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Cis-4-Octene

    • Product Name Cis-4-Octene
    • Alias (cis-4-Octene, cis-Oct-4-ene)
    • Einecs 212-743-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    650288

    Cas Number 2292-93-5
    Molecular Formula C8H16
    Molar Mass 112.21 g/mol
    Appearance Colorless liquid
    Density 0.72 g/cm³
    Boiling Point 116-118 °C
    Melting Point -87 °C
    Refractive Index 1.414
    Flash Point 13 °C
    Solubility In Water Insoluble
    Vapor Pressure 43 mmHg (25 °C)
    Structure Type Alkene (cis configuration)
    Smiles CCCC/C=C\CC

    As an accredited Cis-4-Octene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Cis-4-Octene is packaged in a 100 mL amber glass bottle with a secure cap, featuring clear hazard and identification labels.
    Shipping Cis-4-Octene is shipped in tightly sealed containers, typically made of metal or high-density polyethylene, to prevent leakage and evaporation. It should be stored in a cool, well-ventilated area, away from sources of ignition or heat. Shipping must comply with local, national, and international hazardous materials regulations.
    Storage Cis-4-Octene should be stored in a tightly sealed container under a nitrogen or inert gas atmosphere, away from heat, sparks, and open flames. Keep it in a cool, dry, well-ventilated area, separated from strong oxidizers and acids. Use only in an area equipped with proper ventilation and spill containment. Store at temperatures below 30°C to minimize decomposition and evaporation.
    Application of Cis-4-Octene

    Applications of Cis-4-Octene in Industrial Manufacturing

    Cis-4-Octene serves as a key chemical intermediate in several advanced industrial sectors. The following sections detail proven downstream manufacturing applications, process integration stages, usage parameters, industry compliance requirements, and the primary types of finished goods produced at commercial scale using this material.

    1. Production of Linear Low Density Polyethylene (LLDPE) Comonomer

    Cis-4-Octene acts as a strategic comonomer in the manufacture of LLDPE, contributing to increased toughness and enhanced flexibility of blown and cast films. Polyethylene plants incorporate this olefin during solution or gas-phase polymerization, where its molecular structure helps tailor the mechanical properties required for high-performance packaging films and industrial liners. The material’s consistent purity and controlled isomer ratio are crucial for maintaining batch-to-batch reproducibility in final polymer attributes.

    Industry compliance standards

    • FDA 21 CFR 177.1520 (USA, food contact polyolefins)
    • EU Regulation (EU) No 10/2011 (Plastics regulation for food contact, Europe)
    • GB 4806.7-2016 (China National Standard for food use plastics)
    • ISO 9001:2015 Quality Management for polymer production

    Typical usage ratio

    • Comonomer feed ratio: 5%–12% by mol in LLDPE copolymer blends
    • Adjustment based on target melt index and density ranges (0.915–0.935 g/cm3)

    Downstream process integration

    • Metered addition directly to the polymerization reactor feed stream
    • Blended with ethylene and catalyst prior to initiation
    • On-line quality monitoring for comonomer conversion efficiency

    Final product types

    • Cling stretch films for palletizing
    • Food-grade packaging films
    • General-purpose liners and sacks
    • Agricultural mulch films

    2. Synthesis of Polyalphaolefin (PAO) Synthetic Lubricant Base Oils

    Cis-4-Octene undergoes oligomerization to produce PAOs, widely used in high-performance synthetic lubricants for automotive and industrial equipment. The precise chain structure of the cis isomer delivers viscosity characteristics favored by formulators for next-generation engine and gear oils. Refineries and synthetic oil producers integrate this raw material in continuous or batch oligomerization units under well-defined catalyst regimes to optimize molecular weight distribution.

    Industry compliance standards

    • API Base Oil Groups III & IV Specifications (Automotive Lubricants)
    • ACEA Oil Sequences (European Automotive Standards)
    • ILSAC GF-6 (Engine oil standards)
    • ISO 14001:2015 Environmental Management in lubricant production

    Typical usage ratio

    • Feedstock inclusion: up to 20% by mass, adjusted for targeted PAO viscosity (2–100 cSt at 100°C)
    • Isomer composition adjusted to meet pour point and volatility requirements

    Downstream process integration

    • Catalytic oligomerization in fixed or fluidized bed reactors
    • Product fractionation and hydrogenation to refine base oil
    • Blending into finished lubricant formulations post-QC

    Final product types

    • Fully synthetic engine oils (SAE 0W-20, 5W-30, etc.)
    • Gear and transmission oils
    • Compressor and hydraulic fluids
    • Industrial greases and specialty lubricants

    3. Specialty Plasticizer Intermediate in Polyvinyl Chloride (PVC) Compounding

    Cis-4-Octene functions as a reactive intermediate in the synthesis of specialty plasticizers designed for use in high-flexibility PVC applications. Chemical manufacturers react this oligomer with phthalic or adipic anhydrides to form custom diester plasticizers, which are blended into PVC compound formulations, improving cold flexibility and low-temperature impact performance without compromising transparency. The material’s defined double-bond geometry ensures uniform reaction rates and final product consistency.

    Industry compliance standards

    • EN 71-3:2019 (EU Toy Safety for plasticizers in toys and children’s products)
    • REACH Regulation (EU), Substances of Very High Concern (SVHC) exclusion
    • ASTM D2124 (Plasticizer content in PVC)
    • ISO 9001:2015 Quality protocols in additive manufacturing

    Typical usage ratio

    • Plasticizer synthesis: cis-4-octene contributes 20%–35% by mol in diester yield
    • PVC compounding: plasticizer content 25–40 phr (parts per hundred resin), adjusted for target flexibility

    Downstream process integration

    • Reacted with anhydrides in esterification reactors at 150–180°C
    • Plasticizer purified and quality tested for purity and migration rates
    • Incorporated into PVC dry blends prior to extrusion or calendaring

    Final product types

    • Flexible PVC flooring and wall coverings
    • Wire and cable sheathings for electronics
    • PVC hoses and tubing
    • Toy and childcare product components

    4. Olefin Metathesis Intermediate for Fine Chemical Synthesis

    With high reactivity in metathesis reactions, cis-4-octene is used as a chain transfer agent and intermediate for synthesizing aliphatic specialty chemicals, including fragrance ingredients and pharmaceutical side chains. Chemical synthesis plants rely on the geometric purity of this isomer to achieve selective conversions and minimize byproduct formation during metathesis catalyzed by ruthenium or molybdenum complexes. The process underscores the importance of controlled isomer feedstocks for downstream high purity fine chemical manufacturing.

    Industry compliance standards

    • IPEC-PQG GMP Guide for Pharmaceutical Excipients (Good Manufacturing Practice)
    • USP–NF (United States Pharmacopeia / National Formulary) compliance for APIs and excipients
    • EU Regulation (EC) No 1907/2006 (REACH compliance for intermediates)
    • ISO 22716:2007 Cosmetics GMP (in fragrance chemical manufacturing)

    Typical usage ratio

    • Olefin substrate: 1–3 molar equivalents in selective ring-closing or cross-metathesis reactions
    • Dosage tailored based on targeted molecular chain length and functionalization yield

    Downstream process integration

    • Dosed into metathesis reactors with selected catalyst loadings
    • In-line GC monitoring of olefin conversion and byproduct suppression
    • Subsequent purification by distillation or chromatography for downstream synthesis use

    Final product types

    • Aliphatic alcohols for flavors and fragrance synthesis
    • Pharmaceutical API side chains and intermediates
    • Cosmetic grade esters
    • Fine chemical building blocks for agrochemical R&D

    5. Chemical Intermediate for Alkylated Aromatic Production

    Manufacturers use cis-4-octene as an alkylating agent in the production of alkylaromatic compounds, particularly for high-performance surfactants and specialty additives. Its molecular geometry ensures controlled reaction selectivity, supporting the production of alkylbenzenes with specific chain branching, which contributes to favorable biodegradability profiles in downstream surfactant applications. Integration at the alkylation reactor stage allows adjustment of branching content to strict customer and environmental requirements.

    Industry compliance standards

    • OECD 301 series (Ready Biodegradability Rules for surfactants)
    • EU Regulation (EC) No 648/2004 (Detergents regulation – surfactant biodegradability)
    • ISO 14001:2015 for environmental management in surfactant manufacturing
    • REACH registration as alkylating base chemical

    Typical usage ratio

    • Feed ratio: 8%–15% by mol of total alkylation charge for linear or branched alkylbenzenes
    • Optimized based on downstream surfactant formulation detergency and biodegradation rates

    Downstream process integration

    • Added directly to aromatic hydrocarbons in fixed-bed alkylation reactors with acidic catalysts
    • Continuous product withdrawal and purification to separate unreacted olefin
    • Performance testing for finished surfactant blends

    Final product types

    • Household and industrial detergent surfactants (e.g., biodegradable alkylbenzene sulfonates)
    • Specialty emulsifiers for oil recovery
    • Textile processing and wetting agents
    • Cleaning additives for automotive and institutional markets
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    Certification & Compliance
    More Introduction

    Cis-4-Octene: Direct from the Manufacturer’s Floor

    Getting to the Heart of Cis-4-Octene Production

    Cis-4-Octene, CAS number 2985-68-6, walks a careful line in the chemical world. At our facility, it gets shaped and refined to answer precise industrial priorities. Not every octene is the same, and we’ve spent long hours on our reactors to understand, and sometimes wrestle with, the traits that make Cis-4-Octene worthy of focused attention. Our process doesn’t start on a spreadsheet. It starts on the shop floor, in the way we balance temperature and pressure, and in the everyday grit of recovering the product to high purity. The molecule offers its own set of behaviors, as anyone who's tried to separate it from a batch of isomers can confirm.

    Identity and Model

    Cis-4-Octene pushes beyond the general bucket of linear or branched alkenes. It’s one of the middle isomers in the octene family, identified by the double bond resting between carbon atoms four and five, both locked into the “cis” orientation. That geometry means something: it shows up in the way material packs, boils, and interacts downstream. In practice, we draw out this isomer using a mixed-olefin stream, harnessing distillation gear—sometimes beefed up with custom trays or packed columns—to tighten the purity window. Models on our floor center on batch and continuous runs, tuned to whichever side stream feed offers the cleanest separation. Over the years, we’ve tweaked reflux ratios and cut points to pull Cis-4-Octene above 98% in the main fraction, though every crude batch comes with its own surprises.

    Why the “Cis” Matters

    Pure cis alkenes carve out demand because their molecular shape defines what comes next in synthesis. The shape of the “cis” double bond—a kind of bend in the molecule—means it reacts differently than its “trans” sibling. This bend isn’t academic. In manufacturing, especially in the plastics and specialty polymer industries, feedstocks are not just numbers on a spec sheet. We see this in how catalysts tackle cis versus trans structures: yields diverge, side products shift, and catalyst fouling risk climbs or drops depending on which isomer leads the reaction.

    We learned early that some processes stubbornly resist feedstock blending. A pure stream of Cis-4-Octene lets our partners avoid problems downstream—sticky polymerization, off-smelling byproducts, or batches that look fine on paper but can’t clear quality control before shipping. Each of these issues can trace back to the fine print of double bond geometry. Over the years, this reality led us to invest in more selective rectification and to fine-tune sidecut purges, so our customers don’t pay for cleanup out of pocket.

    Real Usage: Going Beyond Just Numbers

    Out in the field, Cis-4-Octene deposits real value in polymerization—not only as a comonomer in specialty polyethylene, but as a bridge to fragrances, flavors, and even lubricants base stocks. Downstream chemists bank on its predictable reactivity; they tell us it minimizes chain branching and dodges the volatility that can stall a run. Talking to engineers running Ziegler-Natta or metallocene catalyst systems, the feedback is direct: the right cis isomer keeps mechanical and tensile properties in spec, and batch consistency holds when raw material drift stays in check.

    You don’t get there with a generic octene mix. Troubles crop up if a feed skips the “cis” isomer or lets “trans” run wild. Maybe it’s a slower start to polymerization, or an uptick in off-spec extrusion. Resin clarity, melt index, even product taste (in food contact applications) track back to the isomeric makeup. These aren’t just anecdotes. We see it in the way big polymer buyers send scouts to verify feed-backup logs and check on our column maintenance. It’s a reality that’s shaped how we run our continuous analyzers—always looking for hints of isomer drift, ready to pull a vessel off line if results start to slide.

    What Sets Cis-4-Octene Apart?

    Lining up isomers side by side, Cis-4-Octene tells a different story than its close octene cousins. 1-Octene, as an alpha-olefin, packs a double bond at the end. That’s great for some processes but too reactive for others. Trans-4-Octene, structurally speaking, splits from the cis in both boiling point and how it blends. These differences change distillation curves and impact downstream kinetics. We field requests now and then for isomer blends, but more end-users keep zeroing in on pure cis content, especially for new-generation copolymer work.

    The point isn’t just about being different; it’s about reliability. Cis-4-Octene responds to catalysts in ways its family members won’t. In producing film-grade materials—where ductility and tensile strength won’t budge—the right feedstock narrows the operational headache and holds costs down. We’ve seen formulations collapse when suppliers cut corners with isomer-blended material. Our own line can’t pass periodic audits unless we guarantee not just nameplate purity, but isomeric composition, batch after batch.

    Digging Into Specifications

    Years in commission have taught us that some buyers put more faith in real world tracking than in a line of numbers. We target a minimum content close to 98% for Cis-4-Octene, with moisture and halide readings below the quantifiable cutoffs typical for polymer-grade streams. The organoleptic profile matters, especially where smells or traces can punch above their weight. Engineers on our line sample every lot—running GC and FTIR—to confirm the isomeric split, and we publish those readings because downstream it saves everyone time and troubleshooting costs.

    Purity is not just about compliance. Picture a situation where 1% off-spec isomer shows up consistently in a feedstock batch—over six months, end users call back with yield dips, a few quality control headaches, and suddenly requests for documentation snowball. That feedback loop has driven us to invest hard in analytics and operator training, with on-the-floor checks pulling random samples. Any batch that fails the isomeric threshold doesn't leave through the main gate.

    Handling Storage and Logistics

    Alkenes aren’t famous for stability, and Cis-4-Octene is no exception. In practice, the material reacts to light and oxygen, so storage solutions start at the tank farm and run through to delivery. Our drums and tanks run inerted to slow down any chance of peroxide formation, and we maintain nitrogen blankets until offloading at the customer’s gate. We build our shipping schedule so product doesn't sit inside hot containers. More than once, we’ve seen smaller producers cutting costs by holding product in marginal tanks, leading to haze or foul odor—a risk you only want to take once.

    Stability matters in more than just storage. In some areas, the shipping lanes add a week or more from plant to end user. That’s where batch stability rides alongside purity on the spec sheet. We calibrate inhibitor levels (excluding those not compatible with downstream processes), testing every outgoing load for residue and sulfur trace. Documentation follows the batch, and our supply chain hinges on this chain of custody. Partners running multi-week synthesis cycles can’t afford to guess on what landed at their facility; they want the same lot tracked back to the reactor run that produced it.

    Differences That Matter: Cis-4-Octene Versus the Pack

    Working with octenes every day, we see tangible differences in performance and logistics. 1-Octene finds favor in LLDPE, especially when toughness and clarity are prized. Trans-4-Octene, for its part, might give a slightly more stable product under extreme thermal and UV exposure, but it lacks the blending finesse of cis, especially in fine-tuned food and specialty chemical synthesis. In fragrance and flavor, the odd note or trace impurity in a “trans” isomer can send batches to waste. Each user has a story about a supply mistake that led to a lost order or stopped line. We put long-term relationships ahead of one-off orders, focused on keeping traceability and authenticity in the foreground.

    Now and then, customers ask why price points on pure Cis-4-Octene run higher than generic mixtures. The real answer lives in the cost of separation and ongoing quality surveillance. Mixed-octene streams look tempting on a spreadsheet but can breed process headaches and unpredictable reaction profiles. We don’t just ship to finish one deal; our reputation hangs on year-in, year-out reliability.

    Meeting Regulatory and Safety Expectations

    Nearly every market since 2015 has tightened regulatory controls on unsaturated hydrocarbons, particularly for materials entering food packaging or other human-contact chains. Safety calls for more than a line on a safety data sheet. We run trace analytics for peroxides, aromatics, and chlorinated contaminants—some days pulling more checks than the standard calls for. Supply demands shift with every revision of global guidelines: from REACH in Europe, to US FDA standards, to the rising bar in South Korea and Japan.

    Traceability took center stage after several industry recalls linked to mishandled hydrocarbon streams. We responded by building a digital backbone tying reactor batch, analyzer logs, tank inventory, and outgoing shipment together. Every customer, no matter how small, receives the full data trail, not just a sample certificate. This transparency is non-negotiable after past industry failures; it keeps operations honest and upholds trust when the next audit team arrives.

    Grasping Challenges in Cis-4-Octene Supply

    On the factory side, the hardest part isn’t the headline separation—it’s managing variability in feedstock and fine-tuning conditions across seasons. Daytime temperatures move, solvent losses creep up, feed volatility shifts. In peak summer, condenser cooling struggles and fractionation margins tighten up. We’ve lost sleep tweaking set points during batch runs, knowing that a fraction off the boil means chasing re-blend and re-distill later. There’s no shortcut; bringing cis-4-octene to spec depends on constant vigilance.

    Feedstock supply can tighten in resource-constrained years. Competition for base C8 streams runs high when regional cracker outages or geopolitical shifts rock the wider commodity market. To keep contracts filled, we’ve built up buffer storage and alternate supplier relationships, and extended maintenance windows to build flexibility. We learned from past falls in supply: contingencies work best when built upfront, not after the pipe runs dry.

    Solutions: Investing in Reliability and Innovation

    The cost of maintaining a clean stream of Cis-4-Octene doesn’t just fall on today’s sales. Investments we’ve made—overhauling distillation trains, doubling up on inline analyzers, and upgrading tank venting—are aimed at building confidence across the supply chain. Each process tweak cuts waste and narrows batch drift, which shows up both in product quality and how fast custom lots leave the plant door.

    We continue to lean on feedback from users in polymer production, flavors, and specialty syntheses. Their priorities shape our innovation pipeline, from revamped purification resins to tighter moisture controls. The push never stops on improving energy efficiency, too—recovering process heat or fine-tuning column insulation to hold down utility costs. These investments filter directly into stable supply and short lead times.

    Looking Forward: How the Industry Shifts

    Demand for Cis-4-Octene keeps tracing upward alongside new applications. Advanced catalyst systems, greener surfactants, and specialty lubricants look for pure, repeatable feedstocks. Down the road, we expect meal-replacement and pharmaceutical applications to bring even tougher scrutiny to input chemicals. Our shop stays a step ahead—in part from lessons learned over decades, and in part because the stakes keep rising.

    We see the chemistry behind Cis-4-Octene not as a mere problem to be solved, but as an ongoing craft. Each batch is another chance to reinforce reliability, craft purity, and work in sync with partners who build high-value products from the foundation up. Our job isn’t finished when the truck rolls away; we track every drum, every tank, until our customer’s process runs smoothly day after day. That’s the real measure of value in specialty manufacturing—not just counting molecules, but delivering confidence and peace of mind each time the material gets put to work.