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Sodium 1,2,3-Triazole-5-Thiolate

    • Product Name Sodium 1,2,3-Triazole-5-Thiolate
    • Alias Sodium 5-mercapto-1H-1,2,3-triazole
    • Einecs 247-371-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
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    Specifications

    HS Code

    712045

    Chemical Name Sodium 1,2,3-Triazole-5-Thiolate
    Molecular Formula C2H2N3SNa
    Molecular Weight 123.12 g/mol
    Cas Number 34641-97-5
    Appearance White to off-white powder
    Solubility Soluble in water
    Melting Point Decomposes before melting
    Storage Conditions Store in a cool, dry place, tightly closed container
    Ph Neutral to slightly basic in aqueous solution
    Synonyms Sodium triazole-5-thiolate
    Stability Stable under recommended storage conditions
    Odor Odorless

    As an accredited Sodium 1,2,3-Triazole-5-Thiolate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing White HDPE bottle, screw cap sealed, labeled with hazard symbols, contains 25 grams Sodium 1,2,3-Triazole-5-Thiolate, desiccant included.
    Shipping Sodium 1,2,3-Triazole-5-Thiolate should be shipped in tightly sealed, chemical-resistant containers, protected from moisture and light. Transport according to local and international regulations for hazardous chemicals. Label clearly with hazard information. Avoid contact with acids and oxidizers. Handle with care, using appropriate personal protective equipment (PPE) during packing and unpacking.
    Storage **Sodium 1,2,3-Triazole-5-Thiolate** should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from moisture, acids, and oxidizing agents. Protect it from light and incompatible substances. Ensure the storage area is equipped with appropriate spill containment and is clearly labeled. Use only non-reactive shelving and avoid excessive heat or direct sunlight.
    Application of Sodium 1,2,3-Triazole-5-Thiolate

    Applications of Sodium 1,2,3-Triazole-5-Thiolate in Industrial Manufacturing

    Sodium 1,2,3-Triazole-5-Thiolate serves as a critical intermediate and functional additive in several industrial production lines where high-performance corrosion inhibition, targeted organic synthesis, and specialty chemical formulations are required. As the direct producer, we support various sectors with material tailored for consistent integration, precise dosages, and compliance with established quality and safety parameters.

    1. Corrosion Inhibitors for Water Treatment Chemicals

    In industrial water treatment, especially closed-loop heating and cooling water systems, this raw material acts as a highly effective copper and alloy corrosion inhibitor. Its thiolate group forms a protective film with metal ions, minimizing pitting and electrolytic degradation even under fluctuating pH and temperature. Operators introduce this compound directly during the make-up water phase or maintenance dosing to stabilize system metals in power plants, HVAC cooling towers, and process piping.

    Industry compliance standards

    • ASTM G31—Standard Practice for Laboratory Immersion Corrosion Testing
    • EU Biocidal Products Regulation (BPR, Regulation (EU) 528/2012)
    • ISO 5667 for Water Quality Sampling Programs
    • US EPA Guidelines on Water Additive Approval (Drinking Water Additives/Coatings)

    Typical usage ratio

    • Apply at 5–50 ppm depending on system metal composition, chloride content, and recirculation rates.
    • Adjust concentration higher for systems with elevated copper or brine exposure.

    Downstream process integration

    • Dosed into water tanks, circulation lines, or automated dosing pumps immediately after system start-up or after chemical cleanouts.
    • Compatible with pre-blending into multi-component inhibitor packages with phosphonates, azoles, or polycarboxylates.

    Final product types

    • Industrial corrosion inhibitor concentrates
    • Multi-metal cooling water treatment blends
    • Pre-mixed power plant system protection liquids
    • Closed circuit boiler and HVAC inhibitor solutions

    2. Synthesis of Specialty Triazole Derivatives in Fine Chemical Production

    Chemical manufacturers leverage Sodium 1,2,3-Triazole-5-Thiolate as a nucleophilic reagent and key intermediate to synthesize bespoke triazole derivatives. These high-purity compounds play an essential role in producing agrochemicals, API building blocks, and photoinitiators. Typical processes include nucleophilic substitution and cyclization reactions under controlled conditions, resulting in high-selectivity routes for target molecules that conventional azoles cannot achieve.

    Industry compliance standards

    • Current Good Manufacturing Practice (cGMP, ICH Q7 for APIs)
    • REACH (EC 1907/2006) registration for intermediates
    • ISO 9001:2015 Quality Management Systems
    • Synthetic organic chemistry best practices for trace metal and impurity control

    Typical usage ratio

    • Stoichiometric or slight excess ratios: 1.05–1.20 equivalents per target electrophile.
    • Process chemists optimize input based on yield and downstream purification efficiency.

    Downstream process integration

    • Introduced to batch reactors after charge-in of solvents and partners under nitrogen or controlled-temperature conditions (20–80°C).
    • Purification via crystallization, extraction, or preparative chromatography follows completion.

    Final product types

    • Pesticide intermediates (e.g., triazole-based fungicides)
    • Pharmaceutical API precursors containing triazole rings
    • Photo-curable resin monomers
    • Customized triazolyl ligands for catalysis

    3. Electroplating Bath Additives for Printed Circuit Board (PCB) Manufacturing

    PCB fabricators use this ingredient as a sulfur-containing brightener and complexing agent in copper and tin electroplating baths. Its unique structure enables fine-grained, uniform metallic coatings by modulating cathodic polarization, grain refiner deposition, and metal adhesion. It enters the electrolytic bath tank, synchronizing with pulse-plating schedules for high-density interconnect (HDI) and multilayer PCBs targeting advanced electronics applications.

    Industry compliance standards

    • IPC-6012—Qualification and Performance Specification for Rigid Printed Boards
    • RoHS (2011/65/EU) and REACH compliance for heavy metal and additive restrictions
    • UL 796 Certification for Printed-Wiring Boards
    • In-house plating solution authentication by AOI and XRF analysis

    Typical usage ratio

    • 0.05–0.5 g/L bath concentration, with adjustments based on deposition thickness and bath turnover rate.
    • Continuous monitoring by titration or inline sensors for process stability.

    Downstream process integration

    • Direct addition to copper or tin plating baths prior to start of plating lot.
    • Maintained via continuous feed system for high throughput PCB lines or periodic manual boost.

    Final product types

    • HDI and flexible PCBs with fine line spacing
    • Multilayer electronic circuit boards for automotive and telecommunications
    • Surface-finished, corrosion-resistant copper foils
    • Microvia electroplating in next-generation semiconductor substrates

    4. Vulcanization Accelerator Synthesis for Rubber Processing

    Rubber compounding plants utilize this raw material in the synthesis of specialty triazole-derived accelerators. These accelerators, when incorporated into sulfur vulcanization systems, deliver defined cure rates and improved crosslinking efficiency for industrial rubber goods. Producers conduct condensation and cyclization reactions with this compound to manufacture downstream additives specifically suited for tires, hoses, and technical rubber parts that demand precise thermal and mechanical performance.

    Industry compliance standards

    • ISO 9001:2015 Quality Systems for chemical manufacturing
    • ASTM D2084—Rubber Property—Cure Characteristics Measurement
    • EU REACH registration for triazole-accelerator intermediates
    • Industry-specific restricted substance protocols for automotive and heavy machinery

    Typical usage ratio

    • 0.2–2.0% by weight of accelerator during vulcanization additive synthesis.
    • Final accelerator addition to rubber formulation at 0.1–1 phr (parts per hundred rubber), tailored by cure curve data.

    Downstream process integration

    • Charged into accelerator synthesis reaction under controlled pH and inert atmosphere (nitrogen or argon).
    • Finalized accelerator filtered and pelletized before blending into rubber masterbatch mixes.

    Final product types

    • High-performance rubber vulcanization accelerators
    • Radial tire treads and inner liners
    • Automotive sealants and vibration isolators
    • Flexible industrial hoses and conveyor belts

    5. Photostabilizer Precursor for UV-Resistant Polymer Additives

    Polymer additive manufacturers employ this intermediate in the synthesis of innovative photostabilizers. These downstream stabilizers protect plastics and fibers from UV-induced degradation, color fading, and physical property loss. The raw material enters key ring-opening reactions, yielding triazole-thio derivatives with strong UV absorption and radical quenching capacity—essential for automotive, outdoor construction, and synthetic fiber markets.

    Industry compliance standards

    • ISO 4892—Plastics—Methods for Exposure to Laboratory Light Sources
    • FDA 21 CFR § 177.1520 Polymer Additive Approvals (where applicable)
    • EN 13523-10: Coil Coated Metals—Resistance to UV Light
    • Quality control under ISO 9001:2015 for additive synthesis

    Typical usage ratio

    • As synthesize precursor: 1.0–1.5 equivalents to target alkyl or aryl halide partners.
    • Finished photostabilizer loading in polymer: 0.05–0.5% by weight.

    Downstream process integration

    • Fed to reactors in bulk or semi-batch operation for condensation with UV-active partners.
    • Final additive purified, dried, and pelletized before blending with base polymer granules.

    Final product types

    • Hindered amine light stabilizers (HALS) precursors
    • UV-resistant polyethylene and polycarbonate compounds
    • Outdoor building plastics and automotive trim components
    • Weatherable synthetic fibers for textiles and geotextiles

    6. Copper Surface Passivation in Electronic Component Assembly

    Assembly lines for connectors, relays, and terminal blocks employ thiolate-based passivators for selective copper surface treatment. The sulfur content in this compound forms an adherent, conductive, but oxidation-resistant layer on copper, improving solderability and reducing contact resistance for high-reliability electrical parts. Operators apply the treatment as a dip or spray pre-process, minimizing downtime in automated soldering and final packaging sectors.

    Industry compliance standards

    • IEC 60068-2 Environmental Testing—Surface Insulation Resistance
    • IPC-A-610 for Electronic Assemblies Acceptability
    • ANSI/J-STD-003—Solderability Tests for Printed Boards
    • RoHS-compliance for surface finishing agents

    Typical usage ratio

    • 1–10 g/L in aqueous passivation bath, depending on copper thickness and cycle time.
    • Short immersion times: 30 seconds to 2 minutes for best surface coverage.

    Downstream process integration

    • Deployed in pre-solder dip tanks or inline spray systems before assembly or component packaging.
    • Integrated with post-rinse and forced-air drying steps to prevent moisture/fingerprint issues.

    Final product types

    • Electronic relays and switch contacts
    • Connector/block assemblies for electrical harnesses
    • Silver-plated copper wire terminals
    • Surface-finished busbars for low-voltage switchgear
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    Certification & Compliance
    More Introduction

    Sodium 1,2,3-Triazole-5-Thiolate: Precision and Reliability in Every Batch

    Understanding the Product

    Sodium 1,2,3-Triazole-5-Thiolate stands out among triazole derivatives through its tight molecular structure and efficient reactivity profile. Working with chemicals every day, people like us in the manufacturing end see the unique features of this compound both in the consistency of the finished material and in how end users—the formulators, technologists, and plant operators—can rely on it perform the same way with every delivery. The sodium salt form of triazole-5-thiol offers easy handling, stable storage, and compatibility with various formulations, which keeps it at the front among choices for thiolating agents or as a building block in custom synthesis.

    Specifications We Trust

    High-purity sodium 1,2,3-triazole-5-thiolate usually arrives as a pale yellow to off-white powder, free-flowing and easy to measure. Our standard model (with CAS number 34673-38-0) comes with a triazole content above 98%, and moisture content stays below 0.5%. Chemical workers appreciate the low hydroscopicity—handling remains straightforward in typical industrial environments, and the material avoids unwanted caking or loss of activity under ordinary warehouse conditions. For analytical work, elemental sodium appears right on the dot at around the expected stoichiometry, and sulfhydryl group content aligns precisely with synthetic demands.

    What that means on the floor: you can trust the material to stay ready and active whether it’s shipping cross-country or sitting in your blending area for a week. Technicians value the absence of dust issues and the way the powder behaves in solution, letting them scale up new batches without having to recalibrate every chemical addition. That reliability cuts down total production time and reduces headaches, especially when switching between large and small scale synthesis.

    Applications in Industry

    Sodium 1,2,3-triazole-5-thiolate plays an important role in the synthesis of heterocycles, where its sulfur atom reacts cleanly with electrophiles in both laboratory and plant settings. This makes it a popular intermediate for custom APIs—not just in pilot lots but scaled up to tons for pharmaceutical production. You’ll spot it in crop protection development too, thanks to its ability to attach to aromatic rings and form sturdy sulfur bridges, a property that’s essential for the new wave of target-specific agrochemicals.

    Its performance as a corrosion inhibitor draws attention from engineers responsible for pipelines, process equipment, and heat exchangers, especially in sectors working with harsh brines or aggressive cooling systems. The triazole backbone resists oxidative degradation, so it clings to metal surfaces longer than similar thiols, extending the time between shutdowns or maintenance cycles.

    The versatility goes further—people use this compound in dye chemistry for introducing sulfur-containing groups into colorants, tuning shade stability, and anchor properties on fibers. The textile field, always looking for more durable and colorfast products, benefits from the steady performance of sodium 1,2,3-triazole-5-thiolate. We’ve seen customers use it to improve pigment adhesion or as a precursor in creating new polymer additives, and the results match or beat their expectations every time.

    Comparing with Other Thiol Sources

    Anyone familiar with thiolate chemistry knows the difficulties of sodium mercaptide or similar low molecular weight thiols—handling hazards, unpredictable reactivity, strong odors, and storage headaches. Sodium 1,2,3-triazole-5-thiolate changes that experience. Compared to sodium mercaptobenzothiazole, it brings a milder odor profile and greater stability against air oxidation. Traditional sodium hydrogen sulfide has never matched the safety and selectivity profile here, given the risk of hydrogen sulfide release and the possibility of strong base degradation.

    Our team watched purchasing departments weigh up the real costs: sure, bulk price sits a little higher than some baseline thiol sources, but fewer batch rejects, easier shipping, and better storage stability shrink total costs per kilo of finished product. Operators taught us that you win more from a chemical you can trust, every time you open a new package—fewer reworks, fewer stoppages, and cleaner equipment at the end of the shift. When you start using sodium 1,2,3-triazole-5-thiolate, its predictability puts you ahead in both safe handling and synthesis targets hit on the first try.

    We’ve taken material side-by-side with competitive alkali triazoles, and every time we focused on process efficiency, ours offered smoother dissolution and less intervention during charge. That pays back, not just in achieved yields, but in lower overhead for cleaning, waste treatment, and corrective maintenance.

    Consistency and Quality: From Our Plant to Yours

    Decades in chemical plant experience have taught us that repeatability isn’t just a box to check for audits—it’s what keeps lines running, teams safe, and customers happy. Every lot of sodium 1,2,3-triazole-5-thiolate goes through multi-step verification. We screen for trace impurities, monitor pH range (to keep it between 8.5–10 in aqueous solutions), and test long-term behavior under typical warehouse conditions. Customers testing our material often send back the same feedback: dissolved solution stays clear, reaction end-points remain sharp, and downstream filtration doesn’t stall out. We track customer feedback closely and adjust particle sizing as needed, always staying within the limits for safe pneumatic handling and blending.

    Quality assurance doesn’t end at “meets spec” paperwork. Our process engineers actively look for root causes of any deviation—down to microscopy on crystal habit and surface area measurement for each lot. That level of detail makes a real difference in high-throughput applications, where even a slight difference in dissolution speed can back up the entire batch. Keeping gas evolution at a minimum, we prevent dangerous pressure build-ups, especially relevant in large reactors with little headspace.

    Environmental and Safety Considerations

    With thiol chemistry, safety cannot take a back seat. Sodium 1,2,3-triazole-5-thiolate strikes a balance between powerful reactivity and practical safety. The sodium salt, unlike many organosulfur liquids, resists rapid oxidation and doesn’t emit the characteristic pungent odor. Most operators note that air monitoring requirements drop, and, barring spills or heating far above 100 ºC, indoor air stays within occupational limits for total sulfur and triazole vapors.

    Controlling waste streams goes smoother as well. Our product dissolves readily in water, forming a clear, slightly alkaline solution. In the event of accidental release, neutralization with diluted acid brings the waste stream pH into manageable range for municipal treatment. The stability of the triazole ring helps lower the risk for secondary reactions, which reduces the number and complexity of byproducts requiring downstream removal.

    Disposal regulations vary greatly, but we see customers able to meet their local standards with minimal pretreatment. As always, we stress to customers that PPE, good ventilation, and handling protocols matter more with industrial thiols than with simple salts. In years of shipping and support, feedback confirms that incidents occur less frequently than with more volatile or corrosive thiol sources.

    Our Approach to Reliability and Supply Chain Management

    Manufacturing sodium 1,2,3-triazole-5-thiolate consistently at scale brought challenges over the years. Consistent quality needed tight upstream control—starting from high-spec raw azide, pure sodium, and crisp control at every reduction step. We invested in instrumentation for batch real-time monitoring, catching any off-color formation before it reaches final crystallization. The end product shows its worth both in the assay report and in how smoothly customers transition from R&D to scale-up.

    We communicate closely with logistics teams to ensure shelf-life promises are kept. Our standard packaging uses heavy-duty multi-layer bags with secondary containment, guarding against leaks and moisture uptake even in long transit. Customers in hot, humid locations receive material fresh, in the same free-flowing form as it left our plant, because we lock down shipment timing and use humidity indicators with high-volume contracts.

    Material traceability forms another backbone—batch numbers, synthesis route verification, and long-term archiving connect every kilogram to its process records. This backup protects not only our long-term business, but gives customers the confidence to pass even the most detailed regulatory audits.

    Technical Support and Partnership

    The distance between the chemical factory and the process room on the customer end always shrinks with good support. We pay attention to supporting users with data, but technical advice comes informed by our own scale-up trials, troubleshooting experience, and customer process walkthroughs. Whenever a customer faces new impurity profiles, our chemists walk through all possible side reactions, helping de-risk the next step—either by purity adjustment, tailored particle size, or consultation on process equipment that best fits the compound’s character.

    Sometimes a new process demands a pilot lot with slight tweaks. Our team can shift reactor conditions or purification, working with the customer’s spec instead of wedging them into a standard cut. Not every plant can do this flexibly—our investment in modular process units pays off when customers call for those one-off runs or fast turnarounds. Every solution we suggest—whether it’s dilution in a particular solvent or a swap in downstream isolation—is backed by firsthand lab data, not generic advice.

    Questions about dissolution, compatibility with other reagents, or scale-up safety usually come up early in the adoption process. We help site managers predict potential bottlenecks, avoid mixing hazards, and get their personnel comfortable with the product format long before full production starts. Our internal knowledge base grows with every tech consult—in the last five years, we’ve built a reference set spanning synthetic dyes, advanced pharma, agrochemical intermediates, and specialty resins.

    No solution comes from a helpdesk script. It's real engineers talking to engineers, process chemists working both sides of the line, and direct feedback baked into product improvement. Where needed, we supply test data, offer trial lots, and follow up after production to see how the compound performed in the customer’s unique system.

    Continuous Improvement: Closing the Loop

    Our relationship with sodium 1,2,3-triazole-5-thiolate isn’t static—we see ways to improve every year. After major audits or during routine reviews, process data points to small optimizations. By shaving seconds from reaction times or tightening filtration yield, our own batch cycle time gets better. When customers give feedback on unexpected color changes or microfine residues, we chase down every possible upstream adjustment. That means cleaned feed lines, shave-downs on milling steps, or even tweaks in pH during crystallization.

    We incorporate this data not just for compliance, but because every manufacturing improvement cuts risk and passes value right down the line. Turnover speed in the plant improves, and our customers don’t face interruptions or late deliveries. Sustainability isn’t just a buzzword—minimizing waste and reworks reduces energy and material input, and safer handling lowers insurance and training costs for everyone.

    We also invest energy into downstream research—testing compatibility of our sodium 1,2,3-triazole-5-thiolate with greener solvents, looking for ways to lower the total system VOC load, and supporting customers developing water-based formulations. Our in-house team sees a direct tie between the chemical’s structure, the way it flows and dissolves in the plant, and the long-term cost structures that matter to customers under ever tighter compliance rules.

    Closing Thoughts: Experience and Trust Delivered

    Working for years as a manufacturer, we move beyond just meeting numbers on a spec sheet. Every batch of sodium 1,2,3-triazole-5-thiolate we send reflects that mindset—tested by our staff, proven by industrial partners from the plant floor to the QC lab. We favor close, technical relationships with end users, always aiming to learn from their process feedback and incorporate actual industrial needs back into every run. That perspective—rooted in practical know-how and a hands-on understanding—keeps our sodium 1,2,3-triazole-5-thiolate not just competitive, but valued by operations teams across different industries.

    Every kilogram is a promise: precise, reliable, and engineered for the realities of chemical manufacturing. This isn't just fulfilling orders. It's earning trust—one synthesis, one tank, and one satisfied partner at a time.