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Methyldiallylamine

    • Product Name Methyldiallylamine
    • Alias N-Methyldiallylamine
    • Einecs 214-663-3
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    239038

    Cas Number 6605-90-7
    Molecular Formula C6H11N
    Molecular Weight 97.16 g/mol
    Iupac Name N-methyl-N,2-propadienylamine
    Synonyms N-Methyldiallylamine, MDAM
    Appearance Colorless to pale yellow liquid
    Boiling Point 111-113 °C
    Density 0.783 g/cm³ at 20°C
    Solubility In Water Miscible
    Flash Point 19 °C (closed cup)
    Refractive Index 1.430-1.433
    Chemical Class Allylamine

    As an accredited Methyldiallylamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 250g of Methyldiallylamine is supplied in a sealed, amber glass bottle with a secure cap. Clearly labeled with safety information.
    Shipping Methyldiallylamine should be shipped in tightly sealed containers, protected from heat and moisture. Transport in accordance with local, national, and international regulations for hazardous chemicals. Use appropriate labeling and documentation. Store upright in a cool, ventilated area, and handle using personal protective equipment to prevent exposure or leaks during transit.
    Storage Methyldiallylamine should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from direct sunlight, heat sources, and incompatible substances such as strong oxidizers and acids. The storage area should be equipped with spill containment and proper labeling. Avoid exposure to moisture and air to minimize degradation or hazardous reactions. Store under recommended temperature conditions.
    Application of Methyldiallylamine

    Applications of Methyldiallylamine in Industrial Manufacturing

    Methyldiallylamine, a high-purity aliphatic amine, supports several core industrial sectors as a cationic monomer with high reactivity. The following sections outline its primary use cases in actual downstream manufacturing, emphasizing industry standards, formulation ratios, integration points, and resulting products.

    1. Water Treatment Polymers

    Leading water treatment chemical producers incorporate methyldiallylamine into cationic polymer flocculants and coagulant aids, where its unique diallyl functionality promotes efficient chain formation during polymerization. This raw material increases the charge density of polyamines and polyDADMACs, delivering improved contaminant removal in municipal and industrial effluent processing. Manufacturers frequently adapt its input based on feed water conditions and target contaminant profiles, especially in sensitive discharge applications requiring high cationicity.

    Industry compliance standards

    • NSF/ANSI 60 (Drinking Water Treatment Chemicals – Health Effects)
    • 40 CFR Part 141 (US EPA – National Primary Drinking Water Regulations)
    • EN 1407 (European Standard: Chemicals used for treatment of water intended for human consumption)
    • GB 5749-2022 (China's Standards for Drinking Water Quality)

    Typical usage ratio

    • 0.5–15% by weight as a co-monomer in copolymerization; higher ratios for high-charge polymers for oily wastewater.
    • Adjusted according to desired molecular weight, cationic degree, and compliance with residual amine monomer limits as specified by end-use region.

    Downstream process integration

    • Dosed directly into aqueous-phase polymerization reactors alongside acrylamide or other cationic monomers to produce polyamine or polyDADMAC chains.
    • Process monitoring ensures minimal unreacted monomer in final flocculant dispersions or powders.

    Final product types

    • Polymeric flocculants (liquid or dry powders) for municipal or industrial wastewater treatment
    • Oil refinery effluent clarifiers
    • Paper mill retention aids
    • Drinking water purification polyelectrolytes

    2. Paper Wet-Strength Resin Manufacturing

    Pulp and paper chemical formulators select methyldiallylamine for cationic resin synthesis, targeting improvements in permanent wet strength without excessive formaldehyde content. Through co-polymerization with other unsaturated amines or epichlorohydrin derivatives, this monomer provides high charge, ensuring better retention on cellulose fibers during papermaking. Its use enhances the wet durability of finished grades for hygiene and specialty papers subject to stringent regulatory oversight for extractables and consumer safety.

    Industry compliance standards

    • BfR Recommendation XXXVI (Germany, Paper and board for food contact)
    • FDA 21 CFR 176.170 (US, Paper and paperboard components in contact with aqueous and fatty foods)
    • OECD Guideline 302B (Inherent Biodegradability: Zahn-Wellens/EMPA Test)
    • ISO 187:2022 (Paper, board and pulps – Standard atmosphere for conditioning and testing, relevant for QC)

    Typical usage ratio

    • 5–18% by weight as a comonomer in wet-strength resin formulations, depending on the grade and target charge density of the resin.
    • Lower end for soft tissue grades, higher end for specialty technical papers or boards.

    Downstream process integration

    • Enters batch or continuous polymerization with other amines and functionalized monomers.
    • Final resin introduced into the papermaking wet end, dosed just before sheet formation for highest fiber interaction.

    Final product types

    • Tissue and towel papers requiring high wet tensile strength
    • Food-grade wrapping and filter papers
    • Specialty technical and label papers

    3. Ion-Exchange Resin Synthesis

    Industrial resin producers utilize methyldiallylamine in forming cationic ion-exchange materials for water softening and desalination. The presence of diallyl groups contributes to cross-linkable networks required for robust bead structures with tailored porosity and functional group accessibility. Proper dosing and reaction conditions directly influence exchange capacity, mechanical stability, and leachable amine content, with strict adherence to local and customer-specific regulatory expectations for potable and industrial process resin use.

    Industry compliance standards

    • NSF/ANSI 61 (Drinking Water System Components – Health Effects)
    • EU Regulation (EC) No 1935/2004 (Materials and articles intended to come into contact with food, as applicable to ion-exchange resins)
    • US FDA 21 CFR 173.25 (Ion-exchange resins in food processing)
    • Chemical-specific leachables limits as referenced in Japan Food Sanitation Act

    Typical usage ratio

    • 2–12% of total monomer feed, adjusted based on the targeted degree of cross-linking and resin bead charge density.
    • Higher ratios for strong-base anion-exchange types for specialty water purification.

    Downstream process integration

    • Polymerized with styrene/divinylbenzene or macroporous support beads using suspension or seeded emulsion techniques.
    • Blending and functionalization followed by curing, sieving, and post-reaction washing cycles to remove unreacted residuals.

    Final product types

    • Strong-base and weak-base anion-exchange resins (beads, granules)
    • High-capacity water softening columns
    • Industrial process stream purification cartridges

    4. Antistatic Agent Manufacturing for Polymers

    Producers of plastics auxiliaries and surface modification chemicals incorporate methyldiallylamine into permanent antistatic agent formulations for use in polyolefin and engineering plastic processing. Through copolymerization or chemical grafting, the cationic amine is anchored within the host polymer matrix, allowing for persistent anti-static effects even after repeated use or cleaning. Formulators must carefully regulate input to balance electrical dissipation efficiency, mechanical compatibility, and regulatory compliance as dictated by electronic packaging and automotive interior standards.

    Industry compliance standards

    • IEC 61340 (Electrostatics – Protection of electronic devices from electrostatic phenomena)
    • REACH Regulation (EC) No 1907/2006 (Registration, Evaluation, Authorisation and Restriction of Chemicals, ECHA, EU)
    • US FDA 21 CFR 177.1520 (Polymers for food contact, applicable for packaging grades)
    • RoHS Directive 2011/65/EU (Restriction of Hazardous Substances in Electrical and Electronic Equipment)

    Typical usage ratio

    • 0.2–2% by weight within masterbatch formulations; precise input depends on polymer type and required surface resistivity target.
    • Increased proportion for thick-wall or filled polymers, based on QC electrical discharge data.

    Downstream process integration

    • Blended into polymer masterbatch during extrusion or injection compounding, or grafted onto polymer backbone prior to pelletization.
    • Process QC includes surface resistivity and color stability testing of compounded granules or sheets.

    Final product types

    • Permanent antistatic masterbatches for polyethylene (PE), polypropylene (PP), and ABS
    • ESD-safe injection-molded trays and housings for electronics
    • Automotive interior components requiring low static buildup
    • Cleanroom packaging films and sheets

    5. Asphalt Emulsifier Production

    Cationic emulsifier manufacturers employ methyldiallylamine in the synthesis of quaternary ammonium compounds for road construction emulsified asphalt systems. This monomer provides tailored reactivity during the quaternization step, resulting in surfactants with high emulsion stability and rapid-breaking properties, essential for demanding climate or surface applications in highway paving and maintenance. Dosing levels and downstream process parameters require close adjustment to match regional regulatory migration testing and environmental restrictions.

    Industry compliance standards

    • ASTM D977 (Standard Specification for Emulsified Asphalt)
    • EN 13808:2013 (Binders for surface treatments of roads)
    • AASHTO M140 (Emulsified Asphalt Specifications, North America)
    • Local environmental discharge and migration limits for quaternary ammonium surfactants

    Typical usage ratio

    • 1.5–8% by weight as a precursor for quaternary ammonium emulsifiers within total surfactant blend.
    • Adapted to specific asphalt type, bitumen grade, and climate requirements—higher in rapid-set formulations, lower for slow-set products.

    Downstream process integration

    • Chemically reacted with alkylating agents (e.g., methyl chloride) in pressure reactors, followed by dilution and neutralization for final surfactant concentrate.
    • Formulated surfactant then added to bitumen emulsification system at the asphalt blending facility.

    Final product types

    • Rapid set and slow set cationic asphalt emulsifiers
    • Cold-mix and surface treatment asphalt emulsified preparations
    • Modified binders for durable road construction
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    Certification & Compliance
    More Introduction

    Methyldiallylamine: Building Quality from the Molecule Up

    Our Commitment to High-Purity Methyldiallylamine Production

    For decades, our team on the factory floor has shaped the approach to odds-on chemical reliability. Methyldiallylamine stands apart among the specialty amines in the labs and reactors. Unlike commodity amines made by the thousands of tons, our methyldiallylamine runs do not hide behind bulk numbers. Every kilogram on our line reflects the collective hours spent dialing in temperature ramp rates, tuning distillation columns, and wringing out all trace impurities from feedstocks. The pursuit for top-purity output begins at loading of the raw allylamines and continues though every controlled meter of the process. Precision starts with hands-on vigilance, not just at bottling but from commissioning of each reactor train.

    The Chemistry That Sets Methyldiallylamine Apart

    Methyldiallylamine (CAS 5067-23-8) brings a unique structure into play: a secondary amine center linked to two allyl groups and a methyl group. On paper, this composition hints at sharp reactivity. In practice, that translates into performance fine-tuned for water-soluble polymers, ion-exchange resins, and specialty flocculants. Compared to generic diallylamine or mono-alkylamines, our methyldiallylamine brings a balance of reactivity and stability. The structure resists unwanted homopolymerization while remaining ready to anchor itself during copolymerization or crosslinking reactions.

    Not all diallylamine derivatives hit this careful balance. Facilities focused on bulk diallylamine often accept higher water content or carryover byproducts—sometimes enough to cause fouling downstream in polymer and resin manufacturing. The purity from our purification line controls the levels of tertiary-amine byproducts and residual unreacted precursor, which means our methyldiallylamine avoids injection poisons in customer processes. Our techs monitor purity regularly above 99%, and dryness checks on each drum leave no room for residual water to creep into sensitive organic reactions.

    Why Industry Turns to Methyldiallylamine

    Down at the reactor output, production teams in polymer plants count on methyldiallylamine for molecular weight control and functional group placement. It finds a principal place in the creation of homopolymeric and copolymeric resins, especially those used as flocculants in water treatment, medium for ion-exchange columns in mining, and charge control agents for paper additives. The compound carries a proclivity for cationic modification, especially valued in papermaking and municipal water treatment. Its ability to bring stable charges into a chain beats out other mono-cessation amines, which can lack efficiency in charge density and have lower process compatibility.

    Our own application testing center collaborated with several water treatment partners who needed tighter batch-to-batch quality. They struggled with inconsistent floc performance when using low-purity alternatives. After fine-tuning dosages with our methyldiallylamine, they reported improved formation of larger particle aggregates and reduced sludge handling costs. For polymer synthesis, our customers cite reliable chain growth initiations, low incidence of fish eyes, and clean end product color—all proof that methyldiallylamine’s production quality flows straight through the value chain.

    Differences That Matter: How Quality Shows Up

    Some manufacturers push cost-cutting measures at the expense of chemistry, trimming corners on raw input control or skipping rigorous distillation. Here, we build quality through direct control of supply and process at every stage. We source precursor amines only from long-standing partner facilities with traceable records. Our synthesis lines use multi-stage glass-lined reactors, which cut down side-reactions and contamination from metal ions. Five-micron polishing filters ahead of final packaging trap any residues unnoticed by bulk detectors. Plus, our hands-on technical team tracks every batch using real-world application testing—not just paper specs.

    Methyldiallylamine is not a “universal solvent” or a generic feedstock. In use cases ranging from cationic monomers for acrylic polymerization to charge modification in latex manufacturing, trace organic impurities make all the difference. Inferior quality products, high in water or mineral content, leave end users with slower cure times, unpredictable polymer weights, or even regulatory compliance failures. By filtering and distilling each lot beyond market minimums, we offer a product that sidesteps the pain points downstream users face from supply houses and brokers. The assurance comes not just from a single test but a culture of relentless improvement and batch transparency.

    Advanced Specifications: What We Deliver, Every Drum

    As a chemistry-driven manufacturer, we never obscure the real details behind “spec conformance.” Methyldiallylamine from our site typically ships with purity greater than 99%, water content well under 0.2%, and stabilized to prevent premature polymerization in storage or transit. We hold color (APHA) values under 20, and we test for halide and residual acid contamination below limits of detection. Our QA teams repeatedly find that off-spec imports contain excess primary and tertiary amines, which disrupt polymer chain propagation and show up as end use inconsistencies. Clean, reliable amine input means fewer headaches, less costly downtime, and simpler regulatory compliance at our customers’ plants.

    We don’t approach process automation as a replacement for hands-on attention; it’s a supplement to our generations of experience with the chemistry. Every lot undergoes both classical wet-chemical analysis and modern analytical methods—GC-MS, Karl Fischer titration, and photometric checks—for a complete, transparent record. When customers share end-use data, our R&D group folds that feedback into ongoing process refinements, whether that means a tweak in distillation hold time or finetuning of antioxidant loads during final fill.

    Direct Experience: Running the Chemistry Ourselves

    In this industry, it takes years to sort out which details shape performance on the reactor floor. Many handling teams visiting our site remark on the absence of common aromatic contamination issues they see with competitors’ lots. Our plant implemented a closed-loop vent scrubber to limit external oxygen introduction, reducing color aging and acid formation in sensitive finished material. Regular upgrades to PTFE-lined gaskets and glass hardware slash contamination risk in the final product. We know every move matters—even down to storage humidity—since bench-scale neglect can build to ton-level headaches.

    Our technical support staff work with customers to assist with dimerization suppression and preference for consistent monomer reactivity. For those adapting to new monomer blends or resin specs, we’ve run pilot scale-up in our lab to confirm mixing protocols and provide on-the-ground suggestions. This “down to the reactor” support is only possible when we fully understand every nuance of the methyldiallylamine we produce.

    Practical Performance in Industry Applications

    In everyday use, methyldiallylamine finds favor in manufacturing cationic copolymers that serve as water clarifiers, textile enhancers, and paper dry strength agents. Companies working on emulsion polymerization, including specialty latex formulation, require methyldiallylamine that resists sticking or premature gelling at process temperatures. By tightening purification and quality checks, our drums let processors maintain consistent product viscosity, avoid stuck filters, and keep their lines moving.

    We’ve had direct calls from plant managers at paper mills frustrated by inconsistent dye uptake or breaks during slitting, sometimes traced back to off-spec amines. After switching to our methyldiallylamine, those problems subsided, and they saw tighter color control and smoother runnability. For producers focusing on ion-exchange resin production, the precise composition of our methyldiallylamine means fewer off-color beads and higher resin yields per batch. Our methyldiallylamine lets them avoid costly waste handling or batch failures.

    Distinct from Commodity Amines

    Methyldiallylamine’s properties diverge sharply from standard diallylamine or substituted aliphatic amines. The dual allyl structure offers reactivity unavailable with simple methylamines or diallylamines, particularly in copolymerization for charge density. Methyldiallylamine anchors more steadily into acrylamide copolymers and delivers greater thermal and hydrolytic stability in finished materials. In our years of pilot-scale work, we’ve watched diallylamine alternatives introduce side reactions that show up as haze, gel, or off-odors—issues resolved only through cleaner, more stable methyldiallylamine.

    Through systematic analysis, we see marked reduction in formation of unwanted byproducts and residue during free-radical polymerization. Users benefit from better yield and reduced post-polymerization cleanup. In ion-exchange resin synthesis, the cationic group density delivered by methyldiallylamine enables better pollutant or metal capture performance. Unmatched selectivity and lower fouling risk in resins come from precise manufacturing, not generic or re-bottled raw ingredient sources.

    Reliability that Passes End User Scrutiny

    We have fielded site visits and audits from some of the world’s most demanding multipurpose plants. Any inconsistencies—rotating workers, inconsistent summer heat, or overreliance on reprocessed lots—show up quickly under these lights. To satisfy the strictest auditors, we provide complete batch records and, where permitted, third-party retest results. Repeat orders from contract manufacturers and major water utilities demonstrate the value of precise, high-purity methyldiallylamine instead of less-controlled alternatives. Knowing our chemistry has stood up to these cross-checks drives us to keep improving every synthesis and QA cycle.

    Facing Industry Challenges Head-On

    Recent years have brought increasing scrutiny over impurities, environmental impact, and traceability in specialty amine production. Trace side-products such as N-methyl byproducts or residual volatiles can accumulate, leading to application end-use limitations or regulatory red flags. Unlike traders or brokers, we control the full lifespan of our methyldiallylamine, starting with the raw material validation and ending with secure storage and vendor-managed drum return. Reducing emissions from synthesis, minimizing reject volumes, and investing in closed-alloy transfer lines all supply environmental, operational, and regulatory benefits to our team and our customers.

    Environmental and workplace safety standards play a role daily. In past cycles, we adjusted reactor exhaust scrubbing to meet new VOC emission targets without sacrificing batch productivity. Our plant invested in worker health monitoring and spill response improvements ahead of regulatory deadlines, believing those changes would add to both worker trust and long-run productivity. The knock-on effect: customers can rely on high-integrity product and documentation, avoiding downstream snags over regulatory gaps and supporting their own quality certifications.

    Collaboration and Innovation from Factory to Laboratory

    Embedded innovation keeps our methyldiallylamine dependable. Many competitors only scale up to meet short-term demand surges, and in doing so can lose attention to process nuances that guarantee purity and reactivity. We invest in small-lot R&D for new application segments—whether for trialing innovative co-monomers, advancing ion-exchange bead formulation, or improving color stability for premium-grade flocculants. Consultations with research partners led to the addition of on-line FTIR monitoring in key reactors, which directly reduced off-spec formation. That spirit of adaptation runs throughout the line, ensuring batches delivered today are only the starting point for the next generation of functionalized polymers and resins.

    Industry standards do not stand still, and neither do we. Continuous consultation with downstream processors and feedstock partners tightens supply chain security, something no outside distributor can match. Feedback cycles move in both directions—what comes back from a customer’s application lab feeds directly into process control, batch validation priorities, and even drum fill sequence. That way, the methyldiallylamine we deliver each year embodies not just chemistry, but collaboration.

    Supporting the Next Generation of Applications

    Methyldiallylamine’s uses range ever wider, from traditional water treatment and resin manufacture to newer roles in advanced textiles, biological research, and industrial adhesives. We work directly with innovators at the bench, reviewing suggestions for new scavenger formulations and dipolymer blends. Each new request doubles as an opportunity to refine purification, test for finer separations, or develop custom stabilizer blends. Manufacturing here is more than routine chemistry—it is a constant commitment to support tomorrow’s technical benchmarks while solving today’s production puzzles.

    Where competitors may focus on the sales cycle, our loyalty lies in making sure that every lot of methyldiallylamine acts as engineered in our customers’ lines. For startups developing novel resins or water solutions, we offer flexible minimum order quantities, rapid pilot batches, and full technical documentation. The feedback we receive from these partners makes its way back to our formulations, and many of our largest application breakthroughs started with a small-lab inquiry.

    A Partner Beyond the Drum

    At the core, our customers value more than a drum of amine. They want to limit production delays, guarantee quality with each delivery, and cut costs linked to off-spec outputs or forced debottlenecking. Having built our process to these realities, we ensure prompt response and technical dialog whenever new requirements arise—whether it’s lowering the residual acid target, providing batch-specific performance certificates, or reviewing performance data from an on-site trial.

    Our performance as a manufacturer, measured over years not quarters, rests on the delivery of reliable methyldiallylamine—purity you can trace, reactivity you can predict, and support that extends long past the shipment date. For the factories, labs, and R&D groups trusting their production to our chemistry, we bring not just material but responsiveness built from decades in their shoes.