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Chlorodimethylsilane

    • Product Name Chlorodimethylsilane
    • Alias Dimethylchlorosilane
    • Einecs 213-897-3
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    791660

    Cas Number 1066-35-9
    Molecular Formula C2H7ClSi
    Molecular Weight 94.62 g/mol
    Appearance Colorless liquid
    Boiling Point 36-38 °C
    Melting Point -111 °C
    Density 0.882 g/mL at 25 °C
    Refractive Index 1.390
    Flash Point -22 °C (closed cup)
    Solubility In Water Reacts violently
    Vapor Pressure 552 mmHg at 25 °C
    Synonyms Dimethylchlorosilane

    As an accredited Chlorodimethylsilane factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, 500 mL capacity, sealed with PTFE-lined cap, labeled with hazard symbols and product details for Chlorodimethylsilane.
    Shipping Chlorodimethylsilane should be shipped in tightly sealed containers under a dry, inert atmosphere. It must be clearly labeled and handled as a flammable, corrosive liquid. Transport according to local, national, and international regulations for hazardous materials, ensuring protection from moisture and ignition sources. Wear appropriate PPE during handling and shipment.
    Storage Chlorodimethylsilane should be stored in a cool, dry, well-ventilated area away from moisture, heat, and sources of ignition. Keep it in tightly sealed containers made of compatible materials, such as glass or specific plastics. Protect from air and water, since it reacts violently with moisture. Clearly label all containers and store away from oxidizing agents, acids, and strong bases.
    Application of Chlorodimethylsilane

    Applications of Chlorodimethylsilane in Industrial Manufacturing

    Chlorodimethylsilane, as a highly reactive organosilicon compound, is critical in multiple specialized sectors where silicone-based intermediates and functional materials form the backbone of advanced manufacturing. The following sections highlight established industrial fields where our chlorodimethylsilane supports dependable production outcomes, strict compliance, and targeted performance profiles.

    1. Silicone Polymer Synthesis for Elastomers

    Leading silicone elastomer producers rely on chlorodimethylsilane as a key silylation agent and chain terminator in the controlled synthesis of polydimethylsiloxanes (PDMS). During continuous or batch processes, the material enables precise regulation of molecular weights and reactive end group functionality, which is vital for mechanical, chemical, and barrier property specification in silicone rubbers used by industries with demanding durability and thermal stability requirements. Our supply integrates with mature PDMS production lines supporting large-volume dispersions and advanced vulcanization systems.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management Systems for Elastomer Manufacturing)
    • REACH Regulation (EC) No 1907/2006 (European Union Chemical Registration)
    • GB/T 20106 (Chinese National Standard for Silicone Rubber Materials)
    • ASTM D412 (Tensile Properties of Vulcanized Rubbers)

    Typical usage ratio

    • 0.5–2.0% (w/w) in PDMS polymerization; dosage set by desired chain length and functional group density for downstream crosslinking; exact proportion determined via dynamic viscosity targets and platinum-catalyzed curing dynamics.

    Downstream process integration

    • Added during oligomerization or chain-end capping stages post-initial hydrolysis/condensation of siloxane monomers; mixing under controlled moisture and inert gas conditions to prevent premature hydrolysis.

    Final product types

    • High-consistency silicone rubbers (HCR)
    • Liquid silicone rubbers (LSR)
    • Room-temperature vulcanizing (RTV) silicones
    • Silicone elastomer sheets and parts for automotive, electronics, and healthcare sectors

    2. Silane Coupling Agent Manufacture for Adhesives & Coatings

    Chemical manufacturers use chlorodimethylsilane in coupling agent synthesis, introducing dimethylsilyl reactive groups into organosilanes for specialty adhesives and advanced surface treatments. The intermediate’s reactivity is essential to produce silane-based adhesion promoters that interface with organic polymers and inorganic minerals or glass, improving mechanical bonding and compatibility in complex formulation environments. Our strict production controls ensure consistent purity that downstream formulators demand for high-performance coatings.

    Industry compliance standards

    • ISO 14001:2015 (Environmental Management for Chemical Plants)
    • Directive 2004/42/EC (EU VOC in Paints and Varnishes)
    • JIS K 5674 (Japanese Industrial Standard for Primer and Adhesive Agents)
    • ASTM C1315 (Liquid Membrane-Forming Compounds for Curing and Sealing Concrete)

    Typical usage ratio

    • 0.3–1.0% (w/w) of total silane stream; the addition depends on targeted alkyl substitution and desired silane equilibrium in downstream grafting; process QC often sets exact ratio per free chloride content and GC-MS purity analysis.

    Downstream process integration

    • Dosed during the alkoxylation or hydrolysation phase of silane coupling agent production; reacts with alcohols or alkali solutions to form downstream functional silanes under strict temperature and pressure control.

    Final product types

    • Silane adhesion promoters for hybrid adhesives
    • Glass fiber sizing agents
    • Water-repellent protective coatings for mineral substrates
    • Modified resin binders for architectural paints

    3. Semiconductor-Grade Silicone Precursors

    High-purity chlorodimethylsilane serves as a vital silicon precursor in the electronics industry, especially for the deposition of ultra-thin silicon dioxide or organosilicon films via chemical vapor deposition (CVD) and atomic layer deposition (ALD). These films form critical gate dielectrics, passivation, and planarization layers in integrated circuit and MEMS wafer fabrication. Our dedicated production systems provide electronics-grade chlorodimethylsilane, minimizing trace metal and moisture contamination in ultra-cleanroom process environments.

    Industry compliance standards

    • IATF 16949 (Quality Systems for Automotive Semiconductors)
    • SEMI C57 (Specifications for Silicon Compounds in Microelectronics)
    • IEC 62258 (Semiconductor Die Product Quality)
    • JEITA ED-4701 (Japanese Semiconductor Reliability Testing)

    Typical usage ratio

    • Typically 0.1–0.5 molar equivalents relative to additional silicon or oxygen sources in CVD processes; adjusted per film thickness and conformality requirements monitored via ellipsometry and FT-IR endpoint analysis.

    Downstream process integration

    • Directly introduced into CVD/ALD chambers under high-purity inert carrier gas flow; vapor-phase contacted with heated substrates to generate controlled deposition of silicon-containing layers.

    Final product types

    • Interlayer dielectric films for microchips
    • Planarization coatings for MEMS wafers
    • Protective organosilicon films for display panels
    • Thin silicon oxide interface films for advanced sensors

    4. Intermediate for Organosilicon Pharmaceuticals & Agrochemicals

    Active substance manufacturers use chlorodimethylsilane as a selective silylating reagent when synthesizing organosilicon intermediates embedded in complex pharmaceutical and agrochemical molecules. The controlled introduction of dimethylsilyl functionalities protects reactive molecular groups during organic transformations, enabling elaborate, multi-step synthesis schemes in regulated cGMP production environments. Material traceability and reproducibility stand as core priorities for our supply streams serving this sector.

    Industry compliance standards

    • ICH Q7 (Good Manufacturing Practice for Active Pharmaceutical Ingredients)
    • US FDA 21 CFR Part 211 (Pharmaceutical API Production)
    • EU Regulation (EC) No 1107/2009 (Plant Protection Product Actives)
    • Chinese Pharmacopoeia – General Testing Methods for Organosilicon Intermediates

    Typical usage ratio

    • 0.1–1.5 molar equivalents depending on substrate reactivity in silylation reactions; precise addition determined in pilot studies to control target API isomeric purity and minimize by-product formation.

    Downstream process integration

    • Reacted during protection/deprotection steps in pharmaceutical multi-step synthesis or as a silicon source for silylated pesticide intermediates; applied in closed, validated reactor systems with automated dosing control under GMP documentation.

    Final product types

    • Silylated pharmaceutical building blocks for APIs
    • Protected intermediate compounds for radiolabeled tracers
    • Silanized pesticide actives
    • Custom organosilicon reagents for medicinal chemistry research

    5. Specialty Hydride Reducing Agent Synthesis

    Producers of advanced silane-based reducing agents employ chlorodimethylsilane as a controlled precursor in the production of hydride donor reagents, such as dimethylsilane derivatives. These reagents serve chemoselective reduction roles in the pharmaceuticals, flavors & fragrances, and specialty chemicals sectors where alternative metal hydrides lack desired selectivity. Our process ensures low trace metal content and high batch-to-batch reproducibility for demanding organic synthesis workflows.

    Industry compliance standards

    • ISO 13485:2016 (Quality Management for Fine Chemical Production)
    • US Pharmacopeia (USP) Monographs for Reagent Quality
    • OECD Principles of Good Laboratory Practice (GLP)
    • EU Regulation (EC) No 1272/2008 (CLP for Hazardous Chemicals)

    Typical usage ratio

    • 0.5–2.5 molar equivalents versus target substrate for hydrosilylation reactions; precise proportion optimized via bench-scale reactivity screening using GC yield and NMR selectivity endpoints.

    Downstream process integration

    • Chlorodimethylsilane introduced into moisture-sensitive batch processes, often under anhydrous conditions, with subsequent reduction to active silane hydride reagents used in couplings, reduction of carbonyls, or protection group chemistry.

    Final product types

    • Specialty hydrosilane reagents for organic synthesis
    • Silane-based reducing agents for chiral synthesis
    • Silanized intermediates for fragrance ingredients
    • Research-grade reducing agents for analytical laboratories
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    Certification & Compliance
    More Introduction

    Chlorodimethylsilane: Our Experience from Reactor to Real World

    How Chlorodimethylsilane Became a Foundation for Advanced Chemistry

    We have spent decades working with silanes in our production halls. Chlorodimethylsilane, with its straightforward structure—one silicon atom, two methyl groups, and a chlorine—remains one of those workhorse molecules that often goes ignored outside of specialty circles. Yet its strength in synthesis and functional group protection plays a critical role in the modern chemical industry.

    Our commitment to high purity standards comes from countless batches and process tweaks. At the molecular level, small impurities can compromise reliability. Many chemists using chlorodimethylsilane aim to introduce Si–Me bonds into organic backbones. A minor contaminant changes reactivity and gives unpredictable yields. That is why we’ve made precise distillation and gas-phase monitoring standard at our facility. We insist every lot tested leaves the distillation column with purity above 99%. Colorless and clear, our product carries the unmistakable sharp odor of genuine silanes, a scent that gives any production technician pause in respect for the chemical’s reactivity.

    Every reactor run is careful. Chlorodimethylsilane supports its own set of challenges. Moisture turns it into hydrochloric acid and dimethylsilanol, so everything—lines, valves, drums—gets dried, flushed, and monitored for leaks. Nighttime alarms tell stories of overpressure reliefs in the face of water intrusion. These lessons taught us the importance of discipline and the value of time spent investing in quality assurance.

    Passing on the Value: What Chlorodimethylsilane Actually Delivers

    We see the real value of chlorodimethylsilane in the way our customers put it to use. You’ll spot this compound everywhere professional chemists need sharply defined reactivity. Most often, they use it to introduce the dimethylsilyl group onto alcohols, amines, or acids, setting up a temporary shield for those functionalities while more aggressive reactions run their course. In the realm of pharmaceuticals, where a single misplaced atom can destroy a synthesis, chlorodimethylsilane shines as a protecting agent. The resulting silyl ethers clean up sharply after the job is finished.

    Another application comes in crosslinking silicone rubbers or resins. By leveraging the Si–Cl bond, chlorodimethylsilane inserts reactive sites exactly where a formulation requires mechanical strength or hydrophobic barriers. Coating developers take advantage of this molecule to anchor functional silanes on glass, textiles, and ceramics, building weather-resistant films on the smallest scale. Each time we ship a drum out, we imagine it ending up in an environment where longevity and reliability matter deeply—wind turbine blades, architectural glass facing ocean spray, or insulator housings facing UV load year after year.

    We’ve watched our product move beyond the lab bench and into industrial pilot lines. From electronics to fiber optics, it creates the foundation for advanced coatings or dielectric layers. Its chemical structure opens doors in organic synthesis, material science, and surface engineering. This isn’t an abstract concept for us: we remember optimizing solvent ratios to suppress unwanted oligomerization; we recall fielding calls from process engineers dialing in reaction temperatures for reproducible batch quality. Every feedback—good or bad—fed into our own internal improvements.

    Key Differences from Other Silanes: Depth from Daily Production

    Working hands-on with the full family of chlorosilanes, we get questions about why chlorodimethylsilane stands out compared to close relatives. We regularly manufacture trimethylchlorosilane, methyltrichlorosilane, and dimethyldichlorosilane, too. Each one offers something different, but subtle distinctions in reactivity and volatility often determine success or failure downstream.

    Trimethylchlorosilane, for instance, delivers bulkier silyl groups, but lacks the same balance of reactivity. Its silylation reactions go fast, sometimes too fast, favoring side product formation with sensitive substrates. On the other hand, dimethyldichlorosilane brings two chlorines, making it better suited for crosslinking or polymer advanced work. But that added reactivity turns handling into a risk management exercise: rapid exotherms, unwelcome HCl, and product decomposition if not managed correctly.

    Chlorodimethylsilane occupies a middle ground. You get control over the degree of substitution. Its Si–Cl bond is less aggressive yet precise enough for most silanization reactions. We find that our customers who scale up lab findings into pilot or commercial production prefer the confidence chlorodimethylsilane brings. Its volatility is high but manageable under normal plant conditions. Built-in methyl groups help tune hydrophobicity in end-use applications, from surface treatments to custom monomers for silicone elastomers or resins.

    Our team often recommends chlorodimethylsilane to those developing new active pharmaceutical ingredients or modifying catalyst supports, and we’ve assisted research groups optimizing deposition on silicon wafers. Those customers achieve repeatable, high-yielding results with fewer side reactions and less byproduct cleanup. That makes a meaningful difference not just in lab notebooks, but in billable production hours and waste management costs.

    Lessons in Handling and Real-World Dispensing

    Anyone with experience in chlorosilane storage knows the brutal truth about moisture sensitivity. Even with elaborate nitrogen blanketing, product transfer lines collect micro-droplets over time. We train our staff to anticipate the “pop” sound of a reacting valve—a result of accidental water contact. Over the years, we’ve replaced countless gaskets, upgraded valves, and overhauled venting systems. These aren’t abstract investments; they come after midnight emergency room visits, after corroded control panels, and after wasted product.

    In our loading bays, strict personal protective equipment rules protect operators from splashes and HCl evolution. Respirators aren’t optional, and spill trays sit everywhere. We learned early that old-fashioned visual checks matter more than paperwork at the end of a shift. This vigilance guarantees safe operations and dependable supply. Our hope is that by setting a high standard in our own plant, we help our customers avoid similar difficulties downstream.

    Once shipped, chlorodimethylsilane arrives at research labs or bulk chemical plants worldwide. Some customers purchase it in drum lots for surface modification, while others specify ampoules or cylinders for air-sensitive organic synthesis. We worked with one electronics manufacturer to map out exact temperature control curves, reducing polymerization risk during vapor deposition. In another case, a fragrances company needed pinpoint water content to avoid trace acid formation in their perfumery intermediates. Each application brought its own lessons and pushed us to refine analytical checks and packaging options further.

    Supporting Development in Chemicals, Pharmaceuticals, and Materials Science

    New markets keep emerging thanks to scientists and engineers hungry for new molecular tools. One area where chlorodimethylsilane found renewed interest is in selective surface functionalization. Advanced optics and microelectronics companies now request custom treatment kits to adjust everything from refractive index to electrical insulation. Our teams coordinate closely with R&D partners, shipping test lots and adjusting production parameters until they hit precise customer targets.

    In pharmacy, process chemists use chlorodimethylsilane in the assembly of complex intermediates. The chemical unlocks routes otherwise blocked by uncooperative functional groups. Its predictable reactivity as a protection agent allows multi-step syntheses to succeed with higher throughput and greater purity. We’ve also tracked chlorodimethylsilane’s integration into specialty paints and coatings. Marketing pitches aside, the performance feedback lands in our inboxes—requests for tweaks in volatility, purity specifications, or delivery sizes.

    We believe strongly in supporting our customers’ technical progress. We devote resources not just to product consistency, but to understanding the journey our chemical takes in the wild. Every year, engineers and compliance officers visit our plant and walk the production line. Inspecting loading arms, they ask about batch traceability and gas analysis routines. We lay out our in-process data, from chromatographic fingerprinting down to ppm-level analytics for contaminants. Each dialogue strengthens our own systems and gives customers assurance they can trust our supply over decades, not just a single delivery.

    Environmental Stewardship and Regulatory Realities

    Anyone making or shipping chlorodimethylsilane faces two overlapping realities: its value in technical applications, and its potential to do real harm if uncontrolled. Our environmental health and safety group keeps close ties to local and national regulators. Inspections and compliance exercises aren’t boxes to tick but chances to tighten our own processes. Tanks stand behind rain shields and oil-leak detection sensors. Emergency neutralization vats sit under drum platforms. Neighboring residents grow more comfortable seeing our team on walkarounds, checking valves and bunds after storms as a matter of routine.

    Transports always stress-test our logistics chain. Whether we ship domestically or send containers overseas, drivers follow detailed handling protocols. Labels communicate not just the product, but procedures in case of environmental release. Throughout the supply chain—warehouse stops, customs—real people make real decisions about safety. We contribute our operational experience to industry working groups, sharing lessons learned around minimizing spill risks and training external partners. It’s not enough to make a product technically; producers owe responsibility for every molecule, from synthesis through disposal.

    Building for Tomorrow: Innovation Paths and Customer Collaboration

    Making chlorodimethylsilane isn’t static. Our R&D staff constantly revisits reactor design and downstream processing. Recent breakthroughs include closed-loop solvent recycling that cut total organic solvent emissions by more than half. New scrubber media capture HCl byproduct at higher efficiency, keeping workplace air and effluent water cleaner. Production investments aren’t PR talking points—they drive tangible gains in both staff safety and environmental performance.

    We see these advances as part of a longer tradition. Years ago, plant operators relied on intuition and paper logs. Today’s systems digitize every step, catching pressure and temperature shifts before they reach critical thresholds. Digital process control, smarter sensors, and automated analytics give us tools to compete with global suppliers on both price and reliability. Most importantly, these advances reduce batch failures and short shipments. Stable supply chains mean our customers can keep their manufacturing lines moving without interruption.

    We foster a feedback culture with our industrial and research customers. Chemists testing new reaction pathways or engineers scaling up advanced materials often encounter unforeseen challenges—from coking in pipes to unexplained color formation. Our technical support staff makes expert recommendations built from first-hand production trials and detailed literature. Sometimes, the path leads us to a new grade or packaging size, made possible by process innovations. We celebrate these collaborations, recognizing that industry only moves forward by sharing knowledge openly.

    Being a chemical manufacturer today means integrating technical mastery with stewardship and a commitment to community. For us, every drum or cylinder of chlorodimethylsilane shipped carries a story—of process refinements, safety lessons, regulatory learning, and hope for what our customers will build next. The journey from silicon metal to Si–Me2Cl runs longer than most people realize, so we remain both proud and vigilant stewards of this vital compound for the chemistry community.