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Ethyl 3-(N,N-Dimethylamino)Acrylate

    • Product Name Ethyl 3-(N,N-Dimethylamino)Acrylate
    • Alias DMAA
    • Einecs 202-564-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales7@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    130878

    Chemical Name Ethyl 3-(N,N-Dimethylamino)acrylate
    Cas Number 924-99-2
    Molecular Formula C7H13NO2
    Molecular Weight 143.18 g/mol
    Appearance Colorless to pale yellow liquid
    Boiling Point 197-199 °C
    Density 0.981 g/mL at 25 °C
    Refractive Index 1.445-1.447
    Melting Point -43 °C
    Flash Point 82 °C
    Solubility Slightly soluble in water; soluble in organic solvents
    Purity Typically ≥98%
    Smiles CCOC(=O)C=C(N(C)C)
    Inchi InChI=1S/C7H13NO2/c1-4-10-7(9)5-6-8(2)3/h5-6H,4H2,1-3H3

    As an accredited Ethyl 3-(N,N-Dimethylamino)Acrylate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 250g clear glass bottle with a white screw cap, labeled "Ethyl 3-(N,N-Dimethylamino)Acrylate," hazard warnings, and handling instructions.
    Shipping Ethyl 3-(N,N-Dimethylamino)Acrylate is shipped in tightly sealed, chemical-resistant containers to prevent leakage or contamination. It is transported under ambient conditions but kept away from moisture, heat, and incompatible substances. Appropriate labeling, documentation, and adherence to local and international regulations for hazardous chemicals are strictly followed during shipping.
    Storage Ethyl 3-(N,N-Dimethylamino)acrylate should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from heat, ignition sources, and incompatible materials such as strong oxidizers and acids. Protect from moisture and direct sunlight. Use secondary containment to prevent leaks or spills. Follow all relevant safety regulations and ensure proper labeling and handling procedures.
    Application of Ethyl 3-(N,N-Dimethylamino)Acrylate

    Applications of Ethyl 3-(N,N-Dimethylamino)Acrylate in Industrial Manufacturing

    As direct manufacturers of Ethyl 3-(N,N-Dimethylamino)Acrylate, we supply this specialty acrylate monomer to established industrial clients across specialty polymers, advanced coatings, and chemical synthesis sectors. Here we outline principal downstream application scenarios, with essential technical and regulatory information for each sector.

    1. Functional Monomer in Cationic Flocculants for Water Treatment

    In industrial and municipal water treatment, cationic polyacrylamides use Ethyl 3-(N,N-Dimethylamino)Acrylate as a functional monomer, providing enhanced charge density and improved flocculation for suspended solids removal. Operators value the ability to fine-tune polymer performance for specific effluent qualities, especially in systems with variable solid or organic loads.

    Industry compliance standards

    • ANSI/AWWA Standard B453
    • US EPA 40 CFR Part 136 (effluent guidelines for public utilities)
    • EN 1406 (European standard for water treatment chemicals)
    • ISO 9001:2015 quality management for polymer production

    Typical usage ratio

    • In copolymerization: 2–12% by weight in total monomer feed, adjusted based on targeted cationic charge and molecular weight of the flocculant.

    Downstream process integration

    • Chemical enters during aqueous free-radical solution polymerization, often with acrylamide and other acrylates. It is dosed with controlled feed rates to ensure uniform polymer charge distribution and solubility.

    Final product types

    • Cationic polyacrylamide powders
    • Liquid flocculant concentrates
    • Effluent treatment formulations for sludge dewatering and clarification

    2. Intermediate in Synthesis of Quaternary Ammonium Acrylate Polymers for Antistatic Coatings

    Producers of antistatic additives value the unique N,N-dimethylamino group of this material for preparing quaternized copolymers that impart permanent antistatic effects in plastic coatings, electronic packaging, and automotive parts. The intermediate allows high conversion and predictable chain architecture under quaternization and copolymerization conditions.

    Industry compliance standards

    • IEC 61340-5-1 (Electronic static control standards)
    • ASTM D257 (Electrical resistivity of insulating materials)
    • REACH/CLP compliance — registration of intermediates and final polymers
    • RoHS Directive (Directive 2011/65/EU) for electronics & automotive applications

    Typical usage ratio

    • 5–15% weight in polymer backbones for antistatic performance; quaternization ratio varies depending on end-use conductivity requirements.

    Downstream process integration

    • Introduced during solution or emulsion copolymerization, usually with methyl methacrylate, butyl acrylate, or styrene. Post-polymerization, the dimethylamino group undergoes quaternization via alkyl halides.

    Final product types

    • Permanent antistatic coatings for electronic device housings
    • Electrostatic dissipative (ESD) packaging films
    • Conductive automotive interior coatings

    3. Reactive Component in UV-Curable Acrylic Oligomer Synthesis

    Manufacturers in the advanced coatings industry employ Ethyl 3-(N,N-Dimethylamino)Acrylate as a chain modifier and functional group donor in UV-curable oligomer formulations. The tertiary amine functionality participates in photo-initiated curing and pigment dispersion, supporting rapid throughput lines where coat uniformity and throughput speed are essential.

    Industry compliance standards

    • ISO 9001:2015 for quality manufacturing
    • ASTM D7767-19 (Standard practice for UV/EB cured coating application)
    • ECHA REACH — safety assessment and substance registration
    • VOC compliance regulations (US EPA 40 CFR Part 59, EU Decopaint Directive 2004/42/EC)

    Typical usage ratio

    • 0.5–4% by total oligomer system weight; percentage adjusted for desired crosslink density and reactivity with photoinitiator blends.

    Downstream process integration

    • Integrated into the prepolymer synthesis stage; reacts with diacrylate or triacrylate monomers via Michael addition or copolymerization, enabling functional tuning of final oligomer and influencing cure speed under UV light.

    Final product types

    • UV-cured industrial coatings
    • Inkjet and flexographic printing inks
    • Protective varnishes for electronics and packaging

    4. Fine Chemical Intermediate for Pharmaceutical Synthesis Pathways

    Specialty fine chemical manufacturers utilize Ethyl 3-(N,N-Dimethylamino)Acrylate as an intermediate in multi-step pharmaceutical syntheses, especially where tertiary amine or activated acrylate moieties are required in API scaffolds. Controlled processing ensures precise impurity profiles and batch traceability, beginning with our monomer as a foundation block for innovative actives.

    Industry compliance standards

    • Ph. Eur. / USP / JP for API manufacturing
    • ICH Q7 Good Manufacturing Practice (GMP) guidelines
    • 21 CFR Part 210 & 211 (US FDA cGMP for drug products)
    • ISO 9001/14001 for chemical plant operations

    Typical usage ratio

    • Highly variable; typically stoichiometric ratio with coupling/condensation partners, often 1:1, in small-scale batch processing. Final proportion adapts to route specificity and regulatory filing batch records.

    Downstream process integration

    • Introduced as a primary or secondary reactant during early-stage organic synthesis, particularly for Michael addition, Mannich-type, or acylation reactions in the scheme for building pharmaceutical intermediates and APIs.

    Final product types

    • Pharmaceutical intermediates for CNS and cardiovascular APIs
    • Precursors for targeting amine-containing drug molecules
    • Building blocks for custom research and pilot-scale drug discovery

    5. Additive for Enhancing Adhesion in Acrylic Pressure Sensitive Adhesives (PSA)

    PSA manufacturers include Ethyl 3-(N,N-Dimethylamino)Acrylate as a functional monomer to improve adhesion and peel strength, especially in applications demanding robust performance on difficult substrates like low-energy plastics or high-gloss films. Its amine-rich side-chain increases polar interactions at the adhesive-substrate interface, facilitating superior bonding.

    Industry compliance standards

    • FDA 21 CFR 175.105 (for indirect food contact adhesives)
    • ISO 9001-based QC for batch production
    • FINAT Testing Standards (e.g., FINAT FTM 1 for peel adhesion)
    • REACH compliance for specialty acrylate use in adhesives

    Typical usage ratio

    • 1–7% of total monomer load in waterborne or solvent-based PSA formulations, adjusted for balance between tack, shear, and peel performance as per customer laminate requirements.

    Downstream process integration

    • Added to the monomer blend for emulsion or solution polymerization, directly impacting co-polymer structure during in-situ formation of pressure sensitive adhesive matrices.

    Final product types

    • Acrylic PSAs for film and label stock
    • Tapes for automotive assembly
    • Specialty high-peel adhesive films for electronics and medical device assembly
    Free Quote

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    Certification & Compliance
    More Introduction

    Ethyl 3-(N,N-Dimethylamino)Acrylate: A Straightforward Introduction

    The Realities Behind Ethyl 3-(N,N-Dimethylamino)Acrylate Manufacturing

    At our chemical facility, the process of synthesizing Ethyl 3-(N,N-Dimethylamino)Acrylate unfolds every day across steel vessels and glass-lined reactors. This isn’t just another acrylate in a catalog. For those working in fine chemicals or specialty monomer development, you soon realize that this compound, with its CAS number 924-99-2, finds its way into a surprising range of applications. Many chemists know it for the reactivity that comes from its electron-rich dimethylamino group, but hands-on experience shows that it often bridges the gap between lab curiosity and commercial solution.

    Specifications That Matter in Practice

    People seem to ask the same question all the time: what really sets one supplier’s Ethyl 3-(N,N-Dimethylamino)Acrylate apart from another’s? After decades surrounded by tall drums and sharp scents of organic amines, we know quality shows up at every stage – not just on a data sheet. Our standard product offers a purity above 98%, with residual water and inorganic salts always well below detection. More importantly, we’ve learned to keep color as pale as possible, preventing impurities that interfere with polymerization or downstream reactions. For packaging, we seal everything under nitrogen in lacquered steel drums, since contact with air causes slow darkening and hydrolysis. This isn’t just for the certificate: customers who synthesize advanced polymers or pharmaceutical intermediates notice the difference, especially in yield and downstream purity.

    Applications: Not Just Numbers on a List

    Ask anyone in our production team if they know where Ethyl 3-(N,N-Dimethylamino)Acrylate goes next, and you’ll get a quiet smile. Years of shipments taught us that its value comes from versatility. The monomer itself rarely gets poured straight into commodity plastics. More often, research groups or specialty formulators use it as a building block for functional polymers, sometimes as a co-monomer in water-soluble acrylic systems or as a precursor for modified drug carriers. Medicinal chemists favor it in Mannich reactions; if you look in the patent literature, you’ll find a steady trickle of advanced molecules stemming from this core structure. Even in surface coatings, the molecule’s reactivity stands out. Compared to plain ethyl acrylate or methyl acrylate, the dialkylamino group increases electron density, which nudges the compound into a niche market for controlled-release materials and certain ion-exchange applications.

    Why This Molecule, Not That One?

    Many clients start out unsure. Ethyl 3-(N,N-Dimethylamino)Acrylate seems closely related to dimethylaminoethyl methacrylate (DMAEMA), and the acrylates look interchangeable on a structural chart. In plant operations, though, differences show up fast. DMAEMA carries a methacrylate backbone, making it less prone to uncontrolled homopolymerization in radical reactions. Our product, by contrast, offers a more reactive site at the acrylate end, so customers see better incorporation into some statistical copolymers, especially when working with hydrophilic or functionalized side groups. For pharmaceutical teams, the electron-donating amine opens up selective alkylations or quaternizations, which give birth to entirely new families of potential actives or delivery agents.

    Handling Practicalities: Lessons Learned from the Shop Floor

    We don’t see much romance in organic synthesis, just a thousand details that matter. Ethyl 3-(N,N-Dimethylamino)Acrylate reacts easily with moisture, so our filling lines stay bone-dry. Every batch gets vacuum tested for peroxide levels, because a little slip there leads to sticky transfers and headaches in the polymer tank. Over the years, customers have told us about funny smells drifting from poorly capped containers, a sign that storage controls slipped. We switched our closure systems to thicker PTFE linings, cutting off volatile seepage and saving the customer requalification headaches. In our team, most mistakes come from treating this as “just another acrylate,” but those who respect the amine’s basicity and reactivity don’t suffer sticky pipes or solidified residues. Chemists new to this molecule should always double-check compatibility with acid-sensitive constituents, as the basic amine reacts in ways methyl acrylates never do.

    Quality as Experienced, Not Claimed

    Over years of manufacturing, we noticed one simple thing: customers who switched from traders or re-bottlers often call after the first drum. They pick up on purity immediately. Residual dimethylamine, often left in from incomplete vacuum stripping, matters in both regulatory submissions and downstream reactivity. Strong control during the last stages of vacuum distillation keeps our byproduct content below 0.1%. Some people order up GC trace documentation, but more often, performance in the customer’s process does all the talking. Polymer chemists report fewer off-odors and sharper polymer molecular weight control. For anyone pushing reactions to >99% conversion, trace impurities jump from nuisance to nightmare. We invested in in-line NIR monitoring not as a luxury, but after seeing one too many failed copolymer runs when competition delivered off-color or water-logged goods.

    Challenges Unique to Ethyl 3-(N,N-Dimethylamino)Acrylate

    Most organic esters show similar handling quirks, but this molecule sharpens the edge. Its strong base character pulls in trace hydrochloric acid vapors, so storing drums around aggressive cleaners often leads to discoloration. Even a tiny slip in temperature during storage accelerates hydrolysis. To sidestep this, we keep temperature-controlled stockrooms and rotate inventory at fixed intervals. These might sound like small details, but every plant manager knows how a single leaky drum can set off a chain of batch failures, especially if hydrophilic polymers start to crosslink ahead of schedule.

    Transporting this compound through long supply chains adds its own stress. In summertime, three days in a hot container leads to darkened oil. Customers sometimes call, worried about performance drop-off. On our side, we pre-chill shipments in the hot season and dose with small amounts of polymerization inhibitor, adjusted for journey times and climates. This level of care doesn’t show up in data sheets, but it shows in batch-integration performance.

    Regulatory Pressures and Reliable Sourcing

    As regulators sharpen focus on trace impurities, consistent quality counts for more each year. In-house QA teams prefer material sourced directly from manufacturers rather than middlemen, and with good reason: changes in impurity profiles or color lead to headaches during registration of new pharmaceutical ingredients or advanced polymers. We worked through multiple customer audits, each poking into raw log books, not just tidy certificates. Our team gets training on consistency, and we trace every drum. This approach lets clients cut red tape on annual product reviews. For biopharmaceutical teams, being able to show a rock-solid chain of custody for every shipment means less downtime in qualification and less risk of site rejection.

    Why Model and Batch History Matters

    Clients rarely realize how much batch size and reactor histories can change the character of Ethyl 3-(N,N-Dimethylamino)Acrylate. Larger batch runs keep side-product levels lower, since temperature ramping stays more consistent. Small-scale syntheses, often from lab suppliers, pick up byproduct traces from wall effects and slow-cooling. We favor batch sizes between 500 and 2000 kilograms, giving us the right combination of uniform heat transfer and quick downstream filtration. Years of scale-up trials have taught us that fine-tuning cooling rates yields cleaner product and keeps final color within a barely perceptible range. Batch histories translate to fewer surprises on the customer’s end: no mid-batch gelation, no surprise pressure build-ups during storage, and no unexplained product failures during pilot runs.

    Delivering Confidence, Not Just Drums

    Our operational philosophy grew out of years spent troubleshooting at customer plants, not in abstract business meetings. The trust we build comes from real-time support. Over the phone, our technical staff trade notes with customers about specific process challenges, whether that means filtration tips to keep out unseen gels or advice on maintaining nitrogen blankets during transfer. More than a few times, direct intervention during a midnight shipment kept a client’s continuous reactor running. We know that each batch we ship reflects not just our process controls but our willingness to problem-solve alongside our buyers.

    Comparing to Generic Acrylates and Why It Matters

    Many buyers still treat acrylates as fungible, assuming only the functional group changes. From our end, the contrast is stark. Ethyl acrylate or methyl acrylate lack the amine’s unique reactivity and risk profile. Chemically, the dimethylamino group renders the molecule far more nucleophilic, which boosts its value in tailored synthetic routes requiring addition reactions or in the formation of switchable polymer systems. This property opens doors in fields as varied as sensor films, specialty adhesives, and advanced medical device coatings – places where plain acrylates fall short. Mistakenly substituting with a generic version leads to lost time and missed performance targets. Our experience with researchers from early-stage biotech up to global materials science firms shows that minor tweaks in functional groups demand trustworthy manufacturing processes and a careful supply chain. No generic will compensate for batch-level consistency or contaminant profiles specific to N,N-dimethylamino-acrylates.

    Solutions Built into the Process

    We never treat problems as paperwork. We assemble production batches like recipes, adjusting vacuum levels and residence times based on seasonal changes and customer requirements. As new regulations tighten around impurities, our response comes from hands-on changes, such as substituting cleaner grades of intermediates or shifting to jacketed filtration vessels that reduce contamination risks. Direct conversations between our technical staff and end-users sometimes spark small tweaks—lowering isomeric byproduct content or extending stabilizer concentrations. Years spent climbing up and down process towers and wrestling with clogged lines taught us the value of responsive, practical innovation to keep production moving.

    Building the Future with Reliable Acrylate Supply

    Customers expect stability, and so do we. Meeting global demand for Ethyl 3-(N,N-Dimethylamino)Acrylate requires more than routine production. Investments in new distillation columns, tighter environmental controls, and continuous personnel training keep us prepared for shifts in both technical standards and market requirements. As downstream applications become more sophisticated, with ever-tighter impurity budgets and performance parameters, we push manufacturing disciplines harder. Supporting this molecule doesn’t mean treating it as a background solvent or a commodity ester. Every order is a partnership with researchers and process developers who count on our experience to keep their own projects running smoothly and without delay.

    Direct Experience: What End-Users Gain

    Veteran users of Ethyl 3-(N,N-Dimethylamino)Acrylate see the difference that comes from manufacturer-sourced material. Early-phase researchers benefit from samples that mirror the properties of larger, scalable lots. Development groups working on clinical supply or pilot-scale polymer plants reach for the same drums we use for routine production. The lack of batch-to-batch variation stands out during method validation: analytical signals track smoothly, and failures rarely trace back to input material.

    Engineers in scale-up facilities appreciate routine technical exchanges—minor questions about inhibitor concentrations during exothermic polymerizations or adaptive filtration methods for particularly sensitive monomers turn into production advantages. Our technical team shares real-world advice, drawing from plant experience, not just lab analytics. End-users tell us that these collaborations lead to reliable outcomes and straightforward troubleshooting, shrinking downtime almost to zero.

    Summary: Ethyl 3-(N,N-Dimethylamino)Acrylate as a Choice for Specialists

    For researchers, engineers, and process chemists who require precise, functional molecules further along the acrylate family tree, Ethyl 3-(N,N-Dimethylamino)Acrylate offers more than just a passing option. Years in manufacturing shaped our view: every batch, every lot shipped, matches a promise to deliver not just on numbers, but on the specifics that make complex projects work. Its differences from other acrylates—rooted in its amine reactivity, its color and purity stability, and its integration into advanced synthesis pathways—stand out because we work to preserve them at every turn.

    At the root of our daily work stands the conviction that true value in chemical supply comes from unvarnished experience, transparent quality, and the ability to solve problems as they arise. Ethyl 3-(N,N-Dimethylamino)Acrylate’s importance in specialty chemistry owes much to what happens at the point of manufacture—a deep understanding of both molecular and operational demands. Those who work with the product day after day know that reliability, safety, and hands-on support translate directly into success for those who take on the challenges of advanced synthesis, polymer science, and active ingredient development.