate of origin. We follow up with updates when new regulations come in, running periodic impurity scans and working with outside auditors for compliance.

    Occasionally, end users request a custom lot for product registration in new markets. Our in-house labs and experienced documentation staff speed up this process. Partnering with their compliance teams means the paperwork and technical support do not hold up product launches. Unlike generic traders, our batch consistency and QA records back up every claim about chemical makeup and process traceability, which counts more in today’s tender-driven world than any flashy marketing.

    Meeting Today’s Market Needs Without Sacrificing Reliability

    Pricing always figures into buying decisions, but our focus remains on supplying reliable material that meets long-term production needs. Plants running thousands of tons per year rely on predictable supply, not just sticker price on a single order. Consistency in quality cuts both variables and hidden costs for our partners—yield losses, downtime, or costly adjustments can add up quickly if raw materials swing batch to batch.

    By investing in technology and keeping open lines with industrial chemists and plant supervisors, we remain responsive in the face of changing technical requirements. Newer dye chemistries, stricter waste rules, and the shift to water-saving dyehouse methods all drive us to make our sodium 5-hydroxynaphthalene-1-sulphonate more than just a technical grade chemical, but a reliable building block in advanced manufacturing. Our job is to meet that challenge through honest manufacturing, steady improvement, and close partnership from order to final use.