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Propham

    • Product Name Propham
    • Alias Isopropyl carbanilate
    • Einecs 204-492-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    545539

    Chemical Name Propham
    Common Use Herbicide and sprout suppressant
    Molecular Formula C10H13NO2
    Molar Mass 179.22 g/mol
    Appearance White crystalline solid
    Melting Point 91-93°C
    Solubility In Water 32 mg/L at 25°C
    Cas Number 122-42-9
    Iupac Name Isopropyl N-phenylcarbamate
    Density 1.08 g/cm3
    Vapor Pressure 1.1 × 10−4 Pa at 20°C

    As an accredited Propham factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging for Propham consists of a 25 kg white polyethylene bag, clearly labeled with hazard warnings, product name, and batch number.
    Shipping Propham should be shipped in tightly sealed containers, clearly labeled with appropriate hazard warnings. Transport in accordance with local and international regulations for agricultural chemicals. Avoid excessive heat, moisture, and incompatible substances. Use sturdy packaging to prevent leaks or spills during transit, and ensure documentation accompanies the shipment for safe handling and emergency response.
    Storage Propham should be stored in a cool, dry, well-ventilated area away from sources of heat, sparks, or open flame. Keep containers tightly closed and store away from food, feed, and drinking water. Protect from moisture and direct sunlight. Use appropriate chemical storage containers and label clearly. Ensure storage area is secure and accessible only to authorized personnel.
    Application of Propham

    Applications of Propham in Industrial Manufacturing

    Propham serves as a specialized chemical raw material supporting several industrial application scenarios, primarily within the agriculture and polymer modification sectors. Our manufacturing process ensures consistent quality and compliance with regulatory standards, providing downstream businesses with reliability for their production lines.

    1. Post-Harvest Potato Sprout Inhibition

    In commercial storage and transport of potatoes, Propham plays a critical role as a sprout suppressant. Storage operators treat bulk potatoes directly after harvest or before shipment, using controlled aerosol or liquid application systems. This process keeps stored potatoes marketable and within regulatory germination limits over extended periods. Treatment protocols vary based on regional residue regulations, lot size, and potato variety, and post-application monitoring ensures compliance with residue limits prior to final distribution.

    Industry compliance standards

    • EU Regulation (EC) No 396/2005 on Maximum Residue Levels (MRLs) for pesticides
    • US EPA Tolerances for Residues of Propham (40 CFR Part 180)
    • Japan Food Sanitation Act, MHLW MRL requirements
    • Codex Alimentarius Pesticide Residue Requirements

    Typical usage ratio

    • Applied at 30–50 mg active ingredient per kg potato bulk, based on storage duration
    • Dose adjusted by expected storage period (up to 9 months) and ambient warehouse conditions
    • Periodic reapplication possible, not to exceed total allowed residue levels
    • Formulation can be aqueous solution, emulsion, or direct powder, tailored by equipment

    Downstream process integration

    • Direct application during initial warehouse loading
    • Surface treatment using conveyor spray or fogging systems
    • In-tunnel recirculating systems for uniform coverage in large-scale storage
    • Residue analysis performed before batch release to processing or sale

    Final product types

    • Fresh table potatoes delivered to supermarkets and wholesale markets
    • Raw material potatoes for chip and crisp production
    • Potatoes designated for processing (French fries, dehydrated flakes)
    • Seed potatoes with controlled sprouting during interim storage

    2. Polymer Intermediate for Aromatic Polyurethanes

    Industrial polyol and isocyanate producers utilize Propham as a chain stopper or structural modifier, especially in producing certain aromatic polyurethane materials. This use supports tailored polymer chain length or functionality, influencing properties like flexibility or thermal performance. Our material undergoes in-line QC for purity to minimize side reactions that could impact downstream polymer performance.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006 Registration, Evaluation, Authorisation and Restriction of Chemicals
    • ISO 9001 Quality Management System for chemical process control
    • Specific customer material specifications for aromatic content and impurity limits
    • Lot traceability according to automotive or electronics sector supply chain requirements

    Typical usage ratio

    • 1–8% by weight relative to diisocyanate monomer feedstock, depending on end-use flexibility requirements
    • Exact loading determined by chain length and hydroxyl number in the prepolymer mix
    • Adjustment possible for temperature or catalyst system used downstream
    • Purity requirements: ≥98%, water content ≤0.5%

    Downstream process integration

    • Added at pre-polyol blend stage in polyaddition reactors
    • Staged addition to control molecular weight development
    • In-line monitoring of viscosity and NCO value after Propham addition
    • Final cast or foamed product curing follows controlled oven or mold temperature profile

    Final product types

    • Flexible foams for automotive and furniture cushioning
    • Non-foamed elastomeric sheets and technical parts
    • High-resilience adhesives and sealants
    • Coating binders for engineered surface finishes

    3. Laboratory Reagent for Organic Synthesis

    Specialty synthesis laboratories and research units use Propham as a carbanilate reagent for the preparation of carbamate derivatives. Reliable batch-to-batch purity and detailed analytics are essential here, as downstream reactions often involve pharmaceutical intermediates or crop protection research. Our supply supports accredited labs requiring consistent analytical performance for synthesis screening and scale-up.

    Industry compliance standards

    • ISO/IEC 17025 Accreditation for testing laboratory practices
    • Good Laboratory Practice (GLP) as per OECD Principles
    • Certificate of Analysis (COA) with each lot, including NMR and HPLC data
    • US Pharmacopeia (USP) General Chapter 621 for chromatography if used in pharma R&D

    Typical usage ratio

    • Equimolar to excess (1.0–1.5 equivalents) against intended amino or hydroxyl substrate
    • Concentration in organic solvent: 0.1–0.5 mol/L typical
    • Adjustment based on specific synthetic method (e.g., SN2, acylation routes)
    • Packaged for laboratory-scale or pilot-plant trials

    Downstream process integration

    • Dissolved in dry organic solvent under inert atmosphere
    • Introduced into controlled-temperature batch or continuous microreactors
    • Followed by in-process sampling and analysis for conversion and purity
    • Post-synthesis workup includes purification and analytical QC

    Final product types

    • Intermediate carbamates for pharmaceutical research
    • Custom reagents for agrochemical candidate libraries
    • Reference standards for QC and method validation
    • Functionalized building blocks for advanced materials R&D

    4. Co-Formulant in Crop Protection Mixtures

    Agrochemical formulators employ Propham as an auxiliary stabilizer or carrier in mixed sprout-control formulations, where it optimizes release profiles of other actives. The substance is chosen for its chemical compatibility and low volatility, allowing precise blending in manufacturing under GMP-like guidelines. This application demands controlled particle size and rapid dissolution properties, enabling even field distribution and predictable residue behavior.

    Industry compliance standards

    • FAO/WHO Joint Meeting on Pesticide Specifications (JMPS) standards for formulation quality
    • ISO 9001 and ISO 14001 certification for manufacturing and environmental controls
    • EU Regulation (EC) No 1107/2009 for placing plant protection products on the market
    • Local country registration and notification systems (e.g., US EPA FIFRA, China ICAMA)

    Typical usage ratio

    • Co-formulated at 10–35% by mass for dry blend products
    • Lower ratios (3–8%) in complex multi-active ready-mix solutions
    • Adjusted according to efficacy trials and compatibility with other technical materials
    • Granule, powder, and emulsion concentrate formulations supported

    Downstream process integration

    • Homogenized with other solid actives and inert carriers during dry blending
    • Pre-mixed in granulation units for water-dispersible granules
    • Dissolved or dispersed in batch or continuous mixers for liquid concentrate products
    • Post-blend sieving and particle size control for application consistency

    Final product types

    • Sprout-inhibitor powder premixes for farm supply
    • Granular field formulations for controlled-release
    • Multi-component crop protection spray concentrates
    • Stabilized liquid suspension concentrates for large-acreage applications
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    Certification & Compliance
    More Introduction

    Propham – A Direct Manufacturer’s Perspective on Its Role and Value

    Introduction to Propham as We Manufacture It

    Every year, our facility produces Propham in batches that require a careful balance of chemistry, plant management, and real-world agricultural insight. The name Propham stands for isopropyl 3-phenylcarbamate, a product rooted in decades of practical use in crop protection. Over the years, we have invested in refining both purity and consistency, learning from each production run what matters most to end-users in the field and those managing food supply chains. From our perspective as the manufacturer, every kilogram that leaves our site has been made with an attention to real needs—crop uniformity and storability, avoidance of sprouting, and compliance with food safety standards.

    Core Chemical Details and Manufacturing Choices

    We produce Propham with a minimum purity of 99%, checked through high-performance liquid chromatography at multiple stages. This high purity is not just a technical detail; it reflects our effort to reduce unnecessary byproducts that could affect the final application on potatoes. Our experience tells us that keeping impurities below 1% allows storage operators to apply our product with confidence, knowing it will do exactly what is needed for sprout suppression, and nothing more.

    Propham runs as a crystalline white powder under standard conditions. We ship it after sieving to a standard mesh size that avoids caking and clumping, which are issues that complicate application in bulk potato storage houses. Over years of feedback, we’ve found that this physical consistency helps reduce downtime during dosing. Moisture content is kept below 0.5%, and we've aligned particle size distribution with real-world application equipment, not just theoretical specifications. Finer particles drift too easily, and coarse cuts can cause segregation in sprayers. We choose this middle ground based on practical experience in different regions—a small example of putting user experience before internal targets.

    Direct Use Cases in the Agriculture Supply Chain

    Customers rely on Propham to keep stored potatoes from sprouting during the months between harvest and processing or market. This use, sometimes called ‘sprout suppression,’ may sound modest, yet it stands as a key point where food quality, appearance, and safety intersect. Sprouted potatoes lose market value rapidly; their sugars shift, and they develop off-flavors and toxins such as solanine. As the manufacturer, we have worked side-by-side with storage managers who need a product that dissolves cleanly in formulation, vaporizes evenly during processing, and, most of all, leaves no residues above regulatory limits.

    Working with our buyers, we see that Propham goes primarily into warehouses servicing regional food supplies. Typical application moves from a dusting in a piler line to more refined aerosol vaporization in large commercial silos. Our team often assists with technical troubleshooting, whether it’s overcoming cold-weather sticking or calibrating dosing pumps for the most uniform distribution. While the bulk of Propham goes to storage, we have manufacturers using it as an intermediate for specialty compounds, and occasionally as an agent in laboratory-scale research, always with strict traceability in place.

    Comparing Propham to Alternative Sprout Suppressants

    Fermentation and chemistry have produced a host of alternative potato sprout inhibitors in recent years. Chlorpropham, or CIPC, dominated markets for decades. In response, many processors and supply chain managers ask how Propham compares. Both belong to the carbamate family, and their sprout-suppressing action depends on interfering with cell division at the eye of the potato. CIPC has held the lead in terms of broad, low-cost application, but several countries started phasing it out due to accumulation of residues and food safety concerns. Propham offers an advantage here, with a less persistent residue profile. From our own batch analysis, and reinforced by international risk assessments, finished food processed from Propham-treated potatoes generally tests beneath current maximum residue levels.

    Essential oil solutions—like spearmint or clove oil—are frequently discussed as alternatives by industry groups. We have worked with some of these trials ourselves over the years. Essential oils can be attractive for smaller scale or organic markets but experience volatility and consistency issues. More fundamentally, their cost per treated ton can run several times higher than Propham, and efficacy across storage seasons may prove less predictable, especially in warmer climates. Our industry experience teaches us that operators aiming for reliability, uniform shelf life, and predictable output for processing need a chemical suppressant like Propham supported by regular, standardized quality control.

    Safety and Regulatory Considerations from the Manufacturer Point of View

    Manufacturing Propham means responsibility. It’s impossible to separate the chemical’s potential benefits from its risk profile. Over the past 20 years, regulatory oversight on carbamates intensified. We’ve adapted our workplace controls and product traceability systems to match. As regulation tightened around worker exposure, our line management improved sealed transfer lines, and included advanced filtration at emission points. Finished product is sealed and labeled directly from the primary reactor, and batch samples are archived offsite for future checks if needed.

    For the downstream user, safety doesn’t stop at plant gates. Our technical support team spends much of its time providing guidance on application procedure, cleaning protocols, and record-keeping. Some regions demand lot-by-lot certification; others focus on end-product residue testing. To meet these expectations, we added external validation labs to our own in-house checks, so users can access independent verification reports as part of routine shipments. This is not merely regulatory box-ticking; in our experience, the peace of mind granted to both regulators and food processors far outweighs the modest expense.

    Public concern about any chemical additive in food supply must be met with transparency. Over years of batch production, we find the fastest route to trust is open reporting and a plain-spoken review of possible alternatives. Propham does not belong in direct human food, so we design packaging and transit documents to remove any ambiguity regarding its intended use. This extends beyond the legal minimum standard, covering everything from resistant closures on drums to supplying additional dust masks to larger farms. Mistakes happen, so we conduct periodic retraining on both the plant floor and during customer visits.

    Environmental Impacts and Continuous Practice Improvements

    Propham’s role in the environment comes up often with our clients, especially as consumers ask harder questions about chemical footprints in food. Our team has worked with regional waste-handling centers to limit improper disposal and ensure leftover material does not enter water systems. Waste streams from our facility are treated for carbamate breakdown through both chemical hydrolysis and activated carbon processes, with periodic audits to confirm effluent limits are respected.

    We have studied runoff and soil binding in cooperation with agricultural colleges and field operators. Propham does not accumulate in soil at significant levels, breaking down within a season under typical weather cycles, but we continue to monitor for unexpected persistence. Some customers have shifted toward even lower annual dose rates, asking us to formulate custom blends that fit into new integrated pest management plans. By manufacturing in-house, we retain a tighter control over formulation adjustments, adjusting synthesis steps when customers report changing regulations or requirements.

    Consistency and Reliability – Building from Batch Records and Field Experience

    Our longest-standing clients—many running storage facilities across multiple harvests—have told us that what matters most is the predictability of product behavior. Each batch of Propham runs through a double QA process, comparing sample retention across both plant and external inspection. This level of documentation adds to cost at the outset, but saves much more by reducing off-target effects in the field.

    In storage facilities, testing spray rigs with Propham after delivery often uncovers particle-size shifts that can affect application rates. As a manufacturer, we use those results to tweak granulation or drying steps. Instead of a “set and forget” mentality, we revisit mixing parameters each season, responding to user feedback about nozzle clogs or dust drift. Our operators learn just as much from end-user challenges as from in-house lab reports, leading to a continuous loop between R&D teams and field practitioners.

    Application Equipment and Training Backed by Manufacturing Know-How

    We support the deployment of Propham not with armchair consultation but with direct, hands-on training. Many of our warehouse customers use proprietary application rigs, and over time we have retrofitted or custom-built demo units in our training center. Operators and maintenance teams regularly join our workshops to review best practices in dosing rates or cleaning routines after seasonal use. As equipment updates, we supply both real-world test data and formulation tweaks to match.

    Those dealing with facility changes, or moving to automated systems, ask for advice on dosing integration. Our plant teams have set up demonstration runs using both drum and tote delivery, testing out vaporization efficiency versus direct powder application on unwashed produce. By simulating the same storage conditions on a smaller scale, we have identified process bottlenecks, and fixed those through supply chain or packaging improvements, not merely at the factory gate.

    Traceability and Batch Security from a Manufacturer’s Perspective

    Traceability is not an afterthought in our production cycle. Every drum of Propham includes batch-specific identifiers embedded both on the label and in digital delivery notes. If a question arises about a treatment lot or storage outcome, we pull retained samples from secure storage for cross-review. Our logistics partners follow strict chain-of-custody protocols, but responsibility for security stays firmly with us as producer. In one recent case, a customer flagged a discrepancy in treatment outcome. Our joint investigation traced the issue to unauthorized mixing outside our supply chain, underlining why direct engagement between user and manufacturer matters so much more than remote or anonymous sourcing.

    We believe strongly in offering open-access training and sample retention. This gives our partners, from small warehouse managers to multinational processors, the confidence to escalate issues early—long before any impact reaches the consumer shelf. Our commitment to traceability also means real readiness to recall product if needed, demonstrating the level of accountability required by leading food markets.

    Continuous Improvement: Listening to Users and Responding to Changing Market Demands

    Much of what guides our improvements arises not from theoretical bench work, but from troubleshooting in actual food storage settings. In one season, storage managers wanted a way to monitor real-time release rates after Propham application. We worked with engineers to integrate colorimetric strips into field test kits, giving end users immediate assurance of correct dosing. These solutions come from ongoing dialog, not from generic market trends.

    We also modify product features in response to regulatory changes, such as requests for biodegradable packaging or audit-friendly shipment records. As legislation reduces the list of available crop protection chemicals, food processors and storage managers look for reassurance that their chosen suppressant remains legally supported and practically effective. This means keeping open communication lines, regularly updating technical bulletins, and being ready to flex production as new guidance emerges.

    Supporting Health, Quality, and Market Confidence

    By manufacturing Propham in-house, we not only control its purity and formulation but are held accountable for its reputation among the food industry and regulators. Our facility stands open to audit and review, both by government inspectors and industry partners, confident that every stage in the pipeline meets or exceeds safety requirements. Over the years, as we supply processors that serve millions of consumers, we have learned that transparency and responsiveness underpin trust as much as any technical data sheet.

    The outcome of consistent, well-documented Propham application is plain to see in the produce aisle: visually appealing, safe, and durable potatoes that endure shipping, storage, and retail display. When a batch meets all conditions and end users report no losses from premature sprouting, the result is not just a filled order, but an intact link in the broader food security chain. Each feedback report, whether positive or highlighting a challenge, feeds back into the way we run the plant—never static, always learning.

    Conclusion: Why Manufacturer Partnership Matters in Propham Supply

    Our team’s cumulative experience in producing Propham gives us a clear view into both its strengths and its limitations. Many users report switching to us after experiencing mysterious performance drops from generic, poorly controlled batches routed through unclear trading networks. With transparent production, tested lot control, and real engagement with storage realities, we deliver a product specifically crafted for both practical working conditions and evolving food safety requirements. In a world where each link in the supply chain matters, our approach grounds itself in real solutions that start in the plant and extend to actual food on tables around the world.