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Lithium Bromide

    • Product Name Lithium Bromide
    • Alias Lithium bromide
    • Einecs 231-439-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
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    VTB
    Specifications

    HS Code

    271874

    Chemicalname Lithium Bromide
    Chemicalformula LiBr
    Molarmass 86.845 g/mol
    Appearance White hygroscopic solid
    Meltingpoint 552 °C
    Boilingpoint 1,265 °C
    Density 3.464 g/cm³
    Solubilityinwater 166 g/100 mL (20 °C)
    Casnumber 7550-35-8
    Odor Odorless
    Ph 7-9 (50 g/L, 20 °C)
    Ecnumber 231-439-8

    As an accredited Lithium Bromide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Lithium Bromide is packaged in a sealed 25 kg HDPE drum with a chemical label, hazard warnings, and handling instructions.
    Shipping Lithium bromide is shipped in tightly sealed, corrosion-resistant containers to prevent moisture absorption, as it is highly hygroscopic. During transport, containers are labeled with appropriate hazard warnings, and handling follows regulations for non-flammable, low-toxicity chemicals. Proper storage and ventilation are maintained to ensure safety and chemical stability throughout shipping.
    Storage Lithium bromide should be stored in tightly sealed containers made of materials resistant to its corrosive nature, such as glass or certain plastics. Keep it in a cool, dry, well-ventilated area away from moisture and incompatible substances like strong acids and oxidizers. Ensure the storage area is clearly labeled and follow appropriate safety guidelines to prevent accidental exposure or contamination.
    Application of Lithium Bromide
    Purity 99%: Lithium Bromide of 99% purity is used in absorption refrigeration systems, where it ensures high cooling efficiency and minimal corrosion. Melting point 550°C: Lithium Bromide with a melting point of 550°C is used in thermal energy storage, where it provides stable phase-change performance at elevated temperatures. Anhydrous form: Lithium Bromide anhydrous is used in pharmaceutical synthesis, where it delivers precise reactivity and consistent yield. Particle size <100 µm: Lithium Bromide with particle size below 100 µm is used in industrial drying agents, where it achieves rapid and uniform moisture absorption. Aqueous solution 50%: Lithium Bromide aqueous solution at 50% is used in humidity control systems, where it maintains accurate and reliable environmental moisture levels. Stability temperature up to 400°C: Lithium Bromide stable up to 400°C is used in high-temperature chemical processes, where it enhances process reliability and longevity of equipment. Low chloride content: Lithium Bromide with low chloride content is used in electronics manufacturing, where it reduces risk of electrical failures due to ionic contamination. High solubility: Lithium Bromide of high solubility is used in dehumidification towers, where it supports rapid vapor absorption and process continuity. Battery grade: Lithium Bromide battery grade is used in advanced energy storage systems, where it improves charge-discharge cycles and overall battery life expectancy. Viscosity 35 cP: Lithium Bromide with viscosity of 35 cP is used in absorption chillers, where it enables optimized fluid dynamics and system efficiency.
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    Certification & Compliance
    More Introduction

    Lithium Bromide: An Essential for Absorption Chillers and Industrial Processes

    Our Perspective on Lithium Bromide Production

    Lithium bromide has established itself as the backbone of absorption refrigeration, and working as a long-standing chemical manufacturer, we have seen the story of its growth unfold over decades. Our production lines have followed strict standards for purity and consistency, shaped by years of direct engagement with engineers, procurement officers, and facility managers. Demand for high-purity lithium bromide kicked off as soon as manufacturers looked for more efficient, non-mechanical cooling solutions, especially for buildings, hospitals, and process plants. The product quickly became more than a commodity—its reputation rested on reliability batch-to-batch, and the ability to deliver when complex chillers went online or critical moisture-sensitive reactions called for extreme control.

    Product Models and Specifications

    Our lithium bromide comes as a high-purity, white crystalline powder or clear, colorless concentrated solution, depending on application requirements. Standard product grades center on technical and high-purity models: technical grade purity sits at 98.5% or higher, and refrigeration grades cross the 99.2% mark on a dry basis. For research and fine chemical applications, we refine the process further, delivering trace-metal specifications in the ppm range.

    We manufacture bulk solution at concentrations ranging from 30% to 55% by weight in water, adjusted for viscosity, solubility, and optimal performance in large absorption chillers. Every run passes through our strict in-house quality controls: we check sodium, potassium, calcium, magnesium, sulfate, and chloride levels with ICP-OES, ensuring low impurity profiles that keep our customers' equipment running longer and with less required maintenance.

    Meeting Demands in Absorption Chillers

    Most of our output flows directly into the absorption chiller industry. These refrigeration systems leverage lithium bromide’s exceptional hygroscopic properties—its affinity for water vapor surpasses most salts in practical temperature ranges. Water acts as the refrigerant, and lithium bromide acts as both a solvent and desiccant in the closed cycle. Because our lines serve chiller OEMs and power plant operators, our processes have been refined to ensure not just chemical purity, but solution clarity, storage stability, and corrosion control. We also ship pre-mixed solution, which responds to real-world feedback from customers who asked for easy handling and less on-site preparation.

    Facilities managers regularly tell us about the stakes: chiller units in metro hospitals, data centers, or chemical plants cannot tolerate fouling or plugging from trace contaminants. A single off-spec shipment will result in major downtime, lost cooling, and expensive service calls. We’ve spent years building up the rigorous blended solution protocols that deliver consistent density and performance. Some of our clients operate their chillers 24/7 for over a decade, relying on single bulk tank feeds—no manufacturer can get away with corner-cutting on trace ions, so we’ve invested in continuous process analysis and advanced resin purification to deliver what the chiller industry expects.

    Distinctive Features Compared to Other Products

    Many who are new to chemical procurement ask: why lithium bromide and not sodium bromide or calcium chloride? There is no replacement as an absorbent in the field of water-lithium bromide absorption chillers. Its principal strength comes from both its highly favorable vapor pressure suppression and strong water absorption at moderate pressures and temperatures. Sodium bromide, while less expensive, does not create the strong hygroscopic environment needed for effective absorption below room temperature. Calcium chloride finds its place as a general desiccant, but forms precipitates and scales under heat cycling, leading to reliability problems in closed refrigeration circuits.

    We regularly receive requests from new entrants into absorption chillers, or from engineering firms exploring alternative refrigerants. While many salts can absorb atmospheric moisture, few do it as aggressively and reversibly as lithium bromide across a broad temperature range. Its low vapor pressure minimizes losses from the system, and users who try to cut corners with substitutes often see their chillers run below design performance, accumulate scale, and burn out heat exchangers prematurely. Years of batch and fractional crystallization experience have taught us that even minor deviations in bromide content or cation contamination (like sodium carryover) quickly translate into excessive corrosion, pump failures, or foaming in the field.

    Lithium bromide also differs in storage and lifecycle impacts. Sodium bromide, often produced from cheaper byproducts, may contain halide impurities or heavy metals. Our lithium bromide comes from direct reaction of lithium carbonate (sourced under stringently controlled conditions) with hydrobromic acid, followed by sequential recrystallization and filtration. This allows us to deliver reliable supply for chiller manufacturers and high-purity solution for analytical, pharmaceutical, or polymerization use.

    Reliability and Consistency in Chemical Manufacturing

    Supplying lithium bromide on a commercial scale takes more than just raw ingredients and batch reactors. Batch-to-batch consistency, traceability, and transparent documentation guard our customers' assets. Once, an absorption chiller OEM in East Asia ran into major warranty claims—dozens of units broke down under warranty because of a single supplier's shipment with excessive sodium, likely from process shortcutting. Our own internal recordkeeping—full batch histories, impurity maps, in-process checks—meant we could demonstrate that none of our lots contributed to the failures, and our customer contracts grew as a result.

    The market often looks for stable sources with a proven track record, especially when significant capital is on the line. End users demand more than stated technical specs—a real-world track history matters most. Our decades of manufacturing have taught us that a paper certificate means little unless backed up by consistent results at the point of use. Annual audit visits from global OEMs are routine in our facility. Every year, they send teams well-versed in analytical chemistry, climb our process lines, and pull random drums for third-party analysis. This open scrutiny forces us to keep quality protocols strong, invest in laboratory upgrades, and push the lowest impurity levels feasible with current lithium feedstock.

    Lithium supplies often fluctuate, given volatility in battery and mining markets, but our own supply chain team keeps tabs on contract fulfillment so that customers are never left with shortfall in peak summer periods. There's little tolerance for errors when large absorption chiller units run across city blocks or pharmaceutical contracts depend on uninterrupted process streams. Trusted supply partnerships grow only from proven consistency—not from spot-market dealing.

    Handling, Storage, and Process Integrity

    Handling and storage concerns often come up among our customers that move from small-scale to bulk operation. Lithium bromide, in solution and crystal form, absorbs moisture rapidly and pulls water from the surrounding air. This requires us to maintain strict humidity control in our packaging plants and during drum filling, which guarantees product stability during long-term storage and transit. Every new facility that transitions to bulk solution typically faces the learning curve of keeping transfer lines and storage tanks tightly sealed, minimizing air contact, and maintaining system cleanliness to keep the solution from turning viscous or forming unwanted deposits.

    Large industrial users have told us about storage tank incidents tied to improper material compatibility. Lithium bromide is a mild to moderate corrosive—it can attack pipelines made of plain steel. We strongly recommend materials like 304 or 316 stainless steel for process equipment, or at minimum using well-lined storage tanks to prevent corrosion debris from ending up in circulating loops. We routinely share our material compatibility findings with clients embarking on new plant installations, making sure pain points can be anticipated and solved up front.

    On shipment, our product packaging has changed to meet both regulatory and customer feedback. We phased out traditional fiber drums in favor of high-density polyethylene and composite stainers, giving a longer shelf life and cleaner dispensing. Even these details haven’t been overlooked—one season, a shipment to a tropical customer led to elevated solution coloration, traced to poor seals in the previous container design. Since adopting improved closures, we have eliminated such occurrences.

    Supporting Innovation in Emerging Fields

    Beyond absorption chillers, lithium bromide interventions are emerging in other chemical synthesis and pharmaceutical applications. Some fine chemical manufacturers leverage its specific ionic properties to drive organic reactions such as alkylation or as a specialized Lewis acid. Laboratory researchers opt for our highest-purity batches when exploring new frontiers in catalysis or advanced battery technologies. Each field brings its own demands: where refrigeration operators focus on long-term equipment reliability, synthetic chemists emphasize documented impurity control at the sub-ppm scale to avoid product loss or failed runs.

    We've also collaborated on innovations in brine concentration, hydrometallurgical separations, and as specialty reagents in polymerization. Application engineers in these fields often approach us with unique requirements, from custom packaging size to documentation on contaminant origins. Our direct experience with wide-ranging end uses makes us nimble in responding to these emerging needs.

    Environmental and Safety Considerations

    Within our industry, environmental stewardship takes center stage. Lithium bromide solutions in chillers must avoid uncontrolled discharge into municipal drains or waterways, given their strong ecological impact if mishandled or spilled. Part of our responsibility as a manufacturer sits with technical support—clients consult with us regularly to develop responsible containment measures, use secondary barriers, and formulate response plans for unplanned leaks. Our in-house safety and environmental teams constantly audit wastewater streams, minimizing loss and maximizing recovery of lithium and bromide ions for reuse in new batches.

    Product safety extends to human health concerns. We keep close records of medical literature on lithium compounds, tracing their exposure thresholds and recording customer feedback about handling incidents. While lithium bromide is far less hazardous than the acidic or strongly oxidizing agents seen elsewhere in chemical facilities, training remains crucial. Our technical staff frequently lead in-person seminars and remote learning sessions for client plant operators—these engagements help minimize risk and prevent costly operational mistakes. For web customers and newcomers alike, we continue to publish articles and handling guidelines extracted from long field experience.

    Current Market Trends and Challenges

    Over the past decade, the chemical industry has seen pivotal changes in lithium sourcing. Competing markets for lithium—from electric vehicles and energy storage—have put fresh pressures on feedstock prices. Chemical manufacturers like us have had to double down on supply contracts and logistical planning, keeping operations steady while other sectors experience bottlenecks and cost swings.

    The impact of this volatility goes far beyond procurement costs. Many chillers installed in the 1990s and early 2000s now require major overhauls and replacement. Older OEMs often specified lithium bromide grades which no longer line up with modern impurity standards. We actively work with clients to characterize old system residues, advising them on phase-in strategies for modern solutions. By conducting compatibility testing and trial batch analysis, we help chiller operators navigate the transition without major shutdowns or warranty disputes.

    The regulatory environment for lithium compounds continues to shift as well. Our compliance staff keeps current with transport, health, and environmental updates on all major continents, responding quickly to changes in safe handling procedures and reporting thresholds. In one case, a sudden update in maritime transport rules in Europe led to a surge in compliance documentation requests. We responded by releasing transport-specific support materials, and updating all shipping containers with standardized hazard pictograms required by new local codes.

    Future Directions and Solutions

    We view ourselves as partners with end users—adopting new product forms, evolving handling procedures, and building robust supply strategies. To address rising demand and scarce mineral resources, our R&D teams now examine options to recover lithium from spent solution streams at end-of-life chiller installations or obsolete brine tanks. These recycling efforts show promise, cutting operating costs for large users and helping to conserve global lithium reserves. Industrial circularity is not a futuristic concept here; we already have demonstration pilots operating in several customer facilities, generating new product streams from old, off-spec crypto.

    Technological improvements inside the plant also make an impact. We use advanced ion-exchange systems and multi-stage evaporators in our crystallization units, reaching lower residual impurity levels than previous-generation equipment. Every yield improvement means less mine-sourced lithium is required for the same market volume, easing pressure on scarce supplies. Our advances get communicated directly to customers in quarterly partner bulletins, with access to batch-specific data summaries detailing impurity, batch genealogy, and performance metrics from real-world field results.

    On the product development side, customer requests influence our scale-up choices. The rise in mini- and micro-chillers for green building deployment has pushed us to design streamlined 30-40% lithium bromide solutions packaged in single-use, resealable pails. Feedback loops from these deployments improve our handling recommendations and cut occupational exposure risks, adding real value for facilities moving toward staff safety certification or reducing harsh chemical use onsite.

    We don't stop at technical solutions. Our technical service team supports with live troubleshooting for chiller startups, keys to desiccant process optimization, and custom impurity reporting. Centrifugal and rotary absorption machines now integrate more electronics and diagnostics, so we align our batch documentation with the latest OEM compatibility tools, allowing field technicians to validate product in minutes using portable in-line meters.

    Industry Collaboration and Knowledge Sharing

    The lithium bromide market does not stand still. Every year, industry consortia, chiller OEMs, and major energy operators meet to discuss advances, bottlenecks, and technical failures. Our company leans into these forums, sending chemists, engineers, and technical account managers to trade shows, standards meetings, and technical conferences, often bringing field data and lessons learned to broader industry attention.

    Field feedback from hundreds of actual installation sites underlies every decision we make in process upgrades, packaging format innovation, and even in the research we fund for corrosion inhibitors or system tolerances under heavy urban air pollution. Our experience says the best solutions grow from open, two-way conversations between chemical manufacturing experts and working maintenance professionals at user plants.

    There will always be more to learn and room to raise the bar. That is the honest reality of making, selling, and supporting the use of lithium bromide. We produce not only to specification, but to a long-standing commitment that grew out of direct, evolving partnerships with our customers. By listening, adapting, and maintaining transparency in everything from raw material source to after-sale technical support, we help build a more reliable, efficient, and sustainable future for industrial cooling and specialty chemistry.