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Ferrous Chloride Tetrahydrate

    • Product Name Ferrous Chloride Tetrahydrate
    • Alias Iron(II) chloride tetrahydrate
    • Einecs 231-843-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    320779

    Chemical Name Ferrous Chloride Tetrahydrate
    Chemical Formula FeCl2·4H2O
    Molar Mass 198.81 g/mol
    Appearance Green crystalline solid
    Solubility In Water Very soluble
    Melting Point 37°C
    Density 1.93 g/cm³
    Cas Number 13478-10-9
    Ph Of Solution 2.0 - 3.0 (for 5% solution)
    Odor Slight hydrochloric acid-like odor

    As an accredited Ferrous Chloride Tetrahydrate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Ferrous Chloride Tetrahydrate, 500g, is packaged in a tightly sealed HDPE bottle with a clear, hazard-labeled exterior.
    Shipping **Description:** Ferrous Chloride Tetrahydrate is shipped in tightly sealed containers to prevent moisture absorption and oxidation. Store and transport it in a cool, dry, and well-ventilated area, away from incompatible substances. Proper labeling and handling according to hazardous material regulations are required to ensure safety and maintain product integrity during shipping.
    Storage Ferrous Chloride Tetrahydrate should be stored in a cool, dry, well-ventilated area, away from moisture and incompatible substances such as oxidizing agents. Keep the container tightly closed and protected from light to prevent decomposition. Use only corrosion-resistant containers. Avoid exposure to air to minimize oxidation. Label storage containers clearly and handle them carefully to prevent leaks or spills.
    Application of Ferrous Chloride Tetrahydrate

    Applications of Ferrous Chloride Tetrahydrate in Industrial Manufacturing

    Ferrous Chloride Tetrahydrate serves specialized roles in several core chemical and industrial sectors. As the direct producer, we support integrators and manufacturers requiring strict purity, reproducibility, and precise delivery specifications for mass production. Below, we outline real downstream uses, compliance parameters, technical integration points, and end product outputs forming the backbone of demand for this intermediate.

    1. Wastewater Treatment & Effluent Control

    Municipal and industrial customers incorporate this compound as a coagulant and reducing agent for removing heavy metals, phosphates, and odor-causing agents in effluent streams. Its strong reduction capability facilitates precipitation of soluble species and effective dechlorination prior to discharge. Operators dose the salt at controlled intervals, monitoring redox potential to uphold permitted effluent levels. Dedicated dosing systems and secondary treatment units manage process integration under tightly defined SOPs.

    Industry compliance standards

    • EN 12255-15:2003 (Wastewater Treatment Plants – Chemical Treatment)
    • US EPA 40 CFR Part 133 (Secondary Treatment Regulation)
    • ISO 14001:2015 (Environmental Management)
    • Local authority discharge permits

    Typical usage ratio

    • 50–250 mg/L for phosphorous removal, adjusted by influent concentration and targeted effluent values
    • Dosage refinement based on lab jar testing and real-time effluent monitoring

    Downstream process integration

    • Inline dosing after primary clarification or before tertiary filtration beds
    • Dosing pumps calibrated to inflow volume and contaminant loading
    • Flocculated slurry removed by belt filter presses or clarifiers
    • Compatible with standard PLC-controlled treatment trains

    Final product types

    • Treated process water meeting potable/reuse standards
    • Pipe-discharge compliant with regulatory permits
    • Stabilized sludge suitable for further drying or disposal

    2. Synthesis of Iron Pigments

    Pigment producers in the coatings, plastics, and ceramics sectors employ this intermediate as a precursor for generating high-purity iron oxide pigments. The process depends on carefully controlled hydrolysis or oxidation to achieve consistent color shade and particle morphology. Formulators select this raw material due to its solubility and limited contamination profile, supporting reproducible outcomes at scale. Downstream units implement closed-loop reaction vessels and in-process analytics for batch traceability.

    Industry compliance standards

    • ISO 1248:2014 (Iron Oxide Pigments – Specifications and Methods of Test)
    • ASTM D3721–06 (Pigment Content Determination Standard)
    • REACH registration (Annex VII-IX)
    • GMP for food and cosmetic pigment applications (when required)

    Typical usage ratio

    • Stoichiometric or slight excess relative to oxidation requirements: typically 1.1 parts per part of Fe2O3 pigment target output
    • Concentration adapted to reactor size and process throughput

    Downstream process integration

    • Introduced into aqueous media for oxidation (air, NaOH, or H2O2 methods)
    • Monitored using pH, temperature, and colorimetry at key conversion points
    • Filtration, washing, and calcining performed downstream of oxidation
    • Integrated with pigment slurry finishing circuits

    Final product types

    • Micronized iron oxide red (Fe2O3) pigments
    • Yellow iron oxide pigment batches (goethite FeO(OH))
    • Ceramic glaze raw pigment blends
    • Masterbatch pigment dispersions for plastics

    3. Chemical Manufacturing: Reducing Agent in Organic Synthesis

    Producers in fine chemical and pharma ingredient markets select this compound for reduction of nitroaromatics, carbonyls, and halogenated intermediates, leveraging its strong electron donation profile and controlled solubility. Customers benefit from consistent reactivity, minimizing byproduct formation. Each integration relies on real-time monitoring and staged neutralization to ensure reaction selectivity and regulatory compliance for downstream purification stages.

    Industry compliance standards

    • cGMP (ICH Q7, 21 CFR Part 210/211) for regulated API production
    • USP/NF compendial monographs (where applicable)
    • ISO 9001:2015 (Quality Management for Specialty Chemicals)
    • REACH compliance for European installations

    Typical usage ratio

    • Varies between 0.5–1.5 molar equivalents vs substrate, set by substrate reactivity and scale-up kinetics
    • Pre-customized for batch vs continuous flow synthesis setups

    Downstream process integration

    • Metered to reaction vessels in pre-dissolved or slurry form
    • pH-controlled reactors ensure precise reduction rates
    • Effluent passes through iron removal beds or precipitation units post-reaction
    • Critical in closed-loop production with in-process QC analytics

    Final product types

    • Aniline and haloaniline intermediates
    • Reduced aromatic building blocks for dyes
    • Active pharmaceutical ingredients (APIs) and pharma intermediates
    • Specialty solvents and flavor intermediates

    4. Metal Surface Treatment and Pickling

    Ferrous chloride tetrahydrate is routinely processed in the surface finishing industry as an acid pickling and pre-treatment salt for ferrous and non-ferrous metals. Its chloride ions support the rapid removal of oxide scale and rust, whilst minimizing pitting and base metal attack compared to harsher mineral acids alone. Customers install integrated bath monitoring to achieve consistent surface profiles for subsequent plating, coating, or conversion treating operations.

    Industry compliance standards

    • ASTM A380/A967 (Surface Preparation and Passivation of Stainless Steels)
    • ISO 15730:2000 (Metallic Coatings – Electroless Nickel Coatings on Metals and Non-metals)
    • RoHS and REACH for manufacturing steps involving surface treatments
    • Local workplace safety and emissions standards

    Typical usage ratio

    • Bath concentrations range from 50–200 g/L depending on alloy composition, surface scale load, and desired pickling intensity
    • Adjusted by real-time titration and continuous bath monitoring

    Downstream process integration

    • Charged to acid pickling tanks and spray tunnel units
    • Integrated with automated load/unload systems for industrial throughput
    • Post-treatment rinses minimize drag-out and salt carryover
    • Compatibility with subsequent phosphatizing or anodizing lines

    Final product types

    • Pickled steel and stainless sheet/coil products
    • Surface-activated hardware and fastener components
    • Precision stamped, plated, or painted manufactured goods

    5. Catalyst Preparation for Industrial Processes

    Downstream catalyst makers utilize this tetrahydrate as a precursor for supported iron catalysts and multimetal catalytic systems. Accurate hydration state and impurity control support consistent active site generation during catalyst synthesis. Dedicated blending, drying, and calcining equipment incorporate this material directly into final catalyst shaping and activation, with supporting analytical checks at each stage to meet high-volume technical markets.

    Industry compliance standards

    • ISO 9001:2015 (Quality Systems for Technical Ceramics and Catalysts)
    • EU/US chemical process safety legislation and site-specific GMP guidelines
    • Environmental audit standards for catalyst manufacturing (e.g., EMAS or local equivalents)

    Typical usage ratio

    • Initial inclusion: 5–20% by weight in combined catalyst support blend, modified by final catalyst activity targets
    • Batch-specific adjustment to impurity profile and desired particle structure

    Downstream process integration

    • Pre-dissolved or dry-mixed in slurries for catalyst precursor stages
    • Co-fed with promoters and binder systems during extrusion or granulation
    • Calcination in atmosphere-controlled ovens locks composition and oxidation state
    • QC confirms Fe dispersion across final catalyst matrix

    Final product types

    • Preformed iron oxide catalyst pellets for Fischer–Tropsch synthesis
    • Mixed-metal catalysts for hydrogenation and dehydrogenation
    • Desulfurization catalysts used in oil refining
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    Certification & Compliance
    More Introduction

    Ferrous Chloride Tetrahydrate: Manufacturing Insight and Practical Use

    Real Experience Behind Production

    Producing ferrous chloride tetrahydrate isn’t just about combining iron and hydrochloric acid. It takes steady control over raw material quality, precise reaction temperatures, and reliable isolation of the tetrahydrate crystals. In our plant, we prioritize iron purity, choosing low-sulfur feedstock and monitoring the dissolution process closely. Avoiding oxidized product starts at the source – from keeping air and water exposure in check during every step. Each crystal batch passes methods honed through years of galvanizing, etching, and wastewater treatment supply. As manufacturers, we see the difference not only in the clarity and structure of the crystals but also in the feedback from our industrial users who count on consistent behavior in their own processes.

    Model, Specifications, and Consistency

    Ferrous chloride tetrahydrate leaves our facilities in its recognizable greenish crystalline form. We follow established industry practices, with our current model providing minimum assay levels at 98%, measured on a dry basis. Iron (II) purity matters less in a lab than in an industrial installation, where trace metals or residual acid can disrupt reactions and corrode equipment. Moisture content stays controlled by tight packing and quick transfer from crystallizer to final packaging. We hit these numbers through continuous, real-time analytical checks and an old-fashioned culture of pride in craft, where every batch sheet is signed off by the shift lead. Each lot’s uniform crystal size and clear composition reflect our plant’s deep production experience.

    How We Use It and What We Hear from Others

    We have supplied ferrous chloride tetrahydrate to customers in dye manufacturing, textile treatment, and water purification for decades. In dye plants, it’s the essential reducing agent when private formulations call for a slow, predictable supply of Fe(II) ions, especially when tin or zinc alternatives threaten downstream environmental compliance. Textile operators reach for our tetrahydrate as the preferred mordant for delicate fibers, demanding bright color yield without unwanted metal contamination. International plating outfits have reported fewer instances of deposit blemishes after switching to tightly controlled tetrahydrate – a seemingly small improvement that drives up final product acceptance rates.

    Our production crew has learned, after years of listening to wastewater plant chemists, that a steady supply of tetrahydrate often means direct, efficient phosphate removal with low ferric carryover. That cuts downstream sludge handling costs and simplifies compliance reporting. Electroplaters who have made the switch speak frankly about batch consistency: less variation in crystal water and Fe(II) content means fewer surprises mid-shift.

    What Sets Tetrahydrate Apart from Other Ferrous Salts

    Ferrous chloride exists in a handful of forms, but not all behave the same. Anhydrous ferrous chloride comes as a dry powder—fine for sealed synthesis systems, but less reliable in situations open to air. As a tetrahydrate, each crystal binds four water molecules, stabilizing the Fe(II) valence and making for a safer, easier-to-handle solid during weighing and transfer. No drifting hydrochloric odor, no rampant hydrolysis, no lumpy caking. This means our tetrahydrate works dependably in humid, real-world production areas, and remains free-flowing from sack to process tank.

    Many customers initially ask about using cheaper iron(II) sulfate. We understand budgets, but in our own trials, sulfate brings extra sulfate ions and more iron(III) contamination, especially when stored wrong or sourced from inconsistent suppliers. That means unpredictable downstream impact, including increased maintenance demands in filtration systems and higher chemical demand in effluent polishing. Ferrous chloride tetrahydrate, on the other hand, gives a highly soluble iron source that comes into solution quickly, avoiding the sluggish dissolution or surprise residue left behind by other iron salts.

    Safe Handling and Longevity in Industrial Use

    As a direct manufacturer, we don’t just care about producing a high-quality product; we care about what happens to it once it leaves our gate. Our operations team has been hands-on in many customer plants, helping install and test new ferrous solution dosing setups. In environments where temperature and humidity swing wildly across seasons, the tetrahydrate’s robust stability lowers risk around spills, unexpected fumes, or reactivity. Our customers find that bags or drums of tetrahydrate keep longer in storage than anhydrous forms or lower-purity hydrates, which can form clumped, oxidized mounds that must be discarded or sent for reworking.

    We have partnered with customers during technical audits. Some switch to our tetrahydrate after tired of dealing with dusting from fine ferrous powders, which create safety headaches for operators and raise airborne iron levels above workplace best practice limits. Product that pours cleanly, dissolves quickly, and leaves minimal residue in tanks and pipelines protects both people and process.

    Serving a Range of Industries with Real-World Support

    Through direct dialogue with end-users, we’ve improved bulk packaging—from lined bags that resist puncture and water ingress, to larger flow bins for high-volume applications. Our plant logistics team doesn’t rely on third-party reps for feedback. We visit wastewater plants, chemical blending facilities, plating lines, and dye manufacturers to watch how product moves from storage to solution tank. These visits shape our process changes and improve the next production runs.

    One example stands out: a customer in the printed circuit field needed consistent Fe(II) supply with extremely low metallic impurity for etching copper traces. Working side by side with their quality team, we adjusted our purification wash steps, swapped an older filter press for a new plate and frame unit, and tracked every test batch until their reject rates fell below half the industry average. These kinds of improvements benefit every buyer after that, not just the original customer.

    Environmental and Regulatory Considerations

    Public and private treatment plants face ever-tightening rules for metals and phosphorus discharge. Ferrous chloride tetrahydrate acts as a mainstay because its chemistry supports faster, more complete reactions at lower iron dosing levels. Our regulatory affairs group keeps a close eye on local and international guidelines, shifting raw material purchasing and end-product testing to satisfy not just our own quality targets but also shifting benchmarks on heavy metal traces and acid purity.

    We push to reduce waste at every step. Recycle streams from our crystallizers go back for reprocessing, and iron-rich sludge from side reactions gets processed rather than landfilled. We log every batch test for heavy metals, and only approve lots that meet strict internal cutoffs. By running our own emission point checks and mass balance reviews, we minimize not just waste, but also the sort of accidental contamination that comes from trying to cut corners on byproduct management.

    Long-Term Outlook and Process Improvements

    The demand for ferrous chloride tetrahydrate tracks closely with population growth, urbanization, and the shift toward stricter water standards. As our direct relationships with buyers have grown, we’ve diversified our process controls—moving from older manual monitoring to automated in-line sensors for acidity, iron content, and water pickup. The value of these investments shows up in fewer customer complaints, smoother downstream processes, and less rework on our side.

    Operators report that consistent tetrahydrate performance shortens equipment cleaning time and reduces the need for extra clarifiers, which saves on both labor and consumables. We’ve introduced a program for regular joint audits, sending our plant chemists to customers’ facilities to troubleshoot and recommend small changes—new feed mechanisms, better tank stirring, or temperature control—to extract maximum value from every kilogram purchased.

    Ongoing Challenges and Solutions

    Challenges come in many forms, from rising cost of iron and acid, to shipping constraints and packaging reformulation. After experiencing disruptions caused by international freight delays, our supply chain managers reviewed local sourcing options, and built new partnerships with domestic steel producers who guarantee both chemical and physical traceability of scrap. This shift allows us to guarantee reliable, on-time supply and audit every batch for non-conforming metals before it enters the production cycle.

    On occasion, operators encounter handling issues as production volumes ramp up—a sticky residue here, misplaced drum there, or a mistaken exposure to air leading to mild surface rust. We don’t brush these aside. Lessons from years in the field have led us to provide not only revised application guides but also hands-on training with plant crews who are reviewing or scaling up their dosing systems. Our technical staff makes site visits part of the new customer onboarding, using real process data to recommend transfer systems, safe storage layouts, and compatible dosing lines that fit the realities of each site’s workforce.

    For those working in high-throughput plants with variable inflows, having a stable, predictable iron source means being able to automate chemical feeds confidently. Our team works directly with automation and controls engineers to test pump compatibility, ensuring no surprise precipitation or clogging at the injection point, and minimal downtime for tank changeovers. These details, learned after plenty of real-world problem solving, help explain why our tetrahydrate stays the choice for demanding applications.

    Improvements Through Customer Feedback

    We believe in listening to the operators on the ground. Their feedback builds product improvements over time. One batch of ferrous chloride might run fine through a lab glass column but slow down or crust up a full industrial transfer pipe. Likewise, a fine crystal grade preferred in small-scale dye work sometimes gives too much dust for large-scale magnetic separation jobs. We’ve created multiple size cuts and recalibrated our drying times based on these real observations.

    Customers who handle reactive or sensitive raw materials want transparency about what’s coming off our line. That’s why we give complete batch histories and, if needed, open our plant for inspection by technical teams. Over time, these visits have led to shared improvements in raw material selection, packaging, traceability, and even plant hygiene.

    Why Consistent Product Matters

    Tetrahydrate, as produced in our facility, gives assurance of result, not just chemical composition. Consistency saves operators from surprise downtime, helps procurement managers plan inventory, and lets process engineers tune their systems for peak performance. Our product helps stabilize their operation—fewer interruptions, reduced out-of-spec rework, less chemical waste. Each of these improvements gets passed down the chain, turning a small upstream upgrade into thousands of dollars’ savings, safer working conditions, and easier regulatory compliance.

    Some top-drawer metal treaters rely on us because they’ve learned, across several years, what a stable ferrous supply does for their bottom line. We document our every adjustment and partner with industry experts to raise standards year after year. We’ve seen competitors rush for cheaper inputs or skip essential post-production testing, only to backtrack after batches fail in the field. Our approach treats ferrous chloride tetrahydrate as more than a commodity; it is an integral part of our partners’ success.

    Summary: The Manufacturer’s Role and Responsibility

    We produce and own our product, standing behind every bag and drum without putting layers between our process and the customer. The knowledge we gain from the floor—mixing, filtering, drying, packing—flows into technical guides, on-site support, and quick problem solving. Ferrous chloride tetrahydrate, in our operation, embodies a commitment to better results for everyone who relies on it: faster process chemistry, safer handling, fewer equipment stoppages, and environmental compliance met with confidence. It’s not just about specs and test results; it’s about real plant managers depending on repeatable outcomes, batch after batch, year after year.