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Methyl Allyl Disulfide

    • Product Name Methyl Allyl Disulfide
    • Alias 3-(Methylthio)prop-1-ene
    • Einecs 221-277-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    574126

    Chemical Name Methyl Allyl Disulfide
    Molecular Formula C4H8S2
    Molecular Weight 120.24 g/mol
    Cas Number 2179-57-9
    Appearance Colorless to pale yellow liquid
    Odor Strong, garlic-like
    Boiling Point 146-148°C
    Density 1.03 g/cm³ at 25°C
    Refractive Index 1.530–1.535
    Solubility Insoluble in water, soluble in organic solvents
    Flash Point 38°C (closed cup)
    Vapor Pressure 2.56 mmHg at 25°C
    Pubchem Cid 13847
    Smiles CSSCC=C

    As an accredited Methyl Allyl Disulfide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Methyl Allyl Disulfide is supplied in a 100 mL amber glass bottle with a secure screw cap, labeled with hazard warnings.
    Shipping Methyl Allyl Disulfide should be shipped in tightly sealed containers, clearly labeled, and protected from heat, flames, and strong oxidizers. It must comply with transport regulations for hazardous chemicals, typically under UN 3334 (Aviation Regulated Liquid, N.O.S.), and handled by trained personnel, ensuring upright transport and secondary containment to prevent leaks or spills.
    Storage Methyl Allyl Disulfide should be stored in a tightly closed container, in a cool, dry, well-ventilated area away from sources of ignition and incompatible materials such as strong oxidizers. Keep the chemical out of direct sunlight and protect it from moisture. Use appropriate chemical-resistant containers and ensure proper labeling to prevent accidental misuse or exposure.
    Application of Methyl Allyl Disulfide

    Applications of Methyl Allyl Disulfide in Industrial Manufacturing

    As a direct manufacturer of methyl allyl disulfide, we supply this organosulfur compound for specific downstream industrial sectors where its functional properties meet stringent processing, compliance, and product performance requirements. Below, we outline the real-world applications where methyl allyl disulfide delivers clear benefits through proven production integration and alignment with internationally recognized industry protocols.

    1. Flavor and Fragrance Formulation

    Methyl allyl disulfide serves as a specialty top-note constituent in savory food flavor preparations and certain fragrance bases, leveraging its characteristic alliaceous aroma to replicate natural onion and garlic profiles in processed foods and aroma compositions. Producers in this domain select methyl allyl disulfide for its stability during heat processing, precise flavor reproducibility, and proven safety under food regulations.

    Industry compliance standards

    • FCC (Food Chemicals Codex)
    • IFRA (International Fragrance Association) Standards
    • EU Regulation (EC) No 1334/2008 on flavorings and certain food ingredients
    • US FDA 21 CFR Part 172 (Direct Food Additives Permitted in Food for Human Consumption)

    Typical usage ratio

    • 0.01–0.1% by weight in compounded flavors and aroma bases (final inclusion varies by intensity target, food matrix, and regional flavor preference regulations)

    Downstream process integration

    • Added during post-dilution flavor blending or at the final compounding stage in liquid flavor concentrate and essential oil mixes, ensuring uniform distribution and minimizing volatilization losses during subsequent food processing

    Final product types

    • Ready-to-eat snacks (onion, garlic, and savory profiles)
    • Instant soup seasonings and bouillon
    • Prepared ready-meal flavor packs
    • Savory sauce and condiment flavorings
    • Fragrance intermediates for perfumery incorporating green, sulphuric top-notes

    2. Agrochemical Intermediates

    Methyl allyl disulfide acts as a sulfur donor in the synthesis of certain eco-friendly crop protection actives and soil fumigants, chosen for its reactivity in alkylation and sulfidation reactions critical to modern, targeted agrochemical molecule manufacturing. Its manageable volatility and established toxicological studies allow for compliance within regulated synthetic routes.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006
    • ISO 9001:2015 Quality Management for pesticide active ingredient intermediates
    • OECD Guidelines for the Testing of Chemicals (Agrochemical Synthesis)

    Typical usage ratio

    • 0.5–5% as process reagent by weight in multi-step syntheses (exact ratio governed by target molecule, required sulfur incorporation, and in-process yield monitoring)

    Downstream process integration

    • Charged into the reaction vessel after pre-neutralization of base reagents, serving as the sulfur source during controlled synthesis of sulfur-containing intermediates or finished crop protection active ingredients before isolation and downstream formulation

    Final product types

    • Soil fumigants
    • Sulfur-based nematicides
    • Organosulfur herbicide and fungicide actives

    3. Rubber and Polymer Vulcanization Accelerators

    Methyl allyl disulfide functions as a processing aid in the manufacture of rubber vulcanization accelerators where its dual allyl and disulfide moieties participate in cross-linking reactions, optimizing cure rate and mechanical resilience of finished elastomers. This application is well-established in both automotive and industrial polymer component production.

    Industry compliance standards

    • ISO 9001:2015 for rubber chemicals and auxiliary materials
    • EU REACH registration for substances in manufacturing and article supply
    • ASTM D2000 (Classification System for Rubber Products in Automotive Applications)
    • RoHS Directive (2011/65/EU): Restriction of Hazardous Substances

    Typical usage ratio

    • 0.2–1.5% by weight in vulcanization accelerator compound blends (dosage adjusted for targeted hardness, elasticity, and processing time required for each polymer batch type and end-product technical specification)

    Downstream process integration

    • Introduced during the compounding phase of rubber mixing, before addition of sulfur donors and activators, to ensure homogeneous reaction during subsequent high-temperature vulcanization cycles

    Final product types

    • Tire treads and sidewalls
    • Industrial conveyor belts
    • Molded automotive seals and gaskets
    • Flexible hoses and tubing subject to dynamic fatigue

    4. Specialty Sulfur-Based Corrosion Inhibitors for Metalworking

    Industrial lubricant and metalworking fluid producers incorporate methyl allyl disulfide as a reactive sulfur additive to enhance boundary lubrication and inhibit oxidation on ferrous and non-ferrous metal surfaces under high-load, high-shear machining operations. Its distinct sulfur chemistry supports formation of a protective film during severe service.

    Industry compliance standards

    • ISO 6743-13:2002 (Classification of Lubricants, Industrial Oils and Related Products)
    • ANSI/ASTM D130 (Detection of Copper Corrosion from Petroleum Products)
    • ECHA (European Chemicals Agency) regulatory assessment for metalworking additives

    Typical usage ratio

    • 0.15–1.0% by weight in formulated metalworking fluids, with precise concentration dependent on base oil viscosity, application temperature, and required load-carrying performance

    Downstream process integration

    • Blended directly into concentrated lubricant additive packages before dilution into bulk base oil and final QC, guaranteeing consistent integration in high-performance cutting, grinding, or forming lubricants

    Final product types

    • High-pressure cutting fluids
    • Heavy-duty forming and stamping lubricants
    • Corrosion-inhibiting hydraulic oils
    • Anti-wear additive systems for industrial gear oils

    5. Pharmaceutical Intermediate Synthesis (API Precursors)

    Methyl allyl disulfide finds controlled use in advanced synthetic pathways for pharmacologically active substance intermediates, especially where sulfur linkages are required for bioisostere or pro-drug formation in small-molecule API manufacturing. GMP-grade processing ensures traceability, residual control, and regulatory compliance in this critical application area.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice for Active Pharmaceutical Ingredients
    • US FDA 21 CFR Part 210/211 (Current Good Manufacturing Practice for Finished Pharmaceuticals)
    • European Pharmacopoeia (Ph. Eur) monographs for API intermediates
    • ISO 9001:2015 and ISO 14001:2015 Integrated Management

    Typical usage ratio

    • 0.02–0.2 molar equivalents in multi-step synthetic routes, adjusted according to precursor loading, yield tables, and stoichiometry control for efficient sulfur incorporation

    Downstream process integration

    • Applied at designated intermediate steps during batch or continuous synthesis, commonly following first-stage condensation or alkylation, under strictly monitored conditions per validated process protocol

    Final product types

    • Sulfur-containing drug intermediate compounds
    • API precursors for cardiovascular, anti-infective, and metabolic disorder therapies
    • Pro-drug delivery molecules requiring sulfur bridges
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    Certification & Compliance
    More Introduction

    Methyl Allyl Disulfide: Reliability Through Experience in Chemical Manufacturing

    Our Experience with Methyl Allyl Disulfide

    Staying close to our processes for decades, we have seen a lot of demand shifts in the global fine chemicals market. Among various sulfur compounds, Methyl Allyl Disulfide has earned distinct attention within the sectors that rely on highly selective and consistent sulfur-based intermediates. Unlike some specialty chemicals that come and go on hype alone, this material’s value has shown staying power, particularly where reliability, safety, and precise reactivity matter most. We know from years of hands-on synthesis, purification, packing, and shipping, that every small inconsistency ripples out to end-users and their operations. We learned which models deliver fewer off-odors, dodge dangerous byproduct formation, hold up in storage, and behave the way customers need at scale.

    Model, Appearance, and Chemistry

    The Methyl Allyl Disulfide leaving our reactors presents itself as a colorless to pale yellow liquid. This outcome comes from carefully managing reaction conditions using proven protocols that reduce tars and make for easier downstream purification. Unlike related sulfur analogs, such as diallyl disulfide or methyl mercaptan derivatives, Methyl Allyl Disulfide carries both the methyl and allyl groups on the same sulfur backbone. This distinctive structure delivers a balance between volatility, reactivity, and solubility properties. We pinpoint the boiling range value through repeated batch analysis, and every lot matches what formulators ask for in their application. Over time, we learned that even slight variations in boiling point can signal mix-ups or impurities, so we never guess here.

    Production Focus: Batch Controls and Purity

    Customers expect certain things from a sulfur compound: stability in the bottle, manageable odor, and consistent physical properties. Our team focuses on three areas: raw material screening, temperature control, and the collection cut. Every charge of allyl chloride and methyl mercaptan gets full tracking. Temperature swings at the reactor wall are kept in a tight window. Collection uses fractionation and detailed gas analysis, so side-products like methyl mercaptan or allyl polysulfides don’t slip through. These methods didn’t just fall into place; we reached them through noisy plant trials, late-night troubleshooting, and plenty of feedback from end users. In each step, small changes turned out to make big differences in plant safety and yield, which became habits not shortcuts.

    Comparing to Other Sulfur Compounds

    Looking out at the crowded shelf of organosulfur molecules, the unique properties of Methyl Allyl Disulfide become clear. Compared to diallyl disulfide, Methyl Allyl Disulfide has a distinct profile with a single methyl and allyl group. This difference matters for flavor and aroma producers because methyl introduces sweeter, rounder top notes, while the allyl group gives sharper, spicy undertones. In pesticide and flavor formulation, who wants an overpowering onion note when what customers want is a milder, less intrusive sulfur aroma? Over several seasons working with clients in Asia and North America, product consistency gets noticed. Other sources add methyl allyl trisulfide or diallyl sulfide, which can bring extra regulatory headaches and off-odors that sink a batch. We stuck with refining pure Methyl Allyl Disulfide because it hits the sweet spot for those needing just the right punch of sulfur, without overwhelming formulations or processes down the line.

    Specification Matters: Not All Methyl Allyl Disulfide Is Created Equal

    The main things that separate high-quality Methyl Allyl Disulfide from the average are purity, odor profile, and chemical stability. Over several years of pilot trials and bulk shipments, we tracked customer feedback and lab results. Our material consistently lands above 98% purity by GC, which matters for anyone making flavors, fragrances, pesticidal actives, or pharmaceuticals. Impurities like methyl allyl trisulfide or allyl mercaptan lead to unpredictable reactions or lingering odors; the market’s top brands reject lots with those signatures. We spend extra time scrubbing thiols and closely watching reflux temperatures. These controls make our product easier for clients to use safely, and they keep it within expected bounds in later blending or synthetic steps. Others have tried shortcuts, but the difference in use always comes out when a client tests a fresh batch.

    Expanded Applications Supported by Direct Feedback

    We first began producing Methyl Allyl Disulfide for use in flavors and aroma chemicals. Customers looking to capture the spicy-sweet nuances of onion and garlic without aggressive side notes picked up on its versatility. Over time, newer applications arrived: crop protection, sulfide-based crosslinking, and even polymer modification. Each sector requires its own approach to consistency and documentation. In crop protection, the difference between a clean, single-peak GC trace and one cluttered with co-eluting byproducts often decides which manufacturer gets repeat orders. In food grade, clients need assurance their final product will clear regulatory hurdles and pass batch panel tests. All this hard-earned trust reflects a simple fact: generic, trader-supplied material rarely satisfies the most demanding specs. We measure batch performance by more than internal lab numbers; we listen when a client calls to flag unexpected issues or raises a compliance question.

    Ensuring Consistency Through Direct Oversight

    Consistent physical handling pays off. Temperature swings during storage or haulage have a habit of shifting the material’s sulfur content and color. Getting burned by an accidental shipment exposed to sunlight or an overheated tank taught our team the hard way how important it is to own the process from start to finish. Decades ago, trucking firms treated sulfur compounds as just another flammable load. After a few rejected loads due to odor complaints or darkening, our plant invested in double-walled, temperature-controlled containers. Every container gets sampled both at loading and offloading. By shielding batches from temperature abuse and limiting headspace, we consistently hit the promised color and avoid “sour” smells only discovered during blending.

    Worker Health and Safe Handling

    Plants, logistics partners, and formulation teams worry about exposure, and rightly so. Years of plant trials and close calls led us to adopt strict handling protocols. We seal all transfer lines, use gloveboxes for sampling, and treat vapor emissions with activated carbon units. The routine training gets repeated every quarter — we’ve learned that even seasoned operators benefit from reminders and drills, especially given the low threshold of odor detection and the acute effects of some sulfur gases. Respirators, suits, and containment barriers are not optional. These day-to-day actions go further than just chasing certifications. The feedback loop from plant floor incidents and near-misses shapes how we design new transfer stations, storage systems, and shipping protocols. Direct experience outpaces paperwork any day when it comes to safety with these materials.

    Quality Control Earned Over the Years

    In the early years, the temptation to outsource GC testing or skip property checks seemed attractive. Shortcuts only led to headache. Anomalies, leaks, and unpredictable reactivity came back at every supply chain node, eroding trust and business relationships. By installing in-line monitoring, investing in multiple backup GC-FID machines, and keeping a backup analyst team, we keep every batch traceable. This investment in redundant testing pays back ten-fold through lower complaint rates, fewer drums returned for “off” smell, and more predictable regent performance in downstream reactions. We don’t cut corners, and we chose this route because the alternative — disappointed customers and wasted lots — costs far more.

    Storage Lessons Learned

    We learned the hard way about oxygen and sunlight exposure. A few years back, a batch stored in a translucent tank picked up slight yellowing within weeks. UV and trace air infiltrating the tank spiked impurity levels, with enough color and odor change to force a recall. Now, all bulk product gets housed in inert-gas-blanketed vessels, painted in light-blocking coatings, away from direct sunlight and heat sources. Inventory now gets rotated tightly. We advise customers to keep storage temperatures stable and to avoid plastic drums for lengthy holding, as minor diffusion and reactivity with some polymer liners cannot be ignored. This approach cuts down on oxidative degradation and guarantees product shipped out matches samples sent for trial.

    Batch Record Transparency and Customer Trust

    People want to know what they’re buying, where it came from, and how it was made. We keep digital and physical batch books with every critical variable — input lots, reaction temps, yields, and QC values. Customers often ask for Certificates of Analysis and supporting chromatograms. Detailed, truthful batch records build trust, because buyers know they can match what shows up at their plant or lab with what we’ve documented in-house. Audits and spot checks show that direct producers, not middlemen, are most prepared to back up their spec sheets with real evidence.

    End-User Education and Technical Support

    Direct communication with end-users helps head off many common mistakes. Sometimes a client reports haze or phase separation, only to learn it traces back to improper blending order or storage outside ideal ranges. Our tech support team draws from actual production incidents and case studies, making troubleshooting real, not theoretical. We’ve found that demonstrating correct transfer, dosing, and mixing practices makes troubleshooting about facts, not guesswork. Frequent factory visits and remote video intros boost user confidence and shrink waste on both sides. The best feedback comes not from perfect paperwork, but from hearing someone at our customer’s plant echo, “this batch works like the last one.”

    Meeting Regulatory Demands Without Guesswork

    No one likes unpleasant surprises from inspectors or trade partners. Keeping a robust compliance file on every batch, with process and purity documentation, avoids regulatory headaches in both domestic and export markets. We monitor the changing landscape around sulfur compounds in food, flavor, chemical intermediate, and pesticide laws, so batches never set off red flags at border controls or downstream audits. The volume of experience our compliance team holds heads off costly delays, especially when export codes shift or paperwork rules tighten. Fear of “unapproved” compounds or mislabeling never slows release schedules, because direct, transparent supply chains give full visibility from lab bench to final application.

    Distinctiveness in Applications: Why Methyl Allyl Disulfide Succeeds

    In practice, Methyl Allyl Disulfide delivers several advantages over similar sulfur chemicals. Its balanced volatility and characterful, well-rounded aroma work well in both food and technical products requiring moderate sulfur notes. In agricultural applications, its unique chemistry gives enough effectiveness without the severe phytotoxicity some diallyl or dimethyl analogues create. Batch-to-batch stability matters here, especially when thousands of liters reach field mixers. On the performance side, its stable shelf life and controlled reactivity let formulators fine-tune release and interaction with other actives. No one frustrates faster than a compounder faced with fluctuating material specs; our direct manufacturing keeps these headaches at bay, so teams get what they expect. Fluctuating quality leads to missed production windows or costly finished product recalls; refined process control is the better answer.

    Scaling Up Without Cutting Corners

    It’s tempting on big orders to push production equipment or “blend up” off-grade material to fill a gap. Years of customer visits and dispute resolution proved to us that each shortcut only trades today’s win for tomorrow’s loss. We’ve grown into larger reactors and expanded batch lines, but never at the expense of purity or traceability. Our plant teams treat each lot like the small batches that built our reputation, holding to the same standards no matter how many tons ship. This way, no client has to worry about shifts in odor, color, or purity just because their order size changed. Real capacity comes from discipline, not from lowering standards.

    Collaborating on New Uses and Formulations

    Formulation scientists often look for subtle differences that open up new applications. Some seek a sulfur donor for controlled polymer cross-linking. Others want to recreate nuanced aroma profiles in prepared foods, where a blunt “onion” note just won’t work. We regularly share samples and application trial results, pooling knowledge from both sides of the industry fence. End-users highlight new requirements, such as reduced levels of certain trace markers or compliance with evolving flavor safety lists. By opening our labs and sharing direct technical experiences, we help reduce the “trial and error” cycle that frustrates research teams faced with ever-tighter regulatory and sensory targets.

    Respecting Sustainability Without Compromising Safety

    Across the chemical sector, sustainability has shifted from buzzword to operational need. We reduced waste by improving fractionation steps, recycling solvents, and converting byproduct streams into useful feedstocks for other plants. Our approach to solvent and energy conservation answered not to slogans, but to lower bills, lower emissions, and safer plant operations. For Methyl Allyl Disulfide, efforts to reclaim spent reaction media and reduce offgas have cut both costs and neighborhood complaints. Balancing production growth, worker safety, and community impact keeps long-term customers coming back, confident we see the shared future of the supply chain as clearly as the day-to-day output metrics.

    Future Directions: Improvements and Opportunities

    No plant or material is perfect, and we haven’t reached the last word on Methyl Allyl Disulfide. We keep an open door to upstream raw material innovations, greener catalysts, further odor masking, and smarter process automations. Each improvement follows the old rule: don’t change what works unless you can demonstrate real benefit, with all risks measured and managed. Our plant teams retry purification approaches yearly, seeking ways to cut energy and reagent footprints while pulling out “odd” note-forming impurities even further. Hands-on feedback from partners and their R&D teams helps set clear priorities, rooted in practical use not just pilot-plant wishlists.

    Summary: What Sets Our Methyl Allyl Disulfide Apart

    Customers return to direct manufacturers for a reason: experience, reliability, personal attention, and no room for guessing. Our Methyl Allyl Disulfide stands on a legacy of plant trials, customer feedback, unvarnished record keeping, and continuous improvements. Compared to mass-traded commodity grades, we offer tailored support, batch-to-batch reliability, and a willingness to deal openly with challenges as they arise. We see every client as a partner, not a transaction, and we put as much pride in safe handling and compliance as in the chemistry itself. Those in food, fine chemical, agricultural, or manufacturing spaces looking for a trusted sulfur ingredient find what they need here — not by accident, but from years of getting it right and learning quickly from the things that can go wrong.