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Ethylene Sulfide

    • Product Name Ethylene Sulfide
    • Alias Thiirane
    • Einecs 208-873-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    135796

    Chemicalname Ethylene Sulfide
    Othernames Thiirane
    Molecularformula C2H4S
    Molarmass 60.12 g/mol
    Casnumber 420-12-2
    Appearance Colorless liquid
    Boilingpoint 56 °C
    Meltingpoint -111 °C
    Density 1.027 g/cm3
    Refractiveindex 1.467
    Solubilityinwater Slightly soluble
    Odor Unpleasant, sulfur-like
    Flashpoint -4 °C
    Vaporpressure 245 mmHg (25 °C)
    Structure Three-membered cyclic ether (thiirane ring)

    As an accredited Ethylene Sulfide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Ethylene Sulfide is packaged in a 500 mL amber glass bottle with a secure cap, labeled with hazard symbols and product details.
    Shipping Ethylene sulfide should be shipped in tightly sealed containers made from materials resistant to corrosive and volatile compounds. The substance must be labeled as a flammable, toxic, and reactive liquid, kept away from heat, ignition sources, and incompatible materials. Transportation must comply with relevant hazardous material regulations to ensure safety.
    Storage Ethylene sulfide should be stored in a cool, dry, and well-ventilated area away from heat, sparks, open flames, and strong oxidizers. Use tightly sealed containers made of compatible materials to prevent leaks and limit exposure to moisture. Storage areas must be equipped with proper spill containment, and containers should be clearly labeled. Avoid direct sunlight and sources of ignition to ensure safety.
    Application of Ethylene Sulfide

    Applications of Ethylene Sulfide in Industrial Manufacturing

    Ethylene sulfide is a key sulfur-containing intermediate used across several advanced chemical sectors. As the producer, we supply this raw material directly to specialized manufacturers who depend on tight process control, batch consistency, and defined compliance standards to achieve specific downstream formulations. Below are detailed application scenarios reflecting established uses in industrial practice.

    1. Synthesis of Ethylene Sulfone for Electrolyte Additives

    Ethylene sulfide serves as a precursor in the synthesis of ethylene sulfone, an important high-performance additive in advanced lithium-ion battery electrolytes. During production, manufacturers oxidize ethylene sulfide under controlled conditions to obtain high-purity ethylene sulfone. This downstream process demands strict impurity management and process calibration for targeted electrochemical application, ensuring both longevity and safety in high-energy cell systems.

    Industry compliance standards

    • IEC 62660-2: Secondary lithium-ion cells for industrial applications
    • ISO 9001:2015 – Quality management systems
    • REACH Regulation (EC) No 1907/2006 – Substances Registration
    • GB/T 36276-2018 – Chinese Lithium Ion Battery Electrolyte Standard

    Typical usage ratio

    • Batch conversion of 100% ethylene sulfide adjusted based on conversion efficiency; downstream electrolyte additive loading typically between 1–7% of total solvent mass, adjusted per cell chemistry needs.

    Downstream process integration

    • Oxidation of ethylene sulfide performed in jacketed reactors with in-line purity monitoring; downstream sulfone isolated, purified, and incorporated into electrolyte blending stages prior to cell assembly.

    Final product types

    • Lithium-ion battery electrolyte formulations
    • High-voltage lithium polymer battery packs
    • Starter batteries for automotive and grid storage
    • Consumer electronics battery modules

    2. Production of Sulfide-Modified Epoxy Resins

    Specialty manufacturers employ ethylene sulfide in epoxy system modification to enhance thermal stability and chemical resistance. This approach involves ring-opening copolymerization where ethylene sulfide reacts with epoxy resin pre-polymers. The resulting materials withstand aggressive chemical exposure, supporting applications across electronics, automotive, and industrial tooling sectors. Quality requirements demand precise impurity control to avoid downstream gelation and defects.

    Industry compliance standards

    • UL 94 HB/V0: Flammability standards for polymeric materials
    • RoHS Directive 2011/65/EU
    • ASTM D1653: Water vapor transmission rate
    • ISO 14001:2015 – Environmental management systems

    Typical usage ratio

    • Ethylene sulfide dosed at 1–10 phr (parts per hundred resin) depending on target sulfur content and end-use exposure profile.

    Downstream process integration

    • Added to resin pre-gel during synthesis in closed systems, followed by in-situ polymerization and downstream dicyandiamide or anhydride curing.

    Final product types

    • PCB laminate resins
    • Thermoset encapsulation compounds
    • Chemical-resistant adhesives
    • Industrial composite tooling boards

    3. Sulfur-Containing Pharmaceutical Intermediates

    Ethylene sulfide plays a critical role as a building block in active pharmaceutical ingredient (API) synthesis, particularly for molecules requiring cyclic thioether motifs. Medicinal chemistry groups utilize its high ring strain to enable regioselective functionalization, constructing key intermediates for both small molecule drug APIs and diagnostic reagents. Manufacturing requires GMP-compliant isolation, trace level impurity mapping, and validated cleaning protocols for cross-contamination prevention.

    Industry compliance standards

    • ICH Q7: Good Manufacturing Practice for Active Pharmaceutical Ingredients
    • 21 CFR Part 211: US FDA Current Good Manufacturing Practice
    • Chinese Pharmacopoeia (ChP) 2020
    • EU GMP EudraLex – Volume 4

    Typical usage ratio

    • Stoichiometric inclusion (typically 0.5–1.5 equivalents to nucleophile) per reaction pathway; actual load adjusted for route efficiency and desired yield of intermediate.

    Downstream process integration

    • Introduced at the thioether ring formation or functionalization step during multi-stage GMP batch API synthesis, with systematic in-process controls and isolated intermediate QA release.

    Final product types

    • Sulfur-containing API intermediates
    • Contrast agents for imaging diagnostics
    • Reference standards for regulatory submissions
    • Fine chemicals for chiral catalyst libraries

    4. Organic Synthesis of Sulfur-Modified Polymers

    Polymer chemists incorporate ethylene sulfide in graft and block copolymer synthesis to impart unique sulfur functionalities, such as enhanced refractive indices or improved oxidative stability. Precise dosing during anionic or cationic polymerization enables the creation of copolymers used in specialty films, optical components, and performance membranes. Process control must manage monomer purity and maintain reaction temperature uniformity to ensure reproducibility and final property targets.

    Industry compliance standards

    • ISO 9001:2015 – Quality management systems
    • JIS K 6922: Japanese Polymer Standards
    • EN 16402: Emission of construction polymers
    • ASTM D638: Standard test method for tensile properties of plastics

    Typical usage ratio

    • Monomer feed ratio between 0.5–8 mol% based on desired chain incorporation and end-use mechanical requirements; recipe validated by downstream performance testing.

    Downstream process integration

    • Monomer blended in reactor charge during feed phase, with continuous or batch addition strategy depending on reactivity and copolymer formation route.

    Final product types

    • Sulfur-modified polyolefin films
    • High-index optical resins
    • Gas separation membranes
    • UV-curable functional coatings

    5. Chemical Synthesis of Sulfoxide Ligands for Catalysis

    In coordination chemistry, researchers and fine chemical producers use ethylene sulfide as a source for the preparation of sulfoxide and sulfone ligands. These ligands play key roles in homogeneous catalytic systems, especially in asymmetric hydrogenation and oxidation reactions. Successful synthesis requires tight process monitoring, solvent handling under inert atmosphere, and advanced downstream purification to guarantee ligand activity and batch reproducibility according to project specifications.

    Industry compliance standards

    • Responsible Care® Global Charter
    • ISO 17025:2017 – Laboratory quality standards
    • OECD Guideline for Testing of Chemicals
    • GLP (Good Laboratory Practice) for fine chemical synthesis

    Typical usage ratio

    • Usage between 0.2–1 molar equivalent relative to other ligand components in synthesis; precise ratio determined by targeted ligand architecture.

    Downstream process integration

    • Ring-opening of ethylene sulfide follows nucleophilic attack or oxidation steps, feeding directly into subsequent ligand complexation or isolation stages.

    Final product types

    • Chiral sulfoxide ligands
    • Homogeneous catalyst complexes
    • Custom catalyst precursors for pharmaceuticals
    • Analytical reagent kits for metal trace analysis

    6. Manufacture of Vapor Phase Sulfur Donors in Rubber Vulcanization

    Ethylene sulfide acts as a specialized sulfur donor in vapor phase vulcanization of synthetic rubber, such as EPDM and butyl rubbers. Its volatile and reactive profile allows for uniform sulfur crosslinking in continuous conveyor-based curing systems, supporting automotive parts and high-performance elastomers. Dosing requires precise vapor injection metering, integrated with real-time monitoring to avoid overcuring and to deliver target mechanical properties.

    Industry compliance standards

    • ISO 2396:2020 – Vulcanized rubber testing
    • SATRA TM77 – Rubber physical property standards
    • US EPA SARA Title III reporting (chemical usage)
    • OSH Act standards for workplace air quality

    Typical usage ratio

    • Vapor-phase feed rate equivalent to 0.5–1.2 phr (parts per hundred rubber) depending on rubber grade and cure profile requirements.

    Downstream process integration

    • Direct injection into curing ovens by closed loop metering; control logic monitors chamber concentration and conveyor speed, linking to downstream mechanical and chemical testing stations.

    Final product types

    • Automotive weatherstrips
    • Industrial rubber hoses
    • Vibration damping mounts
    • Performance elastomer gaskets
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    Certification & Compliance
    More Introduction

    Ethylene Sulfide: A Closer Look From the Manufacturer’s Bench

    Direct From the Reactor: What Years in Ethylene Sulfide Production Have Taught Us

    Ethylene sulfide holds a different place among organic intermediates. Over decades of hands-on synthesis, our plant teams have become closely familiar with its reactivity and properties—right down to the subtle cues during distillation that separate a clean batch from an off-spec run. This product isn’t a commodity we source or repack; it’s something we actively build from the ground up, watching every reaction variable on the floor. In every stage of manufacturing, we notice the details that other eyes might pass over. Ethylene sulfide, also known as oxathiirane, is distinctive for its strained three-membered ring—one sulfur, two carbon atoms—bringing a distinct chemical energy that sets it apart from more stable heterocycles.

    Model and Specifications Anchored in Real-World Use

    While many specifications float through spreadsheets and technical catalogs, real consistency comes from monitoring the product in each batch, from prepolymer chemistry to fine chemical synthesis. Here, typical specifications aim for a purity exceeding 98%, with water content and acid value kept to the barest trace levels—since even small impurities provoke harsh odor, off-colors, or unwanted reactivity. We carefully control storage temperature, since this compound’s low boiling point and volatility make even slight warming a safety hazard. These are the realities that show themselves only to those on the ground—the yellow-green tinged distillate tells us our process has avoided over-oxidation, while cloudiness warns of moisture intrusion in the bottling room. In technical terms, you can reach for a CAS number or boiling point, but practical control comes from simple checks: a steady, unclouded pour and a clean GC trace signal the batch hits the mark.

    From Synthesis to Scale: Standing Behind the Product

    Compared with common sulfur heterocycles or alkene-derivatives, our ethylene sulfide requires careful design at the reactor stage. The feedstock selection—typically using ethanol derivatives and controlled sulfurization—demands experience, since feedstock impurities can convert minor byproducts into major headaches in your downstream chemistry. Over time, we’ve modified reaction setups for both batch-wise and continuous production, adapting everything from coolant jackets to agitation speeds. There’s a reason behind every technical data point in our records; they aren’t just numbers, they trace back to points where things have gone nearly right or nearly wrong.

    What makes our ethylene sulfide stand out isn’t just the spec sheet. It’s the years of work done to track every byproduct, the safety reviews when tweakings to reaction pH change the exposure limits we report, and the batch notes appended when a reactor fouls and delayed the next pickup. Modern customers in the pharmaceutical or polymer industries now expect not just high-purity intermediates, but full traceability on raw materials and minimized non-target contaminants. In practice, that means we’re baking long experience into every lot number we bottle out—catching subtle phase separations during transfer, calibrating delivery schedules so less inventory ages in your warehouse, and running old-fashioned leak checks on new drum designs before sending anything down the dock.

    Practical Usage: Not Just a Catalog Option

    The bulk of our ethylene sulfide heads for specialty organic synthesis. Its short molecular backbone and energetic ring system invite ring-opening reactions—one of the most effective ways to insert sulfur into a target compound’s skeleton. In epoxide chemistry, where ethylene oxide often dominates, the sulfur atom in ethylene sulfide gives routes into entirely new domains of chemical functionality. Over the years, our clients have reported its effectiveness as a precursor for high-performance polymers, specialized chelating agents, and advanced pharmaceutical intermediates, especially where classical oxygen-based analogues lack stability or selectivity. The difference may sound subtle, but in our experience, tightening up the reaction yield from a sulfur insertion—by even half a percent—can dictate which plant stays on budget for the quarter.

    We’ve seen ethylene sulfide unlock series of downstream steps that looked unworkable with more standard reagents. That flexibility comes with its own caution: there are real risks handling such a reactive compound outside controlled environments. Leaks or poorly vented storage can lead to persistent odors and costly clean-ups. Because our teams spend long hours monitoring odors at joints and valves, we can tell the difference between a routine waft and the early warning of a significant emission—something you can’t glean from a material safety sheet alone.

    Comparative Experience: Ethylene Sulfide Versus the Alternatives

    Choosing between ethylene sulfide and more commonly available analogs brings in practical knowledge. Molecularly, ethylene sulfide sits close to ethylene oxide and other simple cyclic sulfides, but its sulfur atom creates different reactivity patterns. In the manufacture of certain alkylating agents and as a sulfur source for ring-opening additions, its unique profile means our customers often see improved coupling efficiency and novel compound frameworks that simply don’t show up when using conventional epoxides or straight-chain sulfides. Other compounds with similar rings—like propylene sulfide—react differently due to size and substitution effects, making them less reactive or selective for some critical reactions. Our history has shown that formulators come back to ethylene sulfide when the chemistry calls for something a little sharper and more agile than standard cyclic intermediates.

    This difference in use case isn’t always clear from theoretical reactivity or published procedures. Repeated trials in the pilot plant tell you more—catalyst residues, mixing times, and even batch odors reveal which molecule fits the process best. In some scenarios, we’ve run direct head-to-heads, where ethylene oxide produced unwanted byproducts while ethylene sulfide maintained high selectivity and yield, saving on costly separation work. Our customers, especially in the fine chemicals sector, often mention that nothing else gives the same combination of sulfur reactivity and manageable volatility. Careful users recognize the necessity of closed handling and on-site monitoring, and we support these needs by ongoing feedback with process engineers on the receiving end.

    On-the-Ground Safety and Handling: Learning From the Real World

    Across our facility, the safety record around ethylene sulfide reflects years of learning. This compound demands sealed transfer lines, local exhaust and fixed detectors—much more than a basic solvent. We’ve encountered cases where a minute valve imperfection led to ongoing maintenance headaches. To keep our teams and customers safe, we focus on proactive monitoring and real-world drills, not just compliance. The difference between a safe shipment and a problematic one can rest on small things: a misaligned gasket, a corroded drum, winter condensation in the wrong spot. Instead of relying only on the formal revision of the chemical’s hazard classification, we lean into ongoing process reviews and frontline feedback. In our last round of facility upgrades, we retrofitted transfer pumps based on input from the plant operators, who had faced vapor release issues that didn’t show in original technical project specs.

    Continuous Improvement: Responding to Changing Technology and End-User Needs

    Plant upgrades and formulation tweaks aren’t marketing moves—they’re based on real-world feedback. Over time, we’ve worked with pharmaceutical partners, polymer developers, and materials scientists exploring next-generation uses for ethylene sulfide. Some are looking for ever-tighter control of trace chlorinated or oxidized impurities, while others need stability under ambient transport. We’ve tuned our own reactor controls and purification steps for these evolving customer requirements, and we keep our teams trained for troubleshooting—since every time a new customer scale-up goes off-pace, we’re getting that call. In this market, traceability isn’t a buzzword; it’s a guarantee backed by decades of batch logs and every real conversation with plant maintenance. That’s the process behind our product evolution—testing, critical self-review, and iterations that circle back to the practical needs of researchers and end-users.

    Supply Chain and Logistics: Anticipating Challenges Before They Become Problems

    Logistics play a critical role in product quality, and with a material as sensitive as ethylene sulfide, every transit stage counts. Over the years, we’ve seen what happens if temperature control lapses or containers lose integrity—minor fluctuations can degrade quality, and returned shipments quickly teach the value of reliable transport partners and certified packaging. We work with dedicated tankers and certified packaging solutions, based on past incidents where routine off-the-shelf containers couldn’t fully contain the reactivity of the cargo. Changes in shipping conditions—mounting summer heat, customs delays, irregular port handling—have all posed challenges. To navigate these, our team directly manages packing and labeling, drawing on operational data rather than just ticking off regulatory boxes.

    We work closely with our customers to fit delivery windows and minimize stock aging, since we understand that no lab or processing line wants to tie up working capital in something that might foul before use. Feedback from logistics staff, especially at international receiving docks, sometimes prompts adjustments in how we stage orders or split lots, allowing for customs clearance hold-ups and weather risks. These practical observations come back full circle to influence decisions in our loading docks and warehouse management systems.

    Market Evolution: Tracking Demand and Adapting to Regulatory Hurdles

    Demand for ethylene sulfide has expanded beyond the early core of pharmaceuticals and specialty chemicals. We’ve watched interest grow among electronics manufacturers, materials scientists exploring new polymer matrices, and academic teams working toward novel catalysts. Each new industry asks its own set of detailed questions—ranging from minimum impurity thresholds to legacy uses in proprietary synthesis routes. Over time, regulations have grown more stringent across many regions, shaping both how we manufacture and ship ethylene sulfide. Updates to transport classifications, occupational exposure limits, and end-use certifications crowd our desks, but we approach these as part of our commitment to responsible manufacturing, not just a paperwork chore.

    Switching from one compliance regime to another isn’t just a matter for our regulatory team; it hits hard in day-to-day plant work. From tweaking process controls to meet evolving emission standards to updating PPE policies as workplace limits shift, the regulatory world keeps us on our toes. Some past changes forced us to overhaul our monitoring equipment or modify root cause analysis when even a single container flagged for inspection. But these demands also drive quality. The call for tighter safety controls and supply chain transparency is not just about following the rules, but also about ensuring steady, reliable delivery that meets both industrial and health standards. Our approach stays pragmatic—listening to regulatory bodies and customers, staying nimble, and ensuring real compliance through robust site management and unfiltered feedback from the plant floor.

    Problem-Solving in Practice: Bouncing Back From Missed Batches and Field Failures

    Every manufacturer faces its share of surprises—contaminated batch, a transport leak, a missed delivery. Our willingness to own these moments and adjust gives us staying power in this business. Several years back, a sudden shift in supplier quality for a minor feedstock led to unpredictable byproducts and several off-grade shipments. The solution came through late-night troubleshooting sessions—pattern-matching batch data, testing alternative purification routes, and communicating openly with everyone affected. Instead of hiding the issue or shifting blame, our team rebuilt protocols around supplier audits and rapid in-house impurity screening. We shared findings directly with our biggest clients, working through the delay together. In another instance, a mislabeled container caused a delivery mix-up. Permanent changes to labeling, documentation procedures, and external audits came out of that. These aren’t theoretical examples—they’re concrete reasons you build experience as a manufacturer, not as a middleman, and why the small things matter in chemical production.

    New entrants to the market may not realize how often the biggest issues stem from overlooked basics: poor raw material checks, basic equipment neglect, routine deviation that slips through the cracks. Our site teams put in daily rounds, cross-checking sensors, reviewing operator logs, and keeping their own handwritten notebooks alongside digital records. This blend of experience—old-school vigilance and modern process control—offers the best protection against avoidable failures. If a shipment gets delayed or a batch comes out wrong, the cause is almost always something you can solve with steady attention, shared responsibility, and honest reporting both inside and outside the plant walls.

    The Value of Direct Manufacturing — Experience at Every Level

    As original producers, we stake our name and record on each shipment, and it shows in how we handle ethylene sulfide at every link in its journey. We don’t rely on distant data or hopeful assumptions. Listening to plant workers who train eyes and noses on the process gives a fuller picture than any top-down directive. Experience shapes the controls we install and the training we repeat, not abstract recommendations or borrowed checklists. In our world, every specification comes with a lived-through story—the time a pressure relief vent design got upgraded after a vapor scare, the investment in on-site emergency drills, the daily task of vetting each lot before a drum hits the loading dock.

    For our customers, this direct approach means there’s always a resource to talk through a challenge, whether it’s an unexpected drop in reaction yield, storage quirks, or regulatory hurdles. Many users report that this support helps them catch issues early—sometimes preventing an unworkable process or wasted materials. The difference from a trading desk is tangible: we’re the ones sweating the fills and the leaks, answering questions from floor supervisors, and troubleshooting complaints in real time.

    Looking Forward: Future Prospects for Ethylene Sulfide and Its Role in Modern Chemistry

    New research areas keep opening possibilities for ethylene sulfide. As demand rises for advanced materials, specialty polymers, and tailor-made pharmaceuticals, the need for high-purity, consistently handled intermediates like this only grows. We stay engaged with academic research and customer-driven improvement—offering samples for new synthetic approaches, collecting feedback on product performance, and adjusting our internal QA controls as novel applications arise. The more we hear about challenges at the bench or in field trials, the more insight we gain into where our product can add value—whether that involves extending purity grades or devising new containment methods.

    Over time, we expect that regulatory updates and market shifts will force even tighter product controls, faster response, and direct support. Industry will embrace automation and digital tracking, but old-fashioned vigilance and deep training remain crucial in handling such reactive chemistries. Maintaining a direct line to the shop floor while investing in monitoring equipment, process upgrades, and workforce training will keep the product reliable for years to come.

    Shared Progress—The Manufacturer’s Perspective

    Our ongoing responsibility reaches beyond regulatory compliance or market share. Manufacturing ethylene sulfide has taught us to respect its hazards, value its strengths, and never take consistency for granted. This sense of stewardship shines through at every level—reactor operation, batch control, packaging, and end-user collaboration. Lessons learned at the production line often end up driving better chemistry, safer facilities, and closer working relationships across the supply chain. Clients routinely tell us the technical discussions and site visits bring practical value—offering not just specifications but grounded advice drawn from experience.

    Direct manufacturing is a commitment—not only to technical achievement but to transparency and ongoing improvement. Every drum filled, specification printed, and shipment organized carries a piece of what we’ve absorbed through decades of real work. As new applications arise and regulations keep evolving, our job stays the same at its core—providing reliable, high-quality ethylene sulfide backed not just by numbers, but by real understanding you only get from doing the work yourself.