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Ethyltrimethoxysilane

    • Product Name Ethyltrimethoxysilane
    • Alias ETMS
    • Einecs 203-550-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    409187

    Cas Number 1840-07-1
    Molecular Formula C5H14O3Si
    Molecular Weight 150.25 g/mol
    Appearance Colorless liquid
    Boiling Point 137-139 °C
    Density 0.94 g/cm3 at 25 °C
    Flash Point 24 °C (closed cup)
    Refractive Index 1.374-1.376 at 20 °C
    Solubility In Water Hydrolyzes
    Purity Typically ≥98.0%
    Vapor Pressure 7 mmHg at 20 °C

    As an accredited Ethyltrimethoxysilane factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Ethyltrimethoxysilane is supplied in a 500 mL amber glass bottle with a secure cap, labeled with hazard and safety information.
    Shipping Ethyltrimethoxysilane should be shipped in tightly sealed containers, protected from moisture and incompatible substances. It is typically classified as a flammable liquid, requiring transportation according to relevant hazardous materials regulations. Ensure proper labeling and documentation. Store and ship in a cool, well-ventilated area, away from heat, sparks, and sources of ignition.
    Storage Ethyltrimethoxysilane should be stored in a cool, dry, and well-ventilated area, away from heat sources, moisture, and incompatible materials such as strong acids or bases. Keep containers tightly closed and properly labeled. Protect from direct sunlight and avoid exposure to air, as it can hydrolyze. Use approved, chemical-resistant storage containers to prevent leaks or contamination.
    Application of Ethyltrimethoxysilane

    Applications of Ethyltrimethoxysilane in Industrial Manufacturing

    Ethyltrimethoxysilane is a critical functional silane widely adopted by manufacturers for its role as a silane coupling agent, surface modifier, and crosslinking promoter in high-value industrial formulations. Its controlled reactivity and organofunctional compatibility enable precise integration into targeted processes where enhanced adhesion, improved water repellency, and advanced material performance are essential for downstream applications.

    1. Silane Coupling Agent in Glass Fiber-Reinforced Composites

    In advanced glass fiber-reinforced plastics (GFRP) production, manufacturers use ethyltrimethoxysilane for chemically bonding glass surfaces to organic resin matrices. Its introduction onto glass fiber bundles improves resin wet-out and the interfacial shear strength, resulting in composite components with high mechanical durability for automotive structural and electrical insulation applications.

    Industry compliance standards

    • ASTM D578 (Standard Specification for Glass Fiber Strands)
    • ISO 1268 series (Glass Fibre Reinforced Plastics — Preparation of Plates)
    • UL 94 (Flammability Standard for Plastics Materials)
    • RoHS Directive (2011/65/EU) for restricted substances

    Typical usage ratio

    • 0.5–2.0% by weight of glass fiber, dependent on fiber diameter and target interface chemistry

    Downstream process integration

    • Direct addition in aqueous or solvent-based glass fiber sizing baths prior to drying and resin impregnation

    Final product types

    • GFRP automotive body panels
    • Electrical cable insulation rods
    • Wind turbine blade components
    • Composite circuit board substrates

    2. Water Repellent Additive for Construction Silane Sealers

    Formulators manufacturing silane-based concrete sealers use ethyltrimethoxysilane to impart hydrophobic barriers within mineral pores, which extends surface longevity and reduces absorption of potentially damaging water, salts, and de-icing agents. Its molecular size supports high diffusion into dense concrete, providing deeper and longer-lasting protection against freeze-thaw cycling and chloride ingress, especially in highway, bridge, and parking structure maintenance.

    Industry compliance standards

    • EN 1504-2 (Products and systems for protection and repair of concrete structures)
    • ASTM C642 (Density, Absorption, and Voids in Hardened Concrete)
    • AASHTO T259/T277 (Chloride Ion Penetration Tests for Concrete)

    Typical usage ratio

    • 5–20% by weight of active silane content in silane emulsion or solvent-based sealer formulations; adjustment by substrate porosity and performance requirements

    Downstream process integration

    • Addition during the sealer blending phase, followed by direct application (spray or roll) onto cured concrete surfaces as a penetrating treatment

    Final product types

    • Highway bridge deck sealers
    • Industrial warehouse floor protectants
    • Parking garage water-repellant coatings
    • Precast concrete surface treatments

    3. Crosslinker in Polyethylene Cable and Pipe Compounds

    Wire and cable compounders and manufacturers of crosslinked polyethylene (PEX) use ethyltrimethoxysilane as a functional crosslinking agent that reacts under controlled moisture and catalyst conditions. This process generates covalent siloxane linkages, increasing thermal resistance, chemical stability, and mechanical performance of the final polyolefin product, especially for long-life cable insulation and hot/cold potable water piping systems.

    Industry compliance standards

    • IEC 60502 (Power cables with extruded insulation and their accessories)
    • ASTM F876/F877 (PEX Tubing for Hot and Cold Water Distribution Systems)
    • UL 1581 (Electrical Wires, Cables, and Flexible Cords)

    Typical usage ratio

    • 1.0–2.5% by weight added to polyethylene during melt compounding, with precise adjustment based on desired crosslink density and processing route

    Downstream process integration

    • Incorporation in polymer melt during reactive extrusion before pelletization, often in combination with catalyst and stabilizers

    Final product types

    • Crosslinked polyethylene (PEX) plumbing pipes
    • XLPE cable insulation and jacketing
    • Underground power distribution cables
    • High-temperature tubing for fluid transport

    4. Surface Modification in Silica-Filled Rubber Compounds

    Tire and industrial rubber manufacturers utilize ethyltrimethoxysilane for treating precipitated silica fillers before compounding. This surface treatment enhances bond formation between the inorganic filler and the organic rubber matrix, leading to improved abrasion resistance, tensile strength, and rolling resistance reduction in tires and performance rubber parts, meeting strict automotive and equipment manufacturing criteria.

    Industry compliance standards

    • ISO 14001 (Environmental Management System for tire plants)
    • SAE J2979 (Vehicle Tire Performance Standards)
    • ASTM D412 (Rubber–Tensile Properties)
    • REACH Regulation (1907/2006/EC – Substances of Very High Concern)

    Typical usage ratio

    • 2–8% by weight of silica filler; specific level dependent on silica surface area and target compound properties

    Downstream process integration

    • Pre-treatment of silica in mixer before incorporation into compounding process, or in situ addition during masterbatch preparation

    Final product types

    • Passenger and commercial vehicle tire treads
    • Sealing gaskets for automotive and industrial equipment
    • Dynamic rubber mounts and vibration isolators
    • High-performance conveyor belts

    5. Primer for Adhesion of Paints and Coatings on Inorganic Substrates

    Coating manufacturers serving the industrial maintenance sector formulate primers using ethyltrimethoxysilane to anchor organic polymers to glass, metal oxide, or ceramic surfaces. The silane’s reactivity with surface hydroxyl groups promotes durable chemical bonding, which stabilizes topcoats applied in environments exposed to severe weathering or chemical cleaning, as required for transportation infrastructure, electronics, and heavy machinery protection.

    Industry compliance standards

    • ISO 12944 (Corrosion Protection of Steel Structures by Protective Paint Systems)
    • ASTM D3359 (Standard Test Methods for Measuring Adhesion by Tape Test)
    • Directive 2004/42/EC (VOC limits in coatings)

    Typical usage ratio

    • 0.2–1.0% by weight in primer or pretreatment solution, tailored to substrate reactivity and process conditions

    Downstream process integration

    • Incorporation into aqueous or solvent-based pretreatment baths, or blending into primer formulations before application to cleaned and pretreated substrates

    Final product types

    • Protective primers for steel bridges and infrastructure
    • Glass and ceramic paint systems
    • Metal oxide semiconductor device coatings
    • Industrial machinery primer coatings

    6. Binder Enhancement in Sol-Gel Derived Coatings

    Producers of high-adhesion sol-gel coatings for electronic and optical devices use ethyltrimethoxysilane for enhancing binder crosslink density. Its hydrolysis and condensation reactions support formation of uniform siloxane networks, providing scratch resistance and low surface energy in end-use films for display screens, photovoltaic modules, and anti-reflective coatings in demanding applications.

    Industry compliance standards

    • IEC 61215 (Crystalline Silicon Terrestrial Photovoltaic Modules)
    • ISO 9211 (Optics and photonics — Optical coatings)
    • RoHS and WEEE Directives for electronics safety and material traceability

    Typical usage ratio

    • 5–15% by weight of total sol-gel precursor content; level set based on target film thickness and substrate wetting characteristics

    Downstream process integration

    • Added to sol-gel precursor solution before hydrolysis and condensation reactions, followed by dip, spin, or spray coating methods on device substrates

    Final product types

    • Anti-reflective coatings for photovoltaic panels
    • Display coatings for handheld electronics
    • Scratch-resistant optical films
    • Protective functional glass coatings
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    Certification & Compliance
    More Introduction

    Ethyltrimethoxysilane: Reliable Chemistry for Long-Term Performance

    Looking Beyond the Label—What Ethyltrimethoxysilane Really Delivers

    Many years producing Ethyltrimethoxysilane have shown us that demand never stands still. Users expect more than a simple functional group on a datasheet—they want trouble-free batch reactions, consistent purity, and reliable long-term results. We have watched new industries take up this silane each year, with coatings engineers, sealant formulators, and electronics specialists all asking: what separates a solid product from an unpredictable one? Having been involved directly from raw material vetting to final drum shipment, our answer always comes from deep practice, not just formulas.

    Model Consistency and Batch Quality

    Ethyltrimethoxysilane, sometimes called ETMS or CAS 110- ethyl trimethoxy silane, offers specific features compared to other alkoxysilanes. The ethyl group, attached via a silicon-oxygen backbone, plays out in real production—especially if the focus is on minimizing hydrolysis rates or balancing reactivity with storage stability. In our own plants, we see how even slight variations in raw alcohol source or moisture content change how a batch behaves during hydrolysis, especially when customers apply it in sol-gel or crosslinking environments.

    Over years of manufacturing, we built multi-step purification stages to push GC purity above 98% and control trace methanol below critical levels. Too much free alcohol creates surface compatibility problems. Exceeding purity guidelines, though more expensive, reduces customer complaints downstream. In hot, humid regions, we tested storage life directly by holding product in different humidity and temperature ranges, measuring for early gelation or phase separation. Our brewing experience taught us that specifying only the model or chemical name never covers the full scope—a successful order means that every drum shipped matches what research labs and bulk polymer plants expect.

    End Uses—Real Applications, Everyday Obstacles

    Customers from many countries reach out about Ethyltrimethoxysilane for adhesion promotion in paints or sealants, especially where hydrolysis and condensation form part of the backbone chemistry. Chemically, the ethyl group creates a slightly less aggressive hydrolysis profile than methyltrimethoxysilane. This trait helps in applications where users require longer open times, such as field-applied coatings or large-scale polymerizations. Less experienced users sometimes expect any silane with three methoxy groups to act identically, but in practice product choices depend on humidity, base resin type, and mixing protocols.

    Compared to other silanes like methyltrimethoxysilane or vinyltrimethoxysilane, Ethyltrimethoxysilane adds noticeable elasticity to rigid silicone networks. This becomes valuable in certain weatherproofing sealants or optical encapsulants where minute changes in crosslink density affect final product performance.

    Direct Experience—From Tanker Loading to End-User Happy Calls

    Daily factory life leaves little room for wishful thinking. Leaky valves, ambient humidity swings, and hard-to-source raw materials all place pressure on each product tank. Our operators monitor every batch tank for fines, side products, and discoloration; no certificate can substitute for what operators see with their own eyes. We spent months, not days, standardizing delivery tanks to prevent even tiny moisture ingress because early hydrolysis contaminates an entire lot—and the phone starts ringing from the field. This practical vigilance goes further than any “premium” branding.

    Customers often share stories where switching to our high-purity Ethyltrimethoxysilane slashed coating rejects far below previous rates. In aggregate-filled adhesives, the difference plays out in bond durability. In our experience, the biggest performance gaps come from seemingly minor parameters: fresh batch turnover, container cleaning, and custom-sized packaging. One solar panel customer needed every drum below a tight moisture threshold, so we installed inline desiccant dryers after distillation and ran 24-hour leak tests on every filled drum. We kept logs on every deviation, however minor, and tightened maintenance cycles until we hit their strict requirements consistently.

    Specification Nuances—Real-World Chemistry, Not Desk-Made Lists

    Anyone can download a PDF of nominal technical data, but only those on the plant floor really grasp how small changes in silane composition cascade into final performance. The moisture content, purity, presence of related silanes, and storage stability all impact curing, adherence, and finished good reliability. In our operations, years of small adjustments—such as reactor temperature tweaking or switching nitrogen blanketing methods—let us achieve batch uniformity across seasons and raw material variations. Our new automated GC-MS gives us higher resolution than what was available even five years ago, catching trace byproduct peaks early. We found that focusing on purity consistency, and not just primary assay value, translates into more predictable performance for the final user.

    Technical teams often ask about the visible smell or small variations in product haze. In practice, odor changes almost always signal trace aldehyde buildup from premature hydrolysis. That feedback loop—customers reporting off-odors or unusually fast gel times—triggers plant investigations, sample pulling, and drum requalification. We caution buyers: demand full batch documentation, not “standard” drum lots. This attention to detail separates routine vendors from a manufacturer with accountable practices.

    Handling, Safety, and Sustainable Practices—What Experience Teaches

    Ethyltrimethoxysilane poses both flammability and hydrolytic sensitivity; respiratory and skin protection must follow real-world exposure scenarios, not just regulatory checkboxes. Over time, improved closed-loading, anti-static piping, and trained PPE protocols made our tanks cleaner and our staff healthier. It proved cheaper in the long run to invest in more robust containment and fire suppression than to risk a single spill incident. Environmental teams learned to monitor air emissions and waste silane neutralization more closely, adopting more contained process loops and on-site recovery, not just off-site washing.

    Sustainability now matters in every chemical market. Our journey from heavy-waste early generations to today’s reactive washing and vapor recovery loops slashed VOC numbers and improved community relations. We found that end users, especially multinationals in electronics or construction, increasingly demand lifecycle data on solvent use and waste recycling rates. By focusing on real emissions data, implementing energy-efficient distillation, and openly sharing progress, we stay ahead of market requirements—well before they turn into legal mandates.

    Comparisons: Ethyltrimethoxysilane Versus the Competition

    Those choosing a silane coupling agent cannot rely on chemical similarity alone. We run hundreds of side-by-side tests of Ethyltrimethoxysilane against other commonly used silanes including methyltrimethoxysilane and vinyltrimethoxysilane. On freshly prepared substrates, the ethyl derivative brings slightly more flexibility but slightly less reactivity. In hot or humid climates, this slows down hydrolysis and delivers steadier shelf-life, critical for large-scale concrete treatment or outdoor application workflows. Engineers look for tolerances rather than extremes—our technical service runs field simulations, not just small-vial bench tests.

    The methyl group in methyltrimethoxysilane can induce more rapid crosslinking, sometimes at the cost of pot-life or increased risk for early gelling. Vinyltrimethoxysilane adds polymerizable double bonds—useful for some plastics but prone to yellowing or poor hydrolytic stability if not handled with care. Ethyltrimethoxysilane’s sweet spot lands in intermediate adhesion, controlled reactivity, and slightly improved workability—best suited to sealants that must flex, paints struggling with hard-to-bond surfaces, or siloxane crosslinkers wanting longer cure times.

    Practical Guidance—Using Ethyltrimethoxysilane in the Real World

    Any compound can look good on paper, but in a practical sense, Ethyltrimethoxysilane’s behavior often surprises first-time users. Overly wet mixing leads to premature gelation. Poor nitrogen blanketing allows atmospheric moisture to cause clumping and off-odors. Our technical bulletins go beyond standard paperwork; every tip we share came from lab mishaps and production hiccups. Adding the silane last, under dry conditions, and using clean, dry mixing vessels makes the difference between perfect batches and rejected product. In composites, we recommend surface pre-treatment followed by rapid mixing and fast application—delaying just minutes can cut functional loading in half.

    For those scaling from bench to plant, agitation speed, order of addition, and resin compatibility matter more than most spec sheets ever show. Our own pilot-scale trials helped dozens of customers avoid yield drops during ramp-up, typically saving days of lost production time. Small investments in line-drying gear and operator training always pay off. Avoid using low-grade or repackaged silane, since surface impurities and unpredictable moisture will erode reliability, especially in long-cure systems or tight compliance environments.

    Packaging Choices and Delivery—Meeting Reliability Demands

    Most buyers care about more than chemical formula—they need prompt bulk delivery, packaging matched to their batch sizes, and safeguarded against transit moisture. We offer steel drums, IBCs, and nitrogen-blanketed ISO tanks, based on decades of data showing which packaging safeguards performance best. A user treating specialty optics demanded glass-lined containers to prevent trace leaching; our flexible packaging enabled trace contaminant reductions to sub-ppm. In crowded warehouse facilities, package footprint and leak-proofing can matter as much as price per kilo, so we keep a steady dialogue going with warehousing and line staff.

    Pre-shipment, our internal protocol includes final GC analysis, water content measurement, and extended standing to watch for sedimentation or phase separation over 96 hours, not just a twelve-hour QC check. Before changing a packaging vendor, we run compatibility and migration tests, pulling random samples after extended storage to mimic field conditions. These methods emerged from years of handling hundreds of export lots, learning from lost-label drums or temperature-abused containers that cost distributors a day or more of downtime. Attention to every delivery detail sustains customer loyalty—far more than short-term incentives or monetary discounts.

    Supporting R&D and Scale-Up—Partnership, Not Just Supply

    Chemistry never stands still, so every few months our R&D team collaborates with customers developing novel materials. Whether for new catalysis approaches, next-generation paints, or high-end optical adhesives, Ethyltrimethoxysilane forms part of many projects. We offer not just product, but active testing—on request, we prepare custom blends and detailed hydrolysis profiles adapted to actual resin formulations. In our experience, providing tight batch documentation and open lab access to customer teams builds real trust and accelerates progress.

    Pilot lines often reveal pain points that don’t show up in single-vial tests. Subtle color shifts, gelation windows, and even drum headspace control each appear at kilogram or ton scale. Our scale-up engineers visit user plants, observe processes, and supply practical feedback, from agitation blade choice to degassing best practices. We believe R&D success should build directly on manufacturing insight; every “failure” at our site gives us new protocols to share back with the field.

    Challenges and Honest Lessons From Manufacturing

    Every production shift brings its own obstacles. Power failures, trace supplier variation, or sudden demand surges test the resilience of the best-laid plans. Instead of hiding problems, recording every deviation, investigating root causes, and sharing findings across all teams builds a culture where safety, reliability, and improvement drive us forward. Years ago, a solvent tank valve failed during a thunderstorm, flooding a batch area and threatening to spoil an entire production run of Ethyltrimethoxysilane. Because our team followed practiced emergency shutdown drills, we lost only a small lot. That led to investment in back-up seals, regular valve cycle testing, and extra process alarms. Every close call becomes a driver for tighter controls and higher plant safety.

    On the regulatory side, evolving standards for volatile organic emissions, workplace exposure, and product traceability forced us to innovate beyond compliance. We worked closely with industry peers to forecast likely regulatory shifts, update process logic, and invest in abatement equipment well ahead of deadlines. These efforts do not appear in marketing literature, yet end-users see them in consistent product quality and transparent documentation that simplifies audits and import clearances.

    Long-Term Outlook—Keeping Ethyltrimethoxysilane Ready for Changing Needs

    The era of commodity-only chemistry has passed. Those who buy Ethyltrimethoxysilane today expect more than purity and timely shipment—they look for proof of environmental progress, supply reliability, and a partner ready to customize blends as new applications emerge. As we see electric vehicle, solar, and high-strength composite sectors expand, we continue to push boundaries on analytics, plant automation, and feedstock qualification. We maintain full supply-chain auditing to back up claims of sustainable sourcing and work with logistics teams for continuous improvements in packaging reuse and emission cuts.

    Technological leaps in downstream materials—heat-cured adhesives, high-transparency films, flexible encapsulants—keep stretching the boundaries of what silane can deliver. Staying a step ahead requires steady teamwork: close listening to user feedback, monitoring new research, and never settling for last year’s practices. Product innovation means nothing without safe, reliable, and responsive manufacturing that adapts with end-user demands and global trends.

    Ethyltrimethoxysilane’s story speaks to the real-life promise of chemistry in action: behind every ton stands hundreds of small improvements, continuous learning, and a commitment to building materials, products, and futures that last.