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N-Methylolacrylamide

    • Product Name N-Methylolacrylamide
    • Alias NMA
    • Einecs 202-207-3
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    537579

    Cas Number 924-42-5
    Molecular Formula C4H7NO2
    Molecular Weight 101.11 g/mol
    Appearance White crystalline solid
    Melting Point 68-72°C
    Boiling Point Undetermined (decomposes)
    Solubility In Water Soluble
    Density 1.196 g/cm3 (20°C)
    Purity >98% (typical commercial)
    Ph Neutral in aqueous solution
    Odor Faint, amine-like

    As an accredited N-Methylolacrylamide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing N-Methylolacrylamide is packaged in a 25 kg net weight fiber drum, lined with plastic bags for moisture protection and safe transport.
    Shipping N-Methylolacrylamide should be shipped in tightly sealed containers, stored in a cool, dry place away from heat, ignition sources, and direct sunlight. Classified as a hazardous chemical, it requires appropriate labeling and documentation and must comply with relevant regulations for transport of toxic and potentially reactive substances. Handle with protective equipment.
    Storage N-Methylolacrylamide should be stored in a tightly closed container in a cool, dry, well-ventilated area away from heat, light, ignition sources, and incompatible materials such as strong acids and oxidizers. Protect from moisture and direct sunlight. Keep refrigerated if possible and avoid prolonged storage. Ensure proper labeling and follow all safety and chemical handling guidelines to prevent decomposition or hazardous reactions.
    Application of N-Methylolacrylamide

    Applications of N-Methylolacrylamide in Industrial Manufacturing

    N-Methylolacrylamide plays a crucial role across several industrial sectors due to its unique crosslinking and copolymerization properties. The following sections describe real-world downstream uses, with each scenario detailing industry standards, specialized formulation parameters, key stages of plant production, and the resulting finished product types. Our expertise as a direct manufacturer ensures technical alignment with actual customer application requirements and up-to-date industrial compliance obligations.

    1. Water Treatment Flocculant Polymers

    Polyacrylamide-based flocculants for municipal and industrial water treatment plants integrate N-Methylolacrylamide as a crosslinking monomer to enhance the cationic and anionic properties for sludge dewatering, suspended solids removal, and wastewater clarification. Performance variances depend on water chemistry, treatment goals, and target solid loads, all within a strict regulatory context to guarantee supply into public utilities.

    Industry compliance standards

    • ANSI/AWWA B453 standards for polymer usage in potable water treatment
    • EN 1408:2008 (Europe) for coagulants and flocculants in water for human consumption
    • 40 CFR Part 141 U.S. EPA National Primary Drinking Water Regulations
    • ISO 9001:2015 for process quality assurance

    Typical usage ratio

    • 0.5–3% by weight as comonomer in polyacrylamide synthesis, with dosage tailored by desired flocculant network density and targeted molecular weight.

    Downstream process integration

    • In situ copolymerization, batch reactor blending, or solution polymerization immediately after acrylamide monomer charge; post-polymerization methylolation adjustments where process flexibility is required.

    Final product types

    • Anionic polyacrylamide flocculant granules or emulsions
    • Cationic polyacrylamide dewatering aids
    • Composite flocculant blends for enhanced precipitation in specialized clarifiers

    2. Paper Wet-Strength Resin Additives

    Paper mills manufacturing tissue, packaging, and specialty paper grades incorporate N-Methylolacrylamide into polyamide epichlorohydrin and other formaldehyde-free wet-strength resin systems to impart permanent wet strength, improving sheet structure integrity during and after exposure to water. Requirements for food-contact paper and packaging drive resin selection and process adaptation.

    Industry compliance standards

    • FDA 21 CFR 176.170 for paper and paperboard in contact with aqueous and fatty foods
    • German BfR Recommendation XXXVI for paper and board intended for food contact
    • ISO 5269 for laboratory sheet forming, wet strength determination
    • REACH registration for use in cellulose fiber applications

    Typical usage ratio

    • 0.2–1.5% by dry fiber weight, adjusted according to end product grade, furnish type, and required wet/dry strength balance.

    Downstream process integration

    • Added to paper machine wet-end as a premixed, freshly prepared solution; dosed continuously or batchwise into headbox feed or pulper prior to sheet formation.

    Final product types

    • Kitchen towel, napkin, bathroom tissue paper rolls
    • Wet-strength labels, packaging boards, food wrap paper
    • Specialty filter papers requiring dimensional stability

    3. Textile Finishing Crosslinkers for Durable Press Effects

    Textile finishing operations utilize N-Methylolacrylamide-based finishing baths to crosslink cellulose fibers, notably in cotton or cotton blends. This chemistry creates durable press, antishrink, and crease-resistant effects, especially in shirting, workwear, and technical fabrics. Process design must adhere to both environmental and consumer safety requirements.

    Industry compliance standards

    • Oeko-Tex Standard 100 for hazardous substances in textile products
    • ZDHC MRSL (Zero Discharge of Hazardous Chemicals) conformance
    • GB 18401 (China) for national textile product safety
    • ISO 105-C06 for color fastness to domestic washing

    Typical usage ratio

    • 1–5% by weight in finishing bath, varied by fabric composition, desired crease recovery angle, and compatibility with resin/fiber type.

    Downstream process integration

    • Mixed with urea, catalyst, and softener in pad-dry-cure finishing lines; applied via padding–squeezing, followed by controlled drying (110–130°C) and thermal curing (150–180°C) to induce crosslinking within textile matrices.

    Final product types

    • Non-iron shirts and trousers
    • Workwear uniforms meeting wash-durability criteria
    • Technical fabrics for medical and hospitality sectors

    4. Adhesive Resin Copolymers for Wood Panel Manufacturing

    Engineered wood panel producers incorporate N-Methylolacrylamide in emulsion or solution copolymers to reinforce adhesive bond strength and water resistance in particleboard, MDF, and composite building panels. The component affords cost effective performance optimization and formaldehyde content reduction across fully integrated press and lamination lines.

    Industry compliance standards

    • CARB ATCM 93120 and EPA TSCA Title VI for formaldehyde emissions
    • EN 312/EN 622 for engineered wood panels mechanical property specifications
    • JIS A 5905 for Japanese fiberboard standards
    • UL GREENGUARD Certification for low chemical emissions

    Typical usage ratio

    • 0.5–2.5% by weight in the adhesive resin formulation, modulated by target board thickness, density, and weather resistance requirements.

    Downstream process integration

    • Dissolved into resin mix tanks upstream of the blender; adhesive is sprayed onto wood furnish before mat formation, followed by continuous hot-pressing (180–220°C) to cure and integrate panels.

    Final product types

    • Furniture-grade MDF and particleboard
    • Structural interior panels for flooring or wall assemblies
    • Laminated building panels for commercial fit-out

    5. Oilfield Enhanced Oil Recovery Polymer Gels

    Petroleum companies formulate in situ profile control and plugging polymer gels with N-Methylolacrylamide as a crosslinking agent to modify gelation kinetics and mechanical strength, critical for increasing sweep efficiency and conformance control in mature water-flooded reservoirs. Additive selection and concentration adapt to reservoir brine chemistry and operational temperature in both onshore and offshore fields.

    Industry compliance standards

    • API RP 63 recommended practices for polymer flooding
    • ISO 13503-2 for fluid performance in well completion
    • Environmental regulations on chemical injection: U.S. EPA Safe Drinking Water Act, OSPAR Convention for use/discharge in the North Sea
    • Internal oil company HSE requirements

    Typical usage ratio

    • 0.3–1.5% by total polymer concentration in gel system, determined by reservoir permeability, formation salinity, gelation time, and required mechanical stability.

    Downstream process integration

    • Pre-mixed with acrylamide/acrylic acid copolymers and injected as a single fluid slug or co-injection into targeted reservoir zones via surface pump units, followed by shut-in period to achieve crosslinked gelation.

    Final product types

    • On-site formed polymer gels for reservoir profile control
    • Conformance control gels for water shutoff
    • Temporary diversion gels for enhanced oil production campaigns

    6. Nonwoven Hygiene Products Binder Systems

    Manufacturers of hygiene and hygiene-related nonwovens (such as baby diapers, adult incontinence pads, and wet wipes) adopt N-Methylolacrylamide crosslinked binders to improve wet tensile properties and dimensional stability without excessive formaldehyde release. Industry demand for low-emission, skin-safe products governs binder design.

    Industry compliance standards

    • EDANA/INDA NWSP standards for nonwovens
    • OEKO-TEX Appendix 6, Product Class I for direct skin contact
    • REACH SVHC guidelines for chemical safety
    • ISO 13485 for medical hygiene supply chains

    Typical usage ratio

    • 1–3% by total dry binder content, applied based on desired web strength, flexibility, basis weight, and compatibility with fiber blend.

    Downstream process integration

    • Formulated in acrylic or vinyl emulsion binder systems and sprayed or foamed directly onto fiber web before thermal drying/curing at 120–160°C during nonwoven line operation.

    Final product types

    • Spunlaid and airlaid hygiene topsheets and backsheets
    • Flushable wet wipe bases
    • Medical and hygiene-grade nonwoven roll goods
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    Certification & Compliance
    More Introduction

    N-Methylolacrylamide: Quality, Reliability, and Real-World Performance

    What Sets N-Methylolacrylamide Apart in Everyday Chemical Applications?

    Stepping onto the shop floor or into the lab, I see firsthand how small differences in chemicals can turn a batch from basic to exceptional. N-Methylolacrylamide, often called NMA by formulation teams, stands out because it fundamentally changes how formulators think about crosslinking and bonding in water-based systems. We manufacture this monomer with a clear focus on what coaters, paper makers, and adhesive producers actually face every single production shift: variability in raw material performance, downtime caused by inconsistency, and the constant demand for tighter end-use specifications. Real challenges need practical tools, and NMA offers more than textbook answers to these problems.

    Our manufacturing facility has spent years refining N-Methylolacrylamide production, not just according to standard technical bulletins but with a dedication to lot-to-lot consistency. What this means for our partners is less troubleshooting, less guesswork, and more time spent optimizing where it matters—in their own process. Every production manager has stories about batches going off-spec or gels appearing in latex. NMA, with its active methylol group, gives formulators a reactive handle without introducing formaldehyde-release hazards common to older crosslinkers, especially when processed at moderate pH and temperature. This chemical outperforms classical acrylamide in making the end polymer system more robust under water, heat, and acidic pressures, making it a preferred crosslinker in paper, textiles, leather, and water-based coatings.

    Using NMA: Insights from the Factory Floor

    On any given day, I watch our operators prepare solutions destined for clients making paper strengtheners, finishing resins for textiles, and adhesives built to resist the humid tropics just as reliably as they work in dry climates. The 98% pure, white crystalline N-Methylolacrylamide surges through our plant in tightly controlled batches, every sample checked for residual acrylamide, free formaldehyde, moisture, and a range of trace impurities that can disrupt process stability. No one wants to rework inventory due to cloudiness or odor. Our teams reflect on customer feedback, whether it's rapid dissolution into water or the absence of problematic byproducts, and steer process improvements with that direct input.

    Middle managers in the textile industry will recognize the headaches that come from resin finishing: yellowing, loss of hand feel, or cracked finishes. Integrators in paper production study how additives crosslink and reinforce the web at the wet-end, giving cups or sack papers that last through shipping and storage. Having a dependable crosslinker that dissolves quickly and doesn’t bring along side reactions simplifies lot adjustments and minimizes scrap, a critical point with rising raw material costs. Quality managers appreciate that NMA, because of its structure, crosslinks more efficiently at lower use levels than traditional melamine-formaldehyde additives. This not only reduces regulatory headaches around formaldehyde emissions but also cuts overall formulation cost by squeezing more performance from each kilo added.

    Specifications That Matter in Practice

    We’ve worked through years of trial, hearing the frustrations of compounders held back by variable monomer quality. Our NMA arrives as pristine, flowable crystalline flakes, with every drum tested to hit a purity above 98%. This quality impacts polymerization rates, solubility, and—crucially—the amount of residual acrylamide (a known neurotoxin) present in finished goods. The methylol content affects crosslinking density directly: a low methylol value means weaker films and adhesives, and clients will let you know if your supply falls short. Our operations team tweaks crystal growth, drying, and packaging conditions until moisture sits at the sweet spot; neither caking nor causing dust in the customer’s process area. These details, overlooked by some, drive real-world ease-of-use and downstream reliability.

    Project engineers from the coatings world often call about viscosity behavior. N-Methylolacrylamide polymerizes rapidly with acrylate and vinyl acetate derivatives, letting formulators dial in rheology and final cure parameters. Unlike generic crosslinkers, NMA offers control over particle size and distribution in latexes—a crucial advantage when producing architectural paints, nonwoven binders, or specialty adhesives for packaging or medical devices. We listen closely to these users, making tweaks not just for lab specs but for industrial-scale performance under the press, dryer, or emulsion reactor.

    Why Users Across Industries Choose N-Methylolacrylamide

    Paper industry leaders know they can’t afford inconsistent strength additives: a failed run can mean lost accounts and returns. Large textile mills must deliver resins that resist repeated laundering, bleaching, and durability testing. Medical device adhesives face the strictest migration and toxicity standards. NMA doesn’t just appear in these formulas because of cost; it’s there because chemists and technical leads have repeatedly tested it for formaldehyde release, reactivity, compatibility, and final film flexibility. We run real pilot lots with our customers, not just handing over a TDS but sitting beside them at scale-up, learning what the numbers mean in practice.

    Much of the competition relies on third-party supply, often reselling imported or repackaged material with less control over trace impurity build-up batch-to-batch. We keep our manufacturing close to customer needs, with direct batch release and a chain of custody visible from raw acrylamide input to the final sealed drum. This intimacy with the product lets us respond to customer pain points—the need for faster dispersion, or for crosslink density at ultra-low add-on levels in specialized food-contact paper grades, where every ppm counts not just for compliance but for long-term partnership trust.

    Direct Differences From Traditional Crosslinkers and Acrylamide-Based Additives

    Our chemists can point to specific distinctions that practicing formulators appreciate. Acrylamide itself offers water solubility but falls short in delivering the wet-strength or thermal resistance needed in finished products. Blends like glyoxalated polyacrylamide come close, but can introduce unacceptable levels of residual aldehydes, pushing regulatory exposure limits and worker safety concerns. Melamine-formaldehyde resins, long cheap and available, increasingly fail tighter emission regulations. Modified starch-based crosslinkers may lower process risk, yet struggle to hit the modulus or flex rating in hot-cup stock or industrial wipes.

    N-Methylolacrylamide comes into play here because it brings the reactive methylol group without overloading the formula with formaldehyde or reducing solvent resistance. In our plant, careful handling and moisture control avoid dusting—a regular complaint with lower-grade acrylamide derivatives. In water or lower-pH systems, NMA activates crosslinking at reasonable cure conditions, avoiding blistering, foaming, or color development that can plague peroxide-cured systems. Formulators can tune cure profiles and mechanical properties by small changes in NMA add-on; the polymer matrix can stay flexible for textiles, or rigid and moisture-resistant for paper and label stock.

    Whereas polyacrylamide by itself makes for a neutral backbone, introducing NMA creates irreversible bonds that stand up to hot liquids, boiling, disinfectant washes, and packaging abuse. We keep technical teams supplied with up-to-date performance validation on finished materials, so the purchasing or QA teams on the customer side can defend their supplier choices with hard data.

    Practical Usage: A View from Batch Production

    Production supervisors who walk the line every shift know the impact of poor-quality monomers. Dust, clumping, or uneven dissolution not only trash a day’s output but sink confidence in sourcing choices. Our NMA, with a minimum 98% purity and a clear melting range, gives them process-predictable dissolution rates and reproducible crosslinking. This lets batch size scale without re-jiggering water addition, pH adjustments, or agitation speed—shaving hours off troubleshooting and keeping the line moving.

    Some clients worry about health and safety: acrylamide is regulated for worker exposure, and any slip can result in shutdowns. We’ve reduced residual acrylamide to levels consistently below federally mandated action limits by paying close attention to catalyst quenching and purification stages. Finished packages roll out with a fresh, neutral odor and no detectable free formaldehyde, supporting worker safety and reducing the risk of downstream product recalls due to regulatory spot checks.

    In higher volume textile and paper applications, the flexibility to switch from one resin or formulation to another without exhaustive line cleaning forms a core competitive advantage. NMA’s high solubility and lack of polymerization inhibition support rapid changeover, which in five-minute increments, can mean the difference between hitting quarterly targets and missing them. Operators see less gel buildup in pipes, driers, or coating heads. Maintainers see fewer blockages, and managers see better bottom-line figures due to less waste and downtime. These details show up on our ledgers and our clients’ annual reviews.

    Supporting Sustainability and Compliance—With an Eye on Real-World Needs

    In the last five years, sustainability buzzwords have hit every level of the chemical supply chain. Walk into a procurement meeting or a plant review, and you sense the growing tension between traditional, petroleum-based monomers and “greener” alternatives. Regulations worldwide have tightened on formaldehyde, acrylamide, and hazardous emissions, increasing the pressure on producers to deliver safer, lower-impact materials. Our approach focuses on incremental improvements—a tighter reaction yield, cleaner purification, and on-the-ground support for customers switching formulations to reduce VOCs or hazardous air pollutants.

    N-Methylolacrylamide gives everyone from EHS managers to R&D directors a practical path toward compliance. Our process design minimizes fugitive emissions and enables closed-system handling, backed by experienced advice from our decade-long push for operator safety and transparency in supply. We partner with clients to run plant trials and validate third-party test results, not just selling a chemical but helping risk assessors and sustainability officers build robust cases for regulatory agencies and business partners. Our ability to adjust particle-size distribution and packaging means that sensitive or bespoke applications—like hospital nonwovens or food-grade packaging—don’t force a compromise between safety and performance.

    Feedback Loops—How Customer Experience Refines Our Product

    Our technical service and development teams sit just steps from the production line. Every return shipment, every odd result from a customer trial goes straight to process improvement meetings. Lean manufacturing and Six Sigma approaches only go so far without real user data. Our operations teams trust what their customer-facing colleagues report: a troublesome batch in a paint plant may trace back to a subtle drift in drying cycle or packaging material. We’ve overhauled driers, respec’d liner materials, and worked directly on-site with clients when a process hiccup points back to our product’s performance. These cycles build trust and allow us to tighten product ranges not just for drum specs but for the real conditions users see in their operation.

    A single missed crosslinking cure in a major packaging run can cost millions in rework and lost customer trust. Our teams have learned that no product bullet point or glossy brochure can compensate for a direct call from a process engineer in distress. We facilitate deep dives to find the root cause, adjusting not only our own production processes but also advising on pH, inhibitor, and feed timing, guided by years of past collaboration across industry sectors.

    Shaping the Future—Where N-Methylolacrylamide Goes Next

    Innovation in the crosslinker field doesn’t always mean chasing the latest trend. For many plants, the search is not for novelty but for a reliable backbone that will perform regardless of shifts in raw material pricing, climatic conditions, or regulatory guidance. N-Methylolacrylamide holds its place because it delivers on these real metrics: shelf-life stability, minimal odor, repeatable crosslink density, and support from a technical team that shares production pressures with its clients. As recycled fiber, alternative fillers, and biopolymer blends become the norm, we see the need for crosslinkers like NMA that adapt, rather than dictate, system requirements.

    Our R&D teams conduct real-world simulation tests—incorporating pilot-scale runs with new biobased monomers, running crosslinking under variable humidity, or subjecting films to rapid aging cycles. Each refinement comes not from guesswork but from decades of iterative collaboration with global paper mills, textile finishers, coating lines, and specialty adhesive makers. We’re committed to learning from every customer experience, working directly on applications from diaper fluff to advanced surface coatings for electronics. In crowded markets, this commitment turns a chemical into a trusted backbone—one that quietly shapes hundreds of products found in homes, hospitals, offices, and streets worldwide.

    N-Methylolacrylamide has proven itself not through abstract claims but in the daily grind of real production. Its track record in improving wet strength, thermal resistance, and crosslinking efficiency places it ahead of conventional, older-generation additives. We see its future in enabling new, more sustainable fiber constructs, safer food packaging, and advanced textiles. Each improvement is measured by feedback from plant operators, R&D chemists, and technical managers. We share these lessons, not as distant observers but as hands-on builders in the chemical manufacturing world—always listening, always refining, and always delivering products that meet the challenge where it matters most: in the process, on the line, and in the product reaching the end user.