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N-(2,4,6-Trichlorophenyl)Maleimide

    • Product Name N-(2,4,6-Trichlorophenyl)Maleimide
    • Alias TCPM
    • Einecs 251-841-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    802270

    Cas Number 13355-96-9
    Molecular Formula C10H4Cl3NO2
    Molecular Weight 276.5 g/mol
    Appearance Yellow to yellow-green crystalline powder
    Melting Point 232-235°C
    Purity Typically ≥98%
    Solubility Slightly soluble in organic solvents; insoluble in water
    Storage Temperature Store at 2-8°C
    Boiling Point Decomposes before boiling
    Density 1.61 g/cm³
    Synonyms 2,4,6-Trichloro-N-phenylmaleimide
    Ec Number 236-400-6

    As an accredited N-(2,4,6-Trichlorophenyl)Maleimide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 25g amber glass bottle with a tight-sealed lid, affixed with a white label displaying the chemical name, hazard symbols, and supplier.
    Shipping N-(2,4,6-Trichlorophenyl)maleimide should be shipped in tightly sealed containers, protected from moisture and light. It must be labeled as a hazardous chemical and packed according to applicable regulations. Use secondary containment, such as cushioned boxes or absorbent liners, and ensure compliance with local and international transport guidelines for chemicals.
    Storage Store **N-(2,4,6-Trichlorophenyl)maleimide** in a tightly sealed container in a cool, dry, well-ventilated area away from direct sunlight, heat, and moisture. Keep away from incompatible substances such as strong oxidizing agents and bases. Use with proper personal protective equipment and avoid prolonged exposure. Always label containers clearly and follow all relevant safety guidelines and local regulations.
    Application of N-(2,4,6-Trichlorophenyl)Maleimide

    Applications of N-(2,4,6-Trichlorophenyl)Maleimide in Industrial Manufacturing

    N-(2,4,6-Trichlorophenyl)maleimide serves as a specialty imide additive in multiple high-value chemical manufacturing sectors. Our factory supplies this material for downstream integrators who require precision intermediates for advanced polymer synthesis, electronic component fabrication, and specialty coatings. Below is a breakdown of its proven applications by industry track, including regulatory standards, mixing protocols, process entry points, and intended end-use products.

    1. High-Performance Polyimide Resin Synthesis

    Our material functions as a key monomeric component in the production of polyimide-based resins. Polyimides require maleimide derivatives with high purity and defined reactivity to impart thermal stability and mechanical strength. End users in this sector utilize N-(2,4,6-Trichlorophenyl)maleimide in melt or solution-polymerization steps to form imide linkages. The final polymers withstand harsh environments, aligning with aerospace and electronics manufacturing needs.

    Industry compliance standards

    • ASTM D5336 (Standard Test Method for Determination of Gel Time of Polyimide Resins)
    • ISO 9001 Quality Management System
    • RoHS Directive 2011/65/EU (for electronics-grade applications)
    • REACH Regulation (EC) No 1907/2006 (concerning chemical registration and evaluation)

    Typical usage ratio

    • Maleimide monomer loadings from 5% to 20% by weight in polyimide formulations, adjusted according to desired glass transition temperature and mechanical properties.

    Downstream process integration

    • Feeds into the co-monomer addition stage in imidization reactors during batch polyimide synthesis.
    • May require pre-dissolution in aprotic solvents such as NMP prior to mixing.

    Final product types

    • Flexible printed circuit boards (FPCBs)
    • High-temperature-resistant film
    • Insulating varnishes for wire coatings
    • Advanced moldable polyimide parts for automotive and aerospace assemblies

    2. Semiconductor Photoresist Crosslinking Agent

    N-(2,4,6-Trichlorophenyl)maleimide acts as an effective crosslinking imide in the manufacture of negative-tone photoresists for semiconductor wafer processing. Its specific halogenation pattern improves UV-initiated crosslink density and etch resistance, making it suitable for lithography layers in advanced node fabrication environments. Strict control of additive concentration and residue mandates the use of this material only by qualified cleanroom processors.

    Industry compliance standards

    • SEMI S2 (Environmental, Health, and Safety Guideline for Semiconductor Manufacturing Equipment)
    • IATF 16949 for automotive microelectronics
    • IPC-6012 (Qualification and Performance Specification for Rigid Printed Boards)

    Typical usage ratio

    • 0.5–3% by weight within the base photoresist solution, fine-tuned by UV absorption and final film hardness testing in pilot line trials.

    Downstream process integration

    • Added during resist formulation blending pre-filtration, ahead of substrate coating and spin application in resist coater tracks.
    • Subject to in-process purity analysis to avoid ionic contaminants.

    Final product types

    • Photolithography resists for advanced node silicon wafers
    • Mask blanks for IC microfabrication
    • Etch-resistant layered films for MEMS components

    3. Speciality Reactive Dyes and Pigment Intermediate

    Downstream colorant and pigment producers source this maleimide derivative as a building block in the synthesis of halogenated dyes and specialty pigments. Its electron-withdrawing groups enhance chromophore reactivity, enabling fine-tuning of color performance and stability against chemical oxidants and acids. Typically, the material is used in multi-step organic transformations, with strict traceability on intermediate handling and environmental compliance for effluent treatment.

    Industry compliance standards

    • OEKO-TEX® Standard 100 (for textiles and eco-friendly dyeing)
    • EN 71-3 (Safety of Toys—Migration of certain elements, for pigments in coatings)
    • ISO 14001 (Environmental Management System)

    Typical usage ratio

    • 10–20 mol% relative to anhydride or amine co-reactants in coupling or cyclization reactions. Ratio adjusted based on desired color index and purity thresholds.

    Downstream process integration

    • Reacted in the intermediate synthesis step post-nitration and pre-coupling to form chromophoric frameworks under inert conditions.
    • Monitored by HPLC for endpoint identification and batch traceability.

    Final product types

    • Reactive textile dyes for industrial printing
    • Halogenated organic pigments for plastics coloring
    • Speciality anti-corrosive paints for metal structures

    4. Heat-Resistant Adhesives for Electronics Assembly

    This intermediate is utilized by formulators of specialty adhesives where temperature and flame resistance are critical. For electronics, compounders select N-(2,4,6-Trichlorophenyl)maleimide for its ability to form thermoset networks with high aromatic content, resulting in adhesives that maintain bonding integrity during solder reflow or under operational device stress. Quality control mandates accurate dosing and full cure verification to meet device reliability standards.

    Industry compliance standards

    • UL 94 (Standard for Tests for Flammability of Plastic Materials)
    • IPC-A-610 (Acceptability of Electronic Assemblies)
    • IEC 61249-2-21 (Materials for Printed Boards and Other Interconnecting Structures)

    Typical usage ratio

    • 5–12% by weight in adhesive resin matrix, with the ratio adapted to thermal cycling requirements and final bond line mechanical targets specified by OEM profiles.

    Downstream process integration

    • Introduced at the resin compounding phase before filler addition and homogenization in high-shear mixers.
    • Subjected to pre-polymerization QC and post-cure thermal analysis.

    Final product types

    • Printed circuit board (PCB) assembly adhesives
    • Chip-on-board underfill encapsulants
    • Thermoset potting compounds for electronic modules

    5. Advanced Composite Materials for Aerospace Structures

    Aerospace composite fabricators depend on this chlorinated maleimide for matrix modification in fiber-reinforced thermoset prepregs. The compound increases cross-link density and improves matrix-to-fiber adhesion for composites exposed to continuous high-temperature and aggressive chemical environments. Production teams control the precise addition to resin baths to match pre-preg tow specifications and final lamination schedules.

    Industry compliance standards

    • AMS 2759 (Aerospace Material Specifications for Heat Treating of Metal Parts)
    • EN 9100 (Aerospace Quality Management System)
    • FAA CFR 14 Part 25 (Airworthiness Standards for Transport Category Aircraft—flammability requirements for interiors)

    Typical usage ratio

    • 3–8% by weight in composite resin matrices, modified according to fiber volume ratio and mechanical property profiling for wing, panel, or cowl structures.

    Downstream process integration

    • Added to mixing phase of thermoset resin formulation prior to wetting carbon or aramid fiber tows.
    • Monitored using DSC (Differential Scanning Calorimetry) for cure profiling.

    Final product types

    • Structural aerospace panels
    • High-performance composite brackets and mounts
    • Heat shields for turbine engine components
    • Prepreg tape and sheets for aircraft skin applications
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