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Citronellic Acid

    • Product Name Citronellic Acid
    • Alias 7-methyloct-6-enoic acid
    • Einecs 246-408-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    630582

    Cas Number 141-18-4
    Molecular Formula C10H18O2
    Molecular Weight 170.25 g/mol
    Iupac Name 3,7-dimethyloct-6-enoic acid
    Appearance Colorless to pale yellow liquid
    Boiling Point 265-270 °C
    Melting Point -30 °C
    Density 0.94 g/cm3
    Solubility In Water Slightly soluble
    Flash Point 133 °C
    Odor Mild, citrus-like
    Refractive Index 1.458-1.460

    As an accredited Citronellic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Citronellic Acid, 100g: Supplied in a sealed, amber glass bottle with tamper-evident cap and clear hazard labeling for safe handling.
    Shipping Citronellic Acid is shipped in sealed, chemical-resistant containers, such as HDPE bottles or drums, to prevent contamination and leakage. The packaging complies with relevant regulations for chemical transport, including labeling with hazard information. During shipping, containers are securely packed and handled to avoid exposure to moisture, heat, and direct sunlight.
    Storage Citronellic acid should be stored in a tightly sealed container in a cool, dry, and well-ventilated area, away from direct sunlight, heat sources, and incompatible substances such as strong oxidizers or acids. Ensure the storage area is free from moisture and properly labeled. Protect from physical damage. Use personal protective equipment when handling to avoid skin or eye contact.
    Application of Citronellic Acid

    Applications of Citronellic Acid in Industrial Manufacturing

    As a manufacturer of citronellic acid, we prioritize downstream industrial applications that have been established by consistent demand, precise regulatory requirements, and formalized quality control systems. Below, we present specific and differentiated uses of citronellic acid across real-world industry segments. Each scenario details regulatory alignment, technical usage parameters, integration points, and corresponding end products to support informed adoption in global manufacturing contexts.

    1. Fragrance Ingredient in Fine Perfume Formulations

    Perfumery producers use citronellic acid as a specialty intermediate to synthesize unique aroma chemicals, especially for modern floral and citrus accords. In this segment, precise profiling and purity dictate its utilization, with the acid often acting as a key precursor for structurally related fragrance compounds. Its application is primarily governed by detailed safety and purity frameworks to guarantee performance and compliance in international fine fragrance production.

    Industry compliance standards

    • IFRA (International Fragrance Association) Standards and Amendments
    • EU Cosmetics Regulation (EC) No 1223/2009
    • REACH Registration, Evaluation, Authorization and Restriction of Chemicals
    • Good Manufacturing Practice for Cosmetic Ingredients (ISO 22716)

    Typical usage ratio

    • Up to 1.5% in bulk fragrance oil formulations; actual level varies based on target olfactive characteristics and base note construction
    • Precursor syntheses: 2–5 mol% relative to primary alcohols/aldehydes in esterification reactions

    Downstream process integration

    • Introduced in the aroma intermediate synthesis stage, typically via controlled esterification or acylation steps prior to blending with other fragrance additives
    • Extensive QC protocols validate identity and residual acid content before compounding into perfume bases

    Final product types

    • Fine and luxury perfumes
    • Eau de toilette and Cologne compositions
    • Fragrance oils for high-end cosmetics

    2. Synthesis of Terpenoid-based Vitamin Intermediates

    In the nutraceutical and active pharmaceutical ingredient (API) sector, citronellic acid functions as a core building block in the total synthesis of select terpenoid-based vitamin intermediates, especially those involving isoprenoid pathways. The safety criticality of this field demands strict supply chain traceability and well-defined compliance, especially for oral or injectable preparations eventually intended for regulated markets.

    Industry compliance standards

    • USP (United States Pharmacopeia) monographs for intermediates
    • ICH Q7 Good Manufacturing Practice for APIs
    • EU GMP for Active Pharmaceutical Ingredients (Directive 2003/94/EC)
    • FDA 21 CFR Part 210/211 for Pharmaceutical Manufacturing

    Typical usage ratio

    • 0.8–3.0% weight/weight in multi-step synthesis routes, with adjustment based on pathway and required product yield
    • Feed ratios are tightly calculated based on reaction stoichiometry and final purity targets

    Downstream process integration

    • Fed into catalytic hydrogenation and cyclization steps as an input for vitamin intermediate formation
    • Pilot and production scale reactors rely on high-purity acid for consistent batch reproducibility

    Final product types

    • Vitamin E (tocopherol) intermediates
    • Terpenoid-based provitamin compounds

    3. Flavor and Fragrance Ester Manufacturing

    Downstream esterification of citronellic acid enables the production of specialty esters with clean, fresh, citrus-floral profiles for use in natural and nature-identical flavorings as well as high-value fragrance enhancers. As food and beverage regulations continue to evolve, every batch must align with comprehensive food additive frameworks and purity requirements, while process engineers optimize conversion rates within multi-step flavor manufacturing lines.

    Industry compliance standards

    • FAO/WHO Codex Alimentarius Guidelines on Food Additives
    • European Union Regulation (EC) No 1334/2008 on Flavourings
    • US FDA 21 CFR 172.515 (Synthetic flavoring substances and adjuvants)
    • FSSC 22000 Food Safety System Certification (for plant operations)

    Typical usage ratio

    • 0.05%–1.2% of total mixture in ester synthesis, dependent on the intensity and volatility profile sought in final ester product
    • Adjusted further based on downstream flavor incorporation limits

    Downstream process integration

    • Charged during automated batch or continuous esterification reactors with monitored catalyst addition
    • Post-reaction purification and fractionation ensure elimination of unreacted acid residues before downstream blending

    Final product types

    • Citronellyl esters for beverage and confectionery flavoring
    • Specialty fragrance esters for personal care and home care products

    4. Insect Repellent Active Ingredient Synthesis

    Industrial producers of modern insect repellent products use citronellic acid as a targeted synthesis intermediate to develop proprietary repellent actives, frequently in combination with citronellol or related cyclic monoterpenes. Scale-up operations for this segment entail continuous monitoring of synthetic conversion efficiency and robust documentation to align with international biocide and environmental safety requirements.

    Industry compliance standards

    • US EPA FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act) Registration for Active Ingredients
    • EU Biocidal Products Regulation (BPR, Regulation (EU) 528/2012)
    • OECD Guidelines for the Testing of Chemicals (for eco-toxicological assessment)
    • ISO 9001:2015 Quality Management (chemical manufacturing)

    Typical usage ratio

    • 1–5% by weight, calculated on a dry actives basis for synthesis of monoterpenoid repellent agents
    • Operators optimize for residual substrate minimization and active yield maximization

    Downstream process integration

    • Introduced during initial condensation and cyclization phases of active ingredient synthesis, with emphasis on precise process controls
    • Extensive downstream purification, including liquid-liquid extraction and vacuum distillation, to remove byproducts and guarantee regulatory-compliant purity

    Final product types

    • Repellent actives for incorporation into aerosol sprays
    • Personal insect-repellent lotions and wipes
    • Outdoor repellent candles and diffusers

    5. Polymer Additive for UV-Stabilization in Specialty Plastics

    Manufacturers in the plastics and polymer modification sectors employ citronellic acid derivatives as specialty additives during UV-stabilization steps in engineering plastics susceptible to photo-degradation. The functionality derives from unique molecular properties that disrupt degradation pathways, with downstream performance and regulatory test criteria shaping formulation design and final inclusion rates for finished resin applications.

    Industry compliance standards

    • FDA 21 CFR 177.1520 (Olefin polymers for food contact scenarios, when relevant)
    • ASTM D2565 (Standard Practice for Xenon-Arc Exposure of Plastics)
    • EU REACH Regulation (testing and registration requirements for polymeric materials)
    • ISO 9001:2015 for additive manufacturing control

    Typical usage ratio

    • 0.1–0.5% by weight in masterbatch formulations, with proportion selected based on resin base and targeted weathering performance
    • Adjustments made after accelerated aging test analysis

    Downstream process integration

    • Added during compounding and extrusion with base polymers to ensure uniform dispersion
    • QC sampling at multiple stages verifies additive homogeneity and final compatibility

    Final product types

    • Weather-resistant polyolefin sheets and films
    • Outdoor-use molded components
    • Functional packaging materials with extended UV-life

    6. Fine Chemical Intermediate in Agrochemical Synthesis

    Within crop protection chemical manufacturing, citronellic acid serves as a tailored intermediate for the creation of selective synthesis routes to novel agrochemical actives and auxiliary agents. Quality assurance demands strict process control and documentation to fulfill international agrochemical trace and residue guidelines, especially in markets with rigorous export and food safety enforcement regimes.

    Industry compliance standards

    • FAO/WHO Specifications and Evaluations for Plant Protection Products
    • China GB2763 Maximum Residue Limits for Pesticides in Food
    • US EPA Pesticide Registration (40 CFR Parts 150–189)
    • ISO 17025 Testing Procedures for Chemical Analysis in Crop Protection Compounds

    Typical usage ratio

    • 0.6–2.5% based on process route, substrate conversion yield, and designed residual thresholds in the final technical concentrate
    • Continuous optimization evolves as new active molecules and registrations emerge

    Downstream process integration

    • Reacted in downstream condensation, cyclopropanation, or esterification units
    • Batch-specific in-process controls and final technical grade QC ensure compliance before formulation into marketable crop protection agents

    Final product types

    • Technical grade fungicide intermediates
    • Auxiliary compounds for herbicide performance enhancement
    • Synthetic adjuvants and safeners
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    Certification & Compliance
    More Introduction

    Understanding Citronellic Acid: Manufacturer’s Experience and Perspective

    What Sets Citronellic Acid Apart

    Citronellic Acid stands out in the landscape of specialty chemicals. Our facility produces it through a controlled oxidation process using high-purity citronellol as feedstock. Working daily with this compound, we see a clear difference in both aroma purity and downstream reactivity compared to other terpenoid acids. Unlike generic fatty acids or mainstream synthetic acids, Citronellic Acid features a nuanced lemon-citrus scent profile and a linear carbon chain structure, putting it in a unique class. The molecules retain a delicate balance between volatility and stability, making them highly relevant for both fine fragrance and complex chemical synthesis. In production, we've learned how small tweaks in process conditions influence odor quality, color, and by-product profile—a detail overlooked when sourcing from less diligent suppliers.

    Typical Model and Physical Appearance

    Everyday operations, from reactor loading to final quality assurance, reinforce the importance of uniformity in the acid’s physical form. Citronellic Acid leaves our crystallization steps as white to off-white crystals or flakes. Consistency in melting point, generally between 22–26°C, shows up in every controlled batch. Our product usually ships as model CA-98, a code denoting a minimum purity of 98%, but our analytical team routinely pushes this higher without sacrificing throughput. A clear, high-grade crystalline solid is not simply an aesthetic detail; it’s the result of eliminating residual solvents, color bodies, and trace aldehydes which, based on feedback from downstream users, can cause off-notes in flavors, fragrances, or polymer intermediates.

    Specifications Shaped by Application Demands

    Our technical team has worked long hours to chase down the every fraction of impurity that chemists and perfumers report. Through iterative feedback, we tuned our chromatographic detection limits and distillation techniques. Typical batch specs include acid value above 350 mgKOH/g, moisture below 0.2%, and heavy metals measured in the low ppm range. Experience has taught us that slightly slack controls—in storage conditions or during liquid transfers—can spike peroxides or turned product in only a few days, especially in hot climates or under poor packaging. These are not theoretical concerns; international customers have rejected poorly stored cargo in the past, a lesson we reference during every loading operation now.

    Direct Usage Based on Decades in the Field

    In our laboratories, Citronellic Acid goes mainly towards two major areas: fragrance intermediates and specialty esters. Each area calls for a different purity window and functional performance. For instance, in fragrance synthesis, the acid serves as a core building block for citronellyl esters, which bring a balanced green floral note to perfumes. Reliable reactivity—no unexpected by-products, no rogue color shifts—puts our production batches in high demand among flavor and fragrance houses. We have worked closely with esterification experts to adjust heating profiles and catalyst dosages just so, replacing less satisfactory alternatives like isononanoic acid or geranic acid, which tend to bring less crispness and fewer olfactory nuances to finished compositions.

    Flavor houses rely on our acid’s food-grade provenance and comprehensive analytical profile. The subtle citrus effect, without bitterness or waxiness, enables formulators to tune beverage, confection, or dairy blends with a light touch. Over 15 years, regular feedback from R&D teams has helped us keep our process free from residual pesticides or high-boiling esters that might disrupt finished food notes. Achieving this means repeat distillations and heavy investment in filtration infrastructure—choices made after batches with detectable off-taste returned from critical customers in the early years of our plant’s operation.

    Chemical manufacturers, especially those in specialties, also value Citronellic Acid as a starting material for functional intermediates. Its unique branched structure opens doors in syntheses that straight-chain acids cannot facilitate. For example, modifications via hydrogenation or further oxidation expand its application into the production of vitamin A analogues, bespoke surfactants, or antimicrobial agents for personal care. Precise purity is less about marketing claims and more about avoiding catalyst poisoning or side reactions during further synthesis; a lesson our technical support team conveys regularly to newly onboarded partners.

    Differences from Other Acids and Common Misconceptions

    Clients sometimes ask whether Citronellic Acid can substitute for more common acids like lauric acid, caproic acid, geranic acid, or citronellyl acetate. From the manufacturer’s side, the answer depends heavily on the end use. Citronellic Acid brings a significant isoprenoid structure, which means it integrates much more seamlessly into formulations requiring ten-carbon terpenoid chemistry. Our production line, designed for minimum color and maximum reactivity, stands apart from large-volume fatty acid facilities geared for soaps or plastics. Unlike lauric or caproic acid, which rarely warrant odor grading or trace pesticide screening, Citronellic Acid undergoes repeated olfactory assessments and advanced chromatographic analysis at each production step. Our on-site GC-MS technicians can pick out minor contaminants before bulk lot certification.

    Unlike geranic acid, which tends to oxidize or polymerize quickly if storage conditions slip, Citronellic Acid demonstrates a steadier shelf life when properly stabilized. From years of warehousing, it’s clear that nitrogen-blanketed drums, cool storage, and amber containers prevent both yellowing and the unwelcome formation of aldehydic degradation products. This extra handling might look expensive, but over time, it cuts down on rejected cargo and keeps reputation intact. Trying to store Citronellic Acid like a bulk fatty acid results in failure—an experience some buyers only have once, after the cost of a lost lot.

    Meeting Industry Challenges and Quality Demands

    Whether shipping to a perfume factory in Europe or a chemical blender in East Asia, all links in the supply chain appreciate traceability. We built our traceability protocols after learning—sometimes the hard way—that even a minor mislabelling or admixture can halt multiple production lines downstream. Citronellic Acid, as produced in our facility, carries documentation from raw material batch, through every synthetic and isolation stage, to finished and certified drum. This means customers do not face unknowns, and our own internal audits can pinpoint issues days, not months, after a deviation.

    Some batch-to-batch variation always emerges, even with the best reactor controls. Early on, we discovered that small changes in the feedstock composition—largely driven by seasonal shifts in citronellol availability—alter yield and minor byproducts. Rather than ignore this, our technical teams run pre-production pilot distillations and adjust process metrics to hit the acid value and GC spec targets. Over time, these variations shrink, and the end users notice fewer surprises in reactivity or odor.

    Logistics, Packaging, and Storage Insights

    From manufacturing through storage, Citronellic Acid benefits from a disciplined approach. Our team learned that improper sealing—not just poor-quality drums—causes oxidative spoilage and can turn a $50,000 shipment into aromatic waste. We use inert-gas blanketing and multilayer containers, and insist on lightning-quick trans-loading in hot or humid climates. Customers facing delays at customs or unreliable third-party storage sometimes call in panic after opening a container to discover yellowed, off-odor material. Our practical advice: never treat this terpenoid acid like a commodity. The added cost in premium packaging and stable transportation pays back in both lower loss rates and longer shelf-store viability.

    In one case, a client in the Middle East experienced material degradation after local warehousing in an uncooled shed for several weeks. Reviewing the log, the batch in question met all specs pre-shipment but arrived with a faint, soapy by-note. These operational missteps pushed us to work directly with end-users during the planning phase of every new shipment, sharing on-the-ground storing and handling tips rather than shipping blindly and scrambling to solve problems after the fact. As manufacturers, we have the resources and technical depth to pre-empt most common pitfalls—a benefit you get direct from the source, not always available from mere intermediaries.

    Regulatory and Environmental Considerations

    Chemical regulations never stand still, particularly for compounds circulating in food, flavor, and personal care channels. Over the last decade, new requirements have appeared for both purity and documentation. Our QC and regulatory staff track updates from international bodies and regional authorities, adapting labels and certificates with each change. Reach, IFRA, and FDA standards feature prominently in our workflow. The slight annual investment in compliance systems avoids costly holdups or recalls—based on earlier years when documentation gaps delayed entire container loads in key markets.

    Environmental performance carries equal weight in today’s decision-making. Citronellic Acid synthesis generates both aqueous and organic effluents requiring careful treatment. Our plant has invested in closed-loop water recycling and advanced scrubbers to lower impact. Monitoring not just stack emissions, but also product residue in packaging reduces long-term liability. Raw material sourcing emphasizes both quality and sustainability, often meaning preferring certified farms for citronellol extraction, even at a price premium. This adds a layer of assurance for downstream users concerned about both ecological and ethical sourcing.

    Collaboration and Innovation through Direct Production

    Being a direct producer, our company maintains an in-house technical support staff capable of responding to formulation challenges and novel application requests. For example, a few years ago, a major flavor house ran trials seeking to reduce off-notes in dairy blends. Working alongside their R&D, we offered samples from several production lots, ran side-by-side GC analyses, and helped adjust acid concentrations for optimal flavor impact. The open, rapid feedback cycle, only possible in short supply chains, led to a new standardization for food-use Citronellic Acid within their facility. Third-party traders, lacking both the technical background and the ability to tweak process variables, simply could not close that developmental loop.

    Innovation, in our experience, stems from close observation and a willingness to adapt. In one project, a synthetic polymer developer ran into problems with unexpected yellowing in a final product. Analysis traced the issue back to trace hexanal contamination in one Citronellic Acid lot. We reviewed upstream distillation processes, identified the likely contamination source—an overheated condenser system—and revised our protocols. These moves, repeated across many small technical crises, keep product performance on track and reinforce the value of buying direct from the manufacturer, who maintains both control and accountability through every step.

    Potential and Future Directions for Citronellic Acid

    Chemicals like Citronellic Acid, once cornered into a few specialty markets, are finding new applications each year. Biotechnology developers have recently brought requests for material with even tighter control of trace metals and solvent residues, targeting pharmaceutical precursor applications. The investment in analytical equipment—like ICP-MS and ultra-trace GC—has already started paying off, as we can provide batch-level reports tailored to these exacting specifications. Environmental chemists, screening for green solvents and biodegradable surfactants, have come to view Citronellic Acid’s renewable origins as a leg up over petroleum-derived alternatives.

    We also see interest in agricultural segments, where new formulations explore the acid’s natural antimicrobial and deterrent effects. Crop protection specialists want longer shelf-life and resistance to photolytic breakdown; we share data on storage performance under various simulated climate conditions. This ongoing feedback loop—absent in arm’s-length commodity trading—allows our R&D effort to focus on real-world problems, not just theoretical improvements.

    Summary of Direct Manufacturing Value

    All knowledge reflected in our Citronellic Acid production comes from living, adjusting, and problem-solving in real time. This sets direct manufacturers apart from resellers or brokers who touch product only in transit. Our team’s background—ranging from synthetic organic chemists to analytical experts to operations veterans—means every shipment represents not just product, but a connected history of tested insight and continual improvement. The margin for error is slim in markets demanding both top-end purity and robust logistics. Reliable Citronellic Acid does not descend from luck, but from years spent learning the nuances of each process variable, user feedback, and regulatory challenge. That knowledge base, built batch by batch and story by story, gives partners confidence that their finished formulations will stand up to both technical and market scrutiny. Our shared successes and occasional missteps continue to add depth to every kilo of Citronellic Acid shipped from our facility.