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Ferrous Ammonium Sulfate Hexahydrate

    • Product Name Ferrous Ammonium Sulfate Hexahydrate
    • Alias Mohr's salt
    • Einecs 233-151-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    388965

    Chemical Name Ferrous Ammonium Sulfate Hexahydrate
    Other Names Mohr's Salt
    Chemical Formula Fe(NH4)2(SO4)2 · 6H2O
    Molar Mass 392.14 g/mol
    Appearance Light green crystalline solid
    Solubility In Water Highly soluble
    Melting Point Approximately 100°C (decomposes)
    Density 1.86 g/cm³
    Cas Number 7783-85-9
    Odor Odorless
    Ph 1 Solution Approximately 3.5 - 4.5
    Stability Stable under recommended storage conditions
    Common Uses Analytical chemistry, water treatment, reducing agent
    Hazard Statements May cause eye and skin irritation

    As an accredited Ferrous Ammonium Sulfate Hexahydrate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging is a sealed 500g plastic bottle, labeled “Ferrous Ammonium Sulfate Hexahydrate,” with hazard symbols and safety instructions.
    Shipping Ferrous Ammonium Sulfate Hexahydrate should be shipped in tightly sealed containers, protected from moisture and incompatible materials. It is not classified as hazardous for transport but should be clearly labeled. Store and transport in a cool, dry environment, adhering to regulations for chemical safety and appropriate documentation requirements.
    Storage Ferrous Ammonium Sulfate Hexahydrate should be stored in a tightly closed container in a cool, dry, and well-ventilated area, away from incompatible substances such as strong oxidizers and acids. Protect it from moisture and light to prevent decomposition. Store in original, labeled containers, and avoid exposure to air to minimize oxidation and maintain the chemical’s stability.
    Application of Ferrous Ammonium Sulfate Hexahydrate

    Applications of Ferrous Ammonium Sulfate Hexahydrate in Industrial Manufacturing

    Ferrous Ammonium Sulfate Hexahydrate plays a critical role in several specialized industrial sectors where precise iron(II) ion introduction, redox control, and analytical reliability are required. As a manufacturer, we supply high-purity material that supports demanding production and laboratory environments. The following sections outline the most significant industrial application scenarios, each distinguished by regulatory expectations, practical formulation, integration in process flows, and the specific nature of finished goods relying on this raw material.

    1. Analytical Reagent Formulation for Laboratory and Process Titration

    In chemical analysis, this compound serves as a primary standard for redox titrations, especially in permanganometry and actinometry, where calibration reliability is critical. Laboratories and industrial QC lines rely on the compound’s precise stoichiometry to prepare N/10 and N/20 standard solutions for iron(II)-based volumetric determination of oxidizing agents in water, food, pharmaceutical, and environmental samples.

    Industry compliance standards

    • ISO 6353-1:1982 (Reagents for chemical analysis – Part 1: Specifications)
    • USP Reagent Specifications
    • ASTM E200 (Standard Practice for Preparation of Standard Solutions for Chemical Analysis)
    • Quality protocols by various regulatory analytical labs

    Typical usage ratio

    • Direct preparation of approximately 39.2 g/L (for 0.1N solution), adjusted by purity and desired normality; final ratio depends on calibration requirements in each analytical method.

    Downstream process integration

    • Added during solution preparation steps, using accurate weighing and dissolution in deionized or double-distilled water, followed by volumetric dilution for analytical standard calibration.

    Final product types

    • Certified reference solutions for titration
    • Calibration standards for water quality control
    • Reagent kits for pharmaceutical and food analysis
    • QA/QC control standards in petrochemical labs

    2. Water Treatment: Chromium (VI) Reduction in Industrial Effluent

    In industrial water treatment, this iron(II) salt is introduced as a reducing agent to lower hexavalent chromium (Cr(VI)) concentrations by converting it to the less toxic trivalent form, allowing downstream precipitation and removal. Metal plating, leather tanning, and pigment manufacturing plants integrate it within dedicated reaction tanks to meet wastewater discharge requirements.

    Industry compliance standards

    • U.S. EPA 40 CFR Part 433 (Effluent Guidelines for Metal Finishing)
    • China GB 8978-1996 (Integrated Wastewater Discharge Standard)
    • EN 12255-10:2001 (Wastewater Treatment Plants — Chemical treatment)
    • REACH Regulation (EC) No 1907/2006 for process chemicals

    Typical usage ratio

    • Dosage varies based on influent Cr(VI) levels; generally 1.2–1.5 times the stoichiometric equivalent to ensure complete reduction, for typical industrial influent, 250–600 mg/L is applied, with on-line adjustment based on real-time Cr(VI) analysis.

    Downstream process integration

    • Dosed into continuous flow or batch reaction basins ahead of clarification/precipitation stages, integrated with pH adjustment systems and automated dosing controls for compliance assurance.

    Final product types

    • Treated industrial wastewater compliant with discharge standards
    • Process sludge for hazardous waste management
    • Compliant effluent for reuse in non-potable water applications

    3. Electroplating Industry: Additive in Iron Plating Baths

    Electroplating facilities depend on this crystal as a source of ferrous ions in iron plating baths, promoting stable deposition of metallic iron on substrates. It allows precise control of bath chemistry, fine-tuning the iron(II)/(III) ratio to influence plating speed, brightness, and deposit integrity for various steel parts, fasteners, and hardware products where coating durability and appearance are critical.

    Industry compliance standards

    • ISO 6158:2021 (Electroplated coatings — Technical requirements)
    • RoHS Directive (2011/65/EU) compliance for finished articles
    • IEC 62321 (Determination of certain substances in electrical and electronic products)
    • Customer-specific automotive and aerospace plating standards

    Typical usage ratio

    • 0.5–3 g/L, optimized according to desired deposit thickness, bath volume, current density, and type of substrate; iron(II) concentration monitored and balanced with other bath additives.

    Downstream process integration

    • Charged into aqueous bath solutions and maintained at setpoints with analytic feedback; added at make-up and replenishment stages via solution dosing or dissolving crystals directly in bath circulation lines.

    Final product types

    • Iron-plated machine components
    • Fasteners with corrosion-resistant coatings
    • Decorative steel products for consumer hardware markets
    • Precision automotive connectors and fittings

    4. Chemical Manufacturing: Intermediate Reducing Agent in Dye and Pigment Synthesis

    Many dye and pigment manufacturers utilize iron(II) compounds as selective reducing agents in organic synthesis, particularly in producing vat dyes, indigo derivatives, and azo dyes. The compound is added during reduction stages to maintain favorable redox conditions which directly influence color purity, conversion rates, and by-product control in batch or semi-continuous synthesis reactors.

    Industry compliance standards

    • OEKO-TEX Standard 100 Annex 6 (for dye intermediates safety)
    • REACH Regulation (EC) No 1907/2006 for raw material registration
    • China GB/T 21866-2008 (Pigment and dye product quality)
    • National quality inspection standards for specialty chemicals

    Typical usage ratio

    • 0.2–1.5 mol equivalent per mol of reducible substrate in process recipes, with actual ratio fine-tuned via oxidation-reduction potential (ORP) monitoring to avoid over-reduction and inconsistent color.

    Downstream process integration

    • Fed as a solid or pre-dissolved solution into reduction vessels at designated stages under controlled temperature, with continuous monitoring and feedback dosing based on in-line redox measurements.

    Final product types

    • Vat dyes and leuco forms for textile dyeing
    • Indigo dyes for denim production
    • Specialty azo pigments
    • Chemical intermediates for advanced polymer colorants

    5. Pharmaceutical Industry: Limiting Reactant in Standardization of Ferric Compounds

    In pharmaceutical quality control and formulation, this iron(II) complex is used to precisely standardize ferric chloride and ferric ammonium sulfate solutions by titration. Accurate quantification delivers reliable iron content for injectable preparations and ensures compliance with pharmacopoeial iron assay requirements during batch release protocols.

    Industry compliance standards

    • United States Pharmacopeia (USP) – General Chapter <1790> Standard Solutions
    • European Pharmacopoeia (Ph. Eur.) 2.2.20: Absorption spectrophotometry
    • Chinese Pharmacopoeia (ChP 2020) – Iron Compound Assays
    • WHO Good Manufacturing Practices for Pharmaceuticals

    Typical usage ratio

    • Based on equivalence: 1 mol per mol of ferric ions in titration; the exact amount is calculated by standardization procedure and adjusted to account for iron(II) content and hydration state in the crystal.

    Downstream process integration

    • Prepared as titration solution and used directly in laboratory and pilot batch assays for iron content verification prior to medicine batch filling and QC sign-off.

    Final product types

    • Iron-based injectable formulations
    • Standardized ferric salt solutions for pharma synthesis
    • Published assay results meeting regulatory dossiers
    • Quality-controlled iron supplements
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    Certification & Compliance
    More Introduction

    Ferrous Ammonium Sulfate Hexahydrate — A Manufacturer’s Perspective

    True Reliability Starts With Real Chemical Know-How

    In the world of laboratory and industrial chemistry, few compounds carry as much daily utility as Ferrous Ammonium Sulfate Hexahydrate. We have seen the shift in demand across research, water treatment, and analytical workflows. Ferrous Ammonium Sulfate Hexahydrate, also called Mohr’s Salt, shows up year after year in orders from quality control labs and teaching institutions. As a direct manufacturer, our experience spans countless production cycles, and what stands out every time is how this product quietly anchors many fundamental analytical procedures.

    About the Product: Pure, Consistent, Trusted by the Chemist’s Eye

    We produce Ferrous Ammonium Sulfate Hexahydrate in granular or crystalline form. Our typical production uses reagent grade quality, with a chemical formula of Fe(NH4)2(SO4)2·6H2O. As the industry sees rapid changes in purity standards, our tight focus on batch consistency, moisture content, and color uniformity comes from years working with demanding contracts: calibration labs, academic institutions, and process industries. Our reference range for iron content falls within all accepted major chemical society standards, routinely exceeding minimum requirements to satisfy precision work.

    Technicians regularly comment on the pale green, clean crystal, which responds with predictable solubility in distilled water. Shelf life relies on careful packaging and storage, which is why all units leaving the factory are sealed against both atmospheric and incidental exposure. Moisture management is fundamental—within our own production area, we've tracked even minor air changes and their effect on finished lots. By tuning our process, we've reduced variation to the point that repeat customers routinely cite ease of solution preparation and reproducible results, both in titrations and in general chemical analysis.

    Meeting the Needs of Redox Titration Procedures

    Most of those working in wet chemistry learned early on that Mohr’s Salt stands at the center of one of the classic redox titration methods. For potassium dichromate or permanganate assays, you need a ferrous standard that is straightforward to prepare, stable, and reliable from batch to batch. The value of working with a freshly manufactured, well-mixed lot cannot be overstated. Impurities, even at low ppm levels, have a direct effect on endpoint detection and on the traceability of results. We have worked through audits from outside laboratories who test for silicates, chlorides, and residual nitrates in supplied Mohr’s Salt. Only batches showing consistent absence of detectable foreign ions make the cut for our highest grade product line.

    Redox titration brought this salt its reputation. Ferrous Ammonium Sulfate Hexahydrate owes its stability to the crystal lattice maintained by the double salt structure. In the daily grind of a QC lab, convenience is everything, and a direct, highly soluble ferrous ion source lets chemists move quickly through routine analyses. Our customers often organize routine training courses using this product as a primary standard, simply because it resists air oxidation far better than ferrous sulfate alone.

    Educational Laboratories—The Roots of Mastery

    For teachers setting up practical classes, reliability in chemical behavior comes first. With Mohr’s Salt, instructors demonstrate the difference that a stable ferrous ion source makes in redox titrations, and students gain confidence by consistently reaching the endpoint—no wild fluctuations in color change or inconsistent results. Over the years, feedback from instructors tells us that our product produces predictable, sharp endpoints, while allowing students to focus on the concepts at hand rather than troubleshooting errors from impurities or decomposition.

    Educational facilities ordering in bulk often test each new lot upon arrival. They compare it to house standards and check for losses in iron content, as older, poorly stored salts can suffer. We back up our shipments with documentation, but our open-door policy means that staff can always call in and discuss specific test conditions or ask for details about raw material sourcing, packaging material traceability, or test methods used in batch QC.

    Comparisons: How Mohr’s Salt Stacks Up Against Other Iron Salts

    Some newcomers to the chemistry world wonder why not use ferrous sulfate or other iron(II) compounds instead. If you’ve ever prepared solutions for standardization work, the reasoning becomes clear fast. Pure ferrous sulfate heptahydrate, though useful, oxidizes in air much more rapidly, especially when exposed to moisture or heat, leading to formation of brown ferric by-products. In our experience, if you pull from an open bottle of this material, results can drift, and solution preparation turns into a guessing game.

    Mohr’s Salt’s structure keeps iron in the ferrous state for much longer. The ammonium ions and sulfate counterions form a tighter, more protective matrix. In real terms, that means students and analysts get better reproducibility and less waste—no expensive rework, no interruptions for solution remakes. The green crystals are not just easier to store—they’re straightforward when weighing out for solution—no need for double-checking calculated concentrations every week due to rapid degradation. Over years on the production floor, we’ve collected a library of returned sample data from outside labs. The clear trend: our batches maintain their declared iron content compared to ordinary ferrous sulfate—even after prolonged shelf exposure when packaged with basic humidity precautions.

    Ferric salts serve very different purposes and would upset the redox balance in titrations. Using ferric ammonium sulfate or ferric chloride leads to totally different assay results and can ruin a whole round of testing, which costs money and time, especially in regulated labs. For anyone relying on iron(II) chemistry, as in colorimetry or direct reduction steps, Mohr’s Salt holds certain advantages that other simple salts cannot match.

    Why Stability Makes the Difference

    With repeated orders shipping to customers with high-volume routine analysis, the practical advantages become obvious. In many urban water treatment plants, for instance, our salt acts as a reliable standard for iron testing—confirming removal rates or calibrating colorimetric procedures. We’ve set up collaborative programs with municipal labs to fine-tune our production process after tracking how batch differences affect final readings. We learned early that water vapor, trace calcium, and airborne particulates enter the mix if a plant doesn’t follow strict storeroom protocols. So, our default packaging comes vacuum-sealed or with desiccant, based on customer preference, and we regularly sample returned product for potential shifts in crystal hydration.

    In instrument calibration, analysts want assurance that the calibration curve doesn’t drift mid-project. Mohr’s Salt’s consistent performance means less downtime, fewer recalibrations, and more productive throughput. We routinely sample our product for oxidation markers by UV-Vis and classical wet chemistry—a routine evolved after one too many ruined batches before we overhauled the old packing line. Thanks to clean, well-ventilated, temperature-controlled storage, we've managed to ship out lots with practically zero out-of-spec returns year after year.

    The Real-World Impact in Trace Analysis and Specialized Industries

    In environmental monitoring—tracking iron contamination in soils, waste streams, or agricultural run-off—precision is everything. Analyzing iron(II) concentrations requires starting with a primary standard that won’t lose its reactivity overnight. Ferrous Ammonium Sulfate Hexahydrate gives just that confidence. We’ve worked with labs developing high-throughput water screening panels where cost and time can multiply with the smallest error in standardization. By controlling particle size and free-flowing characteristics, we help users hit their detection limits every time—translating small production tweaks into big cost-savings for customers.

    Electroplating and photographic industries also turn to Mohr’s Salt. In photo labs, the salt’s stability means consistent reducing power, which makes a difference in developing high-quality negatives. In plating, small changes in iron ion concentration can shift the quality of the finished coat. Supplying directly to these industries gives us perspective on how even subtle impurity shifts play out through to finished goods. In response, we’ve invested in more rigorous washing and drying steps, allowing customers to depend on the same performance from every drum they order.

    Beyond the Lab: Safety, Storage, and Handling Insights

    Shipping out tons of Ferrous Ammonium Sulfate Hexahydrate every year has taught us a lot about material safety and everyday handling. Unlike some other ferrous salts, this compound doesn’t pose excessive hazards under normal use, but any large-scale chemical operation learns fast that good handling habits cut down on costly spills, health incidents, or complaints.

    We focus on strong, puncture-resistant plastic or laminated bags for our bulk and laboratory packs. That simple measure almost erased complaints about caking, hardening, or package rupture in humid seasons. For laboratories, we recommend air-tight jars or plastic bottles kept in cool, dry areas—our warehouse staff follows the same regime to prevent loss from the shelves. Because ammonium compounds do give off a faint ammonia odor in very humid conditions, our team keeps an eye on warehouse humidity and runs regular air checks. In high heat, we use insulated containers for long-haul shipments, making sure the product gets to end-users uncompromised.

    We answer safety data sheet requests directly and never outsource storage instructions. Our own experience dealing with moisture pick-up and accidental mixing with other lab salts saves our clients from headaches. We remind users not to mix with oxidizers or store next to acids in shared chemical closets—years of direct incident reports have underlined the value of simple separation and clear labels.

    Transparency, Accountability, and the Pursuit of Quality

    Supplying a chemical like Ferrous Ammonium Sulfate Hexahydrate is more than running a batch process. Each shipment tells the story of years refining process controls, raw material acquisition, and in-house audits. We run multiple QC checks, not just for iron content, but also for ammonium, sulfate, trace heavy metals, and hydration. Our clients have open access to COAs that reflect actual test data—not generic specs. On more than one occasion, a client has rung up with a technical spike in their control charts, and after joint investigation, a procedural error at the user’s end, not the chemical, wound up as the culprit. The partnership approach keeps both sides sharp.

    Working straight with analytical chemists and educators, fact-based transparency builds real trust—especially when dealing with high-stakes testing in food analysis, forensics, or clinical research. Direct transfer of manufacturing facts—not just sales pitches—creates that confidence in our product’s traceability and repeat behavior. That’s one reason why our manufacturing paperwork stays available for post-order traceability, and why we never dilute results with vague batch labeling.

    Helping Customers Solve Real Challenges

    We have seen cases where switches from other iron salts caused unexplained test deviations or instability in calibration curves. Customers brought in comparison samples, and our technical team broke down the root cause—a simple switch to freshly made Mohr’s Salt cleaned up stability issues and brought back the expected performance. In some labs, analysts used legacy purchasing channels, which led to degraded material in storage. By moving to smaller, regular deliveries, together we aimed for minimal shelf time and fresher chemistry.

    Technical support is not a hotline, but day-to-day calls and email exchanges between manufacturing staff and end-users—discussing test setups, solution aging, and fine-tuning usage to local water or storage conditions. A big part of our production improvement came from direct feedback cycles. Returning spent packaging for analysis, comparing endpoint photographs under different lighting, and loading up calibration data to catch batch-to-batch drift—all of this drives our investments in new process equipment and tighter pre-shipment checks.

    Outlook: Meeting Tomorrow’s Expectations for Purity and Performance

    In the wider landscape of chemical supplies, quality is a moving target. Markets around the world are putting new focus on transparency, traceability, and repeatable results. Our manufacturing response is to raise the bar for raw material screening, automation, and data sharing during each production run. Increasingly precise digital monitoring of reaction conditions, filtered process water, and controlled cooling cycles have helped us keep output quality steady, which matters to universities and research facilities just as much as to big water plants.

    We watched the trends—more labs running automation, routine multi-analyte panels, high-throughput analytical cycles. They do not have time for randomness in their standards. As customer demand moves towards ready-made standard solutions, we’re scaling up our blending and pre-weighed portion packs, combining product integrity with maximum convenience. Smaller packs for teaching labs, vacuum-sealed drums for process industries—each matches a real field-tested need that has come up year after year.

    The Ongoing Dialogue Between Manufacturer and Lab

    Any chemical only earns its reputation from what researchers and analysts say after long hours at the bench. Our responsibility as a manufacturer is to keep that conversation going. We pay attention and adapt: from packaging to documentation, from batch logs to customer-specific purity checks. We don’t take the product or our customers for granted—every new challenge, whether a request for a novel impurity test or a packaging tweak for export markets, directly feeds into our next production cycle.

    Ferrous Ammonium Sulfate Hexahydrate has been around for a century in the lab. Our role has been to keep pace with technology, regulation, and end-user insight. Through transparency in process and a track record that customers have seen in their own results, we continue to deliver a product that does what it says. In today’s environment, that means not just ticking the boxes, but demonstrating real consistency, customer support rooted in field experience, and a willingness to respond to changing needs.

    Those facts ground us, inform every lot we produce, and give our customers the stability and flexibility they count on. The dialogue stays open, the standards stay high, and every shipment reflects a history of earned trust.