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Iridium(III) Chloride Trihydrate

    • Product Name Iridium(III) Chloride Trihydrate
    • Alias Iridium trichloride trihydrate
    • Einecs 231-234-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    870659

    Chemical Name Iridium(III) Chloride Trihydrate
    Chemical Formula IrCl3·3H2O
    Molecular Weight 354.58 g/mol
    Appearance Dark brown to black crystalline solid
    Cas Number 14996-61-3
    Solubility In Water Soluble
    Melting Point Decomposes before melting
    Density 3.36 g/cm3 (approximate)
    Iridium Content Approximately 55% by weight
    Stability Stable under normal conditions
    Odor Odorless
    Ph In Solution Acidic

    As an accredited Iridium(III) Chloride Trihydrate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Iridium(III) Chloride Trihydrate, 10 grams, supplied in a sealed amber glass bottle with safety labeling and tamper-evident cap.
    Shipping Iridium(III) chloride trihydrate is shipped in tightly sealed containers to avoid moisture and contamination. It is typically packed in glass or high-quality plastic vials, cushioned in sturdy outer cartons. Shipping follows regulations for non-hazardous, stable chemicals, ensuring secure transport and clear labeling. Store in a cool, dry, well-ventilated area upon arrival.
    Storage Iridium(III) chloride trihydrate should be stored in a tightly sealed container in a cool, dry, and well-ventilated area, away from incompatible materials such as strong oxidizers. Protect it from moisture and direct sunlight. Store at room temperature and clearly label the container. Use appropriate personal protective equipment when handling to avoid contact with skin or eyes.
    Application of Iridium(III) Chloride Trihydrate

    Applications of Iridium(III) Chloride Trihydrate in Industrial Manufacturing

    As an established manufacturer of Iridium(III) Chloride Trihydrate, we supply this high-purity raw material to industries with demanding performance and quality requirements. Its precise role is critical in select downstream fields, where iridium's unique catalytic, electrochemical, and coloring properties drive innovation in specialized manufacturing processes. Below we detail key application scenarios, process integration, industry standards, recommended use levels, and typical end products.

    1. Catalysts for Hydrogenation in Fine Chemical Synthesis

    Iridium(III) chloride trihydrate serves as a source of active iridium species in the production of homogeneous catalysts for complex hydrogenation reactions, especially in the synthesis of optically active intermediates for pharmaceuticals and agrochemicals. Catalysts derived from this material enable precise asymmetric transformations under mild conditions, allowing for improved selectivity and yield in reaction sequences that would otherwise require harsher conditions or less sustainable alternatives.

    Industry compliance standards

    • GMP (Good Manufacturing Practice) for active pharmaceutical ingredients (ICH Q7)
    • REACH Registration (EC 1907/2006) for chemical intermediates
    • ISO 9001: Quality Management Systems
    • European Pharmacopoeia (Ph. Eur.) guidelines for API synthesis, where applicable

    Typical usage ratio

    • 0.05–0.5 mol% relative to substrate, adjusted based on substrate complexity and desired turnover number; higher for difficult transformations

    Downstream process integration

    • Addition to reactor with substrate and ligand at pre-catalyst activation step; often dissolved in alcohol or acetonitrile solvents prior to in situ catalyst formation

    Final product types

    • Enantio-enriched pharmaceutical intermediates
    • Chemical building blocks for crop protection agents
    • Chiral alcohols and amines for advanced organic synthesis

    2. Precursors for Iridium-Based Electrodes in Chlor-Alkali and PEM Electrolysis

    This material acts as a primary input in the preparation of iridium oxide layers on titanium and other conductive substrates used in industrial anodes for chlor-alkali electrolysis and polymer electrolyte membrane (PEM) water electrolysis. The iridium precursor is subjected to controlled thermal decomposition or electrodeposition, yielding adherent, corrosion-resistant coatings that sustain high current densities and aggressive chemical environments during prolonged operation.

    Industry compliance standards

    • ASTM B843: Standard Specification for Precious Metal-Electroplated Coatings on Metal Substrates
    • IEC 62282-2: Fuel cell technologies–PEM water electrolyzer systems
    • ISO 14001: Environmental Management for waste minimization
    • RoHS (EU 2011/65/EU) for electronic components

    Typical usage ratio

    • 0.2–2.5 mg Ir per cm² electrode surface, tuned for target current density and operational lifespan; uniformity is verified during QC coating thickness checks

    Downstream process integration

    • Applied as a solution or slurry in precursor bath; deposition via thermal decomposition (calcination at 400–600°C) or direct electrodeposition, followed by post-annealing to activate electrochemical properties

    Final product types

    • Dimensionally Stable Anodes (DSA) for brine electrolysis
    • PEM electrolyzer stacks for industrial hydrogen production
    • Anode coatings for laboratory and pilot-scale electrochemical reactors

    3. Raw Material for Iridium-Based Chemical Vapor Deposition (CVD) Targets in Microelectronics

    In advanced semiconductor manufacturing, especially for memory, logic chips, and microelectromechanical systems (MEMS), iridium precursors are essential for CVD processes. These thin films provide robust diffusion barriers and high-conductivity contacts, addressing the stringent purity and defect-density requirements in ultra-large-scale integration (ULSI). The material enters the CVD target or is converted to volatile complexes for atomic layer deposition (ALD), where precise control over film composition and thickness is critical.

    Industry compliance standards

    • SEMI C64: Specifications for precious metal materials in microelectronics
    • ISO 14644-1: Cleanrooms and associated controlled environments
    • IATF 16949: Automotive Quality Management (where automotive MEMS applies)
    • RoHS Directive for electronics manufacturing

    Typical usage ratio

    • Film deposition rates of 0.2–5 nm per cycle; precursor input adjusted according to target thickness, typically 100–300 nm total iridium layer per device feature

    Downstream process integration

    • Preparation of iridium-containing CVD targets or conversion into metalorganic precursors; evaporation or bubbling into process chamber for direct surface deposition under controlled temperature and pressure

    Final product types

    • Integrated circuit chips (logic/DRAM/NAND)
    • Microelectromechanical sensors and actuators
    • High-reliability circuit board contacts and interconnects

    4. Coloration Agent in Specialty Glass and High-Temperature Ceramics

    Iridium(III) chloride trihydrate is applied in specialty glassmaking and ceramic colorant formulations where its introduction at controlled levels imparts deep blue-violet hues, exceptional chemical resistance, and thermal stability for products exposed to harsh mechanical and chemical environments. Its effectiveness surpasses that of traditional transition metal pigments in glass used for scientific apparatus and advanced architecture.

    Industry compliance standards

    • EN 1388-1: Materials and articles in contact with foodstuffs–Test methods for glassware
    • ISO 7086-2: Glassware–Chemical resistance standards
    • ASTM C21: Ceramic colorants and frits specifications
    • UNI 9174: Fire reaction for construction glass, where coloration affects properties

    Typical usage ratio

    • 5–100 ppm Ir(III) relative to total batch weight; coloration depth and opacity adjusted by melt composition and customer specification

    Downstream process integration

    • Direct addition to silica or aluminosilicate melts during the batching stage; homogeneously mixed and fused at 1,400–1,600°C; color development finalized in controlled furnace atmosphere

    Final product types

    • Colored laboratory and reagent bottles
    • Architectural glass panels with thermal/UV resistance
    • Decorative stoneware for industrial/kiln use
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    Certification & Compliance
    More Introduction

    Iridium(III) Chloride Trihydrate: Precision in Precious Metal Chemistry

    Introducing Our In-House Iridium(III) Chloride Trihydrate

    As manufacturers, we engage daily with metals most chemists only read about. Iridium(III) Chloride Trihydrate stands apart among platinum group compounds. In dozens of conversations with researchers, production engineers, and technical managers, one point comes up repeatedly—consistency is crucial. From the shape and color of the red-violet crystals to the integrity of each lot’s moisture content, providing reliability builds trust. We know this firsthand, having refined production for more than a decade with each improvement guided directly by laboratory feedback and real project requirements. Model numbers matter less to our customers than the reliability of what arrives in the bottle.

    Exacting Specification and Quality at Every Step

    Our in-house Iridium(III) Chloride Trihydrate is produced using controlled oxidation and hydration of high-purity iridium metal. Each batch is built to deliver precise Ir content, typically near 36–37% by mass, and chloride within the standard laboratory analytical range. As a team who has assessed many lots under the microscope and in analysis, we guarantee that no off-specification product leaves our facility. Hydration level holds a direct connection to performance in chemical synthesis and catalysis; any deviation—seen in poor solubility, inconsistent crystal habit, or shifting color—signals trouble. We manage drying and storage with routine checks, retaining representative samples from each run. Our chemists share an understanding that a seemingly minor detail, such as residual acidity, may affect catalytic performance and complexation reactions, so each quality checkpoint is rooted in practical outcomes.

    Where Structure Meets Application: Core Uses in Modern Industry

    Iridium(III) Chloride Trihydrate finds its primary audience in research laboratories, catalyst production, and specialty chemical development. Electrosynthesis remains a major growth field—our clients manufacture electrodes for organic and inorganic transformations requiring an active iridium species. High-end electronics, especially organic LED work, draws on its use in precursor solutions. Crystallographers rely on consistent crystalline hydrate for X-ray structure studies, avoiding ambiguous data caused by poorly controlled hydrates. Pharmaceutical laboratories often use our product for specialized hydrogenation and oxidation reactions. Experienced teams look for predictable dissolution rates in water or ethanol and demand that chloride stays within known margins to avoid interfering with sensitive syntheses.

    Comparing this product to traditional anhydrous iridium chlorides and alternative hydrates highlights straightforward benefits. Trihydrate gives more reliable handling characteristics—ease of weighing, reduced dusting, repeatable solution concentrations. Unlike anhydrous material, which clumps and becomes hygroscopic on exposure, the trihydrate form maintains stability in normal laboratory atmospheres. Overdried or ill-defined hydrates lead to vague assay results and compromise the science. Our process ensures a correct stoichiometry, so every gram counts toward the intended chemical pathway.

    Production Details from the Factory Floor

    Most end users never see the inside of a chemical manufacturing plant running precious metals. Our process for Iridium(III) Chloride Trihydrate avoids excess oxidation states and keeps chlorination even across all the metal. Staff with hands-on experience—many with ten, fifteen, or twenty years of iridium chemistry—oversee the critical stages of reaction and purification. We run the process away from the high temperatures that could generate mixed-valent iridium oxides. Instead, controlled aqueous digestion followed by strict evaporation protocols produces the characteristic red-violet trihydrate crystals.

    From there, batch blending and careful bottling guard against caking or premature dehydration. We learned to avoid common pitfalls found in less consistent products: fine dust suggesting incomplete crystallization, uneven color that hints at mixed impurities, and excessive free acid from careless rinsing. Our control chemists track every flask and reactor, plugging the production workflow into quality systems aligned with globally accepted purity and contamination limits. Our customers deserve the same reliable performance every time, whether they work on a small benchtop project or a full-scale pilot plant.

    Beyond the Lab: Addressing Supply and Quality Challenges

    Demand for iridium-based chemicals often outruns the market’s capacity. Many researchers encountered issues sourcing product during shortages, especially in times of geopolitical strain. We have responded by reinforcing our feedstock supply chains and building in buffer stocks internally. By manufacturing in-house from metal feed, we avoid risks posed by resellers and bulk handlers that cannot guarantee chain-of-custody or true origin. Each vial we ship ties directly to batch records accessible by our technical and production staff, not passed through layers of resellers. That matters for applications requiring stringent traceability and reproducibility, such as pharmaceutical synthesis or regulated electronic component manufacturing.

    Comparing With Other Iridium Products

    Other iridium salts, like the anhydrous dichloride or iridium(IV) oxide, serve very different purposes. Anhydrous forms can bring higher iridium content by mass, but this comes at the expense of delicate handling and hydration variability once outside a glovebox. For many downstream transformations, water of hydration is not merely a formality. We have seen failed reactions and sluggish catalysis traceable back to incorrect hydrate formulations, a problem magnified when using erratic, off-brand imports.

    On the flip side, anhydrous or lower hydration chlorides, when handled in the open air, tend to form unpredictable hydrates anyway, confounding stoichiometric calculations. That’s why major research centers and industrial customers settle on the trihydrate form for most aqueous-based chemistry. There’s no need to recalibrate or ‘guess’ at the actual water content per gram—the structure is known and reproducible.

    Batch Results: Customer Case Studies and Feedback

    Our firm’s reputation draws on the success of tech and R&D partners across various fields. A catalyst manufacturer working with C-H activation routes for fine chemicals reported higher turnover frequencies—directly linking this to our batch’s lower residual acid and reliable solubility. Another electronics lab, developing phosphorescent iridium compounds for displays, documented fewer failed synthesis attempts after switching from a competitor’s variable product. Others operating with nanoparticles, who depend on tight particle size control during reduction, found smaller, more uniform results using our trihydrate because the hydration state allowed controlled, slow release of iridium ions.

    Feedback has shaped our process. Early on, clients noted excess acidity causing unwanted chloride side products. After an internal review, we introduced additional washing and more thorough dehydration checks at endpoint. Repeat clients in the medical device sector remarked on the trouble with erratic color—retrained staff now check batches visually as part of the sign-off, since an experienced eye often catches what instruments miss. The end result: better reproducibility, fewer headaches downstream, and confidence that each lot will behave the same as the last.

    Addressing Common Concerns: Moisture, Purity, and Handling

    Customers worried about the effect of ambient moisture on formulation often ask about packaging and longevity. We deliver the trihydrate sealed against humidity exchange, and multiple stability studies demonstrate no loss of hydration or shift in color spectrum for over twelve months under recommended storage. By excluding free acid and maintaining exact hydration, laboratories can prepare reference solutions repeatedly without recalibrating each time.

    Purity defines catalytic and analytical performance. Elemental impurities in iridium chemistry stem from the original ore or from processing vessels. We examine side products by ICP-OES and XRF, routinely exceeding the standard for heavy metal content by a wide margin—so nickel, copper, and trace platinum do not cripple downstream applications. Surface spectroscopy and solubility checks complement these analyses, providing a more holistic understanding of what the product will do once it leaves our doors.

    Improving Product Outcomes Through Direct Feedback

    Open channels between our manufacturing team and technical customers help isolate the root causes of any unexpected performance. A consistent issue—the slow dissolution of iridium salts after long storage—prompted us to refine drying procedures to prevent crust formation on crystals. Another persistent customer challenge involved minor chloride deficiency, not always caught by routine titration. By bringing in ion chromatography as part of the release protocol, this concern was resolved, resulting in tighter conformance to target specifications.

    Ongoing dialogue uncovered another matter: static charge buildup, which often plagues crystalline powders. After several rounds of consultation, we retooled our bottling to reduce powder crumbling and minimize the risk of micro-contamination on dispensing tools. Today, the process produces a trihydrate easily transferred using routine laboratory spatulas, with virtually no loss due to airborne static.

    Meeting Industry Trends and Emerging Needs

    Growth in hydrogen energy conversion, medical imaging, and organic light-emitting diode (OLED) research has created new expectations for iridium(III) chloride trihydrate. We’ve received inquiries about precisely tailoring lot sizes for pilot trials, minimizing waste and cost for expensive metal runs. This led directly to the adoption of flexible packaging solutions, from small one-gram vials for research, up to multi-kilogram packs for scale-up. Chemical composition remains consistent regardless of batch size, which encourages innovators to tackle advanced processes without expensive upfront material commitments.

    We noticed an uptick in demand from sustainable catalysis researchers aiming to recycle and recover used iridium salts. Our experience suggests trihydrate form supports more straightforward recovery after reaction, with less tendency to lose metal to side-processes. We work hand-in-hand with select customers, helping characterize waste streams for potential iridium reclamation, aiming to reduce both environmental and economic costs.

    Advantages Over Commercial and Import Alternatives

    Many buyers still rely on intermediaries where origin, purity, and hydration state fluctuate from month to month. This disrupts both routine assays and advanced device manufacturing. As direct producers, we offer guaranteed batch provenance, maintaining long-term supply relationships with producers of the iridium sponge we use as raw material. Our documentation provides not only a certificate, but an account of handling from metal reduction, chlorination, all the way to crystal isolation.

    Imported material—especially from less regulated supply chains—brings hidden risks: adventitious metals, mislabeling of hydrate content, shipped in unprotected containers. We maintain our edge by investing in in-house analytical infrastructure, delivering every order with batch data directly traceable to the original run. We view each delivery as a partnership; our customer’s success depends on our discipline and attention to real detail.

    Addressing the Future: Sustainability, Scale-Up, and Collaboration

    Iridium remains a rare and strategic metal, subject to supply bottlenecks and price volatility driven by mining yields and demand from new technologies. As we look to future-proof our production, we invest in reclaiming spent iridium from secondary sources and improving yields in purification. We advise our large-scale partners on best practices for recovering iridium after use, and support laboratory customers with detailed technical support to minimize waste during solution preparation and chemical reactions.

    A number of research consortia focused on catalysis and green chemistry have included us in active collaboration, working jointly to develop more sustainable methods of iridium chloride use and recycling. Through these relationships, we pool insights, refine our approach, and ensure the next generation of products reflects both practical needs and growing industry standards for environmental stewardship.

    Conclusion: Committing to Consistency, Clarity, and Customer Success

    Decades of experience and continuous improvement ensure that our Iridium(III) Chloride Trihydrate stands as a reliable backbone in chemical synthesis, catalysis, electronics, and materials research. The product carries the mark of careful manufacturing, always supported by rigorous specification, detailed record-keeping, and truly open customer dialogue. Each lesson in production or feedback from the field shapes the next batch, keeping our standards high—and our relationships with clients strong.