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Ethyl 2-Methyl-4-Pentenoate

    • Product Name Ethyl 2-Methyl-4-Pentenoate
    • Alias ethyl tiglate
    • Einecs 224-510-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    276555

    Chemical Name Ethyl 2-Methyl-4-Pentenoate
    Molecular Formula C8H14O2
    Molecular Weight 142.20 g/mol
    Cas Number 818-38-2
    Appearance Colorless to pale yellow liquid
    Boiling Point 165-167 °C
    Density 0.894 g/cm3 at 25 °C
    Flash Point 50 °C
    Refractive Index 1.415-1.417
    Smiles CCOC(=O)C(C)CC=C
    Pubchem Cid 15530
    Solubility Insoluble in water, soluble in organic solvents

    As an accredited Ethyl 2-Methyl-4-Pentenoate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 500 mL amber glass bottle with tight-sealed cap, labeled “Ethyl 2-Methyl-4-Pentenoate, 98%” including hazard and handling instructions.
    Shipping Ethyl 2-Methyl-4-Pentenoate should be shipped in tightly sealed containers under cool, dry conditions, away from sources of ignition, heat, and incompatible substances. Ensure compliance with regulations for flammable liquids. Use appropriate hazard labeling and packaging to prevent leaks or spills during transit. Consult the SDS for specific shipping guidelines.
    Storage **Ethyl 2-Methyl-4-Pentenoate** should be stored in a tightly closed container, in a cool, dry, and well-ventilated area, away from sources of ignition or heat. Protect from direct sunlight and moisture. Store separately from oxidizing agents and strong acids. Ensure appropriate labeling and restrict access to authorized personnel. Follow all relevant chemical safety guidelines and regulations.
    Application of Ethyl 2-Methyl-4-Pentenoate

    Applications of Ethyl 2-Methyl-4-Pentenoate in Industrial Manufacturing

    As a dedicated chemical raw material producer, we supply Ethyl 2-Methyl-4-Pentenoate for several specialized downstream industries. Its distinctive structure supports key synthesis pathways, especially in flavorants, agrochemicals, pharmaceutical intermediates, and specialty polymer manufacturing. The following sections detail established industrial uses, formula integration levels, standards addressed, automation steps, and specific end products created by our global customers.

    1. Flavor & Fragrance Ester Synthesis

    Flavor compound manufacturers value this ester for its capacity to introduce nuanced fruity and green odor notes. Used as a building block in both food-approved and cosmetic aroma esters, it serves in high-purity syntheses where structural integrity and low impurity profiles are critical. Formulators control batch quality and traceability according to strict purity and residue benchmarks, particularly in regions with comprehensive fragrance legislations.

    Industry compliance standards

    • IFRA (International Fragrance Association) Standards for all aroma chemicals
    • EU Regulation (EC) No 1223/2009 for cosmetic safety
    • US FDA CFR Title 21 §172.515 (Food Additives Permitted for Direct Addition to Food for Human Consumption—Synthetic Flavoring Substances and Adjuvants)
    • ISO 9235 (Aromatic natural raw materials—Vocabulary)

    Typical usage ratio

    • 0.025%–0.10% of final fragrance oil formulation; fine-tuned by intended aroma intensity and target market-specific limits

    Downstream process integration

    • Integrated post-esterification into the compounded fragrance oil, or pre-blended in modular aroma bases prior to final adjustment and filtration

    Final product types

    • Fine perfumes and colognes
    • Toiletry fragrances (soaps, creams, lotions)
    • Beverage and confectionery flavors (in accordance with food-safe approvals)
    • Aroma diffusers and air care solutions

    2. Agrochemical Intermediate (Insecticide & Herbicide Synthesis)

    The agricultural chemicals sector applies this compound in the synthesis of selective intermediates for next-generation crop protection molecules. During active ingredient development, this ester serves as a key synthon for ring closure or side chain extension, with isomeric stability crucial for downstream activity. Production lines feature closed-loop quality monitoring and environmental safety measures, necessitating full adherence to regional chemical safety laws and Good Manufacturing Practice (GMP) for technical-grade actives.

    Industry compliance standards

    • FAO/WHO Specifications for Plant Protection Products
    • REACH regulation (EC) No 1907/2006 (chemical safety and registration for Europe)
    • China GB 2763 (MRL for pesticides in food)
    • ISO 9001-certified QC and batch traceability

    Typical usage ratio

    • 3%–8% of batch weight for intermediate synthesis; determined by pathway efficiency and desired isomer content

    Downstream process integration

    • Charged as a precursor in multi-step alkylation or cyclization reactions within dedicated intermediate synthesis lines, followed by extraction and purification before formulation into technical concentrates

    Final product types

    • Technical-grade insecticide actives (e.g., pyrethroid and neonicotinoid precursors)
    • Selective herbicide actives (for broadleaf and grass weed control)
    • Seed treatment active ingredient blends

    3. Pharmaceutical Intermediate for Heterocyclic API Synthesis

    Pharmaceutical manufacturers employ this compound as a defined intermediate in multi-stage synthesis of therapeutically active heterocyclic ingredients. The high reactivity of its pentenoate segment permits controlled ring closure for non-aromatic cyclic scaffolds central to patent-protected APIs. Process chemists closely manage impurity profiles in compliance with pharmacopeial monographs and cGMP protocols, including isolation and removal of side-products for injectable-grade intermediates.

    Industry compliance standards

    • ICH Q7 GMP for Active Pharmaceutical Ingredients
    • USP-NF Monograph standards
    • European Pharmacopoeia (Ph. Eur.) purity requirements
    • FDA 21 CFR Part 211 (Finished Pharmaceuticals)

    Typical usage ratio

    • 5%–12% of step-wise batch mass, adjusted according to specific route design and required conversion yield

    Downstream process integration

    • Added during intermediate formation in sequential condensations or ring-closure reactions; post-reaction, intermediates isolated by crystallization or distillation before onward transformation and purification of API

    Final product types

    • Prescription-grade APIs for antihypertensive, anti-infective, and CNS drugs
    • Generic pharmaceutical intermediates for small molecule therapeutics
    • Advanced bulk intermediates for contract manufacturing organizations (CMOs)

    4. Specialty Polymer Monomer and Modifier

    Producers of niche polymers and specialty resins utilize this ester as both a co-monomer and terminal modifier during the production of advanced acrylics and UV-curable materials. Its unsaturated pentenoate group imparts tunable flexibility and enhances grafting efficiency. The material’s purity, moisture content, and residual solvents are tightly controlled under polymer industry quality benchmarks, ensuring downstream molecular weight and physical property consistency for specification-driven industrial customers.

    Industry compliance standards

    • ISO 14001 (Environmental management for chemical production)
    • RoHS (Restriction of Hazardous Substances) for electronics resins
    • REACH SVHC (Substances of Very High Concern) exclusion lists
    • ASTM D256 and D638 (Standard test methods for polymer properties)

    Typical usage ratio

    • 0.5%–4% by weight in copolymer or pre-polymer mixture; final percentage customized based on target degree of modification or flexibility

    Downstream process integration

    • Metered directly into the monomer feed during block copolymerization or added to pre-polymer blends before final cure or extrusion; process adapted for both batch and continuous mixing technologies

    Final product types

    • Flexible acrylic coatings for automotive and consumer electronics
    • UV-cured printing inks and adhesives
    • Specialty films and sealants in construction or packaging
    • Engineering plastics requiring custom flexibility-modified segments
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    Certification & Compliance
    More Introduction

    Ethyl 2-Methyl-4-Pentenoate: In the Manufacturer’s Hands

    Our Journey With Ethyl 2-Methyl-4-Pentenoate

    Ethyl 2-methyl-4-pentenoate has become a centerpiece in our lineup because of the reliability it brings to synthesis work, especially in fragrance, flavor, and pharmaceutical applications. After years of controlling every stage—right from raw material procurement to the finishing process—we’ve learned that precision at each step is what defines this compound’s quality. Many customers reach out with nuanced demands for purity or reactivity, and that pressure sent us diving deep into what makes this ester unique against similar alkene-containing esters.

    Our Standard: Purity and Performance

    This ester’s molecular profile, C8H14O2, creates a balance of volatility and reactivity that has found favor both in experimentation and scale-up operations. Focusing on the manufacturing side, we put consistent energy into monitoring every batch for appearance, content, GC purity, acid value, and water content. Being on the producer’s side, we see daily how minor variations in process temperatures or feedstock quality send ripples down into the performance of the final product. For Ethyl 2-methyl-4-pentenoate, we keep the acid content below 0.1% and tightly limit water, which means the substance flows clean and clear for downstream reactions, whether you’re esterifying or trans-esterifying it further.

    Where This Molecule Outshines Others

    It is tempting to group Ethyl 2-methyl-4-pentenoate with other simple esters. Still, from our bench-top experiments and production runs, we’ve seen the double bond at the fourth carbon delivers notably different behavior than saturated or linear analogs. Chemists value that more subtle unsaturation; it opens up selective hydrogenations or Diels-Alder reactions without the unpredictability that sometimes comes with more reactive double bonds. Standard ethyl pentanoate or ethyl crotonate lack this fine-tuned behavior in organic synthesis. We have adjusted our manufacturing approach to emphasize retention of the alkene, avoiding isomerization under heat. Several flavor designers have told us that this molecular configuration also creates a nuanced, fruity-green note that doesn’t shift or deteriorate as quickly as straight-chain esters. Even after years of production, we still get inquiries about whether it’s possible to engineer analogs—or push the degree of reactivity further—so product designers can tweak profiles in fine fragrance or active ingredient synthesis.

    From Lab Bench to Scale: Batch Consistency Stories

    Most end users ask about batch consistency, and we don’t shy away from sharing stories. There was a time in our earlier days when a slight shift in distillation pressure led to extra byproduct formation. We overhauled condenser flow rates and introduced on-line GC monitoring. These investments mean we can hit 98%+ GC purity batch after batch. The bulk of our clients work in fine chemicals, expecting consistency each purchase. This reliability doesn’t only come from automation; it’s our operators, who have built a feel for the process. They notice slight divergences before machines do, such as an off odor or a barely visible hue change. It’s that hands-on vigilance, not just instrument readouts, that has shaped our standards.

    Direct Applications: Flavor, Fragrance, and Pharmaceuticals

    Many believe that the bulk of ester chemistry ends in flavors or fragrances, but Ethyl 2-methyl-4-pentenoate tells a broader story. It serves as a key intermediate for producing certain pharmaceutical building blocks—especially in synthesis routes that benefit from a mild, selectively unreactive alkene. We’ve worked with customers scaling up fine fragrance compounds who rely on our lot’s trace impurity profile to avoid downstream odor off-notes. There’s a small but dedicated set of industrial chemists who use this ester to build up multi-functional intermediates through Michael additions or cross-metathesis reactions. Because we oversee manufacturing, we hold back a reference sample from every run, letting us and our customers look back and confirm consistency.

    Feedback Loop: Driving Improvements

    We practice something many in production chemistry neglect: open discussion with end users. Early on, plant operators didn’t always realize how small fluctuations in residual solvents, or the faintest side product, could alter a perfumer’s trial or a synthetic chemist’s reaction profile. Now, not only do we act on analytical feedback, but we also incorporate precise GC-MS characterization before releasing lots. It’s not just lab paperwork for us; it’s driven by stories like the multinational customer who found a unique aldehyde impurity in one run—the kind of thing only a producer with a close-loop analytical system can catch and correct early.

    Handling and Storage: Practical Learnings

    From first-hand experience, ethyl esters like this can be more sensitive than their saturated cousins, both in terms of shelf life and physical handling. Too much moisture can trigger slow hydrolysis, spiking acid value and reducing reactive yield. That’s led us to customize drum liners and develop real-time inventory checks. Cold storage drops off aroma volatility, but risk of crystallization doesn’t concern us here thanks to the lower melting point. Staff training emphasizes avoiding contact with oxidants and using only tested sealants for long-term storage—pragmatic steps rather than theoretical, since these protocols have cut customer complaints regarding shelf stability.

    Comparing Options: Making Choices on the Production Line

    Choices on which ester to supply for a project often come down to more than just price or flashy lab data. Ethyl 2-methyl-4-pentenoate gives us a toolkit for building complexity. When compared with ethyl isovalerate or ethyl butyrate, the methyl branch and alkene create unique steric and electronic environments. In flavor chemistry, that adds depth instead of the high-note intensity commonly associated with shorter or straight-chain esters. Production chemists trust it for its combination of stability and selective reactivity. Those attributes help shorten synthetic routes, particularly if a customer wants fewer protection-deprotection cycles during complex molecule construction. We’ve worked on hundreds of technical support calls where a customer, stuck with another supplier’s inconsistent lot, turns to us for guidance—knowing our manufacturing experience translates into answers rooted in real performance data.

    Safety: Real-World Perspectives

    Years in the plant have given our staff a practical sense for risk mitigation. Unlike some higher molecular weight esters, this material carries moderate volatility that demands thorough ventilation and basic industrial hygiene. We never rely solely on MSDS documents; actual in-plant monitoring, air sampling, and leak checks have taught us more than a checklist ever could. For instance, we once discovered a hidden vapor leak in an aging gasket system only because a shift supervisor noted a faint, sweet odor in an adjacent area. Experiences like these have nudged us to put double-gasketing and enhanced personal protective equipment into place, even before audits require it.

    Environmental Impact: Our Responsibility as Producers

    Occupying the manufacturer’s seat, we carry the responsibility for how our process affects both upstream suppliers and downstream partners. Waste water from our processes, which contains trace organic residues, previously required off-site treatment. We’ve since invested in in-house treatment—using activated carbon beds and biological filtration—cutting waste truck movements and slashing VOC emissions well below regional limits. Our operations team has also succeeded in recycling spent solvents back into the workflow where possible, lowering not just costs, but our carbon footprint. It’s a rewarding challenge balancing economic viability with environmental stewardship at every planning session.

    Trust From Transparency

    Many buyers approach us after disappointing experiences with third-party traders or unknown entities. Exact origin, complete batch analytics, application guidance, and hands-on customer support matter. From our perspective, accountability comes only when the manufacturer is open about successes and mistakes alike. Once, a batch recall for an out-of-spec shipment pushed us to overhaul our internal traceability—now, integrating blockchain tracking with traditional paper trails. This allows partners large and small to check live data on their lots, covering every shift report and lab chromatogram at each stage. This transparency, more than any marketing pitch, earns wider trust in a crowded marketplace.

    Pushing the Boundaries: R&D in Practice

    We have always reserved resources for ongoing research and development, even if that means production volumes sometimes take a back seat. Having biweekly feedback meetings with synthetic chemists, flavor formulators, and fragrance blenders keeps us nimble. Novel catalyst systems have been a focus: slight tweaks to the process increased reactor productivity and brought down byproduct formation by nearly 10%, benefiting everyone from process engineers to innovation teams. By taking part in joint development agreements, we get early reads on where customers want to go next—tailoring future lots to shifting needs. The story of Ethyl 2-methyl-4-pentenoate isn’t static; it’s shaped by the push and pull of new chemistry, application trials, regulatory changes, and evolving end uses.

    Quality in Every Shipment

    Every manufacturer says their product is reliable, but for us, the journey from raw material to finalized drum or IBC takes real on-the-ground skill. It’s our operators overseeing esterification, those running distillation columns, and the analysis team repeating GC and Karl Fischer titrations who set the bar high. During busy months, much of the team tracks minor deviations, such as hot-spots in the reactor that nudge conversion profiles. Even after scaling up, our testing, trained hands, and continuous upskilling program keep every shipment within the narrowest specifications. Customers have commented they often receive more detailed COA data from us than from multinational giants, because our staff insist on over-delivering on quality documentation.

    Regulatory and Global Compliance: Doing It Right, Not Just Fast

    Stepping into export markets, we know the differences in regulatory standards bring new layers of complexity. Our compliance managers audit both supplier origin and finished product to keep all levels above the minimum thresholds. Ban lists and ingredient restrictions shift by region, but each time, we couple precise analytics with rapid response from our document team. Time and again, we’ve seen that a communicative, knowledgeable producer outperforms a distant intermediary—especially for buyers who rely on 100% traceability in their value chains. Our partners come to us precisely because, as direct producers, we troubleshoot issues on-the-spot instead of passing the buck.

    Customer Partnerships Shape Our Process

    The dialogue goes both ways. Specialty customers—like those designing flavors for nonalcoholic beverages—give us insight into how trace components interact with complex matrices. Hearing a flavor blender call for tighter odor thresholds, for instance, has real influence on our next pilot plant schedule. In the pharmaceutical space, queries about 100ppm impurity specification move us to collaborate with our in-house validation team. It’s these iterative conversations that evolve our manufacturing approach far more than theoretical lab work ever did.

    Looking Ahead: A Manufacturer’s Perspective

    Being at the foundation of Ethyl 2-methyl-4-pentenoate production for years, we aren’t resting on routine. Automation is advancing, but the human element remains crucial: trained teams, open communication with end users, hands-on quality control, and investment in more robust environmental systems. All these make a measurable difference. Future projects will address new sustainability practices, alternative feedstock sourcing, and even smarter process equipment. We’re expanding testing methodologies, exploring new synthetic routes, and training staff to adapt as customer expectations go beyond purity—to traceability, environmental impact, performance, and support.

    The Everyday Value of Manufacturing Experience

    Day-to-day in production, familiar aromas of esters, the hum of chillers, and the steady checks from operators all show that consistency relies less on slogans than on applied experience. Partners—be they fine fragrance formulators, pharmaceutical compound designers, or industrial chemists—care about knowing where their starting materials come from. In the end, it’s knowing both the product and process, recognizing real-world variables, and adapting before problems magnify that enable us to deliver Ethyl 2-methyl-4-pentenoate batches customers can trust again and again. The journey is ongoing, shaped by those who use the molecule and those who make it, working together to keep improving every facet of chemical production.