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HS Code |
708836 |
| Chemical Name | Methyl 4-tert-butylbenzoate |
| Cas Number | 26537-19-9 |
| Molecular Formula | C12H16O2 |
| Molecular Weight | 192.25 |
| Appearance | Colorless to pale yellow liquid |
| Boiling Point | 269-271°C |
| Melting Point | 15-17°C |
| Density | 1.017 g/cm3 |
| Solubility | Insoluble in water, soluble in organic solvents |
| Purity | Typically ≥98% |
| Refractive Index | 1.507-1.509 |
| Flash Point | 120°C |
| Smiles | CC(C)(C)C1=CC=C(C=C1)C(=O)OC |
As an accredited Methyl 4-Tert-Butylbenzoate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | A 100g amber glass bottle labeled “Methyl 4-tert-Butylbenzoate,” features hazard symbols, lot number, and tightly sealed cap. |
| Shipping | Methyl 4-Tert-Butylbenzoate is shipped in tightly sealed containers, protected from moisture and extreme temperatures. The chemical is classified as non-hazardous for transport, but packaging must comply with relevant regulations. Proper labeling and documentation are required to ensure safe and compliant transit. Store in a cool, dry place away from incompatible substances. |
| Storage | Methyl 4-tert-butylbenzoate should be stored in a tightly closed container in a cool, dry, and well-ventilated area, away from sources of ignition and incompatible materials such as strong oxidizing agents. Protect from moisture and direct sunlight. Ensure storage area is clearly labeled and complies with chemical safety regulations. Store at room temperature and avoid excessive heat for optimal stability. |
Applications of Methyl 4-Tert-Butylbenzoate in Industrial ManufacturingMethyl 4-Tert-Butylbenzoate serves as a functional intermediate and modifier within several high-value chemical production chains. The following sections detail its specialized uses across key downstream sectors, with focus on regulatory compliance, formulation practices, workflow integration, and the real finished goods produced by leading manufacturers. 1. Synthesis of UV Absorbers for Polymer AdditivesMany polymer compounders and masterbatch producers rely on this material as an intermediate for high-performance benzotriazole UV absorbers, such as UV-320. These absorbers protect plastics from photodegradation during outdoor service and processing. Producers introduce the methyl ester during the condensation reaction stage, leveraging its stability and controlled reactivity compared to free acid analogues. The integration directly impacts migration stability and color retention in polyolefins, ABS, and PVC products, where consistent additive bonding is critical for product lifetime and regulatory acceptance. Industry compliance standards
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2. Raw Material for Sartan Antihypertensive API SynthesisPharmaceutical manufacturers employ Methyl 4-Tert-Butylbenzoate at multi-kilogram scale for preparing key intermediates in the synthesis of sartan class antihypertensive drugs, notably in schemes for candesartan cilexetil and olmesartan. In these routes, the methyl ester enables selective alkylation before conversion to the acid group during later process stages, supporting purity and yield control across GMP lines. Developers favor this route for its lower by-product formation and compatibility with validated solvent recovery practices, essential for cost-efficient, pharma-grade manufacture. Industry compliance standards
Typical usage ratio
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3. Intermediate for Fragrance Ingredient SynthesisFlavor & fragrance houses use this material to build complex aroma molecules, notably by introducing the tert-butylbenzoate moiety in musk and floral-type fragrances. The ester’s steric hindrance slows undesired side reactions, permitting higher selectivity in Friedel–Crafts acylation and aldehyde coupling. This enhances end-user consistency in perfume bases, household cleaning scents, and functional aroma chemicals, especially where IFRA-compliant safety and purity are mandated. Industry compliance standards
Typical usage ratio
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4. Building Block in Liquid Crystal Monomer SynthesisDisplay materials producers incorporate this raw material during the preparation of specific liquid crystal monomers and oligomers. The methyl ester’s electronic profile enables it to participate in controlled esterification and subsequent etherification, critical for property tuning in LC mixtures for TFT display panels. Strict process management during monomer synthesis ensures target birefringence and viscosity parameters, which downstream device assemblers rely on for display response and long-term stability in consumer electronics and industrial imaging systems. Industry compliance standards
Typical usage ratio
Downstream process integration
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Producing specialty aromatic esters for decades, practical knowledge continues to lead the way in our facility. Every drum of Methyl 4-Tert-Butylbenzoate reflects careful control from raw material selection to the final tightening of the seal. Through repeated batches and close interaction with plant floor processes, it’s clear that consistency and impurity management matter more than what can be captured by certificate lines alone. Transparency also arises from daily handling, actual feedback from industrial customers, and the evolving realities of usage demands. End users trust stable sources, not just because of technical data, but because of the reliability formed from years of getting it right.
Our current specification centers on 99% minimum purity Methyl 4-Tert-Butylbenzoate, tested every day through gas chromatography right at the production site. Moisture content is typically maintained below 0.2%, measured with Karl Fischer titration, so operators on the synthesis and distillation lines monitor solvent drying and storage meticulously. Color specifications remain tight—APHA values rarely stray above 20—since an off-color ester signals problems upstream.
From experience, it is not just about ticking boxes on a spec sheet. One lot sent to a coatings manufacturer years ago taught us the visual impact impurities can have on a final varnish. Slight isomer drift or oxidation in storage causes yellowing, which leads to waste, customer complaints, and production downtime. Reinforcing storage practices and carefully checking tank linings for corrosion have prevented another recurrence. This is one reason why every batch today sees full retention samples for a year and a “second look” by different staff before final sign-off.
Unlike trading sources who buy and relabel, manufacturing involves actual equipment, people, and quite a lot of moving parts. Reactor fouling from trace iron, slight variations in catalyst addition, and subtle shifts in distillation pressure have shown us the limits of automation and the continued importance of skilled operators. One winter, a switch in utility steam pressure changed product purity rates; nobody would have caught it with spreadsheet tracking alone, but old-fashioned vigilance in the control room saved a week’s run. Thus, every parameter—catalyst use, solvent recovery, packaging—emerges from not just design but persistent operational review.
Aromatic esters cover a range of chemical needs, but working with formulators in adhesives, coatings, and plasticizer manufacture, the particular performance of Methyl 4-Tert-Butylbenzoate stands apart. The material offers a unique balance between benzoic core rigidity and the bulky tert-butyl group, which manages both polarity and solubility in organic systems. This dual function converts to actual improvements—clients in UV-cured systems report faster curing rates and better flexibility in product films when using our ester versus lower-purity or alternate isomer mixes from past suppliers.
Long-term partnerships with ink formulators have revealed another advantage: reduced odor contamination and superior compatibility with aggressive monomer matrices, especially in high-solids systems. Some competitors’ batches carry subtle phenol residues or other esterification byproducts due to less precise temperature management or raw material grades. Our synthesis routes, seasoned through years of scale-up and feedback from batch to batch, allow downstream users to skip additional purification steps or expensive blending additives.
Isomer contamination—an increasingly common concern over the past several years due to new, less-experienced entrants—remains low in our batches due to a synthesis route rooted in refined Friedel-Crafts chemistry and modern monitoring tools. Several customers have shared issues with older products leading to gelling, haze, or lower shelf life when using non-selective sources; our materials, by contrast, have shown no such issues in independent application testing and in direct line runs at customer plants for making synthetic lubricants and polymer intermediates.
Supplying not just to domestic plants but to integrators across international markets, feedback arrives from finishers, mixers, and technical directors building real end-use products, not just laboratory tests. One customer in the flexible packaging business described how batch-to-batch odor variation led to spoiled inventory; another in specialty thermoplastics noted an unexpected rise in melt viscosity when using lower-purity Methyl 4-Tert-Butylbenzoate from a distributor. We trace these issues back to uncontrolled side-reactions and contamination from competing or outdated synthesis methods. Through their reports, it becomes clear that robust purification and freshness matter all the way to the final product line.
Regular site visits, joint troubleshooting, and even crisis intervention—like identifying off-gassing during a holiday production round—have led to direct improvements in our anti-oxidant handling steps and packaging upgrades. Customers have requested drum liner changes after tiny traces of oxidized material made their way into sensitive applications. We responded by moving to nitrogen-purged filling and closer inspection controls, a step that has cut off-odor complaints in half over the past two years.
Producing and packaging methyl 4-tert-butylbenzoate on a ton scale, safety comes not only from paperwork but from firm, established routines. Local teams understand the risk points: ester vapors staying low to the ground, the need for grounding during drum filling, and particular caution during loading operations in humid weather. Over the last five years, we redesigned the loading arms after a spill incident highlighted splash-back potential. These small but important upgrades come from dialogue between operators and technical leads, shaped by hands-on experience, not policy memos.
Some buyers may underestimate the compound’s hidden volatility or lightly treat personal protective equipment standards in storage environments. On-site, it became obvious that open drums in storage increase hydrolysis, and careful capping reduces contamination and product loss. This may not appear in a distributor’s spec sheet, but daily interaction teaches which drums deserve double-checking and which procedures raise consistent results.
Having watched both small and industrial customers integrate methyl 4-tert-butylbenzoate into varied processes, unique performance trends have become familiar. In UV-curable coatings, the compound supports thin-film leveling and accelerates hardening without introducing the excessive yellowing seen with comparable esters. In pressure-sensitive adhesives, manufacturers describe smoother mixing and higher clarity in finished rolls, made possible by the balance of the alkyl substitution and benzoate structure.
Compared to similar esters like methyl benzoate or methyl p-tert-butylbenzoate variants, the tert-butyl benzoate shows markedly improved thermal stability in end-use plastics, especially during extrusion at higher temperatures. Our customers running continuous lines see less breakdown and fewer issues with discoloration. Feedback also indicates less migration in adhesive layers, a must for food packaging or medical applications, and a benefit that ties directly to the manufacturing discipline behind the material.
In fragrance and flavor intermediate applications, the clean, slightly floral base note allows for direct blending without the masking step sometimes needed with other aromatic esters. Several perfumery clients have extended their product suite based on this characteristic, reflecting real-world utility that library data rarely foresaw.
Chemical supply chains feel every shockwave, from international logistics to seasonal labor swings. As a primary producer, the value of on-site storage, direct tanker loading, and reliable shipping partners is never theoretical. Several industries rely on this availability—paint plants running just-in-time batches can’t wait three weeks for a missing drum, nor can a plastics molder afford delays in stabilizer supply.
During a recent regional power outage, only plants with secure, advance-stocked deliveries could keep working. Our standing agreements with carriers, vast inventory at both plant and dedicated warehouse sites, and experience in pre-clearance for port movements kept supply steady. As costs fluctuate and new regulations arise, the value of a maker who actually understands the bottlenecks comes clear.
People looking at item listings might wonder why slight price differences show up from different sources. As a company that both manufactures and ships, not just resells, our costs go into not only raw materials and labor but also investment in closed-system storage, real-time analysis, and fumigation controls that traders rarely see. Customers who switch from resellers to factory supply commonly report drops in failed batches, fewer incident investigations, and increased on-time delivery.
Questions from industrial users often reflect deep technical curiosity: “Where was this material last distilled?” “How long does it sit before shipment?” “What's the track record for reactivity in highly pigmented blends?” Only a manufacturer with control over each step can answer with the granular information that a formulator or plant manager requires, and only years of hands-on work can surface the subtle process tweaks that keep product lines running efficiently and safely.
Recent years have brought rising requirements around traceability and environmental stewardship. Our site’s investment in full-barcode batch tracing allows any user—even years after a drum ships—to verify lineage back to the original synthesis. Where environmental compliance now polls higher in end-user priority lists, solvent recovery systems and emissions scrubbers, installed and maintained at our facility, match or exceed mandated thresholds. These upgrades did not happen in a vacuum—they respond to client audits, new market access demands, and shared responsibility for sustainable operations.
Shifts in regulatory frameworks—TDS submission requirements, RoHS and REACH compliance—require detailed documentation. Instead of scrambling for paperwork, long-term record keeping and operational discipline ensure that compliance checks rarely disrupt deliveries. Our specialty teams respond daily to requests for updated certificates and registration data, all backed by in-house laboratories whose performance is checked routinely by outside auditors.
Steady manufacturing is never static. From introducing energy-efficient pumps to gradual solvent changes prompted by customer feedback, adjustments shape every incoming and outgoing lot. One transition—from older glass-lined vessels to stainless—drove down the background contamination levels, cutting end-user filtration needs and reducing off-spec returns. Suggestions from technical managers at customer facilities led us to add new sampling ports, so they could check purity before accepting bulk deliveries, improving their own process efficiency.
These tweaks, documented across facility shift logs and confirmed by customer test records, prove that the most effective improvements respond to hands-on, real-world feedback. Regular reviews and upgrades, shaped by more than opinions, define a product line that adapts as markets and technologies grow.
Unlike those who simply match buyers with stock, our connection to product outcomes comes back often in technical support requests, troubleshooting calls, and even on-site interventions. Several cases mark the difference: a batch for a Japanese adhesive producer needed tighter moisture control, so the plant switched to double-vacuum drying. For a European electronics compounder, we transitioned to specialized low-extract packaging to cut ion migration.
The feedback loop is direct. Regular discussions with practitioners—factory chemists, operations supervisors, supply chain leads—mean customers see the entire train from their loading dock to our reactor, a level of insight that only manufacturers with open books and physical accountability can provide.
It’s easy to group all sources of Methyl 4-Tert-Butylbenzoate together, but years of handling, packaging, logistics, and complaint resolution show how small differences compound into usable, reliable product. There are always cheaper and quicker options, but when raw material inconsistencies, delivery problems, or regulatory shortfalls strike, the manufacturing partner with actual production, real records, and the capacity to solve problems keeps customer processes open and on track.
Practical experience overcomes data-sheet claims; plant-scale production brings a level of assurance, clarity, and traceability that buyers remember in each successful batch.
Interest in higher-specification esters, lower VOC generations, and advanced packaging grows every year. As downstream users demand more transparency, flexibility, and issue resolution, established manufacturers like us—invested in each step from raw input to shrinking the last drum lid—set the pace. The aim stays consistent: deliver a product with reliability built in, a supply chain that answers for its performance, and a technical support structure that sees the world through the eyes of the users actually building finished goods.
Chemical supply and manufacturing face new challenges every year, but every customer challenge, audit, or improvement request becomes an opportunity for deeper insight and practical progress. Our steady production of Methyl 4-Tert-Butylbenzoate represents not just a set of data points, but a reflection of real work, shared success, and a long-term commitment to industry.