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Citronellal

    • Product Name Citronellal
    • Alias 3,7-dimethyloct-6-en-1-al
    • Einecs 204-911-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    328278

    Cas Number 106-23-0
    Iupac Name 3,7-dimethyloct-6-enal
    Molecular Formula C10H18O
    Molecular Weight 154.25 g/mol
    Appearance Colorless to pale yellow liquid
    Odor Lemon-like, citrus
    Boiling Point 206-208°C
    Melting Point -10°C
    Density 0.855 g/cm³ at 25°C
    Solubility In Water Insoluble
    Refractive Index 1.449 - 1.454 at 20°C
    Flash Point 80°C (closed cup)
    Vapor Pressure 0.2 mmHg at 25°C
    Purity Typically ≥95% (commercial)
    Storage Conditions Store in a cool, dry, and well-ventilated area

    As an accredited Citronellal factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, 500 mL, with screw cap. Label displays “Citronellal,” hazard symbols, batch number, and safety instructions.
    Shipping Citronellal should be shipped in tightly sealed, chemically resistant containers, protected from light, heat, and moisture. It must be labeled as a flammable liquid and handled per relevant transport regulations (e.g., UN 1993). Ensure appropriate documentation, use secondary containment, and avoid shipping with incompatible substances such as strong oxidizers or acids.
    Storage Citronellal should be stored in a cool, dry, and well-ventilated area, away from heat, open flames, and direct sunlight. Keep the container tightly closed and protected from moisture. Store separately from strong oxidizing agents and acids. Use approved containers made of compatible materials. Proper labeling and secure shelving prevent accidental spillage or mixing. Follow all relevant safety regulations for storage.
    Application of Citronellal

    Applications of Citronellal in Industrial Manufacturing

    As a specialized manufacturer of high-grade citronellal, we supply this key compound to multiple well-established industrial sectors with stringent performance and compliance demands. Below, we detail the major application areas for citronellal—each scenario representing a proven value chain where formulators and producers require consistent quality and reliability supported by regulatory certitude and process knowledge.

    1. Fragrance Ingredient Synthesis for Fine and Functional Perfumes

    Perfume and aroma chemical producers utilize citronellal as a vital intermediate for synthesizing key fragrance notes and specialties such as citronellol, hydroxycitronellal, and synthetic rose or lily-of-the-valley accordants. Its role in composing both fine fragrances and mass-market perfumery demands alignment with rigorous olfactory performance parameters and trace-level impurity controls, especially for leave-on personal care products and premium consumer goods.

    Industry compliance standards

    • IFRA Standards (International Fragrance Association)
    • REACH Annex XVII and SVHC restrictions (for Europe)
    • Cosmetic Regulation (EC) No 1223/2009
    • ISO 9235: Aromatic Natural Raw Materials—Vocabulary

    Typical usage ratio

    • 1–12% in fragrance concentrate formulations (adjusted to targeted scent profile and regulatory restrictions on finished product)

    Downstream process integration

    • Entry at aroma compound blending or as a feedstock for further hydrogenation/oxidation in aroma chemical manufacturing suites; typically charged into reactors equipped with distillation and GC-QC analytics for batch approval.

    Final product types

    • Designer perfumes, deodorants, fabric softeners, home care odorizers, fine soap fragrances

    2. Synthesis of Insect Repellent Active Ingredients

    Chemical manufacturers in the pest control industry leverage citronellal as a core raw material for preparing citronellal-based actives and derivatives, notably for insect repellent formulations where both volatility and skin safety are critical. The downstream processing strictly demands product stability tests, residual solvent management, and compliance with multi-region pesticide regulations.

    Industry compliance standards

    • US EPA 40 CFR 152 (Insect Repellent Registration)
    • European Biocidal Products Regulation (BPR, Regulation (EU) 528/2012)
    • China National Standard GB/T 27741-2011 (Insect Repellents)
    • WHO/FAO Guidelines for Public Health Pesticides

    Typical usage ratio

    • 8–20% as formulated in liquid sprays and lotions; exact inclusion depends on desired effectiveness, flash-off profile, and dermal safety requirements.

    Downstream process integration

    • Introduced during the compounding stage into emulsion or solution matrices, followed by homogenization and microemulsion adjustment; pre-packed bulk passes through QA testing for repellency and purity before packaging.

    Final product types

    • Personal insect repellent sprays, skin lotions, aerosol-based room repellents, coil- or mat-type insect repellents

    3. Synthesis of Flavors for Food and Beverage Applications

    Citronellal serves as a starting material or blending component in natural and nature-identical flavor manufacturing, particularly in citrus or lemongrass profiles. Flavor houses process citronellal under food-grade protocols, focusing on migration limits, residual solvent controls, and consistent batch traceability laid out by regional food safety authorities for both direct and indirect flavoring.

    Industry compliance standards

    • FCC (Food Chemicals Codex)
    • EU Regulation (EC) No 1334/2008 on Flavorings
    • US FDA 21 CFR 172.515 (Synthetic Flavoring Substances and Adjuvants)
    • GB 2760—Chinese National Food Additive Hygiene Standards

    Typical usage ratio

    • 0.003%–0.03% in final food and beverage products; flavorists adjust levels based on regional maximum residue limits and sensory threshold targets. Not suitable for use in infant foods.

    Downstream process integration

    • Charged into flavor compounding reactors at the flavor house, incorporated at solvent blending or blending-tank stages, with focus on minimizing oxidation and off-flavor formation; output undergoes GC-MS analytical confirmation before distribution to food processors.

    Final product types

    • Beverage concentrates, confectionery flavors, bakery essences, tea and ready-to-drink citrus flavoring syrups

    4. Intermediate for Vitamin A and Related Fine Chemical Synthesis

    Pharmaceutical API and nutraceutical intermediates manufacturers incorporate citronellal as an early-stage intermediate in the synthesis of citral, which serves as a direct precursor in the industrial production of vitamin A. This supply chain operates under validated cGMP regimes, with stringent control of by-product profiles, purification pathways, and impurity documentation to conform with pharmaceutical-grade output specifications.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice Guide for Active Pharmaceutical Ingredients
    • Ph. Eur./USP monographs for Citral and Vitamin A
    • ISO 9001:2015 Quality Management Systems
    • EU Directive 2001/83/EC on Medicinal Products

    Typical usage ratio

    • 100% feedstock (reactor charge basis) for citral synthesis steps; downstream conversion yields are optimized through catalyst and reaction pathway selection.

    Downstream process integration

    • Charged at the initial feed stage in multi-stage continuous reaction systems or batch reactors to undergo oxidation and condensation; followed by fractional distillation and crystallization of intermediate species; compliance with rigorous in-process QC is mandatory for pharmaceutical-grade routes.

    Final product types

    • Vitamin A acetate, vitamin A palmitate, intermediate-grade citral, and pharmaceutical-grade citral feedstock

    5. Manufacture of Household Cleaning Agent Fragrances

    Citronellal is widely adopted in the compound fragrance sector for household cleaning and air-freshening products, imparting recognizable lemon and floral notes while withstanding alkaline and surfactant-rich environments. Formulators require compliance with regulatory chemical inventories and allergen labeling directives, while maintaining high stability over storage and exposure to oxidizing agents in detergent formulations.

    Industry compliance standards

    • CLP Regulation (EC) No 1272/2008 (Classification, Labelling and Packaging of Substances and Mixtures)
    • US TSCA Inventory (Toxic Substances Control Act)
    • Detergent Regulation (EC) No 648/2004
    • Allergen disclosure per EU Cosmetics Regulation Annex III (for overlapping product classes)

    Typical usage ratio

    • 0.05–1% in concentrated fragrance oil blends for household and institutional cleaners; the final inclusion in end-product ranges from 0.005–0.12% depending on product type and market region.

    Downstream process integration

    • Dosed at fragrance compounding stage, followed by mixing with anionic and nonionic surfactants; incorporated via cold-blending for liquid detergents and added in agglomerate or spray-dried forms for powder detergents; blends tested for odor fastness and shelf stability.

    Final product types

    • Dishwashing liquids, multi-purpose household cleaners, floor cleaning agents, laundry powders, solid air fresheners

    6. Precursor in Agrochemical Intermediate Production

    Producers of agrochemical intermediates rely on citronellal to synthesize a range of downstream aroma chemicals and specialty intermediates integral to certain plant growth regulator and pheromone formulations. Each synthesis is subject to agrochemical traceability and controlled waste handling protocols due to exposure scenarios unique to the crop protection sector.

    Industry compliance standards

    • FAO Specification for Plant Protection Products
    • ISO 17025 laboratory testing requirements
    • Globally Harmonized System (GHS) for Classification and Labeling
    • OECD Guidelines for Testing of Chemicals

    Typical usage ratio

    • Varies from 5–35% in the intermediate product reactors, depending on end intermediate concentration and target downstream conversion efficiency.

    Downstream process integration

    • Added to batch or continuous reactors as initial substrate; the process typically involves catalytic transformation such as selective reduction, condensation, or esterification; material handling adheres to closed-system protocols and intermediate QC for agricultural use profiles.

    Final product types

    • Pheromone lures, plant growth regulators, intermediate APIs for selective agrochemical synthesis
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    Certification & Compliance
    More Introduction

    Citronellal: Reliable Ingredient Backed by Real Manufacturing Experience

    What We Know from Decades of Producing Citronellal

    Our daily work with citronellal puts us right at the pulse of what professionals expect from this valuable terpene aldehyde. Each batch rolling out from our reactors reflects a hands-on approach that balances chemistry, practical production targets, and feedback from global partners who depend on consistent results. The technical name—3,7-dimethyloct-6-en-1-al—might sound distant, but its purpose runs close to home for us and for those who depend on the real substance, not just the formula.

    Citronellal sits on the intersection between fragrance, flavor, and insect-repellent industries. Our team has built a routine around both the nuances of purification and the value of meeting tight assay specifications, knowing that these details mean much down the line for soap makers, perfumers, candle manufacturers, and producers of advanced repellents. Every shipment starts with validated raw materials and follows a route of fractionation, vacuum distillation, and stringent GC analysis. These are hands-on steps we practice daily—not just talk about. Our typical product ranges above 95% purity by GC, and we include precise data on R-(+), S-(-) ratios for formulators who insist on the sharpest fidelity from plant-based origins.

    Differences Among Citronellal Grades and Why They Matter

    We have seen firsthand that citronellal does not come as a single monolithic ingredient. Demand runs from technical grade, suitable for general formulations, to grades tailored for demanding perfumers who seek a clear, fresh character without grassy undertones. Over the years, our R&D team compared samples from multiple origins—citronella oil, lemon eucalyptus, and synthetic routes. We noted that the source, along with process controls, changes not only the odor notes but also the minor impurity spectrum and shelf stability.

    Some customers request a product that’s nearly colorless to pale yellow, blending seamlessly in delicate fragrance profiles. These batches require extra care, with cold storage and extensive light control to prevent unwanted side reactions. From experience, a few tenths of a percent impurity—especially isopulegol or geraniol residues—will shift the final scent, leaving soapers or home care blenders with off-notes that ruin months of recipe development. Our engineers have worked through these challenges batch by batch, sometimes swapping out catalysts, sometimes extending distillation schedules, sometimes fine-tuning filtration technology to push down those last traces of unwanted material.

    Working with Industry Partners: Avoiding the Pitfalls

    We have learned about the real pain points from everyone in the value chain. Early on, a major candle making partner flagged us on a faint musty note that only showed up during long-term storage in tropical climates. That wasn’t visible on the initial COA. We traced it back to trace aldehyde isomers that slipped past a certain distillation cut. Correcting the process meant modifying temperature profiles and doubling up on certain analytical proofs. Now, the same customer shares six-month stability data with us, helping us tweak every run for that specific requirement. So for us, citronellal is not just a tick-the-box item in a datasheet—it’s an ingredient with a 'history of fingerprints' that starts with our team, passes through our partner’s hands, and ends in a final product that reflects countless decisions along the way.

    Working with citronellal also means being diligent about packaging and shipment conditions. Pure citronellal easily picks up foreign odors and can oxidize if mishandled. Our operators swap out container linings if even the slightest remnant smell remains from previous cargo. These small steps save hundreds of liters from spoilage or unwanted product returns.

    The Real-World Use Cases that Drive Innovation

    Few substances see such diverse application as citronellal. Take the perfume industry. Nose after nose—whether in Paris or Mumbai—pulls apart fragrances to hunt for natural, fresh, lemony-green notes. We support them by controlling not just the major component, but by managing chiral ratios that tweak the perception of 'freshness' or 'mint' in the final blend. The S-(–) isomer leans more toward the eucalyptus nuance, while the R-(+) gives a softer, rose-like lift, critical for high-end florals or certain household cleaners. Our reactors run stereoselective methods during key campaigns to supply narrow-isomer batches, even if these represent just a fraction of annual output.

    On the other end, suppliers to the home care market tell us that lasting insect repellent power matters more than the finest fragrance note. In hot and damp geographies, our customers count on the aldehyde’s volatility to drive off mosquitoes in formulations blending citronellal with other terpenoids and fixatives. It’s not only about keeping the purity up—it’s about bottling the right combination of release rate and residual power. Field trials sometimes force us back to the lab, iterating on the distillation process to optimize what gets left in and what gets stripped out.

    Citronellal also enters the flavor and food additive space. These partners, bound by strict regulatory tables, don’t leave any room for shortcuts. Every microgram of solvent or trace impurity gets flagged. Here, we rely on our in-house GC-MS and HPLC systems, running hundreds of checks with each campaign. More than once, that strict testing caught unexpected carry-over from earlier utilities. Rather than shipping compromised product, we invested in equipment upgrades, cleaning cycles, and raw material procurement audits. The results show up in clearer certificates and fewer call-backs for support.

    Meeting Changing Market Demands—Adaptation Built on Fact, Not Hype

    Recent years brought a sharp uptick in natural and renewable sourcing requests. Synthetic citronellal from petrochemicals meets plenty of industrial specs at competitive cost, but for a growing segment, that’s not enough. They expect closed-loop or fully bio-based supply chains, confirmed with origin analysis and traceability audits. To meet these, we’ve spent time, resources, and brainpower setting up side streams that use sustainable feedstocks sourced from certified farms. Our plant team learned how different extraction and conversion processes impact yield and impurity load. Some runs needed rethinking, since yield dropped but compliance rose; other times, we faced the opposite trade-off. There’s no single answer, but commitment to customer goals—whether classic or sustainable—means being honest about performance, not chasing buzzwords or claims we cannot support.

    Years of working side-by-side with certifying agencies, regulatory inspectors, and field auditors taught us the high value of transparency. When export markets tightened requirements on allergen declarations and contaminant levels, we responded not with paperwork promises, but with process changes and public batch reports. Careful process logging, full disclosure of stabilizer use, and voluntary batch recalls, when justified, built trust over time with partners who do not take shortcuts.

    Some partners request Exemption from animal-sourced contamination, HALAL, KOSHER, or non-GMO certifications. We’ve adjusted processing schedules, trained operators, and selected cleaning agents to deliver fully segregated campaigns where the data supports the story. If any step does not meet the mark, we run more tests or wait until it does. We see the value in truth over marketing spins—customers who ask a direct question always get the lab results, not a vague assurance. In the rare event a specification is missed, we disclose the deviation and document our plan for remediation.

    Why Practical Details Matter in Real Application—Lessons from the Floor

    We notice that many who buy citronellal ask for technical data but really want practical insight. How fast does it oxidize in open containers on a production floor? How much does container headspace influence stability? We have real-world stories to share. A few years ago, a shipment left our plant tightly within spec, but months later, customer complaints showed up about fading scent in their laundry scent booster line. Samples brought back from the field tested at a lower active content—our own packing team had underestimated the warehouse’s poor ventilation and high ambient humidity, which sped up aldehyde loss. We revised our procedures, invested in vapor-tight, nitrogen-flushed drums, and included handling recommendations in every shipment.

    Pipework material also tells its own tale. Stainless steel minimizes leaching and contamination, while older, unlined iron or poly fittings sometimes impart off-flavors or slow oxidation. We switched part of our facility’s lines after an off-lot event traced back to legacy plumbing. No analysis on a standard report would have picked it up without day-to-day vigilance and a willingness to investigate surprises.

    Some partners experiment with citronellal in pharmaceutical applications, as an intermediate or functional scenting agent. These users press us hard on residual solvent and trace metal content. Every time a new regulation hits, we pull historic batch data, run cross-validation tests, and disclose everything—sometimes to our own commercial disadvantage. It keeps us honest, our operators sharp, and the process constantly improving.

    Differences from Similar Compounds and Implications for the End User

    Citronellal sits close in the chemical family tree to other key fragrance aldehydes, like citral and citronellol. The distinctions matter, especially in real-world applications. Citral brings a strong lemon-green note, sharper and more aggressive, making it useful where bright top notes are valued. Perfumers who need a softer, more diffusive lemon note—balanced by a touch of floral roundness—come to us for citronellal. It serves as a crucial bridge between a dominating top note and gently persistent mid tones. Citronellol, on the other hand, shares the backbone but swaps the aldehyde for an alcohol group, rounding it off and making it less volatile, less prone to off-flavors under heat or UV exposure.

    Several partners initially came to us looking for a one-for-one swap between these materials. Based on years of running development pilots, we offer caution. A soap that works with citral can turn harsh and even reactive with pure citronellal. A detergent blend that holds color with citronellol can yellow when exposed to aldehyde stress. The lesson: similarities in name or origin do not translate to plug-and-play performance across consumer goods.

    We’ve also supplied blends that intentionally combine citral, citronellol, and citronellal for certain aerospace and technical scent applications—learning through trial, not theory, about compatibility and long-term integrity. Only after multiple stability and compatibility tests—real-life shelf aging, climate stress boxes, hands-on odor evaluation days—do we suggest a revised formula or a technical substitution.

    Sourcing Honesty: What Can—and Cannot—Be Promised

    Every customer wants reliability, whether sourcing by the drum, the ton, or the tanker. Price fluctuations in feedstock—whether from synthetic or natural sources—impact batch cost and delivery time. For natural citronellal, wild swings in citronella grass and eucalyptus harvests drive both quality and yield. Our farm partners send daily updates during harvest season, and we schedule runs to match available botanical feedstock, not warehouse inventory sheets. The synthetic route brings its own variables—availability of base chemicals, energy price swings, and environmental controls. We’re upfront that supply robustness means people, plant engineering, and on-the-ground logistics working together every season.

    Shipping citronellal safely also calls for true stewardship. The compound can develop pressure in containers if stored for long periods in heat—rare but not unheard of. After one such event, we invested in pressure-relief packaging and temperature-controlled shipping lines. Each safety incident becomes a direct call to rethink processes from the ground up, reducing future risk across the board.

    What We Have Learned about Regulatory and Environmental Trends

    Environmental and worker safety regulations evolve quickly, sometimes outpacing manufacturing practices by months or years. We send staff to regulatory workshops and industry roundtables not just to listen, but to participate and steer guidance in a direction that’s grounded in true working knowledge. Whenever a jurisdiction implements new labeling or disclosure rules, we don’t scramble at the last minute. New documentation comes from established, daily practice—not hastily assembled data sets. Auditors often spend more time on our workshop floors than at the office, picking up unplanned comments or minor incidents that lead to better policies in the long run.

    Occasionally, a market bans certain stabilizer additives or enforces stricter limits on aldehydic impurities. Our compliance desk works alongside technical staff to reformulate on the fly—sometimes forcing tough calls between cost, performance, and upstream supplier audit cycles. Every time, we document every changed step, so all partners can see the rationale and downstream impact of new decisions. If that leads to production delays or cost adjustments, we share those too, believing in joined expectations over short-term fixes.

    The Value of Hands-On Problem Solving

    Our time working with citronellal has proven that the compound’s success is never just about the specification sheet. It’s about attention to unseen details—how plant climate during storage swings affect final batches, how cleaning solvents impact purity margins, how operator training influences downtimes and batch variability. Citronellal may be a common ingredient by number, but in the real world, it either works or fails based on the commitment embedded in its journey from synthesis to finished goods.

    Customer concerns rarely come isolated. A request about shelf stability often uncovers hidden questions about batch-to-batch consistency or fit in a multi-component blend. We maintain an open lab-door policy, including random sample validation, joint troubleshooting sessions with customers, and live analysis sharebacks. This focus allows us—and our partners—to get ahead of market curveballs, regulatory changes, and evolving consumer demands.

    Our Commitment to Ongoing Improvement

    We treat every citronellal batch as a responsibility, not just an SKU. Over the years, we’ve been both challenged and encouraged by our partners’ feedback, their successes and setbacks, and the way they trust our team with their toughest formulations. Being a manufacturer means more than producing consistent chemical output—it means standing ready to address bottlenecks, troubleshoot off-spec outcomes, and innovate, not by rewriting brochures, but by solving concrete, daily problems for real customers.

    For anyone relying on citronellal—whether in a fragrance launch, an insect repellent line, a technical blend, or a sustainable product mission—our doors remain open, and our people stay at the bench, focused on facts that matter in practice. We learn as much from failures as from successes, and every improvement in our process comes from acknowledging what the field teaches us. That’s the difference real manufacturing experience brings to citronellal, and it’s a promise as genuine as the product in each drum we ship.