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Propanil

    • Product Name Propanil
    • Alias Stam
    • Einecs 203-621-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    675006

    Chemical Name Propanil
    Cas Number 709-98-8
    Molecular Formula C9H9Cl2NO
    Molecular Weight 218.08 g/mol
    Appearance White crystalline solid
    Melting Point 91-93°C
    Solubility In Water Low (0.13 g/L at 25°C)
    Usage Herbicide
    Mode Of Action Inhibits photosynthesis (photosystem II inhibitor)
    Toxicity Moderate acute toxicity (oral LD50 in rats: 430 mg/kg)
    Vapor Pressure 2.3 × 10⁻⁷ mmHg at 25°C

    As an accredited Propanil factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging for Propanil features a sturdy white plastic container, labeled clearly, containing 5 liters of liquid herbicide for agricultural use.
    Shipping Propanil should be shipped as a hazardous material in accordance with relevant regulations. It must be securely packed in approved containers, properly labeled, and accompanied by safety data sheets. During transport, it should be protected from moisture, heat, and incompatible substances. Only trained personnel should handle Propanil shipments.
    Storage Propanil should be stored in a cool, dry, well-ventilated area away from direct sunlight and sources of ignition. It must be kept in tightly sealed, labeled containers, separate from food, feed, and incompatible substances such as strong oxidizers. Storage areas should be secure, with spill containment measures in place, and access restricted to trained personnel only.
    Application of Propanil

    Applications of Propanil in Industrial Manufacturing

    Propanil serves as a key active intermediate in multiple agrochemical and specialty chemical manufacturing chains. By controlling quality and process stability at our manufacturing site, we support industrial partners with consistent grade and technical documentation for large-volume production. Below, we detail specific downstream industries by application, compliance scope, usage ratio, integration stage, and resulting end products.

    1. Rice Paddy Herbicide Formulation

    Herbicide producers use Propanil as the principal active ingredient in commercial selective weed killers for rice cultivation. Blending with surfactants and adjuvants at the premixing stage ensures efficacy against annual weeds such as Echinochloa and Cyperus species. Strict regulatory controls require lot traceability and full impurity profiling. Final formulations adjust Propanil load based on the weed spectrum and application protocols in specific geographies.

    Industry compliance standards

    • FAO Specification 263/TC (Propanil technical concentrate requirements)
    • US EPA Pesticide Registration (40 CFR Part 180)
    • China GB/T 19140-2013 (National standard for Propanil technical material)
    • ISO 9001:2015 for quality management in formulation factories

    Typical usage ratio

    • Active content: 35–50% in SC (suspension concentrate) and 25–36% in EC (emulsifiable concentrate); exact ratio modified by region-specific use patterns and weed resistance data

    Downstream process integration

    • Direct addition during herbicide mixing, after primary solvent charging and before milling/dispersing
    • Quality control includes particle size and stability testing post-formulation

    Final product types

    • Water-dispersible herbicide formulations (SC, EC, WP)
    • Tank-mix compatible herbicidal products for rice paddy application
    • Pre-packaged liquid and granular weed control products

    2. Custom Agrochemical Intermediate Synthesis

    Bulk Propanil technical finds use among chemical synthesis customers as a strategic coupling intermediate when manufacturing substituted anilides and structurally related herbicidal compounds. Companies utilize strict process documentation, intermediate impurity monitoring, and dedicated synthetic lines, particularly when producing export-oriented active ingredients.

    Industry compliance standards

    • ISO 9001:2015 for process control and traceability
    • REACH (EC/1907/2006) Annex VII for registered intermediate use in Europe
    • China Measures for the Environmental Management Registration of New Chemical Substances (MEE Order No. 12)
    • Good Manufacturing Practice (GMP) for active ingredient synthesis in regulated regions

    Typical usage ratio

    • Starting material load: 1.0–1.3 molar equivalents relative to target compound, adjusted by target conversion efficiency and process yield optimization

    Downstream process integration

    • Batchwise charge to synthesis reactors after solvent and base addition
    • Followed by acid/base work-up and phase separation before purification

    Final product types

    • Herbicidal anilide derivatives
    • Chlorinated aromatic intermediates for further agrochemical synthesis
    • Custom contract-manufactured crop protection actives

    3. Environmental Residue Analysis Calibration

    Analytical laboratories and reference standard producers utilize certified-grade Propanil to calibrate LC-MS and GC-ECD instruments for residue analysis in agricultural products, especially rice and related grains. The calibration process demands high-purity stocks, method validation compliant with food safety and residue regulation protocols, and documentation for every batch.

    Industry compliance standards

    • Codex Alimentarius MRLs (Maximum Residue Limits in food)
    • European Commission Regulation (EC) No 396/2005 (pesticide residues)
    • US FDA Pesticide Analytical Manual (PAM) Method I
    • ISO/IEC 17025:2017 accreditation for testing laboratories

    Typical usage ratio

    • Reference solution concentration: 0.05–5.0 μg/mL depending on instrument sensitivity and target residue range

    Downstream process integration

    • Preparation of multi-level calibration curves for chromatographic quantification
    • Direct dissolution in acetonitrile or methanol prior to injection

    Final product types

    • Certified reference materials (CRM)
    • Analytical grade calibration solutions
    • Quality control kits for routine lab screening

    4. Herbicide-Treated Seed Coating Manufacturing

    Seed treatment production lines use Propanil during the coating process for paddy rice and specialty grass seeds, targeting early-stage weed suppression before crop emergence. The blending step requires precise active distribution and adherence to seed coating uniformity standards enforced by agricultural authorities. Finished products undergo germination and phytotoxicity assessment before commercial release.

    Industry compliance standards

    • OECD Guidelines for the Testing of Chemicals No. 208 (Seedling Emergence and Seedling Growth Test)
    • European Seed Treatment Assurance (ESTA) Certification
    • Japan Ministry of Agriculture, Forestry and Fisheries (MAFF) Guidelines for Treated Seeds
    • ISO 21571:2005 (Detection of genetically modified organisms in seeds)

    Typical usage ratio

    • Propanil content: 0.8–1.5 g active/kg seed, tailored based on seed type, anticipated field conditions, and local phytotoxicity restrictions

    Downstream process integration

    • Active incorporation into polymer binder solution
    • Applied via spray coating drum or rotary atomization at final seed processing stage

    Final product types

    • Pre-coated paddy rice seeds with approved herbicidal treatment
    • Herbicide-integrated grass seed blends for managed pastures
    • Professional agronomic seed treatment products
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    Certification & Compliance
    More Introduction

    Propanil: Delivering Reliable Weed Control for Rice Cultivation

    Propanil — A Trusted Product Straight from the Manufacturer

    For decades, rice farmers have relied on Propanil to manage troublesome broadleaf and grassy weeds in their fields. We have produced Propanil in large volumes for years, going through rigorous quality assurance at every stage. Drawing on our own experience in synthesis and downstream formulation, we believe in sharing what farmers have reported back after using our Propanil. This approach lets us fine-tune both performance and consistency batch after batch. In the chemical business, no shortcut ever beats the real-world feedback from the people using what we make.

    The Chemistry and What Sets Our Propanil Apart

    Propanil, known chemically as 3′,4′-dichloropropionanilide, is an acylanilide herbicide. Our company manufactures Propanil, most commonly as a 36% technical concentrate, offering both pure technical-grade material and formulated products intended for direct use in agricultural settings. We use a two-step process based on carefully controlled chlorination and acylation reactions, strictly monitoring the levels of key contaminants such as isomer byproducts and residual solvents. Our facilities maintain current Good Manufacturing Practices, from technical grade down to the finished formulation.

    Through trial and error, we found that the stability of Propanil—and especially the evenness of its particle size in suspensions—matters a great deal to both storage and field performance. Many alternative products on the market have similar active ingredient content but suffer from visible settling or crystallization after sitting on shelves; this causes clogging or uneven coverage in sprayers. Our quality team tests every lot for phase separation and prolonged shelf-life, providing reliable mixing even in older stock.

    What sets our Propanil apart is our refusal to cut corners at the formulation step. Feedback from co-ops and large farms has driven us to include antifoaming agents and high-quality dispersants, improving ease of application at scale. Many generic Propanil formulations omit these steps to save cost, but every year we see better field results when growers have fewer hassles at the tank and in the field.

    Key Product Specifications and Benchmarks

    Most of our clients order Propanil in either bulk technical grade or as a water-dispersible liquid concentrate at 360g/L active ingredient. For technical grade buyers, our minimum active ingredient specification is 97% by weight, with related substances kept below 1.5%. We control moisture and insoluble residue far below industry-average cutoff points. Our final product passes inspection for crystal morphology, color, and dispersibility, ensuring compatibility with tank mixes and local water sources.

    Every lot comes with a full chemical analysis: content (UV/Vis and HPLC for purity), melting point, and tests for specific byproducts. Our teams monitor for dioxin contamination, a challenge highlighted in industry magazines after accidents at older plants. Over a decade of internal auditing and external inspection have kept these problems at bay in our supply chain.

    Some clients require custom formulations. For example, in regions with very hard water, we modify the surfactant blend to prevent gelling and improve leaf uptake, based directly on data from field demos using real-world water samples.

    Understanding Usage in Rice Fields

    Almost all domestic Propanil consumption goes to direct spraying on rice fields. In China, India, Southeast Asia, and parts of the southern United States, Propanil routinely features in pre- and post-emergence weed programs. The product remains popular because weeds have become resistant to many imidazolinone and sulfonylurea herbicides, but resistance to Propanil is still uncommon outside of a few counties in Arkansas and certain provinces in Asia.

    Rice plants tolerate Propanil better than most other crops. The reason comes down to their unique capacity to metabolize the compound using aryl acylamidase enzymes. Experience has shown us that this selectivity stands up under both low and high application rates, even in mixed fields with unpredictable water management. By avoiding blanket use and sticking to proper application times, farmers can maximize control of barnyardgrass, sprangletop, and a wide range of broadleaf invaders—without risking crop injury or yield loss.

    Mixing Propanil in boom sprayers requires vigilance. Sometimes we see operators drop in fertilizer or insecticides, especially under tight labor schedules. Not every combination works; some premix partners deactivate Propanil or cause rapid crystallization. Over the last five growing seasons, our service teams documented over fifty incidents of stuck lines or tank residue from poorly chosen tank mixes. We offer direct advice about safe combinations and agitation practices so operators spend less time cleaning and more time seeing results in the field.

    Comparing Propanil to Other Herbicides

    In conversations with growers and extension agents, people often ask how our Propanil stacks up against products such as quinclorac, bispyribac, and pendimethalin. Several differences appear in both the molecular mode of action and field reliability.

    Propanil works as a contact herbicide, interrupting photosynthesis in sensitive weeds. Unlike systemic products, which move throughout plant tissue, Propanil requires thorough coverage—the product does not move far inside the leaf. If conditions turn rainy or if application skips parts of the canopy, weeds can escape. On the other hand, this contact action lets rice recover quickly, as the product rapidly breaks down in soil and water. In contrast, systemic products often leave residues that threaten rotational crops or lead to resistance problems if overused.

    Products like bispyribac and imazethapyr target enzyme systems in weeds with high potency at low doses, but resistance builds faster under repeated use. Reviewing data from regional field studies, we see Propanil maintaining near 90% control rates against the top five weed species, even after continuous annual application. Alternatives show much lower control after three or four seasons in a row. The chemical design of Propanil, including its rapid photodegradation and water breakdown, prevents buildup in field soils, thus lowering pressure on future crops.

    Another aspect frequently overlooked is spraying logistics. Propanil requires different nozzle settings and sometimes extra attention to droplet size to avoid drift. Oil-based adjuvants and certain surfactants in our blend help by anchoring the spray to target foliage. Some other herbicides in the rice market need specialist applicators and rigid drift-control programs; our formulation gives a broader application window and easier cleanup.

    Choosing Propanil for Resistance Management

    Resistance management is the central concern for anyone producing or using crop protection chemicals today. Over the last decade, the world has watched how resistant barnyardgrass and other weeds reduced the value of “blockbuster” herbicides. Our own history with Propanil highlights some sharp lessons. In the 1990s, reports from Arkansas predicted widespread Propanil resistance would undermine its use entirely. Yet, by working with university agronomists and shifting application patterns, many farmers stabilized control rates by alternating Propanil with other modes of action or using it in tank mixes. This hands-on approach proved more effective than simply switching to another active ingredient every few years.

    Our field support teams still advise clients to rotate between Propanil and herbicides with different weed-killing pathways. We suggest using Propanil sparingly in areas with documented resistant weed populations. At the same time, our research and development team continues to test blends that combine low doses of Propanil with synergists, including certain safeners and inhibitors that reduce the selection pressure for resistance. Unlike some newer products, Propanil’s limited soil persistence works in its favor—it does not linger, so weed seeds emerging later face different pressures.

    Environmental and Safety Considerations

    Managing exposure and environmental runoff remains a priority. Decades ago, Propanil had a reputation for causing fish kills downstream from rice paddies, mainly due to misuse or direct dumping of tank leftovers into canals. Newer guidelines and our production improvements have changed that. We reduced the amount of insoluble residues, and we offer packaging options that cut accidental spills. On-site recovery tanks, along with training provided to user groups, make it easier to store or neutralize rinse water safely for reuse or proper disposal.

    We have responded to changing regulatory frameworks in the US, Europe, and Asia as well. Our production lines switched to closed-system transfer equipment to reduce factory emissions. Regular worker health screenings, along with investments in vapour extraction at blending points, keep airborne exposure well below published thresholds. Independent audits from both private and government entities check our reports on dioxin and chlorinated byproduct levels, giving buyers and end-users confidence that Propanil meets or exceeds regulatory standards.

    Over the years, end-users reported skin irritation linked to repeated contact with older formulations. We responded by improving emulsifier and co-solvent choices, lowering the potential for dermal uptake. On-site training videos and workshop sessions now stress the importance of gloves and long sleeves, lessons reinforced every season through field visits and issue hotlines.

    Sustainable Manufacturing Practices

    Making Propanil today follows different rules than decades ago. Rising energy prices, stricter waste management targets, and public concern about chemical use drive manufacturers like us to find efficiencies everywhere. Our production site wastes less raw material now by recycling unreacted chloropropionyl chloride and using solvent recovery equipment. We lowered water consumption through in-house filtration and reuse steps, and solid waste gets processed through certified incineration rather than landfilling.

    Transparency in the chemical business builds trust. We publish annual sustainability statements showing not only our output levels but also our performance in energy, emissions, and water use per tonne of finished Propanil. Customers in the EU pay close attention to our greenhouse gas numbers, prompting our plant engineers to invest in heat exchangers and airflow recirculation to shrink the carbon footprint per batch. These small shifts add up during the year and reassure buyers who face their own downstream audits.

    We buy starting materials from vetted, long-term supply partners, always prioritizing those who share our standards for environmental stewardship. Some competitors still chase the cheapest upstream price, ending up with shipments tainted by off-spec chlorinated waste or banned contaminants. By sticking with audited suppliers and mid-scale production volumes, we keep tighter quality control and can swiftly recall or tweak production if new environmental tests suggest a problem.

    Supporting Farmers Beyond the Sale

    Supplying Propanil does not end at the loading dock. We invest in outreach—field days, troubleshooting visits during the spraying window, and regular training updates for farm staff. At least half a dozen times each year, our technical service team receives panicked calls from groups facing weather delays or unexplained weed escapes. Routine in-season monitoring, backed by chemical analysis (sometimes performed right in the field lab), uncovers issues ranging from hardwater interference to spray nozzle blockage. Our willingness to walk the fields and recalibrate application rates reflects our long-term commitment, not just a quick transaction.

    Collaboration with universities following rice cropping cycles drives us to update recommendations as new weed problems crop up. Farmers value honesty about the limits of Propanil—including where resistance has gone too far or wet weather spoiled spray windows. Our approach steers clear of exaggeration and marketing fluff, resting instead on the mix of hard science and real-life user experience. It’s our role to cut through the noise, guide growers towards practical integrated weed management, and keep ear to field-level voices shaping the next year’s production run.

    Looking to the Future of Propanil Manufacturing

    Continuous improvement is the standard. New weed variants, unexpected weather swings, and shifting regulatory policies mean we can never stand still. Our research division partners with extension scientists to profile weeds emerging in paddies from India to the Mississippi Delta, constantly testing new combinations of Propanil, safeners, and next-generation spray aids. We invest in faster, greener synthesis methods, trimming solvent volumes and recovering heat to shrink both cost and environmental impact.

    We are also piloting digital traceability programs, letting institutional buyers track batch origins, safety testing results, and audit history—directly through an online platform. Customers demand faster answers, clearer paperwork, and more transparency about every drum leaving our plant. These requests fuel our drive to lead in service, not only in output volume.

    Farmers expect answers that fit their realities—rain, labor shortages, fluctuating crop prices. By keeping product quality high, technical advice grounded, and communication lines open, we position Propanil not as a commodity, but as a partnership. Day-to-day feedback at both the tank and field level is what molds our process and shapes the way we do business. This combination of stability, listening, and technical rigor sets our Propanil apart in a crowded agrochemical landscape.

    Summary

    Producing Propanil is more than hitting an active ingredient number. Decades in the industry have taught us that each shipment represents a partnership with growers fighting real weeds in challenging conditions. Our Propanil stands out through attention to chemical quality, detailed support, and a genuine drive to match changing field demands with responsible manufacturing. Choice of herbicide can make or break the season; for thousands of rice farmers, we are proud that our Propanil continues to prove its value, year in and year out.