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Rhenium Carbonyl

    • Product Name Rhenium Carbonyl
    • Alias Rhenium carbonyl Re
    • Einecs 235-034-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    992579

    Chemical Name Rhenium Carbonyl
    Chemical Formula Re2(CO)10
    Appearance Yellow to orange crystalline solid
    Melting Point 177°C
    Solubility In Water Insoluble
    Solubility In Organic Solvents Soluble in benzene, chloroform, and ether
    Density 2.43 g/cm3
    Cas Number 14285-68-8
    Main Hazard Toxic if inhaled or swallowed
    Odor Odorless
    Stability Stable under normal temperatures and pressures

    As an accredited Rhenium Carbonyl factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Rhenium Carbonyl, 25g, is supplied in a sealed amber glass bottle with a secure screw cap, labeled with hazard warnings.
    Shipping Rhenium Carbonyl is shipped in tightly sealed containers under inert atmosphere to prevent decomposition. It is classified as a hazardous material and subject to regulations for toxic and flammable substances. Handling requires appropriate labeling, and transport is typically via ground or air in compliance with international chemical safety standards.
    Storage Rhenium carbonyl should be stored in a tightly sealed container, under an inert atmosphere like nitrogen or argon, in a cool, dry, and well-ventilated area. Protect it from moisture, air, direct sunlight, and sources of ignition, as it is sensitive to air and light. Storage in a chemical fume hood is advisable due to its toxicity and potential to release carbon monoxide.
    Application of Rhenium Carbonyl

    Applications of Rhenium Carbonyl in Industrial Manufacturing

    Rhenium carbonyl serves as a specialty chemical intermediate and catalyst precursor across several highly regulated industrial fields. As a direct manufacturer, we supply this compound to certified downstream partners for critical operations where precise transition metal chemistry is required. Our production, quality control, and technical documentation meet stringent international expectations, supporting reliable process reproducibility in all applications below.

    1. Catalytic Hydrogenation Catalyst Manufacturing

    Catalyst producers employ rhenium carbonyl as a source of metallic rhenium when formulating advanced supported or mixed-metal hydrogenation catalysts, widely used in fine chemical, pharmaceutical, and petrochemical sectors. The compound decomposes to disperse rhenium evenly onto oxide supports or alloys, facilitating highly selective hydrogenation catalysts. Our clients use this raw material in controlled environments to guarantee high metal dispersion, essential for manufacturing next-generation catalyst products meeting global environmental and performance regulations.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems for catalyst manufacturing
    • REACH (EC 1907/2006) registration and handling for chemical precursors in the EU
    • 21 CFR Part 211 (U.S. FDA cGMP) for pharmaceutical catalyst intermediates
    • API RP 751 (Petroleum Refining)

    Typical usage ratio

    • 0.1–2.5 wt% rhenium relative to total catalyst mass, adjusted by required catalytic activity and support material
    • Loading varies depending on downstream application—lower end for petrochemical, higher loadings for fine chemical or specialty catalysts

    Downstream process integration

    • Impregnation or co-precipitation onto alumina, silica, or carbon supports, followed by thermal decomposition and reduction under H2 or inert gas atmosphere
    • Used as a final doping step in bimetallic catalyst preps, typically following primary metal loading

    Final product types

    • Rhenium-promoted platinum or palladium hydrogenation catalysts
    • Low-temperature aromatics hydrogenation beds
    • Hydrodesulfurization and hydrocracking catalysts
    • Customized catalytic formulations for pharmaceutical synthesis

    2. Chemical Vapor Deposition (CVD) Precursor for Microelectronics

    Leading electronic materials processors depend on rhenium carbonyl as a volatile precursor for depositing ultrapure rhenium films and nanostructures via CVD and related methods. The compound enables precise gas-phase delivery of rhenium within reaction chambers, supporting the fabrication of niche semiconductor structures, superconducting contacts, and MEMS devices that demand high-purity and uniformity. Material purity, controlled decomposition, and traceability are essential requirements in this segment, which we address through documented batch traceability and analytical support.

    Industry compliance standards

    • SEMI C3-1212 (Specifications for High-Purity Specialty Gases)
    • RoHS Directive 2011/65/EU regarding restricted substances in electronics
    • IATF 16949:2016 for automotive semiconductor supplier quality
    • ISO/TS 16949 and ISO 14001 for environmentally managed microelectronics production

    Typical usage ratio

    • Flow rates typically range from 0.05–0.2 mmol/min of rhenium carbonyl vapor, adjusted for film thickness and deposition area
    • Precursor concentration tailored to precursor delivery system and desired layer properties

    Downstream process integration

    • Loaded into heated bubblers for vapor-phase transport
    • Introduced with carrier gases such as Ar, N2, or H2 into CVD reactors operating at 150–400 °C
    • Thermal decomposition yields metallic rhenium films or nanoparticles onto heated substrates

    Final product types

    • Thin rhenium metallization in microelectronic chips
    • Superconducting contacts and interconnects in quantum circuits
    • MEMS device coatings
    • Microfabricated sensors integrating rhenium layers

    3. Homogeneous Catalysis for Olefin Metathesis and Specialty Polymers

    Manufacturers developing specialty polymers and advanced organic intermediates utilize rhenium carbonyl complexes as homogeneous metathesis and carbonylation catalysts. In these high-value processes, rhenium carbonyl derivatives serve as in-situ catalyst precursors, promoting specific bond rearrangements under stringent batch or continuous reactor protocols. Quality and purity are heavily scrutinized to maintain reproducibility and minimize side product formation, especially for polymers and intermediates destined for regulated performance markets.

    Industry compliance standards

    • ISO 9001:2015 for chemical manufacturing
    • GMP guidelines (ICH Q7) for pharmaceutical intermediates
    • US EPA TSCA (Toxic Substances Control Act) regulations for chemical process safety
    • REACH Annex XVII handling for rhenium compounds in EU polymer industry

    Typical usage ratio

    • 5–100 ppm (parts per million) of rhenium metal relative to monomer or substrate charge, depending on catalyst activity profile
    • Adjusted according to substrate nature, required turnover frequency, and downstream purification capability

    Downstream process integration

    • Direct charging into batch reactors preloaded with substrate and ligand system
    • Continuous metered dosing into continuous stir tank reactors (CSTRs) for large scale polymer or fine chemical runs

    Final product types

    • Specialty cyclic olefin polymers (COPs) and copolymers
    • Functionalized organic intermediates for pharmaceutical or agrochemical synthesis
    • Advanced engineering plastics with tailored mechanical properties

    4. Synthesis of Rhenium Complexes for Analytical and Spectroscopic Reagents

    Scientific reagent manufacturers use rhenium carbonyl as the precursor for synthesizing various rhenium-based spectroscopic and analytical complexes, particularly in X-ray fluorescence (XRF) calibration, Mössbauer studies, and organometallic research. Consistent batch purity and trace metal control are critical for downstream users to produce high-quality calibration standards and reference materials deployed in regulated labs and industrial quality control roles.

    Industry compliance standards

    • GLP (Good Laboratory Practice) standards for analytical reagent manufacturing
    • ISO/IEC 17025 accreditation for laboratory testing and calibration suppliers
    • ASTM E2857 (Standard Guide for Analytical Reagents)
    • REACH registration for analytical supply chains within the EU

    Typical usage ratio

    • 1–10 mmol carbonyl per batch, depending on the scale of reagent synthesis and final complex concentration requirements
    • Stoichiometrically determined by target rhenium content in reference complex

    Downstream process integration

    • Dissolution in dry organic solvents under inert atmosphere followed by ligand exchange or complexation with specified ligands
    • Introduced into flask or ampoule operations under controlled temperature and atmosphere for high purity complex formation

    Final product types

    • XRF and ICP analytical calibration standards for trace rhenium analysis
    • Reference organometallic complexes for spectroscopic benchmarking
    • Specialty kits for chemical and academic research applications

    5. Advanced Metal Powder Sintering for Aerospace Superalloys

    Aerospace material producers incorporate rhenium carbonyl as a rhenium source for synthesizing high-density rhenium powder, subsequently alloyed with nickel or cobalt superalloys through powder metallurgy. This method enables fine elemental dispersion in turbine blade and combustor superalloy powder, supporting prolonged component life under extreme thermal stress. Throughout, manufacturers adhere to global aerospace material specifications and maintain rigorous traceability to guarantee certification in engine and space applications.

    Industry compliance standards

    • AMS 6477 (Aerospace Material Specification for rhenium powders)
    • AS9100D for aerospace quality management
    • ISO 9001:2015 for metal powder processing
    • NAS 410 nondestructive testing procedures for powder metallurgy parts

    Typical usage ratio

    • 2%–7% w/w rhenium content in superalloy powder blends, based on turbine OEM material requirements
    • Initial rhenium carbonyl batch charge calculated from final rhenium target in alloy system

    Downstream process integration

    • Thermal decomposition under reducing atmosphere to produce highly pure metallic rhenium powder
    • Powder blending and spheroidization used prior to hot isostatic pressing (HIP) or additive manufacturing feedstock preparation

    Final product types

    • Nickel- and cobalt-based superalloy turbine blades
    • Rocket nozzle liners
    • High-temperature aerospace fasteners and components
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    Certification & Compliance
    More Introduction

    Rhenium Carbonyl: Developing Chemical Innovation from Manufacturing Experience

    Understanding the Real Value of Rhenium Carbonyl in Industry

    Our facility produces rhenium carbonyl from high-purity rhenium sourced directly from mining operations vetted for responsible environmental and social practices. Years of dedication in chemical manufacturing have proven rhenium carbonyl is not just a specialty product, but a cornerstone for high-performance catalysts, organic synthesis, and even advanced electronics. With a chemical formula of Re2(CO)10, rhenium carbonyl arrives as a red-orange solid—distinct in appearance and unmistakable for anyone familiar with rare metal complexes. We track every batch’s purity, particulate size, and moisture sensitivity because even slight inconsistencies can compromise downstream work with organometallic synthesis or catalysis.

    Production Insights: What Sets Our Rhenium Carbonyl Apart

    Other producers may promise high purity but some stop short at the certificate. We measure purity beyond 99.99%, verified by real-world analytic runs, not just mass-spec printouts from a batch’s best sample. What makes the difference isn’t just the Re content—it’s rigorous control over residual solvents, chloride, and sulfur. Rhenium carbonyl reacts with oxygen and light; our team runs every step under inert atmosphere, in dedicated lines. We keep packaging times short and use customized storage containers, limiting contact with environmental moisture. Routinely, researchers call and thank us for a product that keeps its integrity long after shipping, something only achievable by treating each stage of production as a critical point.

    Performance in Catalysis: Going Beyond Academic Examples

    Our rhenium carbonyl finds its audience not just in research labs, but also in pilot and commercial scale hydrogenation and olefin metathesis. In our early days, a handful of catalyst developers approached us when their yields dropped using generic rhenium sources. We offered Re2(CO)10 made under our protocol and watched as catalyst lifetimes stabilized and selectivity sharpened. For example, in systems requiring homogeneous Re catalysts for fine-chem intermediates, we documented less decomposition and more robust conversion cycles, which led to less catalyst turnover and fewer impurities in target products.

    Every producer touts high-quality, but few discuss repetitive test results over batches and the standards behind their purities. Our analytical routines draw from practical problems: a single contaminated ampoule and your reaction fails. Purity is about trust in industrial operation, not just numbers on a label. As a manufacturer, we have experienced how downtime for contaminated catalyst can jeopardize quarterly output. We built our process around reliability, anticipating batch-to-batch consistency as a real performance metric, not just a marketing claim.

    Synthesis and Reproducibility: The Human Factor Behind the Chemistry

    Many chemists remember the first time they saw rhenium carbonyl’s color shift as it formed—the telltale signal of proper carbonylation and evidence of complex formation complete. We monitor formation by in-line FTIR and UV-Vis, guided by notes taken over decades in the plant. Our staff runs comparative purity checks, not just with intended Re2(CO)10, but also with decomposition products, which teach us how to tune our process as chemistries shift. Several years ago, we shifted reagent purging cycles based on an unexpected infrared peak—a decision informed only by hands-on familiarity with rhenium chemistry and hour-to-hour data review. No algorithm detected it first; one of our supervisors spotted the signal change and adjusted the process conditions real-time. That tradition leads to a higher bar for every kilogram shipped.

    Researchers in medicine and materials science push our batches to their limits. They tell us where even trace byproducts can confound mechanistic studies or slow drug discovery runs. We engineer for fewer side products by controlling reactor geometries, precise temperature profiles, and absolute exclusion of atmospheric oxygen at all stages. Our in-house team sometimes spends weeks on a single root-cause investigation, tracking failure modes through all laboratory and production steps. As a result, we have solved problems others may not even recognize, because we take direct calls from the people running the reactions, not through third-party brokers or intermediaries.

    Material Handling and Logistics: Experience at Every Step

    Shipping rhenium carbonyl is not a straightforward job. The compound decomposes with heat, light, and moisture. We engineered a multi-layer packaging system based on real transportation failures from years past—ampoules cased in nitrogen-purged containers inside temperature-stable crates. Our operations staff still customizes shipping schedules for each customer’s location and environmental risks, based on seasonal data and feedback from logistics teams. We remember summers when unexpected delays meant cargo sat on runways for hours; one such incident taught us to integrate real-time environmental monitoring into our supply chain checks. That particular lesson prevented future damage across all sensitive shipments.

    Customers look to us for flexibility and speed because chemical research works on deadlines, not ideal timetables. Our export paperwork and hazardous material documentation are shaped by direct conversations with customs officials and transport companies, so that packages pass quickly through bottlenecks. Once, after a misplaced customs label put an entire batch at risk of return, we rewrote our documentation templates and retrained our staff in live mock runs. The small details often matter most, and our quality system grew from rolled-up sleeves at loading docks, not policy handbooks on a shelf.

    Comparing Rhenium Carbonyl to Similar Organometallics

    People sometimes ask why they shouldn’t just use molybdenum or tungsten carbonyls, which are often more available or cheaper. Our answer: rhenium’s unique electronic properties translate to practical advantages in catalysis, especially where robust metal-carbonyl bonds are needed. Rhenium complexes tackle specialized reactions in olefin metathesis, selective hydrogenation, and C-H activation where other metals typically lose selectivity or face decomposition. In practice, clients see sharper yields and more stable reaction cycles, particularly in pharmaceutical and high-purity electronics applications.

    We see real differences in customer outcomes, not just literature examples. For instance, tungsten carbonyls often show lower solubility and inferior reactivity toward certain functional groups. Molybdenum offers its own speed but loses selectivity under harsher conditions. Rhenium carbonyl bridges those gaps: its decomposition profile allows for gentler handling, and the metal’s electron density brings catalytic routes unavailable to cheaper metals. The practical result is a broader window for process optimization, visible to chemists running multiple pilot-scale batches.

    We compare our batches under identical laboratory conditions with competing samples. Over time, our Re2(CO)10 demonstrates less off-gassing and slower decomposition in standard atmospheres. That confidence comes from hundreds of real world cycles, not just surveillance in ideal, climate-controlled labs. A new user will notice that reactions using our rhenium carbonyl start clean and stay reproducible; project managers often mention fewer failed screens and less debug time lost to metal contamination.

    Manufacturing Stories: Learning from Experience

    Only someone who has spent years synthesizing rhenium carbonyl under production constraints truly knows how much attention every impurity deserves. One winter, air supply plugged with ice, leading to an unplanned shutdown and a near miss on a major delivery. We learned by audit that a hidden line near the reactor had built up frost and created a condensation pathway for oxygen ingress. No process design textbook flagged the risk at that exact location. From then on, we redesigned our air-handling routines and doubled back on insulation. No batch missed a shipment again for that reason, and our yields ticked up slightly across every run that winter.

    Another lesson came from a handling accident during a pilot scaleup. A single cracked ampoule exposed product to moisture, leading to an unexpected decomposition cascade. We had to run a full root-cause investigation, including interviews at every shift and line, then overhauled our handling systems with new capping and inerting equipment. Not only did we recover the actual yield over the following cycles, but we also reduced employee exposure risk, documented by actual incident rate reduction, not just claims.

    Working as a direct manufacturer gives us these opportunities to react quickly and make changes that really matter. We encourage staff to suggest process improvements and track the results—not with abstract metrics, but with measurable reductions in contamination, higher throughput, and better batch outcomes. A culture of incremental improvement is built not from mandates, but from practical problem-solving, where technicians and chemists bring field knowledge back into the process loop.

    Feedback, Collaboration, and Application Development

    Chemists and engineers who design new reactions or materials routinely ask us about unexplored applications. Some years back, an electronics researcher needed exceptionally pure rhenium carbonyl for doping experimental semiconductors. They turned to us after other vendors failed to deliver material with stable performance. We set up a series of custom syntheses, tuning CO pressure and temperature profiles until we hit the required impurity tolerance. The feedback loop ran directly through our synthesis line, not through layers of distribution or outsourced quality checks. The project succeeded, and the relationship showed how essential manufacturer involvement can be when applications push beyond the typical.

    End-users sometimes request custom particle sizes or specialized ampoule volumes for unique reactor setups. In these cases, we adapt by collaborating directly with the project leads, reviewing process flows to understand where bottlenecks arise—then trialing small batches before scaling to full production. Examples include adapting ampoule design for automated dispensing systems, or precooling containers so delicate substrates arrive ready for use in gloveboxes. These requests teach us as much as any internal audit, and we treat every new use case as a source of knowledge.

    Academic labs often need tailored documentation and traceability. We build complete records for every run, including lot-specific CO purity data and time-stamped process logs, available on request. This level of transparency has helped researchers publish reproducible results and pass academic audits. We believe that sharing details sets realistic expectations and fosters a deeper trust between manufacturer and user.

    Responsible and Sustainable Operation

    Producing rhenium carbonyl draws on critical mineral resources, so we review sourcing at each step. Our operation partners with suppliers willing to document environmental and labor standards. This decision came from confronting reports showing how unsustainable mining can threaten both supply security and local communities’ health. In our experience, transparent relationships protect production lines from geopolitical supply disruptions and preserve long-term customer trust.

    We actively investigate solvent reclamation and off-gas scrubbing. Re2(CO)10 synthesis releases trace carbon monoxide, which we capture with scrubber systems and recycle back into the process. Our waste-handling program evolved after a spill required us to rethink retention ponds and venting circuits. Each incident teaches a lesson that translates to measurable improvement. We report wastes and byproducts clearly, both internally and to regulatory bodies, building a culture where staff know environmental compliance as daily practice.

    Looking Forward: Continuous Improvement from the Manufacturer’s Bench

    Each batch of rhenium carbonyl we produce adds to the collective knowledge bank at our factory. Technicians keep logbooks tracking minor process variations, so we can spot emerging trends or potential risks before they leave the plant. We share anonymized lessons learned at industry forums to help set higher standards for everyone handling rare metal carbonyls. There’s no substitution for firsthand experience, and hands-on oversight at every stage remains our strongest guarantee of safety, quality, and user success.

    Rhenium carbonyl will never be a commodity for upscaling at the lowest price. Its uses in catalysis, materials science, and research require a commitment to precision every time. By retaining direct oversight, making changes based on real feedback, and staying transparent about our processes, we continue to earn the trust of the world’s leading innovators and researchers—batch by batch, day by day.