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Perfluorohexadecanoic Acid

    • Product Name Perfluorohexadecanoic Acid
    • Alias PFHxDA
    • Einecs 206-203-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    247716

    Chemical Name Perfluorohexadecanoic Acid
    Synonyms PFHxDA; Perfluoropalmitic acid
    Cas Number 679-40-5
    Molecular Formula C16HF31O2
    Molecular Weight 678.13 g/mol
    Appearance White powder or solid
    Melting Point 80-84°C
    Solubility In Water Insoluble
    Density 1.8–1.9 g/cm3
    Pka <1
    Logp High (strongly hydrophobic)
    Structure Fully fluorinated hexadecanoic acid backbone
    Usage Specialty chemical, research, surfactant studies
    Hazards Persistent, bioaccumulative, toxic

    As an accredited Perfluorohexadecanoic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Perfluorohexadecanoic Acid, 25g—supplied in a sealed amber glass bottle with tamper-evident cap and chemical safety labeling.
    Shipping Perfluorohexadecanoic Acid should be shipped in tightly sealed containers, clearly labeled, and protected from moisture and incompatible substances. It is typically transported as a hazardous material, following all relevant local, national, and international regulations to ensure safe handling. Appropriate safety documentation and protective packaging are required during transit.
    Storage Perfluorohexadecanoic acid should be stored in a tightly sealed container, away from incompatible materials such as strong bases and oxidizers. Store it in a cool, dry, and well-ventilated area, protected from direct sunlight and sources of heat or ignition. Clearly label the container, and ensure appropriate safety measures are in place to prevent environmental release or accidental exposure.
    Application of Perfluorohexadecanoic Acid

    Applications of Perfluorohexadecanoic Acid in Industrial Manufacturing

    Perfluorohexadecanoic Acid serves specialized roles for chemical process industries where high thermal and chemical stability are essential. We support a range of sectors which utilize advanced fluorinated intermediates in the production of high-performance materials, electronics, and specialty chemical formulations. All application scenarios listed below reflect proven, technically substantiated downstream utilization in international chemical manufacturing.

    1. Fluoropolymer Synthesis for Wire & Cable Insulation

    In wire and cable manufacturing, this fluorinated acid provides a key monomer building block for melt-processable perfluoropolymers used to produce insulation coatings. Operators rely on its unique molecular structure to impart superior dielectric properties, flame resistance, and long-term mechanical strength under continuous exposure to temperature extremes and corrosive media. End users demand strict traceability and compositional purity to minimize variability and maximize insulation safety during service life.

    Industry compliance standards

    • UL 758 (Appliance Wiring Material Standard)
    • RoHS Directive 2011/65/EU (Restriction of Hazardous Substances)
    • IEC 60332 (Flame Retardant Standards for Cables)
    • EN 50267 (Halogen-Free Material Release Regulations)

    Typical usage ratio

    • Monomer feed ratio at 0.5–3.0% by weight within copolymerization blends, adjusted according to targeted melt flow index and electrical breakdown strength for specific cable insulation classes.

    Downstream process integration

    • Introduced during monomer charging stages of emulsion or suspension fluoropolymerization, post-purification, and stabilized prior to extrusion compounding.

    Final product types

    • High-voltage wire coatings
    • Telecommunications fiber optic cable jackets
    • Automotive harness insulation
    • Industrial automation cable sheathing

    2. Anti-Fouling and Anti-Corrosion Surface Coatings

    Paint and coating producers widely incorporate perfluorinated acids to formulate top-tier protective layers against aggressive chemicals, biofouling, and weathering on metal or composite surfaces. The acid acts as a surface modifier promoting low surface energy, water repellency, and chemical barrier attributes, critical for extending service intervals on marine, industrial, and architectural assets. Coatings must consistently pass performance validation under cyclic corrosive and fouling stress.

    Industry compliance standards

    • IMO Antifouling Systems Convention (AFS/CONF/26)
    • ISO 12944-6 (Paints and Varnishes - Protective Systems)
    • ASTM D4587 (UV Stability Test for Coated Panels)
    • REACH Regulation (EC) No 1907/2006 (Chemical Registration)

    Typical usage ratio

    • 0.1–0.4% by total formulation mass in high-durability topcoat recipes; dosage tailored based on desired thickness and expected exposure duration.

    Downstream process integration

    • Post-resin mix-in prior to pigment dispersion in batch reactors; optional surface activation or anchoring through silane crosslinkers for increased bonding strength.

    Final product types

    • Marine hull antifouling paint
    • Platform and pipeline anti-corrosion coatings
    • Outdoor architectural protective films
    • Industrial reactor lining paints

    3. Semiconductor Photolithography Processing Aids

    Fabricators in the semiconductor sector use this acid as a process additive and surface treatment agent during photolithographic fabrication of integrated circuits. Its extremely low surface energy improves resist pattern development and assists in residue-free stripping post-exposure. Use demands ultrapure input with defined ionic contamination thresholds to avoid device failure or electrical leakage in microelectronic assemblies.

    Industry compliance standards

    • SEMI C93 (Specifications for Electronic Grade Materials)
    • JEITA EDR-4708 (Flat Panel Display Materials)
    • ISO 14644-1 (Cleanroom Standards)
    • IATF 16949:2016 (Automotive Electronics Quality Management)

    Typical usage ratio

    • 5–100 ppm in lithography rinse baths, adjusted according to the required pattern resolution, feature size, and line edge roughness for sub-10 nm process nodes.

    Downstream process integration

    • Dosed directly into lithographic rinse and cleaning stages, following photoresist exposure and pre-metalization cleaning, with recirculating system controls for contamination prevention.

    Final product types

    • Logic and memory integrated circuits
    • Advanced system-on-chip wafers
    • Photomask substrates
    • Automotive and telecom microchips

    4. High-Performance Lubricant Additive Manufacturing

    Producers of specialty lubricants and greases utilize perfluorinated acid as a molecular additive for boundary lubrication improvement in critical machine environments. It protects metal-to-metal contacts under severe sliding, high vacuum, or corrosive conditions, relying on the acid’s micron-scale orientation on frictional surfaces. Production mandates consistent blending and homogeneous distribution to guarantee prolonged operating lifetimes of downstream mechanical systems.

    Industry compliance standards

    • ASTM D4950 (Classification for Automotive Service Greases)
    • NSF H1 (Food Grade Lubricant Standard, for incidental contact only)
    • ISO 6743/9 (Lubricant Classification for Special Applications)
    • DNV GL Rules for Classification of Ships (Machinery Lubrication)

    Typical usage ratio

    • 0.02–0.08% by total lubricant mass, customized based on base oil viscosity index, operating load, and application temperature spectrum.

    Downstream process integration

    • Blended into pre-filtered base oil prior to thickener addition; delivered by high-shear mixing to ensure uniform dispersal and prevent agglomeration during packaging.

    Final product types

    • Vacuum pump greases
    • Oven-chain high-temperature lubricants
    • Manufacturing plant reduction gear oils
    • Subsea drilling equipment greases

    5. Oil and Gas Wellbore Treatment Fluids

    Service companies in the oil and gas sector deploy perfluorinated acids in the formulation of advanced wellbore cleaning and acidizing fluids. The acid’s stability in extreme pH and high temperature environments improves emulsion and scale removal, supporting higher hydrocarbon recovery rates and prolonged well life. Compliance with environmental frameworks and operational safety procedures determines adoption at field sites.

    Industry compliance standards

    • API RP 5B1 (Recommended Practice for Oil Well Cleaning Systems)
    • ISO 13628-1 (Petroleum and Natural Gas Industries Processing)
    • OECD Guidelines for Testing of Chemicals (Aquatic Environmental Safety)
    • OSHA Hazard Communication Standard 29 CFR 1910.1200

    Typical usage ratio

    • Employed at 0.005–0.05% v/v in specialized well stimulation and cleaning fluids, formulated relative to reservoir rock type, formation water composition, and target scale deposit metrics.

    Downstream process integration

    • Mixed in blending tanks prior to on-site injection, post-preparation of surfactant or acidizing base fluids; compatibility validated through laboratory test protocols with reservoir core samples.

    Final product types

    • Scale-dissolving downhole treatment fluids
    • Enhanced oil recovery well acids
    • High-pressure well cleaning liquids
    • Corrosion-prevention wellbore rinses

    6. Fluorosurfactant Formulation for Firefighting Foams

    Manufacturers of advanced Class B firefighting foams use this acid as a component in fluorosurfactant blends to lower surface tension and develop rapid-spreading, high-integrity aqueous film layers. These properties are essential for fuel spill suppression, vapour barrier protection, and rapid extinguishment in petrochemical and airport safety responses. All input chemicals demand environmental compliance and must align with international fire safety codes.

    Industry compliance standards

    • EN 1568 (Firefighting Foam Concentrates)
    • NFPA 11 (Standard for Low-, Medium-, and High-Expansion Foam)
    • US EPA Significant New Use Rule (SNUR) for Certain PFAS Chemicals
    • IMO MSC.1/Circ.1312 (International Shipboard Firefighting Foams)

    Typical usage ratio

    • 0.03–0.09% of concentrate by mass, depending on targeted expansion ratio, fuel compatibility requirements, and foam application method.

    Downstream process integration

    • Introduced into fluorochemical surfactant blend tanks, followed by agitation and compatibility analysis; batch QC includes spread rate and film-forming property assessment.

    Final product types

    • Airport fire suppression foam
    • Petrochemical storage tank firefighting foam
    • Port and industrial response foams
    • Onboard ship firefighting agents
    Free Quote

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    Certification & Compliance
    More Introduction

    Perfluorohexadecanoic Acid: Advancing Precision in Industrial Chemistry

    Driving Real Progress in High-Performance Applications

    Perfluorohexadecanoic Acid is a long-chain perfluorinated carboxylic acid that has made its mark in specialty industrial processes. We produce this compound in our facility with a focus on consistent molecular quality, tight impurity control, and strict batch reproducibility. The molecular weight hovers around 414.11, a characteristic that helps shape its role in both niche and large-scale chemical processing. Many industrial labs look for molecules that offer resilience against harsh chemical environments, and perfluorohexadecanoic acid brings exactly that with its fully fluorinated backbone.

    Across the last two decades, the growing demand for surfactants that hold together under aggressive thermal and chemical conditions led chemists to move away from shorter-chain analogs. Our own R&D teams noticed that intermediate chain fluorocarboxylic acids started faltering under the greater structural demands of modern manufacturing—stability dropped, corrosion resistance faded, and the end products started showing shortened life spans. Perfluorohexadecanoic Acid, with its full spectrum of fluorine coverage, harbors a unique resilience against both oxidation and chemical decomposition. Even in situations where process streams carry extreme pH swings, the acid’s molecular backbone does not degrade. That’s vital in applications such as electrochemical plating, semiconductor etching, and specialty coatings, where trace decomposition means not just lost yield, but real operational headaches later in the supply chain.

    Model Consistency in Fluorochemicals: Trust Built on Decades of Experience

    We look to keep our perfluorohexadecanoic acid batches strong and reliable, recognizing that consistency means efficiency for the end user. Wide molecular weight dispersion or variable purity undermines reliability—so we target >98% assay per batch, screened through both NMR and chromatography. Years on the line have proved that even a small dip in fluorine content or excess water in a shipment throws off downstream syntheses, causing waste and downtime. For us, the difference lies in controlled atmospheres during final purification and proprietary drying methods. Competitors with open-system handling risk introducing variable moisture ligands and trace organics, which accumulate and then linger in finished formulations.

    Our acid runs true to its chain length. Others sometimes substitute or mix C14 or C18 analogs, hoping to stretch supply chains or workaround raw material bottlenecks. We reject those shortcuts. Analytical fingerprinting lets us guarantee that when we call it perfluorohexadecanoic acid, every molecule fits the bill—chain length, fluorination, carboxylic acid functional group, nothing shorted.

    Why Chain Length and Purity Shape Outcomes

    End users often overlook the impact of a few carbons extra or missing from a chain, but decades in the field show those details matter. Shorter chains like perfluorooctanoic acid have grabbed headlines for their environmental stubbornness and toxicity profiles, drawing ever-tightening regulation. As a manufacturer with deep roots in regulatory compliance, we actively invest in monitoring and minimizing environmental emissions. Longer chain fluorocarbons such as perfluorohexadecanoic acid offer greater chemical and thermal stability, lowering both usage rates and waste generation. That drives down the risk profile for our clients in manufacturing, especially those under regulatory scrutiny or pressure to phase out legacy surfactants.

    There’s real value in picking the right chain length when working in surface modification, anti-stick coatings, or specialty emulsions. Shorter fluorocarbons may leach, degrade, or alter wetting dynamics unexpectedly. Perfluorohexadecanoic acid locks tight to treated surfaces and disperses minimally. Our partners in the electronics and aerospace coating industries report measurable improvements in corrosion resistance and product longevity when moving up to our C16 acid.

    From Processing to End Use: Real-World Reliability

    Producing this acid in bulk requires real-world attention to process details. Working with fluorochemicals demands materials and equipment that won’t introduce metals or organics. Production runs use lined glass reactors, dedicated fluoropolymer piping, and aggressive filtration. After the acid phase, we pull every batch through active carbon filtration, then dry with multi-stage vacuum systems to get rid of any high-boiling point contaminants. Waste streams get collected and destroyed in compliance with both in-house safety protocols and evolving legal requirements.

    Customers who scale up their own processes often bring challenges back to us, which feeds into how we improve ours. Several years ago, a key partner reported their coating thickness fluctuating with a different supplier’s acid—our team isolated subtle trace metal contamination as the root cause. After adjusting our reactor lining protocols and boosting QC frequency, those problems vanished. This story gets at why dealing directly with the manufacturer matters: hands-on understanding and rapid adjustment beats speculation and finger-pointing every time.

    Differences from Standard-Chain and Short-Chain Analogs

    We see plenty of comparison requests between perfluorohexadecanoic acid and its lower-homolog relatives, like the infamous C8 or even C12 chains. The longer C16 chain means higher melting points, expanded chemical compatibility, lower volatility, and subdued reactivity under environmental stress. In the field, our formulation chemists report that this translates to enhanced barrier properties in protective films and more robust anti-graffiti coatings, especially in outdoor architectural use.

    There’s a push in EU and North American markets to move away from C8 chain chemistry, prompted by increasing recognition of their persistent bioaccumulative properties. The EPA’s chemical reviews demonstrate that C16 chain compounds hold a drastically reduced toxicological profile. By working at the leading edge with longer chains and tight batch controls, we give customers a measurable compliance advantage with new regulatory environments. That’s not just better for the planet. It’s practical; nobody wants to overhaul a manufacturing line just to replace a core feedstock every fiscal cycle.

    Specific Uses in Cutting-Edge Industries

    Advanced electronics manufacture pushes the boundaries of what fluorinated acids can achieve. In photolithography, our C16 acid adapts to thinner application spreads and remains inert under both UV and high-temperature baking conditions. We’ve supplied pilot lots to chip manufacturers transitioning away from silicon-etch chemistry based on shorter chains. They’ve found that the longer perfluoro acid blocks moisture ingress on nano-scale traces, preventing corrosion and material migration.

    In anti-smudge and anti-fouling paints, this compound creates superhydrophobic layers that resist organic and inorganic fouling over extended exposure cycles. Marine researchers working with us on boat hull coatings have demonstrated reduced barnacle attachment and higher gloss retention after one year in full saline immersion, measurements taken directly from controlled harbormaster studies.

    Aerospace partners request this compound when building high-temperature duct linings, cable insulation, or electronic component encapsulation. Conventional organic acids break down, char, and off-gas under prolonged thermal load. Our perfluorohexadecanoic acid, by contrast, sits inert up to the limits of structural materials themselves. Long-term field tests over five years point to zero measurable acid loss or degradation from the coated linings.

    Staying Attuned to Safety and Sustainability

    Manufacturing perfluorohexadecanoic acid comes with a responsibility to safety inside the plant and in the marketplace. We operate closed-loop containment for all waste and byproducts, with annual audits and independent third-party oversight. Years of process optimization have brought fugitive emissions down to single-digit ppm, not just meeting but exceeding the current regulatory requirements by significant margins. Many buyers ask us if our acid contributes to persistent pollutant burdens seen with older perfluorinated acids. With improved purification and responsible air/water treatment, our materials show detection levels well below regional action limits in all downstream effluents.

    We never claim chemical manufacturing is risk-free. Instead, transparency and quantifiable safety metrics—supported by ongoing monitoring—form part of our routine operations. Our expert technical teams consult with downstream users, offering guidance on closed-system application, containment, and safe disposal. From planar chromatographic maps to river effluent test strips, we back every batch with hard data and open lines of communication. We know that end users in water treatment, advanced formulation, or green chemistry can’t afford uncertainty—so we offer more than compliance, we offer partnership.

    Field Stories: Reliability in Action

    Clients shared that our perfluorohexadecanoic acid solved issues that held back entire projects. In one aerospace assembly plant, the use of an inferior-performed batch from another supplier led to unforeseen adhesive failures under cycling humidity. Their engineers switched to our acid and tracked downtime recovery of over 60% with complete elimination of service alerts related to surface breakdown. The acid’s extended chain prevented moisture diffusion and surface migration, where shorter chains had failed.

    A major European automaker adopted our product in their advanced painting lines, seeking durability against roadside grime, acid rain, and weekly car washes. Their field test fleet validated over 18 months that coatings blended with our acid outperformed past recipes, minimizing surface dulling and prolonging vibrant color. In areas of cold weather, traditional coatings became susceptible to salt-driven corrosion, but our acid-based formula maintained barrier integrity, including after repeated freeze-thaw stress.

    Sourcing Integrity: The Direct Manufacturer Difference

    Dealing directly with us, as the origin maker, removes the uncertainties that come from batch reselling, repackaging, and shadow sourcing. We engage customers from technical brief to delivery, mapping out their critical-to-quality attributes and reformulating if something doesn’t match their field data. Our technical consultancy, built on experience rather than generic advice, helps speed up regulatory clearances and shortens time from order to scaled-up production.

    Some markets call for higher than standard acid purities, especially for sensitive electronics and pharmaceutical handling. We fulfill those needs because we have authority over the line—from raw fluorinated feedstock through to fractionation, aging, drying, and secure packaging. Small batch customization is another advantage: a request from a photonic sensor producer prompted us to alter our end-point filtering to exclude particulates down to 0.1 micron, eliminating the sporadic haze defect that caused their previous scrap rates. In return, they provided feedback that allowed us to close another gap in our own QC regimen.

    Regulatory Shifts and Market Futures

    Tightening regulation on perfluorinated substances acts as a reality check across the chemical industry. We anticipate and welcome the move toward transparency, documentation, and life-cycle tracking, acknowledging the need for strong stewardship to avoid repeating the mistakes of the past. Our research investment leans toward ever-purer, lower-impact fluorochemicals and strategies for rapid in-process recycling.

    The shift away from C8 and shorter chains is both a challenge and an opportunity. Perfluorohexadecanoic acid, with its strong performance, controllable environmental profile, and proven process reliability, fits well in the changing landscape. We’re in constant dialogue with industry authorities, providing technical data packages, long-term persistence studies, and process emission proofs. The fact that our materials pass both in-house and third-party eco-toxicological reviews shows that quality and responsibility can work hand in hand.

    Building for the Next Generation

    We don’t just manufacture perfluorohexadecanoic acid for today’s needs. Our process technicians and chemists invest time in developing more predictive testing, machine learning-driven QC, and continuous automation. Our customers count on uninterrupted supply, so we’re expanding production redundancy across our global footprint. We know the stakes—for precision medicine, environmental protection, and next-gen electronics—keep rising. Our response is to anticipate what the market will demand not just this year but for the cycles ahead.

    Direct, real-world manufacturing experience has shown us that performance, purity, and regulatory compliance can’t be separated. It takes more than a spreadsheet of test results or a glossy brochure; it takes years of hands-on troubleshooting, hundreds of pilot trials, and open conversations between production and field users.

    We listen closely because our future depends on trust, not just sales. For every batch of perfluorohexadecanoic acid that leaves our door, we see more than a chemical—it's a culmination of our practical expertise, our investment in safety, and our commitment to the well-being of each industry we serve.