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N-Hexylimidazolium Trifluoromethanesulfonate

    • Product Name N-Hexylimidazolium Trifluoromethanesulfonate
    • Alias [HMIM][OTf]
    • Einecs 629-850-3
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    628703

    Chemical Name N-Hexylimidazolium Trifluoromethanesulfonate
    Cas Number 735974-45-7
    Molecular Formula C10H17F3N2O3S
    Molecular Weight 318.32 g/mol
    Appearance Colorless to pale yellow liquid
    Boiling Point Decomposes before boiling
    Density 1.27 g/cm3 (approximate)
    Solubility In Water Miscible
    Purity Typically ≥98%
    Storage Temperature Room temperature, tightly closed
    Iupac Name 1-hexyl-3-methylimidazol-1-ium trifluoromethanesulfonate
    Refractive Index n20/D ~1.45
    Flash Point >100°C

    As an accredited N-Hexylimidazolium Trifluoromethanesulfonate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 100 g of N-Hexylimidazolium Trifluoromethanesulfonate, sealed in an amber glass bottle with a secure screw cap, labeled for laboratory use.
    Shipping N-Hexylimidazolium Trifluoromethanesulfonate should be shipped in tightly sealed containers, stored upright and protected from moisture. Transport in accordance with local, national, and international regulations for chemicals. Avoid extreme temperatures and direct sunlight. Ensure clear labeling and safety documentation are included. Handle with protective equipment to prevent spills and exposure.
    Storage N-Hexylimidazolium Trifluoromethanesulfonate should be stored in a tightly closed container, in a cool, dry, and well-ventilated area, away from moisture and incompatible substances such as strong oxidizers. Protect from light and sources of ignition. Ensure appropriate labeling and keep the container upright. Store at room temperature, and avoid prolonged exposure to air to prevent decomposition or contamination.
    Application of N-Hexylimidazolium Trifluoromethanesulfonate

    Applications of N-Hexylimidazolium Trifluoromethanesulfonate in Industrial Manufacturing

    Our production-grade N-Hexylimidazolium Trifluoromethanesulfonate supports advanced performance requirements in highly specialized chemical manufacturing environments. Each batch undergoes rigorous in-process quality controls, ensuring extrinsic consistency and traceability for demanding downstream industries. Explore major application scenarios with critical compliance, precise formulation recommendations, workflow integration points, and the target end products supplied by downstream partners worldwide.

    1. Electrolyte Component for High-Energy Supercapacitors

    N-alkylimidazolium trifluoromethanesulfonates serve a proven role as ionic liquid electrolyte constituents in supercapacitor assembly lines, supporting manufacturers pursuing high-voltage stability and improved cyclability. Formulators precisely adjust the ionic liquid content to balance ionic conductivity and viscosity based on required charge-discharge rates and operational temperatures, particularly in hybrid and asymmetric cell types.

    Industry compliance standards

    • IEC 62391-1 for fixed electric double-layer capacitors
    • RoHS Directive 2011/65/EU for restricted substances in electronics
    • ISO 9001:2015 for manufacturing quality assurance
    • REACH Regulation (EC) 1907/2006 concerning chemical safety

    Typical usage ratio

    • 5–20 wt% of total electrolyte volume, fine-tuned according to electrolyte solvent system and target electrical properties; ratio varies by capacitance rating and operational voltage window

    Downstream process integration

    • Batch-mixed with organic or mixed ionic electrolyte solutions during the pre-assembly of supercapacitor cell units; integrated after vacuum dehydration steps to prevent water sensitivity before cell encapsulation

    Final product types

    • Hybrid supercapacitor modules for automotive energy recovery
    • Large-cell supercapacitors for power grid buffering
    • Miniature supercapacitors for wearable and IoT devices

    2. Conductive Salt for Lithium Metal and Lithium-Ion Cell Electrolytes

    This ionic liquid salt is applied as a secondary conductive additive in advanced lithium battery electrolyte formulations, aiming to improve ion transport and suppress dendrite formation during cycling. Cell designers selectively increase its ratio in low-viscosity solvents or solid-state precursors, seeking to boost battery lifespan and enhance safety characteristics in both pouch and prismatic cell architectures.

    Industry compliance standards

    • UL 2054 for household and commercial battery systems
    • SOCMA C-TPAT for chemical transportation and storage protocols
    • IEC 62660-2 for secondary lithium cells in automotive applications
    • China GB/T 31467.3 for traction battery performance and safety

    Typical usage ratio

    • 0.5–3.0% by weight in combination with standard lithium salts such as LiPF6 or LiTFSI, proportion adjusted according to target ionic conductivity, film-forming requirements, and electrode compatibility

    Downstream process integration

    • Added during the electrolyte solvent blending stage prior to vacuum degassing and subsequent cell injection or dry coating onto separator films in solid electrolyte systems

    Final product types

    • Automotive lithium-ion and lithium-metal batteries
    • High-capacity power cells for aerospace
    • Ultra-thin rechargeable pouch batteries

    3. Solvent Additive in Organic Synthesis of Fine Chemicals

    Chemical manufacturers employ this ionic liquid as a functional co-solvent in select organic synthesis processes, most notably in SN2/SNAr substitutions and transition-metal catalyzed coupling reactions. Its thermal and electrochemical stability, coupled with non-volatile behavior, allow for reduced solvent loss and the facilitation of challenging transformations under high-purity, low-contamination conditions.

    Industry compliance standards

    • GMP guidelines for active pharmaceutical ingredient (API) intermediates (ICH Q7)
    • EU Regulation (EC) No 1223/2009 for cosmetic ingredient purity
    • ISO 14001:2015, environmental management systems applicable to fine chemical manufacturing
    • Chemical Facility Anti-Terrorism Standards (CFATS) for production site security

    Typical usage ratio

    • 1–15% by volume as a co-solvent, calibrated against substrate solubility, catalyst activation profiles, and downstream product recovery requirements

    Downstream process integration

    • Introduced after main base/acid neutralization steps and prior to catalyst charging in multi-stage reactors; removed or recycled via vacuum distillation following completion of the target reaction

    Final product types

    • Pharmaceutical building blocks
    • Specialty agrochemical actives
    • High-purity cosmetic intermediates

    4. Antistatic Additive for Polymeric Coatings in Electronics

    Downstream electronics and display manufacturers integrate this ionic liquid as an antistatic modifier in polymer coating formulations, particularly for films used in touchscreen sensors and flexible displays. Its ionic character imparts long-term charge dissipation in ultra-thin coatings, supporting defect reduction during high-throughput roll-to-roll processing and minimizing particulate attraction on sensitive optical assemblies.

    Industry compliance standards

    • IEC 61340-5-1: protection of electronic devices from electrostatic phenomena
    • ISO 14644-1: cleanroom classification, as applies to coating lines
    • QS-9000 for automotive electronics coatings QC
    • Environmental regulations on VOC emissions (e.g., US EPA 40 CFR Part 63)

    Typical usage ratio

    • 0.2–1.0 wt% relative to polymer resin; dependent on target surface resistance (108–1010 Ω/sq) and compatibility with matrix chemistry

    Downstream process integration

    • Added to resin premixes before solvent adjustment and dispersion milling; then applied through slot-die or gravure coating onto PET or polyimide substrates, followed by thermal curing or UV cross-linking as specified by downstream process QC

    Final product types

    • Touchscreen and OLED device films
    • Flexible display substrate coatings
    • Protective antistatic layers for chip packaging

    5. Reaction Medium for Organometallic Catalysis in Chemical Synthesis

    Advanced process chemists utilize this ionic liquid as an inert reaction medium in organometallic catalysis where stability against hydrolysis and high ionic strength are required. Applications center around selective hydrogenation and cross-coupling production routes, where it can modulate catalyst performance and enhance product yield through phase-control mechanisms in continuous and batch operations.

    Industry compliance standards

    • OECD Good Laboratory Practice (GLP) for process chemistry R&D
    • ISO 9001:2015 for chemical production management
    • REACH registered substances for process solvents
    • Responsible Care management systems for safe handling

    Typical usage ratio

    • 10–30% by total reaction mixture, optimized based on solubility of substrates, desired turnover frequency, and catalyst loading requirements; batch and flow process parameters dictate volume fraction

    Downstream process integration

    • Charged into stainless-steel or glass-lined reactors post-inertization, forming the bulk phase or secondary phase for catalyst suspension, before temperature ramping and reactant addition

    Final product types

    • Organometallic intermediates for pharmaceutical synthesis
    • Specialty fine chemical targets for agrochemical and dyestuff industries
    • Purified API-grade hydrogenation products
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    Certification & Compliance
    More Introduction

    N-Hexylimidazolium Trifluoromethanesulfonate: Precision Through Chemistry

    Bringing Forward New Ionic Liquid Standards

    Manufacturing specialty imidazolium salts for over a decade teaches a team to distinguish real requirements from what’s simply advertised. Every molecule has a story and a purpose. Our N-Hexylimidazolium Trifluoromethanesulfonate, which many know by its structure comprised of a hexyl-substituted imidazolium cation with the robust trifluoromethanesulfonate (triflate) anion, represents a solution for those searching for ionic liquids with unique hydrophobicity and electrochemical stability. Across hundreds of kilograms of batches, real-world feedback keeps surfacing from labs scaling up syntheses to pilot-scale reactors: niche ionic liquids solve problems off-the-shelf materials cannot touch.

    In the chemical plant, the challenges are immediate and practical. The right choice of ionic liquid brings more than an incremental improvement—it can change the economics of a process entirely. The N-Hexylimidazolium Trifluoromethanesulfonate that leaves our reactors exhibits a careful balance between alkyl chain length and the performance features scientists now expect in robust electrolytes, extraction agents, and catalysts. Shaped by years of hands-on process control, we know purity impacts downstream results. So every batch is cleaned up and filtered using our proprietary protocols, tested by NMR and mass spectrometry before leaving our site. Only with these guarantees do our partners develop new electrolytic cells, design separation processes, and tinker with organic transformations that demand water tolerance and thermal endurance.

    What Sets N-Hexylimidazolium Trifluoromethanesulfonate Apart

    As ionic liquids go, many stay satisfied with short-chained analogues like methyl or butyl imidazoliums. These serve well enough in prototype work and small-scale applications. Our extensive production experience shows the value in offering variants that unlock performance not possible with generic cations. Introducing a hexyl group stretches the alkyl chain and changes the solubility profile. This brings far lower water miscibility and raises the liquid’s hydrophobic character—a requirement in non-aqueous battery development, biphasic catalysis, and selective metal extraction processes.

    Colleagues in research institutes struggle with solvent compatibility and destabilization in high-voltage environments. N-Hexylimidazolium Trifluoromethanesulfonate finds its way into those experiments, tolerating a wider temperature window and resisting hydrolysis where less engineered materials fail. Every year, customer-driven R&D pulls us to refine our salt preparation routes, keep ionic contaminants under critical limits, and ensure byproduct scavenging meets the latest chromatographic standards. The result is a batch-to-batch consistency that lets industrial users switch from flask-scale synthesis to multi-liter complete processes, without the countless reformulations required by less consistent sources.

    Model and Specification Driven by Community Feedback

    Direct feedback drives our process improvements, not speculative market reports. Since our founding, the best insights come from the benches, reactors, and chromatographs of our clients. Our most-requested grade of N-Hexylimidazolium Trifluoromethanesulfonate features a minimum cation purity of 99%, a moisture content that stays below 0.1%, and triflate anion matching the latest ISO ion chromatography standards.

    Speculative purity declarations bring little comfort unless you see data. Actual users demand test results with each new lot. So every drum, large-bottle, or gram-scale sample carries a certificate tracked to our QC archives, referenced by production date and operator. We mean it when we say science leads the product line. A long-standing university spin-off partner once challenged us to reduce residual halides below ten parts per million; after months of process tuning, we achieved that, resulting in published results and a new set of protocols which we now use across production.

    Supporting Emerging Technologies and Collaborative Development

    Watching ionic liquid chemistry evolve helps keep the operation focused on future needs. Battery developers, metal refiners, and organic synthesis specialists come to us with technical bottlenecks rather than simple chemical shopping lists. For lithium battery labs, our hexylimidazolium triflate provides a non-flammable, electronically robust medium that delivers both ionic conductivity and safety credentials missing from early-room temperature ionic liquids.

    Pilot plant engineers experimenting with biphasic systems depend on the distinct hydrophobicity profile, using our product to extract precious and base metals from strongly acidic or brine matrices, allowing selective recovery without cross-contamination by water-soluble fractions. For pharmaceutical chemists, the alkyl extension tunes solvent properties: enabling selective cross-coupling reactions, boosting yield, and minimizing unwanted side products, especially with sensitive aryl halide substrates.

    Some of the most satisfying projects emerge from getting involved early, before the pilot scale. One client came with an idea for using ionic liquids in CO2 capture, and after many rounds of bench trials, the hexyl variant succeeded where butyl systems failed due to volatility issues and solvent carryover. These interactions shape every new iteration of our preparation methods. Peer-to-peer engagement fosters joint troubleshooting — modifications agreed on by process and research teams rather than imposed by customer relations scripts.

    Comparing Against Conventional and Competitive Materials

    It gets tempting to stay with what’s familiar, like simple imidazolium salts or quaternary ammonium compounds. But real differences in process performance come from trying alternatives and measuring the impact over repeated runs. Technicians in battery fabrication often complain about corrosion issues and decomposition products stemming from cheaper metallic salts or unpurified ionic liquid blends. Upgrading to N-Hexylimidazolium Trifluoromethanesulfonate brings higher oxidative stability, crucial for devices running at elevated voltages.

    Some competitors push more volatile, lower-melting salts that claim “universal” applicability. Yet, in practice, these compounds display limited compositional tolerance, and they rarely survive the reactor environment without side-reactions or gradual build-up of impurities. We’ve witnessed failures due to micro-phase separation, especially where process water cannot be fully excluded. The hexylimidazolium backbone, paired with the inertness of triflate, resists these problems, provides a wider electrochemical window, and ensures lasting purity even under dry and high-heat process streams.

    Engineers developing catalytic platforms often express concern about spent solvent recycling and environmental loadout. Triflate-based ionic liquids produce fewer troublesome decomposition products and are easier to separate from inorganic by-products. Meanwhile, shorter chained imidazolium salts absorb much more water during storage—leading to reproducibility headaches, blocked dosing lines, and unreliable scale-ups. Years spent debugging these issues in our facility and at customer sites proved that chain-length tailoring isn’t theory; it changes workflows, reduces downtime, and drives up project reliability.

    Process Transparency and Quality Control

    Many partners voice frustration about inconsistent supplies and lack of visibility into production history. Our approach stays transparent. Each production campaign of N-Hexylimidazolium Trifluoromethanesulfonate gets tracked from weigh-in to packaging. QC checkpoints run throughout—this stems from witnessing firsthand how missing one testing step jeopardizes weeks of downstream work. We grow our expertise alongside the most demanding clients, whether they’re qualifying ionically conductive formulations for new battery chemistries or validating extraction platforms for trace-level recovery of platinum group metals.

    Our internal data over dozens of project cycles reinforces the same lesson: small changes in precursor quality or reaction parameters show up later as process glitches or variable analytical readings for final users. Low water content does not come by wishing; it emerges from stepwise dehydration, controlled atmosphere handling, and regular instrument calibration. Keeping decomposition markers—like halide or alkali carryover—below strict parts-per-million cutoffs calls for methodical attention, round-the-clock maintenance, and a willingness to halt production if a lot spikes above specification. This discipline keeps repeat clients returning, trusting their next set of experiments to start right where the last batch left off.

    Practical Usage and Handling Recommendations

    Real experience has tempered our usage guidance—there’s a big gap between bench chemistry and factory runs. For customers scaling up, issues like storage, shelf-life, compatibility with hoses and elastomers move from theoretical to urgent. We suggest storing sealed containers in dry, temperature-stable rooms, away from direct sunlight. In our own workspaces, we use nitrogen atmosphere gloveboxes for high-sensitivity applications, since even the best-sealed containers slowly absorb moisture over weeks.

    Transfer operations use dedicated equipment wherever possible. Glass and high-quality stainless steel (316L or better) tubing works best. In labs, disposable polypropylene can tolerate limited short-term exposure, though extended contact softens weaker plastics. Product clean-up after process runs keeps transfer losses minimal; viscous liquids like this resist full recovery from common drums, so custom pumps and pre-warmed hoses prevent costly waste. Decades of experience proved these methods turn cleanup from a lingering afterthought into a quick, reliable routine.

    Meeting Evolving Industry Demands

    Keeping pace with battery innovation, resource extraction, and process intensification in chemical manufacturing doesn’t allow us to stand still. Each new inquiry—from MedTech startups to resource engineers—pushes us to test, upgrade, and document why specific ionic liquids succeed where others fail. The trend toward non-aqueous electrolytes, greener solvents, and safer alternatives to legacy ions becomes clear through daily operations. N-Hexylimidazolium Trifluoromethanesulfonate, forged through iterations and real-world troubleshooting, steps up to wider thermal ranges, lower volatility, and unmatched batch-to-batch purity.

    A project with a leading Asian energy storage group highlights how triflate-based ionic liquids prolong operational lifetimes, resisting breakdown over thousands of cycles at high charge and discharge rates. As those results get published and shared, demand soars for not just any ionic liquid, but specifically those refined for scale. The dialogue with process engineers continues—sharing production data, adjusting process conditions in response to feedback, and jointly developing next-generation battery and catalyst platforms.

    Continuous Learning Through Application Partnerships

    No chemical manufacturer operates in isolation. Every client brings ideas forward and exposes our team to the frontier needs of their field. New product pilot lines, a relined reactor, alternate solvent systems, or a subtle problem with residuals—all of these translate into tweaks and advances in how we make and supply N-Hexylimidazolium Trifluoromethanesulfonate. Some challenges take months to resolve; in one case, a client’s metal separation process failed with a generic ionic liquid—the hexylimidazolium triflate model, after joint troubleshooting, delivered breakthrough selectivity, proving why custom preparation and responsive manufacturing matter.

    The evolving role of specialty ionic liquids ties industry and chemical science together. We view our mission as translating the collective needs of users into process improvements, new purity benchmarks, and faster turnaround on formulation requests. With each successful client deployment—whether for non-flammable battery solvents, tough-to-separate metal matrices, or high-efficiency green chemistry—the role of engineered salts grows. We stay committed to ongoing professional development, consistent data sharing, and a no-shortcuts approach to manufacturing N-Hexylimidazolium Trifluoromethanesulfonate that is ready for tomorrow’s challenges and the unpredictable questions that follow.

    Looking Ahead: Innovation Anchored in Practical Experience

    Being present within the realities of chemical manufacturing—balance tanks, raw material supply shifts, regulatory frameworks and customer demands—forces honest assessment of what delivers real value. N-Hexylimidazolium Trifluoromethanesulfonate does not win with slogans; it succeeds when labs and plants report new performance plateaus or cost breakthroughs. By grounding each batch in controlled chemistry, open communication with users, and readiness to customize to the needs of the moment, we prepare the way for broader industry adoption of ionic liquids.

    The work continues. With every fresh request, we invest more: refining purification, adopting feedback-driven improvements, and reporting results transparently. Our expertise grows not only with each kilogram shipped but through ongoing dialogue—teaching, adjusting, rethinking. N-Hexylimidazolium Trifluoromethanesulfonate stands as both a product and an example of real-world chemical manufacturing: evolving through application, proven by feedback, and always ready for what comes next in the hands of innovators and process engineers worldwide.