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Metam Sodium

    • Product Name Metam Sodium
    • Alias Methyldithiocarbamate
    • Einecs 220-892-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    826588

    Chemical Name Metam Sodium
    Common Names Sodium methyldithiocarbamate
    Chemical Formula C2H4NNaS2
    Molecular Weight 129.18 g/mol
    Appearance Yellow to brown liquid
    Odor Pungent, sulfur-like
    Solubility In Water Highly soluble
    Boiling Point Decomposes before boiling
    Density 1.17 g/cm³ (at 20°C)
    Ph 11-12 (1% solution)
    Cas Number 137-42-8
    Use Soil fumigant and pesticide

    As an accredited Metam Sodium factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The Metam Sodium packaging is a sturdy 20-liter yellow plastic drum with hazard symbols, secure screw-top lid, and clear labeling.
    Shipping Metam Sodium is shipped as a liquid in specially designed, tightly sealed containers to prevent leaks and exposure. It requires labeling as a hazardous material, with transportation regulated by DOT guidelines. Proper ventilation and protective measures are essential due to its toxicity and potential to release toxic gases upon contact with water.
    Storage Metam Sodium should be stored in a cool, dry, well-ventilated area away from sunlight, heat sources, and incompatible materials such as acids and oxidizers. Keep the container tightly closed and clearly labeled. Store away from food, feed, and water sources. Use only corrosion-resistant containers with secondary containment to prevent leaks or spills, and restrict access to authorized personnel only.
    Application of Metam Sodium

    Applications of Metam Sodium in Industrial Manufacturing

    As a manufacturer of Metam Sodium, we supply this key chemical intermediate to multiple specialized industrial sectors. Below, we detail major downstream scenarios, including regulatory frameworks, process specifics, usage ratios, integration stages, and finished goods from each value chain.

    1. Soil Fumigation for Intensive Agriculture

    Commercial growers in fruit, vegetable, ornamental, and nursery crop production adopt Metam Sodium for in-soil treatment to control soil-borne pests, nematodes, pathogenic fungi, and weed seeds. The compound is applied pre-planting as a liquid drench or shank injection, allowing growers to prepare high-value agricultural land for disease-free cultivation, thereby supporting tight planting cycles for crops with intensive rotations.

    Industry compliance standards

    • USEPA FIFRA Registered for soil fumigation (21 CFR 180.364 in the US)
    • EU Regulation (EC) No. 1107/2009 – Approval for plant protection products
    • Relevant Codex Alimentarius MRLs (Maximum Residue Limits)
    • Local environmental and worker safety guidelines (e.g., OSHA, REACH Annex XVII)

    Typical usage ratio

    • Applied at 300–600 liters per hectare (active ingredient basis)
    • Adjusted according to soil type, pest spectrum, target crop, and local regulations
    • Lower rates for lighter soils or short rotation crops; higher rates for perennials or high-pressure zones

    Downstream process integration

    • Injected or drenched into prepared soil beds using specialized fumigation rigs before planting
    • Soil sealed by tarp or irrigation, followed by mandatory re-entry interval as per local authority
    • Clearance validated by soil residue monitoring and quality assurance sampling

    Final product types

    • Table grapes, berries, tomatoes, melons, leafy greens, floriculture nursery stock, and turfgrass sod

    2. Tobacco Plantation Disease Management

    Large-scale tobacco growers use Metam Sodium formulations for pre-plant soil disinfection to suppress black shank (Phytophthora parasitica), root knot nematodes, and related pathogens. The compound is integrated into tobacco seedbed preparation via controlled injection techniques, supporting healthy seedling transplant and processed leaf quality compliance for international trade and manufacturing of smoking and chewing products.

    Industry compliance standards

    • Guidelines from the International Tobacco Growers’ Association (ITGA)
    • Compliance with WHO Framework Convention on Tobacco Control (FCTC) pesticide provisions
    • National Pesticide Safety and Use Norms (e.g., China GB2763 residue limits)
    • Strict adherence to tobacco product residue protocols (CORESTA Guides No. 40, No. 50)

    Typical usage ratio

    • 200–400 liters per hectare in pre-plant soil application
    • Rates adjusted in relation to pathogen pressure, seedbed size, and local regulatory restrictions
    • Rotation with alternative fumigants as part of integrated pest management

    Downstream process integration

    • Liquid or drench injection in seedbeds several weeks before transplanting tobacco seedlings
    • Compliance sampling carried out prior to field planting
    • Integrated residue analysis in pre-harvest monitoring

    Final product types

    • Flue-cured and burley tobacco leaf, cigarette and cigar blends, pipe tobacco, chewing tobacco

    3. Mushroom Substrate Pasteurization

    Industrial mushroom farms incorporate Metam Sodium into their substrate pasteurization protocols, particularly for Agaricus bisporus and specialty mushroom production. The product is introduced into compost or casing soils to mitigate competing fungal contaminants and nematodes. This practice enables scale production under standardized, high-yield composting systems required for fresh and processed mushroom supply chains.

    Industry compliance standards

    • GlobalG.A.P. Compound Input Protocols
    • EU Hygiene Standard Regulation (EC) No 852/2004 for food substrates
    • US FDA inspection guidelines on input quality (21 CFR 110.80)
    • Sanitary compliance for fresh food handling as per ISO 22000

    Typical usage ratio

    • 20–40 liters per ton of composted substrate (active ingredient)
    • Description adapted per organic matter composition and microbial load
    • Requires full decomposition and clearance interval for food-grade use

    Downstream process integration

    • Mixed or sprayed into mushroom compost or casing covering during initial substrate conditioning stage
    • Subsequent aeration and temperature control to ensure breakdown and dissipation
    • Fastidious record-keeping for traceability audits

    Final product types

    • Fresh white and brown mushrooms, processed mushroom products, canned and dried mushrooms

    4. Biofilm and Bacterial Control in Food-Processing Water Systems

    Food processing plants and industrial laundries utilize controlled dosing of Metam Sodium for biofilm, slime, and bacterial load reduction in non-potable process water circuits. The compound acts as a biocidal agent in plant water recirculation systems and irrigation channels, supporting pathogen control and improving the longevity of processing equipment while complying with sanitation standard operating procedures.

    Industry compliance standards

    • US FDA GRAS status for certain processing aids (21 CFR 173.315)
    • USDA NOP Section 205.601 for permitted sanitation aids
    • European Union Drinking Water Directive (EU 2020/2184) for process water limits
    • HACCP risk management requirements for cross-contamination control

    Typical usage ratio

    • 1–5 ppm active ingredient in recirculated water; increased for crisis sanitation
    • Continuous or shock dosing schedules, with run-off level tested before discharge
    • Concentration determined by water organic load and recirculation speed

    Downstream process integration

    • Blended into incoming non-potable water via metering pumps within closed-loop circuits
    • Monitoring via in-line sensors or titration to maintain within regulatory thresholds
    • Documented in facility sanitation master plans

    Final product types

    • Ready-to-eat vegetables, salad greens, minimally processed fruit, clean-packaged produce

    5. Industrial Wastewater Odor and Sulfide Mitigation

    Municipal and industrial operators treat sludge, wastewater, and effluent streams with Metam Sodium for odor abatement and hydrogen sulfide neutralization. Facilities integrate dosing into sludge dewatering, sewer mains, and headworks operations, facilitating compliance with air quality and nuisance odor regulations while reducing corrosion in downstream piping and equipment. The chemical’s ability to bind and decompose sulfur compounds is essential in sectors such as food processing, rendering, and paper mills.

    Industry compliance standards

    • US EPA Clean Water Act (40 CFR Part 136, 133)
    • European Union Urban Waste Water Directive (91/271/EEC)
    • APHA Standard Methods for the Examination of Water and Wastewater
    • OSHA Process Safety Management requirements for on-site chemical handling

    Typical usage ratio

    • 5–20 mg/L of sludge or effluent (active ingredient basis)
    • Dosing varies with sulfide load, pH, and process volume
    • Pre-testing required for system-specific adjustment

    Downstream process integration

    • Injected directly into influent pipes, sludge thickeners, or odor control vessels
    • Monitored through downstream gas phase or odor surveys
    • Dewatered or treated sludge sent for further processing or disposal

    Final product types

    • Compliant treated wastewater, stabilized biosolids, odor-reduced sludge for disposal or landfill
    Free Quote

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    Certification & Compliance
    More Introduction

    Metam Sodium: A Manufacturer’s Perspective on Reliable Soil Fumigation

    Introduction to Metam Sodium

    Metam Sodium stands out as a key component in the world of soil treatment and pre-plant fumigation. After years of producing and handling this important chemical, I understand the critical points growers watch—regulatory status, handling safety, and what separates one product grade from another. As a manufacturer, meeting those needs has shaped how we design our process and guide our clients.

    How We Produce and Supply Metam Sodium

    Our facility specializes in manufacturing Metam Sodium at consistent concentrations, focusing primarily on a 42% solution favored by many agricultural professionals. The production method starts with methylisothiocyanate precursors, refined and reacted to create the final product under controlled conditions. We run rigorous quality control at several points, checking for purity, stable pH, and absence of impurities. We package in corrosion-resistant drums and totes, with proper venting systems to avoid build-up of gases, especially under unpredictable warehouse conditions.

    After decades in the industry, our teams know the risks improper handling brings. Leaks, unauthorized dilution, or exposure to moisture during transit will compromise shelf life and safety. Everything from drum lining to the vent caps has evolved through feedback from growers, applicators, and our own storage staff. Feedback loops like these push us to continually improve—not only to pass regulatory checks but to keep the person handling the product at ease.

    Metam Sodium Use in Agriculture and Beyond

    Metam Sodium’s primary application remains as a pre-plant soil fumigant. It targets nematodes, weeds, fungi, and pathogenic bacteria with broad-spectrum results. The farmer injects it directly into the ground, sealing immediately with water or plastic mulch to limit volatilization. Our product in the standard 42% solution allows more accurate dosing, helping professionals treat large areas efficiently without needing constant calibration changes. Those who use it in open field production report better crop emergence and healthier stands, translating to better yields.

    Beyond field vegetables, Metam Sodium functions as a key treatment step for greenhouse soils, tobacco, and some ornamentals. Golf course superintendents sometimes request our product to sterilize high-use turf areas and reset disease cycles. With water activation, the chemical converts to methylisothiocyanate (MITC), the true fumigant that does the work in the soil profile. Most experienced users time application carefully to match soil temperature, moisture content, and weather forecasts, lessons learned from both successes and costly misses.

    Important Properties and Specifications

    As a manufacturer, we pay close attention to the properties that define good Metam Sodium. Our product leaves the facility with a clear, amber appearance and a sharp, noticeable odor—an indicator of the potency most buyers expect. With a pH range above 9, storage conditions remain stable for long periods if kept away from sunlight and heat. Because the material holds up best under cooler, dry conditions, we advise keeping tanks tightly sealed and away from oxidizing agents.

    We strictly avoid any additives that could leave behind residues harmful to crops or the environment. All batches pass through a test for inorganic salts and heavy metals. Having reviewed competitor samples through the years, we find that stable concentration and minimal contamination directly affect application results. Even small changes in water quality or unintentional mixing with incompatible pesticides alter Metam Sodium’s behavior, so our guidelines always direct users to clean application systems and avoid simultaneous tank mixes unless fully validated.

    Transport, Storage, and Handling in Day-to-Day Practice

    Shipping Metam Sodium requires a hands-on approach. Our logistics teams secure containers that comply with international regulations, including United Nations-approved drums for hazardous goods. We supply documentation not just to move product across borders but to keep everyone involved safe—as spills or leaks can cause strong odors and, at higher levels, irritation. Handling protocols stress chemical-resistant gloves, goggles, and appropriate footwear; no one on our team shortcuts these protections. Field users know these steps prevent reactions with skin or eyes, especially during transfers.

    Ventilation is not a box-checking exercise—our years of loading and unloading product taught us the cost of off-gassing in closed spaces. Warehouse personnel receive routine refresher courses on storage, and we encourage our clients to schedule regular site inspections. Guesswork with container stacking leads to dents, which can escalate to leaking, even if the exterior coating stays intact. That firsthand experience makes us advocate for sunlight-free, low-traffic storage, far from seed, food, or feed materials.

    Meeting Regulations and Certification Standards

    Producing Metam Sodium in a regulated environment means every drum, tote, and tanker truck carries a pedigree. Our plant meets the expectations of both local agencies and overseas markets that apply the toughest scrutiny. Material safety data sheets, proof of environmental testing, and shipment manifests must align perfectly, or the product faces rejection. In practice, this goes far beyond paperwork. Our quality department has caught contamination risks from simple process deviations that a computer might miss—but hands-on oversight catches early.

    Traceability now factors into every batch we release. We maintain production logs, test records, and chain-of-custody documents that extend years into the past. Auditors do not ask for promises; they want physical records. Based on our track record, these habits pay off not just in regulatory audits but also when a client investigates a crop issue and wants history for every barrel applied.

    Delta Between Metam Sodium and Other Soil Fumigants

    Having participated in side-by-side field comparisons, we see Metam Sodium bringing unique advantages and some trade-offs compared with products like dazomet, chloropicrin, and 1,3-dichloropropene. Our product moves through water with ease, making shank injection and drip irrigation the most user-friendly forms. Unlike granular dazomet—requiring physical soil mixing—or gaseous methyl bromide, Metam Sodium’s application can be completed with standard liquid spray or irrigation equipment.

    Growers often share their experiences that Metam Sodium handles variable soil conditions better than stricter alternatives, although heavy clay soils ask for more precise injection to avoid surface runoff. Regulatory burdens have pushed some traditional fumigants off the market or forced them into higher price categories; Metam Sodium maintains its registration in most key regions due to lower bioaccumulation and less environmental persistence. It gives customers flexibility, while still demanding the same due diligence in buffer zone management and re-entry periods.

    Efficiency in volatilization sets it apart from products like chloropicrin: after water activation, the conversion to active MITC usually completes within 24 to 48 hours, releasing acting gas throughout the soil profile. In most cases, plastic tarping is optional rather than required, lowering overall use costs. From the feedback we receive, Metam Sodium provides a practical solution for integrated pest management, especially for growers balancing the cost of fumigation against the price of advanced crop protection chemicals.

    Environmental Considerations and Safe Use Protocols

    No serious farm manager ignores the environmental discussion. From manufacturing through to field use, Metam Sodium presents safety challenges. Our procedures for wastewater and solid waste management comply with current environmental limits, and periodic audits by outside consultants confirm these figures. Inside the field, threats of groundwater contamination or off-target movement remain the talking points during every safety training. We stress correct soil moisture and depth during application since risks balloon when soils are oversaturated or not compacted after injection.

    Our customers face restrictions on buffer zones, waiting periods before planting, and notification rules for workers and neighbors. While these seem cumbersome at a distance, real-world problems—like odor complaints or aquatic toxicity—have taught us the value of getting these steps right. Over several decades, improvements in tamper-evident seals, vented closures, and traceable batch codes reflect not just compliance but lessons absorbed from near-misses.

    We support research into MITC emission reduction, soil bio-filtration, and improved application hardware. Farmers need clear answers on safe plant-back intervals and reliable detection of breakdown products. We collaborate with universities and extension services to provide real application data, building a record over time on different rotation crops, irrigation practices, and climate conditions. This partnership means new protocols evolve from evidence, not simply from theory or simulation.

    Worker and Community Health Safeguards

    As the people closest to the product, our staff values safety more than any check-box exercise. Instructions emphasize respiratory protection, protective suits, and safe transfer practices. Field training drills with first responders and medical services never treat incidents as abstract. While rare, accidental inhalation exposures taught us exactly which protocols matter most—immediate evacuation, prompt medical attention, and thorough decontamination.

    We back up distribution with troubleshooting support. Applicators sometimes call with questions about drift incidents, unexpected wind shifts, or odors in nearby worker housing. By reviewing weather logs, buffer calculations, and field maps, we work together to prevent future occurrences. We would not send out Metam Sodium if we would not apply it on our own test plots or fields. That trust forms the backbone of long-term relationships with both clients and regulators.

    Staying Ahead as a Manufacturer

    While Metam Sodium has earned its place, the future brings more pressure on manufacturers. Regulations tighten, and international agencies inspect everything from labeling formats to the composition of cleaning water left at the plant. Our solution follows three tracks: refining the synthesis process for less waste, investing in improvements to drum and tote safety, and adding worker training sessions both in our own plant and on farms where our product is used.

    Ongoing research occupies a big part of our development work. Our chemists review every complaint, field observation, and incident report, looking for patterns. Trends like soil carbon reduction after repeated fumigation, or residue issues on sensitive crops, become part of our annual review. Each new fact, from better neutralization agents to the role of soil microbial populations post-fumigation, gets reported back to the application and safety teams. For us, producing Metam Sodium never means standing still—it means solving today’s challenges and preparing to answer the next round of questions from the industry.

    Comparison with Emerging Alternatives

    The landscape shifts as biopesticides and plant activators gain ground. Metam Sodium’s performance on large acreage and its spectrum of control remain difficult for some alternatives to match, especially under disease or nematode pressure. From a manufacturer perspective, efficiency on a cost-per-acre and proven results over a wide range of climates remain arguments most of our users bring up again and again.

    Still, demands for greater residue safety and stricter modes of action push us to keep improving. Biological soil amendments, introduced alongside or after Metam Sodium application, attract more attention from crop consultants and food processors. We see a growing role for rotation, lower rates, and more targeted application windows—tips we routinely share based on our ongoing field collaborations.

    For crops with exceptionally tight residue limits or in regions where community sensitivity runs high, our team walks through all available alternatives with clients, breaking down the relative merits of each. Decades of hands-on manufacturing show that transitions work best when experience carries as much weight as published trial data. With Metam Sodium, the credibility comes from roots in the soil—values we aim to uphold across every drum, every acre.

    Concluding Reflections from the Manufacturer’s Floor

    Producing Metam Sodium is more than a formula or a production schedule. It starts with raw materials entering the plant, passes into the hands of people who test, fill, and approve every lot, and ends with the trust farmers place in every scheduled application. Facts matter—concentration stability, safe storage, reliable regulatory history—but they never replace years of hands-on correction, adaptation, and feedback. Crop protection is a partnership. Every acre successfully fumigated tells a story of science and effort, but also of listening and learning.

    Growers and applicators rely on Metam Sodium that works as expected, batches that keep for months, and a support system built on real-world experience. Chemical manufacturing never stands still; neither do our expectations. With every shipment and every field call, we look for ways to do better—as manufacturers and as partners for those who place their trust in proven solutions.