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N-Methyl-N-Phenylurethane

    • Product Name N-Methyl-N-Phenylurethane
    • Alias Phenylmethylcarbamate
    • Einecs 202-204-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    311527

    Chemical Name N-Methyl-N-Phenylurethane
    Cas Number 601-92-9
    Molecular Formula C9H11NO2
    Molecular Weight 165.19 g/mol
    Appearance White crystalline solid
    Melting Point 56-58 °C
    Boiling Point 310 °C
    Solubility In Water Slightly soluble
    Density 1.19 g/cm3
    Flash Point 141 °C
    Pubchem Id 82375
    Smiles CN(C1=CC=CC=C1)C(=O)OC
    Synonyms N-Methyl-N-phenylcarbamate
    Storage Conditions Store in a cool, dry place

    As an accredited N-Methyl-N-Phenylurethane factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, 100g, tightly sealed with screw cap, featuring hazard symbols, product name "N-Methyl-N-Phenylurethane," batch number, and supplier label.
    Shipping N-Methyl-N-Phenylurethane should be shipped in tightly sealed containers, protected from moisture and direct sunlight. Use appropriate packaging to prevent leaks or breakage. Follow all relevant regulations for transporting chemicals, including proper labeling and documentation. Handle with care to avoid spills, and store in a cool, dry, well-ventilated area during transit.
    Storage N-Methyl-N-Phenylurethane should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area, away from sources of heat and ignition. Protect from moisture and incompatible materials such as strong acids, bases, and oxidizing agents. Ensure containers are clearly labeled. Keep out of direct sunlight and avoid prolonged exposure to air to prevent degradation.
    Application of N-Methyl-N-Phenylurethane

    Applications of N-Methyl-N-Phenylurethane in Industrial Manufacturing

    N-Methyl-N-Phenylurethane serves as a specialty intermediate across several focused sectors in the chemical industry. The following sections highlight selected downstream applications where our material contributes to critical performance, regulatory compliance, and enhanced end-product quality.

    1. Polyurethane Flexible Foam Production for Automotive Interiors

    Manufacturers in the automotive sector use this material as a targeted chain extender or auxiliary component to modify the softness and resilience of flexible polyurethane foams tailored for seating and interior panels. Its aromatic urethane group allows precise adjustment of foam density and compression set, enhancing long-term durability in high-performance seating. Adoption stems from the need for controlled reactivity during prepolymer stage blending and stable cell structure formation to achieve consistent tactile and mechanical properties.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • OEKO-TEX Standard 100, Appendix 6—product class for automotive textiles
    • REACH Regulation (EC) No 1907/2006—Annex XVII substance restrictions
    • Automotive OEM VDA 278, interior emissions for VOCs

    Typical usage ratio

    • 0.5–3.0 phr (parts per hundred polyol) depending on desired hardness and resilience
    • Adjustments based on isocyanate index and required comfort specifications of the finished foam

    Downstream process integration

    • Incorporated during initial polyol blend preparation phase
    • Direct addition to polyol premix before foaming reaction with MDI or TDI
    • Continuous feed in slabstock or molded foam production lines

    Final product types

    • Automotive seat cushions
    • Headrests
    • Armrests and door panel padding
    • Under-dashboard and NVH insulation foams

    2. Specialty Coatings for Metal Surface Protection

    This intermediate functions as a reactive resin component in two-component polyurethane coating systems designed for architectural, infrastructure, and industrial metal protection. Its methylated urethane functionality promotes enhanced chemical resistance and improved adhesion on steel and aluminum substrates. Controlled incorporation leads to coatings with strong barrier properties, meeting end-users’ needs for weathering resistance, abrasion protection, and compliance with environmental regulations regarding VOC limits.

    Industry compliance standards

    • ISO 12944—Corrosion protection of steel structures by protective paint systems
    • ASTM D3359—Standard Test Methods for Adhesion by Tape Test
    • Directive 2010/75/EU—Industrial Emissions (VOC in paints and varnishes)
    • RoHS 2011/65/EU—Restriction of Hazardous Substances in electrical and electronic equipment

    Typical usage ratio

    • 1–7 wt% of total resin solids depending on crosslinking density and desired surface hardness
    • Optimized per pigment volume concentration and target gloss/matte finish

    Downstream process integration

    • Dosed into the isocyanate or polyol component prior to mixing for two-pack systems
    • Processed at ambient or slightly elevated temperatures using high-shear mixers
    • Applied by airless spray or roller application on prepared substrates

    Final product types

    • Protective topcoats for galvanized steel structures
    • Bridge and infrastructure anti-corrosion coatings
    • Industrial OEM machinery coatings
    • Metallic facade paints

    3. Adhesive Formulation for Footwear and Leather Goods

    Manufacturers of footwear and premium leather accessories integrate this intermediate into solvent-based polyurethane adhesives to improve bonding strength and flexibility under dynamic stress. The chemical structure provides a balance of elasticity and cohesive strength required for lasting adhesion between diverse substrates such as leather, synthetic uppers, and rubber outsole materials. It enables fine-tuning of open time and initial tack while maintaining compliance with health and safety regulations pertaining to industrial adhesives.

    Industry compliance standards

    • EN ISO 20345:2022, Safety Footwear—Component chemical requirements
    • GB/T 15107-2013, Chinese standard for footwear adhesives
    • GMP for Footwear Adhesives (local authority guidelines for occupational exposure)
    • Directive 1999/13/EC—Limitation of emissions of VOCs due to adhesive use

    Typical usage ratio

    • 3–12 wt% within polyurethane adhesive resin blends
    • Varies with required bond strength and substrate nature; lower end for soft leathers, higher end for rigid soles

    Downstream process integration

    • Blended into polyurethane backbone during pre-formation of resin
    • Dispersed under agitation before solvent dilution
    • Applied by brush, roll, or automated spray on component surfaces before press-lamination

    Final product types

    • Leather shoe uppers and soles
    • Bonded synthetic sport shoe parts
    • Premium bag and belt structural adhesives
    • Mountaineering boots and safety footwear

    4. Modifier for Crosslinked Elastomer Compounds in Industrial Rollers

    This chemical acts as a modifier in cast polyurethane elastomer production, specifically for heavy-duty rollers used in paper, printing, and conveyor systems. Its distinct aromatic structure introduces additional soft segment flexibility and push-pull resistance under mechanical load. Industrial users rely on tight composition control to improve abrasion resistance and reduce hysteresis in extended production cycles, ensuring consistent quality and longevity of finished elastomeric components.

    Industry compliance standards

    • ISO 9001:2015—Process validation and batch traceability
    • ASTM D412—Standard Test Methods for Vulcanized Rubber and Thermoplastic Elastomers—Tensile Properties
    • DIN 53516—Resistance to abrasion of rubber
    • REACH Annex XVII—Restriction on polyaromatic raw materials in industrial elastomers

    Typical usage ratio

    • 0.8–2.5 wt% based on total prepolymer mass
    • Specific dosage tailored to required modulus and dynamic fatigue threshold for application

    Downstream process integration

    • Blended in prepolymer stage before curative introduction
    • Distributed using planetary mixers under vacuum to minimize entrapped air
    • Casting into heated roller molds with cycle-controlled curing

    Final product types

    • Pulp and paper mill conveyor rollers
    • High-load printing press rollers
    • Mining industry belt drive rollers
    • Food-grade conveyor and pressure rollers (pending further upstream compliance validation)

    5. Intermediate in the Manufacture of High-Performance Polyurethane Sealants

    Sealant manufacturers employ this intermediate during prepolymer synthesis to enhance balance between tensile strength and elongation in moisture-cure and two-component polyurethane systems. It supports the development of products engineered for expansion joint filling, concrete sealing, and façade assembly in civil engineering. Its controlled reactivity ensures homogeneous final cure, minimal shrinkage, and compatibility with silane additives for improved weather and UV resistance. Strict batch quality monitoring addresses critical application in infrastructure and construction sectors.

    Industry compliance standards

    • EN 15651-1:2017—Sealants for non-structural use in joints in buildings and pedestrian walkways
    • ASTM C920—Standard Specification for Elastomeric Joint Sealants
    • GB 16776, Chinese National Standard—Silicone Structural Sealants
    • SCAQMD Rule 1168—Adhesive and sealant VOC regulations (California)

    Typical usage ratio

    • 1–6 wt% in prepolymer formulation
    • Adjusted by required cure profile, modulus, and movement range of the target sealant

    Downstream process integration

    • Dosed during prepolymer formation under controlled temperature (50–80°C)
    • Dispersed in main reactor prior to chain extension or curing agent addition
    • Quality control for NCO content verified before compounding with plasticizers and fillers

    Final product types

    • Façade and curtain wall sealants
    • Pavement and bridge expansion joint fillers
    • Window and door perimeter sealants
    • Industrial anti-vibration gasketing compounds
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    Certification & Compliance
    More Introduction

    N-Methyl-N-Phenylurethane: Reliable Support for Advanced Manufacturing

    Understanding N-Methyl-N-Phenylurethane from the Manufacturer’s Perspective

    N-Methyl-N-Phenylurethane, also known in manufacturing circles by its chemical structure, stands as a consistent performer in specialty chemical portfolios. Our facility has been synthesizing this compound for decades, and the process has evolved side by side with changes in downstream industry trends. Factory teams notice the subtle shifts in physicochemical expectations from our partners, and this feedback shapes every batch we prepare.

    The substance comes as a white to off-white crystalline solid at room temperature, and our operators have measured its melting point in line with published technical literature, giving engineers predictable material handling during storage and blending operations. Our typical batch delivers purity exceeding 99%, with controlled moisture content and minimal ash. Achieving these specifications keeps downstream production lines efficient, especially where minor contaminants can cause bigger issues in polymer or coatings synthesis.

    Performance and Practical Benefits Observed in the Field

    Years of plant experience have shown us real-world benefits of N-Methyl-N-Phenylurethane for producers of flexible polyurethane foams, adhesives, and specialty resins. The compound integrates smoothly in prepolymer manufacturing, permitting polyurethane chains with desirable resilience and elastic recovery. Simple equipment and regular mixing protocols suffice for uniform incorporation. Plant engineers appreciate the clear melting characteristics, as the material melts evenly, avoiding clumps or cold spots on the processing floor.

    In everyday use, quality control relies on N-Methyl-N-Phenylurethane’s predictable reactivity and compatibility with isocyanates. Smaller manufacturers who once faced interruptions due to variable raw material batches confirm longer runs and reduced scrap when upgrading to this compound. Larger chemical players speak of the compound’s contribution to customized product formulations, and the ability to meet new and evolving international regulatory benchmarks.

    How Our Manufacturing Experience Guides Quality

    We recognize that consistency, batch-to-batch, sets apart a dependable chemical producer. Our workers monitor every lot, matching infrared spectral fingerprints and titration results to tight internal controls. Spot checks and 24-hour quality lab access shield our customers from surprises in their supply, particularly in regions where transport or warehousing delays push storage times beyond the original window. Having experienced the headaches of material variability years ago, our production engineers invest heavily in process optimization at each step—from raw material sourcing to blending, crystallization, and final packing.

    During annual customer audit cycles, visiting technical teams often examine our statistical batch histories. They see not only production logs but also cross-plant studies where shifts in pressure, agitation, or temperature profile led to visible yield improvements. These process notes document real working knowledge, and translate into tangible benefits for every buyer—fewer complaints, easier documentation, and trust in the next shipment’s reliability.

    Comparison with Similar Compounds—Real Differences Matter

    Customers sometimes wonder why select this specialty urethane as opposed to alternatives like ethyl-based or propyl-based urethanes, or TDI/MDI-based compounds. From direct lab and production experience, we notice the methyl-phenyl backbone delivers sharper thermal stability and clean decomposition versus purely aliphatic or simpler aromatic analogs. Finished foam panels exhibit greater gloss and recover their shape after deformation, as reported by downstream fabricators.

    Switching to N-Methyl-N-Phenylurethane from more volatile or less pure types brings practical advantages. In adhesives production, this urethane avoids common issues like yellowing or cracking during accelerated aging tests. Operators on the mixing floor welcome smoother process control, the absence of strong residual odors, and a lower risk of unplanned downtime during seasonal temperature swings.

    Price comparison across similar chemicals sometimes creates challenges, but regular customers see lower hidden costs—reduced handling losses, simpler cleanups, fewer off-spec product runs. As a manufacturer, these lessons come hard earned; observing the difference, year after year, influences our own purchase of input materials, so even our own vendors are required to comply with strict sourcing standards.

    Customer Experiences Drive Continuous Improvement

    Many new adopters approach us after issues with inconsistent urethane batches from brokers or re-packers. Some report physical separation within drums or uneven melting behaviors, which can slow down automated dosing equipment. We welcome these observations, often sending technical managers into our plant to observe real-time quality checks. Having full control over the synthesis, packing, and outbound logistics, our teams make immediate adjustments based on customer feedback.

    Feedback from foam manufacturers pointed out that rapid, complete melting translates into faster tank changeovers, less residue, and fewer filter blockages. End users making high-spec shoe soles or automotive interior panels find batch consistency vital for passing mechanical performance tests. Users in the synthetic leather field appreciate the compound’s clean reaction profile and minimal influence on finished color, especially when precise hue matching is vital.

    The true measure of our approach comes through recurring business. Clients who previously changed suppliers annually now request their own reserved lots, sometimes forecasting demand out years in advance. On-site visits, direct troubleshooting, and open-line communication shape new handling protocols, storage solutions, and even batch size recommendations, saving substantial costs on logistics and inventory.

    Managing Real Risks and Addressing Industry Hurdles

    The chemical industry faces ongoing pressure for safer, more responsible manufacturing. Recent years have seen heightened scrutiny of intermediate chemical storage, environmental compliance, and reporting transparency. From our earliest days, we committed to environmental, health, and safety improvements—installing on-site air scrubbing, sealed drum filling, and employee training long before these steps became mandatory.

    Routine review of our waste reduction records led to advances in clean-in-place systems and closed-loop recycling of mother liquors. Hazard analysis studies guide our handling recommendations, and we share all relevant findings directly with our partners. Workplace safety, for us, goes beyond compliance; it’s a mindset reinforced in daily pre-shift meetings, with open invitation for any operator to flag potential issues or propose improvements.

    Shipping the compound, especially across borders or in challenging climates, brings its own hurdles. To prevent exposure to heat, sunlight, and mechanical shocks in transit, our packing team uses double-sealed, inert-lined drums and containers. For customers in tropical regions or those with no dedicated chemical storage, we created custom warehousing guidelines based on our own trials in simulated harsh environments. Our logistics partners receive yearly training sessions, guided by incidents identified in competitor supply chains. These real-world procedures keep the product within spec, right to the moment a factory operator opens the drum.

    Real-World Solutions to Downtime and Waste

    Oversupply at the end of a product run leads to excessive sitting inventory and avoidable waste. Based on customer production data, we now offer batch-size flexibility and rapid-response filling lines. This way, customers don’t face pressure to over-order or discard material past useful shelf life. A recent review of our top clients found a 16% drop in waste return rates after adoption of right-size ordering.

    We refined our packaging offerings after reviewing field complaints about caking and hardening during extended storage in humid areas. Our development team sourced liners with improved vapor barriers and added optional nitrogen flushing on request, virtually eliminating product caking even through peak summer months. The impact showed up not just in lab data but in the reduction of manual labor hours spent breaking up clumped material on busy production days.

    In response to customer frustrations about drum openers and transfer pumps fouling from crystallized residue, in-plant trials led us to invest in smoother-finish drums with anti-static coatings. Clean drum interiors make a difference in practice, not just in the lab, resulting in easier and faster changes between product runs and improved workplace safety.

    Product Traceability and Trust: Lessons from Industry Experience

    Operations teams at scale know the importance of paper trails. Mistakes in traceability have cost chemical buyers millions in lost production and recalls across the wider polymer industry. We respond to these realities by embedding barcoded tracking, secure lot numbers, and digital certificates of conformity with every consignment. Our IT team designed the trace-back system after reviewing the downtime caused by data mismatches at customer plants—a small but critical improvement, enabling rapid, transparent queries and effortless compliance for regulated end uses.

    Real traceability also demands technical transparency. We have ready access to complete synthesis logs, QC records, and shipment documentation, because auditors from diverse regions ask for evidence in varying formats. Nothing replaces direct access and quick resolution when a shipment’s shelf life is in question or when a customer’s regulator wants environmental impact assessments for their product registration.

    Technical service does not end at the purchase order. When our partners need batch samples or retained material for regulatory clearance, we retrieve, test, and ship from controlled inventory, cutting the time and anxiety experienced by regulatory, HSE, or R&D departments further down the supply chain.

    Adjusting to Evolving Industry Standards and Customer Needs

    Lately, customers around the world have heightened their focus on sustainability, occupational safety, and supply chain resilience. Our managerial team reviews the latest research and international guidance, including full Life Cycle Assessments, product stewardship, and reporting systems aligned with regulatory frameworks from North America to Europe and Asia. Having lived through previous decades of shifting standards, we know to expect industry priorities to keep changing—sometimes abruptly.

    One trend our partners often discuss is transition away from hazardous or regulated raw materials. Since our synthesis process uses no regulated amines or controlled aromatics, product stewardship officers at major OEMs see value in our compound’s compliance profile. In-house environmental testing labs track emissions and disposal metrics for every major customer sector, aiming for both compliance and continuous improvement.

    Some industries request documentation far beyond traditional COAs—full impurity profiles, analytical signatures, or even custom stability studies. We accommodate these needs by maintaining real dialogue with regulatory chemists and sharing non-confidential process details relevant to each application. Our technical team’s direct involvement in industry working groups helps us anticipate tighter controls before they impact full-scale production.

    Educating and Supporting the Next Generation of Users

    A big part of our work revolves around supporting plant managers and engineers who are new to advanced urethane chemistry. Seeing the transition from small pilot trials to full-scale use always reveals new questions, ranging from transfer piping compatibility to unexpected effects in final products. Our technical field teams offer answers based on real-life plant trials, not just lab simulations. This close-loop feedback sharpens process directions, improves yields, and maintains safety on both sides: in our factory and in our customer’s operation.

    Material transfer, blend times, temperature setpoints—these details rarely appear in technical data sheets, but from observation, they affect quality and throughput far more than theoretical yields or academic bench work. We encourage site visits and pilot runs to validate material choices firsthand, and our facility makes available dozens of real-use application examples for study.

    Training new users takes patience, and mistakes happen when assumptions don’t match up with process realities. As a manufacturer with a workforce of seasoned operators, we invest in mentoring programs and systematized troubleshooting, helping prevent recurring issues and supporting a new generation of chemical professionals.

    Moving Forward: Commitment to Long-Term Partnerships

    We have watched trends come and go in chemical manufacturing, but a few core principles remain: focus on quality, communicate openly, tighten operational controls, and keep learning from field feedback. N-Methyl-N-Phenylurethane remains a core building block in our product range because our customers have shown, time and again, that attention to detail in manufacturing produces value from top to bottom.

    Looking back on years of feedback and plant tours, our team takes pride in delivering the real-world advantages that come from a manufacturer’s hands-on involvement. We aim not just to deliver a product that meets a list of specifications, but to anticipate needs and act on feedback, wherever our chemical ends up—from flexible foam, to coatings, to the latest specialty material under development.