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Dithiobiuret

    • Product Name Dithiobiuret
    • Alias Dithiocarbamoylurea
    • Einecs 219-006-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    373305

    Cas Number 109-08-0
    Molecular Formula CH4N4S2
    Molar Mass 136.20 g/mol
    Appearance White to pale yellow crystalline solid
    Melting Point 138-140 °C
    Solubility In Water Moderately soluble
    Boiling Point Decomposes before boiling
    Density 1.49 g/cm³
    Odor Odorless
    Ph Neutral to slightly acidic (aqueous solution)
    Synonyms Thiobiuret, Thiosemicarbazidodithioic acid
    Stability Stable under recommended storage conditions

    As an accredited Dithiobiuret factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Dithiobiuret is packaged in a 100-gram amber glass bottle, featuring a secure screw cap and a clear hazard warning label.
    Shipping Dithiobiuret should be shipped in tightly sealed containers, protected from moisture and incompatible materials such as strong oxidizers. It must be handled as a hazardous chemical, with appropriate labeling and documentation. Transport under cool, dry conditions, complying with local, national, and international regulations for toxic and environmentally hazardous substances.
    Storage Dithiobiuret should be stored in a cool, dry, well-ventilated area away from incompatible substances such as strong oxidizers and acids. The chemical should be kept in tightly closed, clearly labeled containers made of materials resistant to its corrosive properties. Protect from moisture and direct sunlight. Use secondary containment to avoid environmental contamination in case of spills or leaks.
    Application of Dithiobiuret

    Applications of Dithiobiuret in Industrial Manufacturing

    Dithiobiuret serves critical functions in several specialized industrial applications due to its unique chemical reactivity as a reducing agent and complex-forming compound. Our production integrates strict quality control to ensure consistent performance across downstream manufacturing. Below are the principal sectors where our dithiobiuret is directly incorporated into final products and industrial processes, each with specific compliance benchmarks, engineered dosage, process stages, and end-use articles.

    1. Rubber Vulcanization Accelerator for Specialty Elastomers

    Major rubber product manufacturers rely on dithiobiuret as an ultra-accelerator in the formulation of high-performance vulcanization systems, particularly for the manufacture of nitrile and butyl rubber compounds where fast curing and thermal stability are required. The compound increases crosslink density and improves heat aging resistance, entering the compound as a secondary accelerator during the mixing stage and participating directly in sulfur crosslink formation. Manufacturers adjust dosage based on the required cure rate and mechanical properties of the finished elastomers.

    Industry compliance standards

    • ASTM D3182 – Standard Practice for Rubber – Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    • ISO 2393 – Rubber test mixes – Preparation, mixing and vulcanization
    • REACH Regulation (EC) No 1907/2006 compliance for chemical safety
    • RoHS 2011/65/EU for restricted substances in electrical applications of elastomer goods

    Typical usage ratio

    • 0.15%–0.6% by total polymer weight; the level is set according to targeted cure kinetics and the sulfur donor/accelerator package in the formulation

    Downstream process integration

    • Added to rubber masterbatch during Banbury or internal mixer blending, before addition of curatives and activators, enabling co-cure with sulfur in press or autoclave vulcanization cycles

    Final product types

    • Oil-resistant automotive hoses
    • Chemical process seals and gaskets
    • Heat-stable conveyor belts
    • Industrial glove compounds

    2. Photographic Chemical Formulations

    The silver halide photography industry uses dithiobiuret as a selective reducing and antifoggant agent during the emulsion development phase, valued for its ability to prevent image distortion in black-and-white film and photo paper processing. The compound enters the developer bath as an additive to maintain image clarity and prevent uncontrolled reduction of silver ions. Its precise addition affects image density and grain structure, with quality requirements dictated by imaging and archival standards.

    Industry compliance standards

    • ANSI/NAPM IT9.2 – Photographic Processed Films, Plates, and Papers – Filing Enclosure and Storage Practices
    • ISO 10602 – Photography – Processed silver-gelatin type black-and-white films – Storage practices
    • EPA 40 CFR Part 261 – Management of photographic processing waste

    Typical usage ratio

    • 0.4–1.2 g/L in developer solution, adjusted based on film emulsion sensitivity and processing temperature

    Downstream process integration

    • Dosed directly into the aqueous developer bath at the preparation stage, followed by mixing with other developer components such as hydroquinone or Metol

    Final product types

    • Medical X-ray films
    • Black-and-white photographic paper
    • Archival microfilms
    • Specialized motion picture processing emulsions

    3. Corrosion Inhibitor Additive in Industrial Water Treatment

    In closed-loop water systems, such as recirculating cooling towers and boiler feed circuits, dithiobiuret functions as a sulfur-based corrosion inhibitor. The molecule forms protective films on ferrous and non-ferrous metal surfaces, significantly reducing oxygen-driven pitting and scale formation. Industrial water treatment specialists incorporate it during make-up water preparation and dosage control is linked to real-time monitoring of system pH and metal ion concentration according to regulatory requirements.

    Industry compliance standards

    • ANSI/AWWA B100 – Standard for the Commissioning and Operation of Water Treatment Facilities
    • ASTM D3946 – Standard Test Method for Determining Stress Corrosion Cracking of Metal Alloys in Water Treatment Applications
    • US EPA National Primary Drinking Water Regulations (for indirect application and environmental discharge)

    Typical usage ratio

    • 10–50 mg/L traitement dosage, adjusted depending on water composition, metallurgy, and system turnover rate

    Downstream process integration

    • Introduced into water via proportional dosing pump installation in the feed line, typically after the filtration stage and before water enters heat exchangers or boilers

    Final product types

    • Treated water for district heating and cooling loops
    • Process water in metal finishing facilities
    • Steam production feedwater
    • Recirculating industrial cooling water

    4. Copper Electroplating Bath Additive

    Manufacturers in the printed circuit board sector and precision electronics plating operations implement dithiobiuret as a grain refiner and leveling agent in copper electroplating baths. It enters the electrolyte at controlled concentrations to improve metal deposition uniformity, minimize nodular growth, and ensure consistent surface morphology throughout the finished copper layers. Dosing levels are adapted in real-time based on plating current density and solution agitation parameters in accordance with electronics industry standards.

    Industry compliance standards

    • IPC-6012 – Qualification and Performance Specification for Rigid Printed Boards
    • IEC 61189-5-1 – Test methods for electrical materials and printed boards
    • UL 796 certification (for flame retardance and electrical reliability of finished boards)

    Typical usage ratio

    • 5–20 mg/L in copper sulfate plating baths; concentration is maintained by analytical titration and confirmed by hull cell testing

    Downstream process integration

    • Injected as a pre-mixed dosing solution into the main plating bath immediately prior to plating runs, with periodic monitoring and top-up as required by line throughput

    Final product types

    • Printed circuit board internal and external copper layers
    • Connector contacts for electronic assemblies
    • High-reliability copper-plated lead frames
    • Microelectronic component substrates

    5. Intermediate in Thiourea and Related Pesticide Synthesis

    In fine chemicals and agrochemical manufacturing, dithiobiuret serves as a key nitrogen-sulfur intermediate during the synthesis of various thiourea derivatives that act as contact fungicides and acaricides. Reaction engineers introduce the compound into batch reactors for thiourea formation, where it undergoes further transformation under controlled pH, temperature, and agitation. The entire process chain is governed by stringent environmental and hazardous substances control protocols to ensure product purity and regulatory compliance.

    Industry compliance standards

    • ISO 9001:2015 for batch-to-batch consistency in active ingredient manufacture
    • FAO/WHO Pesticide Specifications (e.g., for thiourea derivative standards)
    • REACH Annex XVII restrictions on intermediate handling
    • GMP for Active Substances used in Plant Protection Products Regulation (EC) 1107/2009

    Typical usage ratio

    • 10–20% molar equivalent as a starting material relative to target thiourea derivative yield, with adjustment for reaction selectivity and waste minimization targets

    Downstream process integration

    • Charged to synthetic reactor systems fitted with closed sampling ports, immediately prior to oxidative thiourea formation and downstream purification stages

    Final product types

    • Contact fungicides for cereals and fruit crops
    • Acaricides for horticultural use
    • Plant growth regulation agents containing thiourea moieties
    • Intermediate-grade nitrogen-sulfur specialty chemicals
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    Certification & Compliance
    More Introduction

    Dithiobiuret: Practical Insights from a Chemical Manufacturer

    For decades, our teams on the factory floor have watched dithiobiuret go from simple lab curiosity to a workhorse in copper extraction, polymer synthesis, and specialty intermediates. Many in the chemical sector rely on its peculiar reactivity or its role in creating stable complexes. Every batch we ship starts with rigorous raw material selection, and each run tracks purity from the mixer to the finished treatment. Keeping consistency across tons of output hinges less on paperwork and more on the quiet expertise of operators watching for the right color and filtering at the right pressure.

    Our Model and Core Specifications

    We produce dithiobiuret under the model DB-01. DB-01 comes in off-white or light yellow crystalline form, which often helps operators identify unwanted impurities right away—our experienced millers can pick up visual cues faster than most spectrometers. We maintain purity above 98%, verified batch by batch, since downstream applications depend on low side-product levels. Moisture content rarely exceeds 0.5% because improper drying leads to caking, forcing customers to spend extra hours breaking up lumps. Particle size is tuned to add efficiently to reactors, allowing quick dissolution for copper leaching or better flow in automated metering systems.

    The chemistry itself is straightforward. Our process starts with hydrazine sulfate, carbon disulfide, and sodium hydroxide—simple raw materials but precise timing and temperature control. We've adjusted our filtration lines over the years to trap fine particulate impurities, which used to cause operational headaches for customers running automated liquid injectors. We've also invested in sealed packaging rooms, so our product avoids atmospheric moisture during final packing. The bags—we use triple-layered PE—help protect from humidity during long sea voyages or storage in tropical climates.

    Application Know-How

    Dithiobiuret finds its widest use in copper hydrometallurgy. Leaching operators often run auto-feed hoppers, drawing from big-bag stocks that must pour without clumping. Upstream consistency means fewer process upsets. Before our current packing system, miners sometimes struggled with moisture-laden or uneven product leading to dosing errors. Since we switched to our current drier and packing workflow, feedback from leaching plants confirms smoother dosing rates and more predictable yields.

    Polymer manufacturers come at the material differently. Their needs focus less on bulk flow and more on purity and solubility. Even minor traces of byproducts affect the final resin characteristics. R&D chemists have told us repeated failures came from unclean raw stocks—one team even traced a persistent dye defect to traces of iron in an old dithiobiuret source. Now, our in-line filtration and post-drying checks screen out these common mineral contaminants. We also keep customer feedback loops open, so our formulation tweaks can align with changing resin requirements on the market.

    Differences vs. Other Chemical Intermediates

    Dithiobiuret shares some characteristics with thiourea, and at first glance, some customers mix them up. In real-world production runs, the two behave quite differently. Dithiobiuret forms chelates with a different affinity and under milder temperature and pH ranges than thiourea. In our plant trials, copper extraction rates using dithiobiuret consistently outperform thiourea in both kinetics and yield. Thiourea often suffers from oxidative breakdown in open circuits—dithiobiuret handles heavier loads before decomposing, so waste generation drops and overall process time tightens up. Our technical contacts in the mining sector have documented at least 12% shorter process times on average, which we trace to this core difference in molecular stability.

    Compared to sodium diethyldithiocarbamate, dithiobiuret rarely introduces sodium contamination downstream. In specialty industries such as catalyst production, that small change in trace metals influences product reactivity. Chemical manufacturers have strict guidelines for "tramp ions" in catalyst intermediates—more than a trace can cause complete catalysis failure or irreversible fouling. Years of close exchanges with catalyst makers gave us insights into how even milligram-per-kilogram sodium input can steer entire processes off course. Where possible, we run dedicated lines to avoid cross-contamination and meet these zero-tolerance requirements.

    Handling and Storage: A Manufacturer’s Experience

    Over the years, improper storage conditions have generated the bulk of complaints we've fielded. Dithiobiuret picks up water if kept open, leading to caking or microbial growth—two issues that spell trouble on the production floor. For consistent results, we keep all warehouse stacks elevated and rotate stock using a "first in, first out" approach based on arrival date. We recommend and practice short warehouse retention times. We’ve shut down an entire lot before shipment after a surprise humidity spike, saving both our reputation and the end customer from a costly reactor clogging event.

    Another major point is operator safety. Our team wears full PPE including nitrate gloves, goggles, and layered coveralls. Even minor spills are handled with industrial vacuum units, not swept away with brooms, because airborne dust can irritate skin and mucous membranes. Routine safety walkthroughs make sure nothing slips through the cracks, especially before those busy late shifts when exhaustion can set in. We train all new hires alongside seasoned workers who demonstrate best practices on the floor. Incidents have dropped since moving to a more hands-on, peer-led approach instead of bland safety slideshows.

    Our storage system also keeps product temperature controlled, especially in summer months with outside highs over 35°C. We've experimented with different storage paints for warehouse walls—white reflective coatings help keep temperatures stable. Our in-house data shows a drop in cake formation when product is kept below 30°C, supporting customer claims about easier dosing and fewer moisture-related clogs in summer deliveries. Plastic-film-laminated pallets form the last line of defense, reducing exposure during transfer to trucks and containers.

    Quality Control Realities

    As a direct manufacturer, we see firsthand how batch-to-batch variation in feedstock can affect the finished dithiobiuret. Early runs would sometimes show yellow hues if the carbon disulfide purity dropped or hydration was off by even half a percent. Our QA lab checks both input and output to catch these shifts. After we installed online spectrophotometry on one of our lines, we documented a 97% reduction in customer complaints tied to color or solubility. This immediate feedback loops from the lab to the line keep product within tight spec at all times.

    Our heavy metal screens go beyond basic requirements because customer R&D teams often run more sensitive analytical instruments than regulators specify. We’ve found that our best long-term partnerships start when we let process engineers visit our site—they learn the quirks of our production, and we gain feedback about real-world performance. Over time, these visits have prompted us to invest in better drying tech, improved blending tanks, and faster packaging lines. Our most demanding clients drive our highest product standards, and this open-door policy has paid off in both safety and purity metrics.

    Environmental and Regulatory Considerations

    The production and downstream application of dithiobiuret come with regulatory pressures, especially regarding effluent management and workplace exposure. We’ve spent considerable resources tightening our wastewater treatment lines—installing secondary containment tanks and advanced oxidation units—to achieve discharge levels well below regional maximums. Regulatory audits now pass smoothly because inspectors see a clear path of containment, from filtered process effluent to final neutralization. Years ago, little attention went to these steps, resulting in several near-miss incidents during storms. Our current setup includes backup power for all pumps, so even during blackouts, process units stay safe and leaks stay contained.

    Air emissions once raised eyebrows in local community meetings, especially with the characteristic carbon disulfide odor. Engagement with neighbors—public walkarounds, open factory days—helped quell concerns. On several occasions, we installed extra vapor recovery units proactively rather than wait for complaints or formal agency requests. Experience shows that good neighbor relations require more than following laws—it’s about informing people and proving care in every decision from vent placement to truck loading schedules.

    Dithiobiuret as a finished good doesn’t often raise the same hazard flags as some other mining or synthetic intermediates, but we still do our part to label, store, and ship with clear hazard markings. Our crew on the packing line cross-checks every pallet and uses tamper-evident seals to keep goods secure in transit. Regulatory visits have commended this diligence—not as a box-checking exercise but as a demonstration of real chemical stewardship in action.

    Continuous Learning and Shared Industry Progress

    Dithiobiuret manufacturing hasn’t always been smooth sailing. Early on, plant managers commonly saw raw material shortages or suffered from minor plant emissions. Every setback—from a runaway reaction to a flash drier outage—became a lesson. Regular meetings with our maintenance crew and QA team helped us catch small inefficiencies before they ballooned into big issues. For example, learning to adjust mixing rates during the rainy season fixed a major bottleneck and improved overall yield by nearly 6% one year. Years of learning created what we call our “living process manual”—updated based on new observations, not just stale SOPs from past management.

    We keep up with academic journals and industry roundtables because even established chemicals like dithiobiuret evolve with new science. For example, recent research suggests new uses as a crosslinking agent in specialty polymers and as a precursor to chelating agents for trace metal detection. Rather than sticking to one market, we track pilot trials in these emerging applications, allocating small-batch runs for leading research partners. Our technical salespeople regularly visit customer labs to compare notes, not just to pitch a sale. Field feedback feeds straight into our planning meetings, reminding us how every small adjustment can save costs or create opportunities for new grades.

    Every shift operator on our teams sees the real impact of process details—temperature swings, small leaks, overlooked filter beds. We encourage staff to record even minor changes as formal log entries. These serve two purposes: helping us spot patterns and maintaining transparency if a customer has a concern about a specific lot. Several years running, this detailed record-keeping uncovered a supplier change that negatively impacted batch consistency. Quick trace-back let us switch raw material sources before serious downstream issues emerged.

    Engagement with End-Users and Industry Peers

    Direct conversations with customers matter. Several plant engineers from the copper leach sector have spent days in our facility, sharing frustrations or successes from their own operations. Those talks keep our formulations relevant and allow us to respond to process challenges in real-time. One partnership with a South American miner resulted in a special low-moisture dithiobiuret lot. Adjusting our packaging and drying lines for that project led to year-long improvements in output consistency, a win for both sides. Manufacturers talking directly with manufacturers—no intermediaries—keep us grounded in real production needs, not just theoretical specs.

    We’re involved with our industry peers as well. Regular factory visits happen not just with customers but also with academics, suppliers, and even competitors. Learning from others’ batch failures or seeing how a neighboring plant resolved dust control challenges usually leads to small but meaningful changes on our own lines. These collective lessons accumulate into industry-wide improvements—every safe plant, every upgraded filtration, every smarter QC protocol moves the field forward. Competition drives plenty of innovation, but collaboration—especially on safety and environmental impact—raises standards for everyone in the supply chain.

    Addressing Ongoing Challenges

    Each production year unfolds with its own set of hurdles. Global raw material swings in recent years exposed the need for multiple supplier contracts. We settle on suppliers only after detailed QA checks, site visits, and assurance of sustainable sourcing. Price spikes usually come with shortages, but cutting corners to make up margins would only erode years of customer trust. Keeping excess raw material in inventory increases overhead, but we prefer stability and reliability over scrambling to fill last-minute orders at the risk of product quality.

    Shipping logistics also test our agility, especially with longer ocean transport to certain regions of Africa or South Asia. Humidity damage used to be a persistent risk before triple-layer bagging and the use of desiccant packs in every container. We pushed for better port storage arrangements through our local agents, ensuring containers stay covered and off the ground before clearing customs. As a manufacturer, responsibility for product performance extends until our material runs through the customer’s feeder—weak links in the chain don’t get hand-waved away.

    Major weather events pose sporadic but real risks, affecting everything from raw material delivery to finished product shipment. After a major typhoon delayed critical feedstock for nearly a month, our management realized that redundancy—alternate suppliers, safety stocks, double-checked shipment tracking—beats any wishful thinking. We now run routine emergency preparedness drills, treating every flood or power outage as a potential trigger for process improvement. Even if the past year unfolds quietly, these drills keep both our people and our product safe.

    Future Directions and Customer Collaboration

    Looking ahead, new research and process upgrades will drive further change in how dithiobiuret is produced and applied. Some development efforts focus on reducing input energy use, shortening synthesis times, and cutting waste output per ton of product. We’re trialing semi-continuous production rigs, exploring how shorter downtimes could turn into real output gains for buyers requiring flexible order runs. Customer co-development gives a window into future trends. One example is mining companies shifting toward greener reagents and closed-loop leach circuits. Dithiobiuret fits well into processes aiming for lower eco-toxicological impact compared to more hazardous legacy agents. We’re working alongside environmental consultants to model long-term leachate impact and build a case for expanding into new regulatory climates.

    Our R&D group expands internal testing—not just for reactive yield but for compatibility with new forms of reactor automation and AI-driven dosing systems now gaining traction in large-scale copper extraction. As those tools mature, our testing lines adapt, feeding back tweaks that make dithiobiuret a better fit for high-tech processing plants running 24 hours a day. Partnering with manufacturers automating their feed systems has already resulted in several product optimizations—especially in mixing behavior and antistatic handling. Each process tweak that lands in our operating manual reflects a real-world trial, not just lab curiosity.

    Collaborative product stewardship will stay central. Sharing best practices between plant engineers, product safety officers, and supply chain managers creates smarter overall use of dithiobiuret. Every improvement in packaging, storage, handling, and even transportation feedback plays a role in improving safety, efficiency, and environmental responsibility. Over time, our field notes, batch logs, and direct conversations ensure both continuous improvement and practical support for end-users worldwide—no textbook summaries, just hard-won lessons learned on the production line and tested on the factory floor.