|
HS Code |
224520 |
| Chemicalname | Difluorochloromethane |
| Commonname | HCFC-22 |
| Casnumber | 75-45-6 |
| Molecularformula | CHClF2 |
| Molarmass | 86.47 g/mol |
| Physicalstate | Colorless gas |
| Boilingpoint | -40.8 °C |
| Meltingpoint | -160 °C |
| Density | 1.21 g/cm³ (at 25 °C, liquid) |
| Solubilityinwater | 0.30 g/100 mL (at 25 °C) |
| Odor | Faintly sweet, chloroform-like |
| Vaporpressure | 9,440 mmHg (at 21.1 °C) |
| Criticaltemperature | 96.2 °C |
| Criticalpressure | 4.99 MPa |
| Unnumber | 1018 |
As an accredited Difluorochloromethane factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Difluorochloromethane is packaged in a 58 kg gray steel cylinder, labeled with chemical name, hazard symbols, and safety instructions. |
| Shipping | Difluorochloromethane (R-22) is shipped as a liquefied, compressed gas in high-pressure steel cylinders. Classified as a hazardous material, it requires careful handling and labeling per international regulations (UN 1018). Cylinders must be stored upright, protected from heat and physical damage, and transported with appropriate safety documentation and protective equipment. |
| Storage | Difluorochloromethane (R-22) should be stored in tightly closed cylinders or containers in a cool, dry, and well-ventilated area, away from direct sunlight and sources of heat or ignition. Storage areas should be equipped to avoid leaks and accidental release. Keep away from incompatible materials such as strong oxidizing agents. Cylinders should be properly labeled and secured to prevent tipping or damage. |
Applications of Difluorochloromethane in Industrial ManufacturingAs a manufacturer specializing in high-purity difluorochloromethane, we focus on its crucial downstream roles in core industrial supply chains. Our material supports essential chemical synthesis and refrigerant applications that require controlled purity, reliable reactivity, and strict conformance with sector regulations. Below, we outline practical, scenario-specific uses of difluorochloromethane, detailing the relevant manufacturing standards, typical inclusion ratios, processing steps, and finished products observed in the field. 1. Refrigerant Fluid Production for Air Conditioning and Chiller SystemsDifluorochloromethane remains widely adopted as a working fluid or as a blend component in the manufacture of refrigerant gases for stationary and mobile air conditioning, chillers, and heat pumps. This compound offers the desirable pressure-temperature behavior and oil compatibility required for compressor-driven systems, particularly in legacy equipment and in regions supporting extended transitional use under phase-out protocols. As a key ingredient, it plays a role in the physical charging and formulation blending stages, where controlled concentration ensures system safety and thermodynamic efficiency in finished refrigerant blends. Industry compliance standards
Typical usage ratio
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2. Pharmaceutical Intermediate and Agrochemical SynthesisAs a foundational halomethane, difluorochloromethane enables selective fluorination and chlorination in the synthesis pathways of active pharmaceutical ingredients (APIs) and certain agrochemical actives. Its controlled reactivity supports stepwise functional group conversion, offering advantages in atom economy and product isolation during fluorination steps. Typically introduced in closed reactor streams for gas-phase or liquid-phase halogen-exchange or addition reactions, it contributes directly to the molecular backbone or as a transient reaction facilitator, always under strict process stewardship to comply with chemical synthesis and cleaning validation requirements. Industry compliance standards
Typical usage ratio
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3. Feedstock for Polytetrafluoroethylene (PTFE) Monomer ManufactureDifluorochloromethane serves as a critical feedstock in the production of tetrafluoroethylene (TFE), the monomer for PTFE. In thermal pyrolysis processes, controlled cracking converts difluorochloromethane into TFE gas, supporting large-volume polymer precursor requirements. Strict feedstock purity is necessary to avoid downstream polymer contamination, and process engineers optimize temperature and feed rates as part of continuous or batch pyrolysis to maximize yield and minimize halogenated by-products. The linkage between upstream raw material and final polymer properties underscores the importance of feedstock traceability and product stewardship in this chain. Industry compliance standards
Typical usage ratio
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4. Chemical Blowing Agent Precursor for Polyurethane Foam ManufacturingAs a foam expansion agent precursor, difluorochloromethane has been historically adopted in the synthesis of hydrofluorocarbon blowing agents through controlled chemical conversion. The raw material undergoes catalyzed halogen-exchange reactions to yield lighter, less ozone-depleting HFC blowing agents, which possess carefully tuned volatility and compatibility profiles for rigid and flexible polyurethane foam manufacturing. Monitoring of batch recipe ratios and trace-by-product levels remains critical to downstream foam consistency and system safety, especially where regulatory constraints on original CFCs and certain HCFCs apply. Industry compliance standards
Typical usage ratio
Downstream process integration
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Difluorochloromethane, which you might know as R22, has shaped the way cooling systems work for decades. Since the late 1930s, our teams have focused on refining the quality and purity of R22 in our facilities, always using feedback from refrigeration engineers and installers in the field. In day-to-day production, we draw on years of trial and error, adapting filtration, distillation, and gas handling practices to get to a consistent, low-moisture, high-purity product. Unlike resellers or traders, we follow this material and its impact from its earliest batch to the cylinders set out on loading docks. Operators ask us about batch analysis, aftertaste in blends, and compressor lifetime—things you only hear about from people who open the valve themselves.
The molecular structure of Difluorochloromethane (CHClF2) reflects a balance between reactivity and stability. This isn't just a textbook detail. Stability under pressure matters every time a system runs long hours in humid climates, or when ambient temperatures swing hard at the loading dock. We closely monitor every filling line to avoid moisture pickup and hold non-condensable gases as low as we can—because even tiny deviations show up in refrigeration performance, foaming in lubricants, or premature wear on valves down the line. Decades in manufacturing show that reliable R22 takes methodical control, from raw HF to the final blend.
While the world sees most of the talk around Difluorochloromethane focused on environmental regulations and lifecycle shutdowns, we meet the hands-on detail that refrigeration techs rely on. R22’s thermodynamic properties have made it a reliable workhorse for mid- and low-temperature refrigeration, comfort air conditioning, and process cooling. Packages using R22 deliver high volumetric cooling capacity and manageable operating pressures. This sounds academic until you stand on a rooftop at noon, watching a compressor run stably in 40-degree heat without constant attention.
We build R22 for commercial and industrial use. Our clients operate milk chilling tanks, process-cooling skids, and heat pumps across a wide climate range. In these sectors, downtime is expensive and repair calls mean lost product or missed production targets. They need material with batch-to-batch consistency and clear documentation. Over more than thirty years, many plant managers keep a close relationship with their refrigerant supplier because they trace wear patterns or component failures back to the cylinder. Our manufacturing records don’t just serve compliance purposes—they let us diagnose issues linked to moisture content, acidity, or contaminants that others miss.
There’s more to R22 than listed numbers. Its boiling point sits at -40.8°C, which supports low- and medium-stage compressors that have to run reliably season after season. R22 keeps miscibility with mineral oils. This point alone reduces maintenance headaches for installations with legacy equipment, as mineral oil lubricates easily and doesn’t come with oil return risks that newer blends bring into older lines.
Pressure testing every batch is more than just regulatory—compressor rebuilders and installers often come directly to us to trace non-condensable gases or to request data on even trace sulfur content. Too much of either and the oil turns acidic or forms sludge; too little quality control shows up months later as system inefficiency. To us, it’s clear: chemical stability, moisture control, and 99.5%+ purity targets aren’t negotiation points—they’re what separates usable product from batch returns. Our technical staff see that difference on the shop floor and at the client’s condenser.
A standout quality of Difluorochloromethane is its single-molecule formulation. Blends like R404A or R410A require constant attention, elaborate charging procedures, and reclaim processes because they fractionate. R22 charges easily in both vapor and liquid phase, without fractionation or glide, so charge adjustments after minor leaks don’t demand a complete pump-down and recharge. Technicians in tight quarters or remote sites appreciate this: time saved on the job returns in trust and lower risk.
After decades supplying to both OEMs and independent coolers, we understand that each system draws out unique strengths from R22. Supermarket racks call for a steady evaporating temperature, and R22 delivers robust cooling without high discharge temperatures that threaten compressor seals or oils. In cross-country cold-chain transport, truck-based and container-based chillers use R22 for its ability to maintain temperature with fewer service calls compared to early HFC blends, which can swell seals or run into glide-related charge imbalances.
Installers regularly report that even after thousands of run-hours in mid-aged plants, R22-based systems have lower record of compressor failure or evaporator corrosion compared to some alternatives. This is not just a claim; it comes from years of tracking compressor warranties and leak histories supplied by our clients, especially in food storage or continuous-process applications. Field data shows that well-manufactured R22 (tightly controlled acidity and dryness) supports repeatable performance, even where charging accuracy isn’t perfect and line lengths vary.
Over the last two decades, R22 faced regulatory phaseout across many jurisdictions. The Montreal Protocol called attention to ozone depletion, due to R22’s chlorine content. We’ve seen refrigerant allocation quotas, end-of-life mandates, and legal restrictions on new equipment installation. Every year, we focus as much on reclaim quality and retrofit support as on initial manufacturing. As legacy systems persist, clients look to keep them running without switching over entire plant piping or sacrificing system performance.
Our engineers work alongside recovery specialists and retrofit techs to manage transition plans. We see real risks in abruptly shifting a system from R22 to a blend with high temperature glide or incompatible lubricant demands, especially in food-grade environments. We often walk maintenance techs through step-by-step changeovers, pointing out the subtle differences that matter only when you open a line or flush a system: carrying out proper evacuation, filtering acids, adjusting expansion valves, and testing for system leaks.
The phaseout has boosted attention on reclaimed and recycled R22. Manufacturers play a key role in setting and enforcing standards for reclaim purity and contaminant screening—because recycled gas sometimes arrives loaded with residual oil, sludge, or even non-condensables drawn in from neglected recovery gear. Our labs routinely reject off-spec reclaim, working with recovery contractors to tighten acceptance specifications and supply chain tracking.
We see possibilities for new equipment. Ultimately, we invest in molecules with zero ozone depletion and low global warming impact. R22’s practical success gives us a model to chase: reliability, material logistics, and deeper knowledge of field-service problems. Blends like R407C or R427A now pick up the job in many sites, but our engineers monitor oil return, discharge temperature, and thermal stability carefully. Design changes in compressors, improved microchannel heat exchangers, and better lubricants all came about because older systems set standards on runtime and serviceability.
Choosing R22 brings fewer surprises to experienced installers. Unlike R410A, which operates at much higher discharge pressures and demands new piping, R22 works safely in moderate-pressure equipment many owners already have. Installers value that older mineral and alkylbenzene oils used with R22 handle miscibility and oil return reliably, ditching the need for synthetic lubricants required by R410A or R32. Reports from field techs confirm that R22 seldom attracts the same degree of internal system corrosion or wax deposits found in some blends, attributed partly to its single-component makeup.
Looking at blends like R404A reveals more tradeoffs: broad glide, increased theoretical cooling, but often more complicated performance in practice. Glide means performance swings if liquid and vapor don’t charge in precise ratios. Some customers tried switching to R404A in the midst of regulatory changes and found the charge tolerance and oil return problems forced extra service visits—stories that travel fast through the maintenance community. The collectors of used compressors, reclaimers, and long-haul delivery drivers all pass feedback up the chain and we listen: reliability trumps theoretical maximum cooling in busy facilities where unplanned outages cost much more than incremental power savings.
With pure hydrofluorocarbons (HFCs), higher molecular weights and vapor pressures raise the challenge for both installers and owners. R22’s moderate pressure and lower compressor discharge temperatures draw praise for their effect on gasket and seal life, which simple R22 chillers deliver day after day. By manufacturing to high-purity standards and controlling non-condensables and water at the parts-per-million level, we help operators maintain these benefits even as changes in regulation push many to adopt alternatives.
As original producers, we see firsthand how raw material quality, equipment precision, and batch control define the final outcome. Hydrogen fluoride and chloroform, our two main feedstocks, create unique handling and safety issues that traders often never see. Our chemical teams deliver tight control by checking real-time parameters at every stage, maintaining rigorous moisture management, filtering acid traces, and setting release only after full data review. Plant-scale feedback cycles don’t just catch out-of-spec material—they guide process improvements that smooth out yield and reduce environmental footprint with each batch.
Every production manager will explain that you can spot rushed or lightly monitored production by checking for off-odors, inconsistent fill pressure, or early breakdowns in field equipment. Downtime, warranty calls, and callback costs add up quickly. Many buyers remember the low-quality boom years, when price-sensitive exporters pushed under-dried, high-acid R22 through the market after regulatory deadlines. That experience built up hard lessons we still talk about today—each complaint, every compressor swap-out, strengthens our insistence on clean, dry, single-lot cylinders, with every drum tracked to its raw lot.
We’re in the plants and workshops decades after the initial charge, hearing about what actually ages, leaks, sludges, or corrodes. In areas where regulatory compliance means equipment stays in service with legacy charge, our reclamation and reprocessing workflow becomes essential to keeping whole towns cooled—especially when ambient humidity, old gaskets, or neglected piping start to push system limits. Our in-house reclamation lines pull returned refrigerant through mulit-stage filtration, molecular sieves, and full spectrum analysis, returning material that meets the same analyzer standards as new production, with strict acceptance criteria around halide content, moisture, and organic residue.
Technicians come to us for guidance not just on which drop-in blend to use, but how to clean scale, flush lines, or adapt expansion valves to handle the different boiling curve. We’ve published data and technical bulletins drawn from both failures and long-life systems, passing along the real cost and savings difference between different retrofit strategies.
On the ground, system owners report real savings and fewer failures where they use R22 produced to strict standards. Cold store managers and site engineers tell us that with consistently pure charge, cleaning intervals can stretch from yearly to every other year, and thermostatic expansion valves need less adjustment drift over time. Milk chillers and frozen food warehouses measure fewer percent deviation in storage temperatures, all tying back to the right material moving through the lines.
It’s tempting to focus only on headline environmental impacts without listening to those keeping older buildings, transport fleets, or food supply running day to day. Our experience leads us to balance strict regulatory compliance with field support and retrofit advice. Every barrel and cylinder sent out reflects not just metric tonnage, but long hours tracking field complaints, testing reclaim quality, troubleshooting with maintenance managers, and delivering training so that every operator understands what drives reliability in the long term.
As a chemical manufacturer, we keep investing in both safer production and more sustainable alternatives, even as we continue to serve the installed base of R22 users where allowed by law. Blends and chemical alternatives will continue to evolve, but we apply the same rigor to testing, documenting, and supporting those options as we always did for Difluorochloromethane. For every technical bulletin or field report, our teams feed lessons back into product development, process safety, and contamination control so that what leaves our plant does the job in practice—day after day, account after account.
In our line of work, credibility rests on more than a commodity shipment. It is built through direct relationships, transparent batch results, responsive technical guidance, and active engagement both with regulatory agencies and the real-world engineers who keep thousands of systems running with R22 and its successors. Every batch we produce, every reclaimed drum we process, and every retrofit scenario we support builds on the foundation set by decades of experience with Difluorochloromethane.