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Manganese (II) Oxide

    • Product Name Manganese (II) Oxide
    • Alias Manganese monoxide
    • Einecs 215-266-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    430005

    Chemical Name Manganese (II) Oxide
    Chemical Formula MnO
    Molar Mass 70.937 g/mol
    Appearance Green crystalline solid
    Density 5.43 g/cm³
    Melting Point 1650 °C
    Boiling Point 2800 °C
    Solubility In Water Insoluble
    Cas Number 1344-43-0
    Molecular Structure Rock salt (NaCl) type
    Oxidation State +2
    Pubchem Cid 14800

    As an accredited Manganese (II) Oxide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle with sealed cap, labeled "Manganese (II) Oxide, 500g," featuring hazard symbols and manufacturer details, moisture-resistant.
    Shipping Manganese (II) Oxide should be shipped in tightly sealed containers, protected from moisture and incompatible substances. It is typically transported as a non-hazardous solid in compliance with local, national, and international regulations. Care should be taken to avoid dust formation during handling and shipping, ensuring proper labeling for identification.
    Storage Manganese (II) oxide should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area. Keep it away from moisture, acids, and incompatible substances. The storage area should be clearly labeled and protected from physical damage. Avoid dusty conditions and ensure containers are kept closed when not in use to prevent contamination and deterioration.
    Application of Manganese (II) Oxide

    Applications of Manganese (II) Oxide in Industrial Manufacturing

    Manganese (II) oxide serves as a key raw material across critical industrial sectors, where it delivers specific functions linked to chemical, ceramic, metallurgical, battery, and ferrite production technologies. Our strict production controls allow exact adherence to downstream customer requirements. Explore detailed scenarios below for accurate application, integration, and compliance detail.

    1. Electrolytic Manganese Dioxide Production for Alkaline Batteries

    Manganese (II) oxide acts as the primary manganese feed source for electrolytic manganese dioxide (EMD) manufacturing, a principal active material for alkaline and zinc-carbon battery cathodes. Metallurgical and electrochemical processes use the oxide under controlled oxidation-reduction conditions, followed by rigorous refining to ensure a narrow impurity profile for battery manufacturers. Customers demand high conversion efficiency and predictable batch-to-batch oxide reactivity, as even minor deviation impacts discharge capacity, battery cycle life, and self-discharge rates.

    Industry compliance standards

    • IEC 60086-2 Safety Standard for Batteries
    • China YS/T 608 EMD Industry Standard
    • Japan JIS C8513 (Primary Battery Manganese Dioxide)
    • UL 2054 Battery Safety Certification

    Typical usage ratio

    • 98–100% manganese (II) oxide as manganese feedstock per batch, adjusted for ore grade and impurity load

    Downstream process integration

    • Dissolution into sulfuric acid leach systems prior to electrolytic cell charging
    • Oxidative conversion, purification of leachate, and controlled EMD crystallization
    • Residue handling and recirculation based on impurity washout

    Final product types

    • Electrolytic manganese dioxide powder for primary and rechargeable batteries
    • EMD granules for zinc-carbon battery cathodes

    2. Soft Ferrite Magnet Manufacturing

    Manufacturers in the soft ferrite magnet industry use manganese (II) oxide as an essential manganese source for Mn-Zn and Ni-Zn ferrite ceramic compositions. The oxide is weighed into batch formulations based on target permeability, core loss, and initial permeability requirements. High material purity reduces unwanted secondary phase formation during sintering, yielding reproducible magnetic properties for transformer cores, EMI suppression components, and inductive devices. Quality assurance involves granular chemical analysis and frequent phase verification.

    Industry compliance standards

    • IEC 60401 Ferrite Materials
    • JIS C2502 Ferrite Standard
    • RoHS & REACH for restricted substance limits
    • UL 1676 Ceramic Material Testing

    Typical usage ratio

    • 15–32 wt% depending on specific formula: e.g., Mn0.6Zn0.4Fe2O4 commonly uses ~27–31% manganese oxide input relative to ferric oxide

    Downstream process integration

    • Weighing and milling with iron oxide and zinc oxide
    • Calcination at 900–1100°C followed by controlled sintering
    • Granulation, pressing, and final firing to attain ceramic microstructure

    Final product types

    • Soft ferrite cores for power transformers
    • Toroidal and E-core ferrite inductors
    • EMI filter and telecommunication ferrite beads

    3. Glass Colorant and Decolorizer

    Manganese (II) oxide is a major additive in commercial glassmaking operations, including specialty containers, flat glass, and glasswool production. Operators use the oxide both to impart desired coloration and as a decolorizing agent to mask unwanted iron impurities. Addition levels are fine-tuned by glass composition, furnace temperature, and the target optical specification. Close control of feedstock color index and particle size distribution ensures stability during glass melt homogenization and prevents batch defects.

    Industry compliance standards

    • EN 1748-1 European Standard for Glass in Building
    • ASTM C1036 Standard Specification for Flat Glass
    • ISO 14001 for environmental controls in melt emissions
    • FDA 21 CFR 177.2600 for food-contact glass (where applicable)

    Typical usage ratio

    • 0.01–0.25 wt% as a colorant; lower range for decolorizing (0.01–0.02 wt%); higher rates for deep tinting

    Downstream process integration

    • Dry mixing into glass batch components, including silica sand and soda ash
    • Direct addition to the feeder hopper or float glass furnace feed belt
    • Continuous in-line QC for hue and transmission index

    Final product types

    • Green and amber glass bottles
    • Architectural flat glass with color control
    • Household glassware and lamp glass

    4. Catalyst Preparation for Olefin and Synthesis Gas Processes

    Chemical process catalyst manufacturers incorporate manganese (II) oxide as a crucial precursor in the fabrication of mixed oxide catalysts for olefin oxidation (ethylene, propylene) and syngas-based auto-thermal reforming. The oxide confers structural and redox stability, forming part of the active phase in multi-metal catalyst tablets and supported beds. Stringent control of particle morphology, grindability, and trace element content helps maximize catalyst strength and selectivity, reducing costs in high-throughput process operations.

    Industry compliance standards

    • ISO 9001-certified manufacturing process controls
    • EU REACH for hazardous substance management
    • NFPA 654 for dust collection and fire safety in catalyst plants
    • API Recommended Practices for chemical plant equipment

    Typical usage ratio

    • 5–30 wt% in finished catalyst oxide blends, based on process design (e.g., for propylene oxide production, typically 10–25% manganese oxide input)

    Downstream process integration

    • Blending with alumina, silica, and other oxides during precursor mixing
    • Spray drying, extrusion, and pelletizing prior to calcination and activation
    • In-situ activation via reduction/oxidation cycling on fixed-bed or fluidized-bed reactors

    Final product types

    • Oxidation catalysts for ethylene, propylene, and aromatics
    • Syngas catalyst blends for ammonia and methanol synthesis
    • Automotive and industrial emissions control catalysts

    5. Feedstock for Specialty Manganese Salts

    Producers of high-purity manganese salts, including manganese sulfate and manganese acetate, rely on manganese (II) oxide as their primary raw material. Purity requirements demand controlled trace element levels, particularly for electronics- and pharmaceutical-grade salts. Salt producers dissolve the oxide under mildly acidic conditions using defined filtration and crystallization sequences to achieve consistent particle size, solubility, and color. The process is tuned for contaminant management, batch yield, and compliance with industry-specific purity thresholds.

    Industry compliance standards

    • Ph. Eur./USP for pharmaceutical-grade manganese salts
    • GB 29209-2012 Food Additive Manganese Sulfate Standard (China)
    • FCC (Food Chemicals Codex) for food-grade manganese salts
    • ISO 9001:2015 for quality management

    Typical usage ratio

    • 99–100% theoretical conversion from oxide to salt; process losses below 2%

    Downstream process integration

    • Acid leaching of oxide in dedicated reactor vessels
    • Sequential purification, filtration, and multiple crystallization cycles
    • Spray drying or granulation based on end-use specification

    Final product types

    • Food and feed-grade manganese sulfate
    • Pharmaceutical and reagent-grade manganese chloride, acetate, nitrate, or gluconate
    • Electronics-grade manganese compounds for catalysts or cathode preparation

    6. Metallurgical Alloy Additive in Steel and Non-Ferrous Production

    Steelworks and foundries deploy manganese (II) oxide as a flux and alloying additive, especially in silicomanganese and ferromanganese alloy smelting. The oxide adjusts melt viscosity, lowers sulfur inclusion content, and supports Mn pick-up during steel tapping. Operators match oxide input to charge weight, desired final Mn content, and target deoxidation efficiency. Continuous sampling during furnace operation ensures compliance with tight steel composition windows and minimizes unwanted interactive phases that can affect mechanical performance and downstream processability.

    Industry compliance standards

    • ISO 5445 and 5446 Ferromanganese Standards
    • ASTM A99/A99M Standard for Ferroalloys
    • EN 10277 Steel Product Delivery Conditions
    • ISO 4957 Tool Steel and Alloy Compliance

    Typical usage ratio

    • 2–12% relative to agglomerated charge weight; higher ratios for specialist alloy production, lower for deoxidation only

    Downstream process integration

    • Direct addition into electric arc furnace (EAF) or blast furnace charge mix
    • Alloy blending in ladle metallurgy operations pre-casting
    • Integration into cored wire for in-situ steel treatment

    Final product types

    • Silicomanganese and ferromanganese master alloys
    • Construction-grade rebar and structural steel
    • Specialty castings and high-strength tool steels
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    Certification & Compliance
    More Introduction

    Manganese (II) Oxide: Production, Applications, and the Value of Material Control

    Direct from the Plant: A Manufacturer’s Perspective

    Manganese (II) Oxide presents itself as a unique blend of chemical reliability and practical versatility. We see every batch from the very beginning—each granule and every dust-free parcel. Working at the source, we know exactly how raw material flows into the process, how impurities can disrupt downstream reactions, and what it takes to deliver not just a labeled drum but a substance fit for the many roles industry demands.

    Model and Specifications Matter

    The grade and appearance of Manganese (II) Oxide can matter as much as the label itself. Over the years, we have focused on a model specification: dense blackish-green to brown powder, Mn at upwards of 60 percent (by mass), and less than 0.02 percent iron. Particle range falls typically between 325 mesh and finer. We control sodium, calcium, silicon, and phosphorus down to fractions of a percent, knowing even small levels can throw off batch consistency. Moisture content stays low, seldom above 0.5 percent, which is vital if the next customer will push powder straight into glassmaking, ferrite production, or a battery cell. Our monitoring does not end after reaction—final sieving and chemical analyses set the quality for the end-user.

    Our in-plant experience shows how even a subtle swing in bulk density or trace elements changes the result in a melting furnace or ceramic kiln. On that floor, the difference between repeat business and an irate phone call often lies in details invisible to a generic spec sheet—variability in reactivity, ash residue from unintended byproducts, or the hue that splits the line between brown and greenish-black. Beautiful uniformity in form means little if manganese does not deliver as it reacts.

    What Sets Manganese (II) Oxide Apart from Other Manganese Compounds?

    Manganese, as an element, wears many chemical hats. Factories and research centers handle manganese dioxide, manganese carbonate, and even complex spinels every day. We have learned each variant carries a different “personality” on the line. Manganese (II) Oxide (MnO) stands apart for one simple reason: its reactivity. Unlike manganese dioxide (MnO2), which acts as an oxidizer and can split oxygen under heat, MnO stays at a +2 valence state—unlikely to throw off oxygen in redox processes, so practical in specialty ceramics and ferrite core materials.

    For glass companies, the story centers on how MnO adjusts the Fe3+/Fe2+ ratio. In steel, foundries demand it to remove sulfur, and only MnO will deliver that without adding the risk of over-oxidation. MnO is more reactive than manganese carbonate when making certain ferrites but avoids releasing CO₂ in the process, so factories win both on energy and downstream air quality. We run side-by-side trials: MnO as a flux or feedstock, and every time, the absence of unwanted byproducts reduces downstream costs.

    Looking at competitiveness, price does not tell the full story. Manganese carbonate and high-purity manganese acetate command premiums but bring forth water, carbon, or acetate byproducts. In a dry mix or solid-state reaction, that extra moisture or “extras” mean more drying time, potential porosity in fired ceramic, and hidden long-term risks. MnO skips those complications.

    A Factory Floor View of Production and Purity

    We take pride in owning the complete process, from feeding manganese ore to the final packing. The heart of production starts with top-grade pyrolusite ore or already-refined manganese oxide. We run reduction using carbon at controlled temperatures, careful not to slip into forming higher oxides or metallic manganese. Observing every reactor load, we know temperature faults can speckle the product with unwanted higher oxides—a blemish that glassmakers spot the moment they test. Only with sharp temperature and oxygen control do we hit a consistent MnO phase.

    Washing removes chlorides, iron, and soluble sulfur compounds that ride into the system from irregular raw material. Over the years, we found even a brief lapse in this cleaning adds haze or off-colors in final ceramics and glassware. Daily, our wet chemistry lab checks every lot—titration for Mn²⁺, photometry for iron, and loss on ignition. It’s labor-intensive, but skipping steps always brings complaints and costly returns.

    Our bagging crews know that product form is never cosmetic—free-flowing powder vs. lumpy fines matter directly for dosing and storage. Anticaking treatments must not react with customer’s solvents or process aids, so we stick close to basic, non-reactive choices. Every label reflects reality: Mn content, batch number, and day of production linked by internal traceability down to the bag.

    How Manganese (II) Oxide Serves Industries

    Glassmakers keep steady demand for our MnO, relying on its color-fixing properties. They know iron contamination in sand tints glass green, but MnO balances the color, removing that cast without hazing batches. We receive photos from clients showing clarity and light transmission on finished bottles—results trace back to controlled Mn/Fe ratios set during melt.

    Ferrite manufacturers depend on the reactivity of our powder, knowing that solid-state reactions hinge on purity. Even minor deviations in manganese or iron shift the magnetic properties of final ferrite beads. We see direct feedback, including failed sintering runs traced to manganese dioxide contaminants that we now screen religiously out. Our engineering team meets regularly with these buyers, swapping process tweaks in pursuit of better throughput and fewer kiln losses.

    Chemical synthesis industries need MnO because of its role as a starting base for compounds like permanganate, manganese(II) salts, and catalytic materials. We have adjusted our powder fineness for these buyers, running extra screening or microgrinding if a customer wants more rapid dissolution or tighter dispersion in their reactors.

    In agriculture, some fertilizer blenders request coarser MnO—to match granule size without caking or powdering in the field. We keep tension with environmental limits on dust, so our site engineers constantly refine granulation lines for better atomization and less airborne loss. Every run gets checked for both size and dust emissions, and the best process is one that balances these against transport stability.

    Ceramics and bricks demand yet another packaging form. High-fired tiles only accept the most stringently controlled MnO—a lesson learned after minor off-colors showed up batch after batch. Our plant has invested in dust-tight valves and bag houses, repeating tests until consistent color spreads appear across dozens of glaze samples.

    Foundries seek MnO for deoxidizing and desulfurizing. Shop leaders tell us about slag consistency—the direct outcome of manganese content and low-iron operation. Tracking lots that delivered a better “pour” means flagging the batch numbers at our end, keeping feedback cycles tight and immediate.

    Why Experience with the Real Material Matters

    Being a manufacturer for years breeds a sense of nuance that generic catalogs don’t capture. The true differences between MnO lots arise not from static chemical tables, but from actual performance during end-use. For example, in glassmaking, only careful reduction and particle size control keep color adjustments viable. Raw ore origin, furnace conditions, and cleaning steps combine in ways visible immediately in melt quality—and not in a datasheet.

    We don’t just wait for complaints. Our quality control hands run routine checks on shipping bags and sample powder for caking, color, and sieve distribution, knowing that the logistics chain from our warehouse to a customer’s loading bay can stress product limits. We have learned to overpack slightly, shield from moisture ingress, and store bags upright for bulk orders, since small leaks during rainy weather can quickly create a clumpy mess. Feedback loops run both ways; end customers routinely alert us to unusual handling challenges and odd application results. Last year, a major ceramics client flagged a recurring patchy glaze—the issue came down to a trace contaminant only our lab’s most experienced chemist caught, pushing us to reinforce vendor screening.

    Changes in demand trigger earlier measures. When battery manufacturers began requesting higher-purity MnO in finer mesh, we rebuilt our grinding and classification stage for tighter limits. Current infrastructure supports particle size extremes as narrow as d90 under 10 microns, now requested not only by battery companies but also by advanced catalysts developers. Maintaining this flexibility means continual requalification, but working directly with evolving requirements has grown our understanding of how process parameters ripple through to customer satisfaction.

    Market Pressures and Lessons Learned

    Global pricing of manganese and energy swings force us to keep improving throughput and yield. Processing costs come from every step—ore sourcing, reduction, energy use, and labor—so only hands-on control keeps results consistent. Fluctuations in ore purity, especially between global suppliers, tend to show up first in Fe and Si content. Our procurement teams keep emergency contacts with trusted mines in Africa, Australia, and the Americas, allowing switching of supply when cargo tracks reveal quality dips.

    Energy represents one of our largest running costs. Over decades, we’ve invested in heat recovery and updated reactors, knowing that using less natural gas per ton of MnO pays off not just in margin but also in environmental permitting. By capturing waste heat and pre-feeding it to the reduction step, we achieve more complete conversion with less residual carbon. These changes did not come overnight: line-by-line evaluations, pilot testing, and sometimes hard tradeoffs mean efficiency improvements demand sustained focus.

    As environmental standards tighten worldwide, our factory continues to reduce dust and gaseous emissions. We have replaced older baghouses with HEPA-rated dust capture and now run continuous SO₂ monitoring at reduction exit stacks. Regulatory compliance has tangible impact: failures mean fines and forced downtime, so the production mindset shifts away from just “making product” toward process stewardship. Certificates and site audits are never an afterthought, but an ongoing demonstration for customers—complete, retrievable records and third-party inspection keep market trust high. The old habit of hidden corners or doctoring inspection logs cannot survive in a modern, transparent market.

    Final packaging carries more weight today than in the past. Export containers demand robust lining and moisture barriers, especially for ocean transit where mistakes lead to clumped, deteriorated powder on arrival. Over time, we’ve shifted packaging from woven bags to double-lined, polymer-sealed sacks, tested over months for water vapor transmission and chemical resistance. The seal on every bag and the batch code laser-etched on the outer layer trace directly to a full record stack: real content, day of fill, constituent metals, and even a QR code scan to our own test report if the customer wants it.

    Supporting Product Development and Customer Innovation

    Our operations team meets regularly with industrial partners to understand developing needs. Sometimes this means blending MnO with zinc or copper precursors for specific ferrite grades. Other times, it’s customizing a granule for a fertilizer blend or tweaking fineness to fit a slurry process. These changes bring the laboratory into real world constraints: scale-up, cost, and storage seasons. Now and then, a scientific breakthrough forces us to change our own standards—not just chasing novelty, but responding to real process improvements for the next generation of materials.

    Research collaborations bring us directly into early-stage discussions—battery makers refining new cathode recipes, ceramicists exploring new glazes, electronics fabricators demanding tighter purity and new packing methods. Each has unique demands; a one-size-fits-all approach readily leads to failure, and our history with direct supply means we track both each experiment and commercial outcome. Some gains come from simple adjustments (different milling regime, longer purification, or packaging redesign), while others require fundamental shifts in plant practice.

    Experience reminds us that adaptability counts more than static capabilities. Proof comes from long-term supply relationships in which a new product or regulation upends established processes. For instance, as some industries adopt greener standards and press for lower heavy metals or stricter dust limits, our staff trains for faster changeovers and better antibody testing of contaminants. Together, industry and manufacturer edge forward, blending hard technical lessons with the flexibility of modern supply chain practices.

    Challenges and Solutions in Manganese (II) Oxide Handling

    From years of producing and shipping MnO, we regularly run into transport and storage challenges. Hydrophilic powders, especially those made at smaller particle size, tend to attract atmospheric moisture during humid shipping seasons. We integrated drying and anti-caking staging pre-packing, plus moisture barrier liners, to answer complaints from large-scale users. Storage silos now carry automated venting and temperature monitors, helping prevent long-term degradation.

    Another recurring hurdle involves delicate handling—measuring, mixing, and transferring the powder without aerosolizing it or packing tightly into feeding systems. Facility-scale users often invest in pneumatic conveyors or dense-phase delivery lines, and our technical advisers work side-by-side with their plant engineers. We operate our own pilot plant, stress-testing mixtures and dosing setups for clients before launch, cutting the time between order and stable operation from weeks to days.

    For customers reliant on rapid dissolution in acid, we now prepare a finer wet-milled form of MnO, dried under reduced pressure to preserve chemical activity. Laboratories can see the difference immediately—as faster solubility cuts batch turnaround significantly. We channel this back into manufacturing for higher-value industrial clients pressing for lower cycle times.

    Safety always grounds our operation. Even at high purity, manganese compounds demand careful handling: inhalation risk, skin contact, and potential environmental runoff. Our site follows thorough safety routines—dedicated PPE, active ventilation, monitored discharge points—less from compliance dogma than direct effect. Every lab incident or near-miss cycles back as a lesson, prompting equipment upgrades, better labeling, or extended team training. Some of our most profitable supply contracts turned on our safety record and transparent incident reporting—plant managers know real risk is never hidden or neglected.

    Insights from Supplying Global Markets

    Exporting MnO brings its own set of lessons. Each country or user might demand distinct documentation or testing, but consistency wins return business. In Asia, battery makers often want extremely low sodium and potassium content—so we added a dedicated tank washing protocol and additional ion-exchange steps. European ceramics customers press for full compliance on REACH regulations, meaning not just purity but evidence of batch traceability, flight manifest, and chain-of-custody paperwork. North American buyers, especially glassmakers and foundries, consistently request support for handling bulk rail or containerized shipments—requiring solid packaging design and on-demand technical assistance.

    International users sometimes encounter unexpected results upon using the product. Where regulatory or material standards differ, real-time communication helps, as do pre-shipment sample confirmations. In one instance, a shipment headed to South America flagged a color variance, threatening a major glassworks launch. Our technical team flew on short notice, analyzed the melt onsite, and pinpointed a trace water inclusion from shipment delay. That trip cemented the partnership, teaching us more about in-field troubleshooting than years of sending routine data sheets ever could.

    As global competition sharpens, cheap MnO from secondary refineries (especially those using remelted battery waste or off-grade scrap) occasionally undercuts price. But the risk of contaminants or unpredictable reactivity keeps many buyers coming back to direct, vetted material. For us, these challenges keep the focus relentlessly on reliability—a product that does exactly what the customer expects, every shipment. Over decades in production, performance and trust outpace a short-term price cut.

    Continuous Improvement and the Road Ahead

    Running a direct MnO production plant means never standing still. Every month brings new requirements, stricter regulatory review, new technology, and feedback from users. Plant upgrades do not stop with hardware—updates strike as much in laboratory procedure, packaging, and process analytics as in reactor design. Our teams invest in direct, ongoing training; many staff have risen from entry line workers to shift leads or technical specialists, carrying deep, hard-won knowledge that no turnover can easily replace.

    Looking forward, industry trends pull us towards higher purities, tighter control on trace metals, and improved environmental stewardship. Battery technology, especially for electric vehicles, challenges us to deliver even more uniform and reactive MnO, pressed into narrower specifications for mass production. Regulations evolve, so our infrastructure must respond, leveraging new analytical devices, automated tracking, and digital reporting.

    From these daily challenges, one simple value persists: deep, direct understanding of the material—how it is made and how it performs in the real world, not just in theoretical tables. Our focus stays on maintaining open partnership with every user, supplier, and regulatory body involved, evolving alongside industries that demand more from every kilogram of Manganese (II) Oxide.