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N-Methylbenzene-1,2-Diamine

    • Product Name N-Methylbenzene-1,2-Diamine
    • Alias 1,2-Diamino-N-methylbenzene
    • Einecs 202-870-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    222613

    Chemical Name N-Methylbenzene-1,2-diamine
    Synonyms 2-Methylaminoaniline
    Molecular Formula C7H10N2
    Molecular Weight 122.17 g/mol
    Cas Number 615-71-4
    Appearance Brown to reddish solid
    Boiling Point 265 °C
    Melting Point 45-48 °C
    Density 1.11 g/cm3
    Solubility In Water Slightly soluble
    Pka 4.76
    Flash Point 136 °C
    Smiles CNc1ccccc1N
    Iupac Name N-methylbenzene-1,2-diamine

    As an accredited N-Methylbenzene-1,2-Diamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, 100 grams, tightly sealed with a screw cap; clear labeling includes chemical name, hazard symbols, and handling precautions.
    Shipping N-Methylbenzene-1,2-diamine should be shipped in tightly sealed containers, protected from moisture and incompatible substances. Transport in accordance with local, national, and international regulations for hazardous chemicals. Handle with care to avoid spills and exposure, and label containers with appropriate hazard warnings. Store and transport in a cool, well-ventilated area.
    Storage N-Methylbenzene-1,2-diamine should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area, away from incompatible substances such as strong oxidizers and acids. Protect from light and moisture. Store at room temperature and avoid exposure to heat or flame. Ensure proper labeling and keep away from sources of ignition to maintain safety and chemical stability.
    Application of N-Methylbenzene-1,2-Diamine

    Applications of N-Methylbenzene-1,2-Diamine in Industrial Manufacturing

    As a manufacturer dedicated to the precise supply of N-Methylbenzene-1,2-Diamine, we focus on its established downstream applications in sectors where its chemical structure brings clear benefits to processes and finished products. Below, we outline key industrial manufacturing scenarios, each defined by unique technical requirements, formulation guidelines, and quality frameworks.

    1. Intermediate for High-Performance Dyestuffs

    N-Methylbenzene-1,2-Diamine plays a critical role as an intermediate in synthesizing azo and anthraquinone dyes for textiles and leather goods. It undergoes diazotization and coupling reactions to introduce specific chromophores that achieve intense, stable color shades resistant to light and washing. Manufacturers rely on its consistent reactivity and purity profile to control color reproducibility and batch quality, meeting the advanced demands of modern textile finishing and leather treatment facilities.

    Industry compliance standards

    • OEKO-TEX® Standard 100 for textile chemicals
    • ZDHC Manufacturing Restricted Substances List (MRSL)
    • REACH (EC 1907/2006) Annex XVII restrictions for dye components
    • ISO 9001 quality management during production and blending processes

    Typical usage ratio

    • 3–7% w/w of total amine feedstock in diazo coupling formulations; adjust based on target dye intensity and molecular design

    Downstream process integration

    • Feeds directly into the diazotization step, followed by coupling with aromatic compounds to construct the dye skeleton prior to purification and spray drying

    Final product types

    • Reactive dyes for cotton and viscose
    • Acid dyes for wool and silk
    • Disperse dyes for synthetic fibers
    • Mordant dyes used in specialty leather finishing

    2. Precursor for Corrosion Inhibitor Formulation

    Downstream chemical formulators select this diamine for its aromatic–amine skeleton when building benzimidazole and benzotriazole derivatives, compounds known for their strong steel and copper corrosion inhibition in industrial water systems. Its high-purity grade streamlines reactions, reducing byproduct formation and lowering downstream purification costs. This allows consistent inhibitor concentrations, minimizes asset downtime, and helps formulators meet stringent anti-corrosion performance benchmarks for automotive, heat exchange, and pipeline environments.

    Industry compliance standards

    • ASTM D1384 (corrosion testing for engine coolants)
    • API 682 (petroleum industry mechanical seal support systems)
    • EU Biocidal Products Regulation (BPR) for downstream derivatives
    • ISO 14001 (environmental management in process chemistry)

    Typical usage ratio

    • 0.8–2.2% w/w as primary diamine precursor, based on final inhibitor loading target and water chemistry

    Downstream process integration

    • Introduced during the cyclization and condensation stage for forming benzimidazoles or related structures, prior to neutralization and blending with solvent systems

    Final product types

    • Industrial water treatment corrosion inhibitors (concentrates and ready-to-use blends)
    • Metalworking fluid additives
    • Circuit board surface treatment solutions

    3. Active Ingredient in Permanent Hair Dye Manufacturing

    Many cosmetic manufacturers depend on this aromatic diamine as a primary oxidation dye base for permanent hair color products, exploiting its amine groups to form stable, high-intensity color molecules through oxidation with hydrogen peroxide. Control of its dosage and purity is essential to achieve shade accuracy, minimize skin sensitization, and meet global cosmetic regulatory requirements. Batch-to-batch reproducibility depends on robust material quality and traceable process controls throughout hair dye compounding and packaging.

    Industry compliance standards

    • EU Cosmetic Regulation EC No. 1223/2009 Annex III limits for diamine content
    • U.S. FDA 21 CFR Part 73 (hair dye ingredient rules)
    • ISO 22716 Good Manufacturing Practices (Cosmetics)
    • IFRA (International Fragrance Association) guidance for allowable primary aromatics

    Typical usage ratio

    • 0.2–1.1% w/w in finished dye cream or emulsion formulations; adjusted according to the desired shade intensity and oxidation kinetics

    Downstream process integration

    • Dispersed into the oxidative dye base pre-mix, followed by combination with hydrogen peroxide developer during filling and mixing of two-part permanent dye kits

    Final product types

    • Permanent hair color creams
    • Professional salon color tints
    • Boxed home-use hair dye kits

    4. Key Starting Material for Pharmaceutical Benzimidazole Synthesis

    Our customers in the pharmaceutical sector utilize this diamine as a core building block for synthesizing various benzimidazole APIs, including antiulcer and anthelmintic agents. Strict control over trace impurities and heavy metal content in this raw material supports downstream GMP compliance and facilitates cost-effective regulatory submissions. The compound enters routes involving oxidative cyclization to form heterocyclic scaffolds, supported by precise addition and validated reaction protocols to maximize yield and minimize side reaction formation.

    Industry compliance standards

    • ICH Q7 (Good Manufacturing Practice Guide for Active Pharmaceutical Ingredients)
    • USP-NF pharmacopoeial purity requirements for starting materials
    • EMA guidelines on elemental impurities
    • FDA DMF (Drug Master File) traceability for API production

    Typical usage ratio

    • 0.85–1.15 equivalents relative to downstream carboxylic acid or aldehyde components in each batch; optimized for throughput and compliance with API yield and purity profiles

    Downstream process integration

    • Fed as the major nucleophile during ring-forming processes (e.g., condensation, oxidative cyclization), upstream of purification and crystallization of benzimidazole intermediates

    Final product types

    • Benzimidazole-based antiulcer drug intermediates (e.g., omeprazole precursors)
    • Anthelmintic benzimidazole intermediates for veterinary API manufacturing
    • Pharma-grade benzimidazole fine chemicals

    5. Component in Polybenzimidazole (PBI) Polymer Production

    This diamine acts as a foundational monomer in the synthesis of polybenzimidazole fibers and membranes, chosen for its ability to yield polymers exhibiting resilience at elevated temperatures and resistance to chemicals. Manufacturers must tightly control stoichiometric ratios and polymerization conditions to ensure molecular weight specifications, critical for achieving the required mechanical and thermal properties for technical fabric and filtration use. The monomer purity directly affects polymer chain length, color, and melt flow characteristics in the downstream spinning and membrane casting processes.

    Industry compliance standards

    • UL 94 V-0 (flammability standard for polymeric materials)
    • ASTM D5207 (standard for PBI fiber properties)
    • ISO 9001-controlled batch documentation and QC
    • RoHS guidelines for absence of restricted substances in polymer applications

    Typical usage ratio

    • 1 mole per mole of acid chloride or dicarbonyl linking agent; batch recipe adjusted for target fiber strength and membrane functionalization

    Downstream process integration

    • Monomer introduced into polycondensation reactors to form PBI prepolymer, followed by solution spinning or membrane casting and controlled thermal curing

    Final product types

    • High-performance PBI fibers for fire-resistant clothing and aerospace applications
    • PBI flat-sheet and hollow fiber membranes for gas separation and ultrafiltration
    • Technical films for electronics and chemical process industries
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    Certification & Compliance
    More Introduction

    N-Methylbenzene-1,2-Diamine: Our Approach to Reliable Production and Genuine Quality

    Introducing N-Methylbenzene-1,2-Diamine

    Our experience manufacturing N-Methylbenzene-1,2-diamine started with a simple goal: supply a product with consistent composition and dependable purity for downstream use in the dye, pharmaceutical, and agrochemical industries. This aromatic diamine, also known as 2-methylaminobenzene-1,2-diamine, delivers specific benefits that set it apart from related molecules, especially through its reactivity and performance in diverse synthesis reactions and formulations.

    Across repeated production cycles, our technicians monitor each batch to ensure a uniform melt point between 68°C and 72°C. That detail matters for customers faced with the challenge of tight processing windows and unforgiving reaction pathways. Residual solvent levels, trace metal contaminants, and color remain tightly controlled throughout our manufacturing—every release includes transparency around those measurements. Our facility employs modern filtration and drying processes, which help keep ash content and moisture to a minimum. Consistency saves headaches for our partners, whether for a laboratory bench scale run or a full-scale manufacturing campaign.

    The Role of N-Methylbenzene-1,2-Diamine in Real Manufacturing

    We see firsthand how our product feeds into many different chemical transformations. Batch records from customers show N-Methylbenzene-1,2-diamine as a vital intermediate for synthesizing heterocycles—including benzimidazole and benzotriazole scaffolds—preferred by pharmaceutical innovators for their efficiency and regulatory acceptance. Our technical support team receives feedback from dye producers who rely on its precise substitution pattern to achieve targeted color fastness and shade homogeneity in finished pigments. Many requests come from formulators aiming to balance reactivity with handling safety, and our quality control history points to our process providing that margin.

    Unlike unsubstituted o-phenylenediamine, the N-methyl version confers useful differences in downstream chemistry. Methylation shifts nucleophilicity and alters the solubility profile, helping to eliminate undesired side reactions and improve yields. In coupling steps, our experience shows more selective bond formation and less formation of polymeric byproducts compared to the parent diamine. Manufacturing staff have conducted stability sampling under various packaging schemes, confirming robust shelf life when material is stored in stainless steel or lined drums away from light and moisture ingress.

    Navigating Challenges in Quality and Scale

    Those choosing between N-Methylbenzene-1,2-diamine and other diamines often focus on purity, particle consistency, and solubility. Quality leaders at our plant discovered several years ago that achieving lot-to-lot uniformity requires controlling reaction time and temperature during methylation and subsequent work-up. Those variables help minimize mono- or tri-substituted impurities, which can complicate synthesis routes for fine chemicals. Detecting trace iron, copper, and other heavy metals became routine in our analytical lab after repeated customer audits flagged even small variations as critical for some final uses.

    Several solvent options exist for crystallization, but through pilot-scale optimization we found that recrystallization from ethanol-water blends gives the most practically filterable crystals—reducing drying time without slumping or excessive fines content. These refinements emerged from process trials, not templates, and save energy month after month. In terms of storage and handling, our shift supervisors recognized that powder caking can slow production and frustrate operators, so they worked with engineering to develop improved blending steps and anti-caking agent controls.

    Comparison with Close Chemical Relatives

    Customers sometimes compare N-Methylbenzene-1,2-diamine to its unmethylated form, o-phenylenediamine, and to its N,N-dimethyl counterpart. We see that the mono-methylated structure offers practical benefits in pharmaceutical chemistry, such as increased selectivity for N-alkylation reactions and gentler reaction profiles when further derivatization is required. The added methyl group limits certain oxidation pathways, lessening formation of undesirable tars or colored impurities—a feature noted by our dye manufacturing customers in quality reports. Meanwhile, formulations that demand additional water solubility or specific substitution patterns sometimes select the dimethyl version, trading off intermediate reactivity for greater solubility or altered reactivity profiles.

    Experience shows that many dye and pigment producers prefer our standard grade N-Methylbenzene-1,2-diamine because its controlled melting range and minimal moisture pick-up lead to predictable outcomes in oxidative coupling and azo dye formation. In contrast, who work with o-phenylenediamine observe a broader temperature sensitivity and a tendency toward oxidative darkening, especially in open storage. These differences mean that product choice ends up driven by real-world performance, as measured on the shop floor and in final quality tests— not by abstract properties alone.

    Formulators in rubber and plastics often note the lower volatility of our product versus less substituted diamines. High-purity material means fewer headaches during extruding, compounding, and curing, with process feedback confirming reduced contamination risk across production shifts. Product managers from these sectors value shipment traceability and documented analytical support, which our long operational track record can provide.

    Practical Considerations for Buying and Handling

    We pack most production batches in fiber drums with polyethylene liners, offering additional container types for partners with automated dispensing or strict clean-room requirements. Our logistics group has learned through repeat order fulfillment that tight packaging, immediate palletizing, and control over warehouse environment reduces clumping and helps operators avoid material loss during transfer. Realistic packaging weights have evolved over time, in part through direct feedback from buyers looking for manageable drum sizes for batch-wise operations.

    Many users ask about compatibility with standard solvents and application conditions. Bench trials performed in our technical center confirm that our product dissolves well in alcohols, glycols, and common polar aprotic liquids, enabling smooth formulation with other organic intermediates and dye precursors. End-users in resin manufacturing or pharmaceutical API routines frequently request custom sieving or milling, and we coordinate with those customers to define mesh or granule size, always mindful of downstream reaction yield and safety.

    Observations on Regulatory and Environmental Concerns

    Growing regulatory scrutiny around aromatic amine handling and emissions has made transparent manufacturing more important than ever. Our operations team routinely reviews batch records and safety data, working with sustainability managers to document waste minimization and responsible solvent recovery. Several years ago, auditors emphasized the need for reduced residual solvents and proper traceability for all raw materials feeding into our process. Investment in updated distillation and solids handling improved both product quality and regulatory compliance, allowing us to pass supplier audits for multinational partners.

    Folks working in European, North American, or East Asian regulatory environments benefit from our regular updates about classification status, waste code assignment, and transportation restrictions. Compliance isn’t just a talking point—it shapes real-world logistics and safe material handling throughout the chemical chain. Workshops on worker safety and spill management reflect lessons learned under real plant conditions, not just from compliance manuals. We take customer requests for low-odor, dust-suppressed, or pre-weighed mini-packs as a signal to stay responsive to evolving workplace standards. Some recent process changes reflect our internal commitment to further lowering occupational exposure risks during packaging and transfer.

    Supporting Larger Scale Production Needs

    Buying in bulk means products not only need to be shipshape, but batch release documentation and response to technical queries have to match. Our medium and large industrial partners choose us in part because of our experience troubleshooting process upsets—whether a pH drift in crystallization, a sticking filter cake, or a reaction stalling due to subtle impurity build-up. From on-site visits to conference room discussions, process engineers engage with us on ways to improve their own operation’s throughput and minimize side product formation, trusting that we draw from production reality rather than marketing claims.

    Larger quantities often bring up just-in-time delivery considerations and warehousing stability, two issues that swallow small differences in product properties and turn them into real cost sinks. Shipping managers prioritize robust drums and moisture barrier linings to eliminate in-transit quality loss. Our regular shipments are routed via established forwarders who understand the quirks of specialty chemicals, avoiding transhipment delays or rough handling as much as possible. Bulk customers look for rapid technical assistance from us, especially if a process variable causes unexpected changes in color, melting point, or solubility.

    Listening to Feedback and Advancing Quality

    Feedback loops have always driven our product improvement cycle. Process changes stem from real-world user comments as much as from in-house observation. For instance, analytical chemists told us several years back that an improvement to our purification method had reduced coloration in critical API intermediates, while dye formulators valued more precise moisture marking after we tightened drum-sealing protocols. Our production supervisors regularly walk the floor, discussing any observed distribution or equipment issues directly with the shift that caught the issue. If suggestions come from a laboratory in Europe or a production floor in Southeast Asia, we take the same approach: careful documentation, rapid test batch, and an honest evaluation of practical value.

    Customers want to know about long-term storage stability, so we have held retention samples under varied site storage conditions—in shaded, ventilated, temperature-controlled, and even high-humidity spaces. Regular analytical work on these samples provides confidence and actionable information to our buyers managing multi-month inventories. The result is less guesswork about potential product drift and fewer urgent last-minute replacements.

    Adapting for New Applications

    N-Methylbenzene-1,2-diamine finds evolving uses outside classic dyes and pharmaceuticals. We see emerging interest from companies developing specialty polymers, battery materials, and performance coatings. R&D labs turn to us for uniform batch composition and consistent reaction profiles. Our technical teams have supported early development campaigns by sharing details of previous compatibility tests, observing thermal stability behavior, and identifying conditions that prevent decomposition or color formation under new use regimes.

    Some innovators have explored coupling our product with specialty aldehydes, acids, or transition metal catalysts to create tailored polymers and advanced materials. These applications stretch current technical boundaries — many require tighter impurity control, narrower particle size distributions, and full documentation of each process run. We welcome these challenges, as they provide ground for incremental improvement and push our manufacturing and quality control teams to refine protocols further.

    Practical Solutions for Common Hurdles

    Over years in the business, we have encountered nearly every material issue—unexpected clumping, subtle off-odors, even a batch arriving during humid weather that showed a higher than specified water content. Our response starts on the shop floor, with retraining teams on drying cycle length and drum sealing integrity, then sharing lessons learned at operator meetings. This way, change is driven by those with firsthand experience, making solutions both practical and sustainable.

    Customers requiring additional technical information about side product formation or waste handling benefit from our regular process audits and improvement sessions. Technical documentation for each lot always tracks solvent recovery yields and confirmed impurity limits, reflecting our plant’s adherence to best practices in environmental and worker safety. On larger projects, our engineers frequently participate in client-led root cause analysis when downstream issues arise, sharing original batch data and recommending process modifications that extend beyond the material itself.

    Continual Innovation Through Experience

    What sets real chemical manufacturing apart from mere distribution is a visceral understanding of both the molecule and the process that shapes it. Each lot of N-Methylbenzene-1,2-diamine bears the imprint of process optimization, persistent feedback cycles, and steady attention to both minute details and broader regulatory shifts. As new applications challenge standard technical boundaries, our teams stay prepared to adjust procedures, rethink routine, and document every material fact that impacts our partners throughout the supply chain.

    We welcome open technical dialogue, unsolicited feedback, and honest critique. Each fresh batch reflects accumulated experience from plant floors, QA benches, warehouse aisles, and customer sites worldwide. This product remains more than a commodity—it is a snapshot of coordinated effort, sustained technical inquiry, and the trust of a diverse customer base.

    Choosing material from our facility means benefiting from a history of close collaboration, an insistence on clear documentation, practical responsiveness, and a daily commitment to better process safety, product performance, and value. We stand behind each lot of N-Methylbenzene-1,2-diamine, drawing on experience, observation, and shared success with every customer who brings new insight to our journey.