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Chlorodimethylphenylsilane

    • Product Name Chlorodimethylphenylsilane
    • Alias CDMPS
    • Einecs 221-226-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales7@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    826968

    Cas Number 1833-53-0
    Molecular Formula C8H11ClSi
    Molar Mass 170.72 g/mol
    Appearance Colorless to pale yellow liquid
    Density 1.046 g/mL at 25°C
    Boiling Point 211 °C
    Melting Point -37 °C
    Refractive Index 1.513
    Purity Typically ≥97%
    Flash Point 91 °C (closed cup)

    As an accredited Chlorodimethylphenylsilane factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Chlorodimethylphenylsilane is supplied in a 100 mL amber glass bottle with a secure screw cap, labeled with safety and hazard information.
    Shipping Chlorodimethylphenylsilane should be shipped in tightly sealed containers under inert atmosphere, protected from moisture and incompatible substances. It must be labeled as a flammable and corrosive chemical. Transport in compliance with local and international regulations, such as DOT or IATA. Store and handle only by trained personnel using appropriate safety precautions.
    Storage Chlorodimethylphenylsilane should be stored in a tightly sealed container under an inert atmosphere, such as nitrogen or argon, to prevent moisture and air exposure. Store it in a cool, dry, and well-ventilated area away from incompatible substances like acids and strong oxidizers. Keep the chemical away from heat, sparks, and open flames, and use appropriate secondary containment to prevent leaks or spills.
    Application of Chlorodimethylphenylsilane

    Applications of Chlorodimethylphenylsilane in Industrial Manufacturing

    Chlorodimethylphenylsilane serves as a key organosilicon intermediate supporting advanced specialty chemical synthesis, polymer modification, and electronic material production. We enable manufacturers to utilize this material at scale, providing tailored integration support and reliable supply for downstream industries. The following application scenarios highlight real-world use, specific compliance requirements, technical process details, and typical finished product types realized across major industrial sectors.

    1. Electronic Encapsulation Silicone Resins

    Manufacturers incorporate this silane during organosilicon resin synthesis to achieve targeted hydrophobicity, thermal stability, and mechanical protection for semiconductor device encapsulation. Chlorodimethylphenylsilane acts as a key phenyl-functional crosslinking agent within condensation reactions, affecting resin structure and function. Quality control ensures minimal ionic contamination and precise substitution, supporting device reliability and downstream assembly yields.

    Industry compliance standards

    • IEC 61249-2-21: Materials for printed boards and metal-clad laminates
    • IPC-4101: Specification for Base Materials for Rigid and Multilayer Printed Boards
    • JEDEC JESD22: Reliability Test Methods for Integrated Circuits

    Typical usage ratio

    • Reactant addition at 5–20% molar ratio relative to other silane monomers, adjusted based on targeted phenyl content and crosslink density requirements

    Downstream process integration

    • Charged in pre-polymerization stage of silicone resin production via alkoxysilane hydrolysis and condensation
    • Post-reaction resin functionalization subject to consistent molecule integration, followed by vacuum devolatilization to remove residual chloride

    Final product types

    • Electronic encapsulation resins
    • LED protective coatings
    • Semiconductor adhesive systems
    • Hybrid organic-inorganic dielectrics

    2. Specialty Silicone Rubber Modification

    Silicone rubber compounders use this intermediate to introduce phenyl groups, improving low-temperature flexibility, dielectric performance, and flame retardant properties. Phenyl modification supports cable insulation, high performance elastomers, and critical electrical housing components. Feedstock purity and consistent actives content remain key to ensure reproducibility and gain regulatory certification for the final compound.

    Industry compliance standards

    • UL 94: Flammability of Plastic Materials for Parts in Devices and Appliances
    • RoHS Directive 2011/65/EU (lead, mercury, cadmium content control)
    • IEC 60811: Electric and Optical Fibre Cables - Test Methods for Non-metallic Materials

    Typical usage ratio

    • 1–8 phr (parts per hundred rubber base), modifiable based on the required level of phenyl substitution

    Downstream process integration

    • Co-fed with base siloxane polymer during heat-catalyzed copolymerization
    • Completion assessed by infrared analysis and mechanical property benchmarking

    Final product types

    • High-performance phenyl silicone rubbers
    • Low-temperature cable sheathing
    • Flexible electronic keypad interfaces
    • High-voltage insulation components

    3. Silane Coupling Agent Production

    Chemical formulators utilize this raw material to manufacture functional organosilicon coupling agents designed to improve adhesion between inorganic fillers and polymer matrices. The phenyl-functional silane derivatives produced enable the composite industry to produce high-durability and weather-resistant materials for coating, sealant, and structure-bonding applications. Downstream conversion requires careful control of byproduct removal and functional group conversion rates.

    Industry compliance standards

    • ISO 9001: Quality Management in Chemical Synthesis
    • REACH Regulation (EC) No 1907/2006 (substance registration for silanes)
    • ASTM C581: Chemical Resistance of Thermosetting Resins

    Typical usage ratio

    • Stoichiometric conversion (typically 1:1) with alcohols or alkoxysilanes; batch runs controlled for 95-98% conversion yield

    Downstream process integration

    • Used as the starting silane in alcoholysis or hydrosilylation reactions under inert atmosphere
    • Post-reaction neutralization and distillation to isolate high purity coupling agents

    Final product types

    • Phenyl-functional silane coupling promoters
    • Specialty primers for composite bonding
    • Improved weatherable paints and sealants
    • Epoxy/filler interface agents

    4. Synthesis of Phenylsiloxane Oils and Fluids

    Bespoke lubricant manufacturers and thermal fluid producers utilize chlorodimethylphenylsilane as a monomer to create phenyl-modified siloxane oils and fluids. These engineered fluids serve critical roles in environments where oxidative stability, radiation resistance, and low volatility are paramount. Production relies on batch-controlled hydrolysis and polycondensation, with continuous monitoring to meet demanding end-use mechanical and chemical purity specifications.

    Industry compliance standards

    • ISO 21469: Safety of Machinery - Lubricants with Incidental Product Contact
    • NSF H1 Certification (for specific grades)
    • ASTM D7042: Standard Test Method for Dynamic Viscosity and Density of Liquids

    Typical usage ratio

    • 30–60% phenyl-containing silane incorporation, tuned based on pour point and oxidation index of the final oil

    Downstream process integration

    • Added at the initial hydrolysis and silica oligomerization stage, followed by molecular weight adjustment via co-polymerization with dimethylsiloxane

    Final product types

    • High-performance phenylsiloxane fluids
    • Transformer cooling oils
    • Nuclear industry lubricants
    • Heat transfer media for wide temperature range systems

    5. Optical Grade Silicone Preparation

    Producers of optical silicone use controlled amounts of this raw material to impart phenyl functionality to polymers, enabling refractive index tuning and improved UV/thermal resistance. High clarity, low haze, and precise refractive index adjustment are critical for advanced lens, encapsulant, and light-guide applications. Manufacturing requires low-metal impurity feedstock and strict in-process solvent control for optoelectronic-grade outputs.

    Industry compliance standards

    • ISO 13485: Medical Devices Quality Management (for intraocular lens materials)
    • ISO 10993-5: Cytotoxicity Testing (medical grade silicones)
    • IEC 60825: Safety of Laser Products (encapsulant compatibility)

    Typical usage ratio

    • 3–15% monomer input per silicone chain unit, based on target optical transmission and refractive index requirements

    Downstream process integration

    • Reacted in the silicone network forming stage alongside clear siloxane precursors
    • Batch qualification via FTIR and haze testing to verify phenyl group content

    Final product types

    • Optical-grade silicone elastomers
    • High-transparency LED encapsulants
    • Precision light-guide pads
    • Vision correction product materials

    6. Advanced Resin and Coating Additive Intermediates

    This silane enables resin and coating manufacturers to synthesize advanced additives, granting improved chemical resistance, gloss, and flexibility to architectural and industrial coatings. It undergoes controlled functionalization to match desired performance criteria with careful monitoring for chloride and byproducts. Stringent material characterization and blend validation ensure regulatory and application-specific requirements are met for downstream use.

    Industry compliance standards

    • EN 927-6: Coating Materials and Coating Systems for Exterior Wood
    • VOC content control per EU Directive 2004/42/EC
    • ISO 12944: Corrosion Protection of Steel Structures by Protective Paint Systems

    Typical usage ratio

    • 5–25% additive intermediate use in resin mass, subject to final film flexibility, gloss, and adhesion profile

    Downstream process integration

    • Used in resin pre-reactor functionalization with pigments or as a chain terminator in hybrid resin synthesis
    • In-line quality verification and post-additive dispersion to ensure compatibility with major vehicle types

    Final product types

    • Chemical-resistant topcoats
    • Flexible architectural paints
    • Weather stable protective resins
    • Hybrid alkyd-silicone coatings
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    Certification & Compliance
    More Introduction

    Chlorodimethylphenylsilane: Precision in Organosilicon Chemistry

    Deep Roots in Specialty Silicone Synthesis

    Manufacturing organosilicon compounds demands more than just access to raw materials. It calls for disciplined process control, technical foresight, and respect for each molecule’s quirks. Chlorodimethylphenylsilane stands out in the portfolio. Over years, our reactors have seen thousands of batches. Through these cycles, we have seen how chlorodimethylphenylsilane’s fine-tuned structure—composed of a benzene ring, two methyl groups, and a chloro-silicon linkage—creates unique possibilities and distinct challenges for users in the chemical, electronic, and materials spaces.

    Model and Specifications: Delivering What Matters

    We manufacture chlorodimethylphenylsilane at a purity grade tailored specifically for robust downstream reactions—commonly exceeding 98% assay by GC. Colorless to nearly colorless liquid, the purity is the result of strictly monitored distillation and rigorous impurity checks. Water content sits below the ppm levels required by most hydrosilylation steps. Our product comes standardized at commercial scales, available batch sizes reflecting demands from pilot plant runs up to metric ton shipments. The boiling point settles around 225-227°C under atmospheric pressure, and we keep every drum filled under inert gas, minimizing hydrolysis and shipping losses. The density holds steady at roughly 1.04 g/cm³ at 25°C, reflecting a predictable behavior in existing process streams.

    Consistency does not rise from intention alone. The way we distill and pack each batch keeps contamination and variability at bay. We don’t outsource synthesis or repackage intermediates. Instead, each drop of chlorodimethylphenylsilane comes only from our own glass-lined facilities, where field-seasoned operators set charge, run feeds, and check profiles by GC and NMR. It’s this sort of discipline that lets formulators in the silicone and resin sectors plan their downstream transformations without bracing for unpleasant lot-to-lot surprises.

    Why This Molecule Stands Out: Experience at Scale

    Having run continuous lines for years, we've seen the difference raw material quality makes in the performance of finished silicone resins, silicone rubbers, and high-performance coatings. Chlorodimethylphenylsilane brings a distinctive set of properties—not just from its basic structure, but because of how the phenyl group shifts both reactivity and thermal stability compared to simpler alkylchlorosilanes. Our chemists have watched the way that even slight traces of hydrolyzable chloride in lesser-quality chlorosilanes can lead to cloudy gels, loss of mechanical properties, or poor dielectric behavior in electronic fluids.

    The phenyl substituent confers higher thermal and oxidative stability to the polymers and copolymers synthesized from it. Customers in electronic encapsulation, for instance, look for these attributes to ensure their final gels don’t degrade under sustained heat or voltage. Meanwhile, the dimethyl groups set apart flow, compatibility, and cross-linking speed in silicone intermediates. The net effect? Practical downstream consistency, particularly in environments where formulation errors become expensive within hours.

    Practical Usage Across Industries

    Chlorodimethylphenylsilane earned its place in specialty silicone synthesis, especially as an intermediate for siloxane and silane coupling agents. Our customers—ranging from electronic encapsulant makers to advanced resin formulators—choose it to build up phenyl-modified siloxanes with superior flexibility at low temperatures, enhanced electrical insulation, and improved compatibility with organic components.

    Where some producers rely on older chlorosilanes like dimethyldichlorosilane, formulators who want better temperature resistance and better optical clarity in the finished silicone often cut in chlorodimethylphenylsilane as a co-monomer. The resulting copolymers bridge the performance gap between basic PDMS and higher-priced specialty phenyl-silicones. We’ve supplied this product to customers who cannot afford variability: manufacturers of LED encapsulants, silicone adhesives for aerospace, and insulating coatings for transformers. These sectors learned the value of predictable reactivity and high purity, especially as regulatory standards for clarity and long-term reliability keep rising.

    Chlorodimethylphenylsilane also supports a wide range of surface treatments. When reacted to form silanols or functional silanes, it readily attaches to glass, ceramics, and certain polymers—enhancing hydrophobicity or fine-tuning electrical properties. This isn’t abstract chemistry; it’s an answer to fouling problems or dielectric breakdowns discovered in production, not just in theory.

    Differences Compared to Other Related Products

    Suppliers field plenty of requests for silanes—there’s dimethyldichlorosilane, methyltrichlorosilane, phenyltrichlorosilane, and others. On paper, these may seem interchangeable. In practice, process engineers and R&D chemists soon learn that outcomes diverge sharply. Phenyltrichlorosilane, for example, brings three chloro groups per silicon, so downstream siloxanes end up with much higher crosslink densities and different cure behaviors. Resin clarity and flexibility often drop as a result.

    Dimethyldichlorosilane offers good bang for the buck in sheer volume, but its performance falls short where low-temperature elasticity and thermal resistance are critical. The addition of a phenyl ring, as in chlorodimethylphenylsilane, shifts miscibility, dielectric properties, and aging profile. Our customers—glass fabricators, electronics firms, and custom silicone coil manufacturers—have learned to weigh these benefits against the modest cost premium. The consistent outcome: improved transparency, better aging under sunlight or radiant heat, and fewer process upsets in hydrolysis steps.

    Quality and Control: Lessons from the Shop Floor

    Scaling up organosilicon reactions takes more than textbook chemistry. Chlorodimethylphenylsilane formation depends on strict temperature control and gradual feed rates to avoid runaways or yellowing. Each small imperfection in raw material or heat transfer can cascade through finished polymers: undetected chloride impurity leads to lingering acid traces in resins, causing saponification or corrosion downstream. While many firms rebrand or resell, we handle every step from chlorination to final purification.

    Testing doesn’t stop at the product tank. Every batch gets checked by GC, and QC staff record not just basic purity but key byproducts or trace volatiles. We collect customer feedback and have adjusted our process over the years in response—not just tightening fraction cuts, but upgrading condenser surfaces and vent management, so samples arrive meeting the cleanest possible benchmarks.

    Supply Chain Reliability: Real-World Consequences

    Years in specialty chemicals have taught us that purity and availability share the same stage. Customers designing new electronics or formulating next-gen rubbers need to know the supply won’t let them down. We’ve seen global disruptions ripple through the silicones market: shortages of key starting materials, political constraints on chloroaromatic imports, sudden spikes in demand from solar and electronic sectors. In these moments, access to in-house raw material pools, fully-owned reaction trains, and longstanding supplier partnerships make the difference between meeting production targets and costly plant downtime.

    We maintain safety stocks on both finished silane and key chlorobenzene inputs, hedging against upstream disruptions. In periods of elevated demand, having multiple reactors on standby allowed us to ramp up output without competing for toll capacity. Many end users have told us that rapid order fulfillment mattered as much as technical mastery—and in both cases, handling the chemistry under one roof built that trust.

    Handling and Safety—Not Just Compliance, But Daily Practice

    Chlorodimethylphenylsilane doesn’t forgive carelessness. Its reactivity with water leads to problematic fumes and acidic byproducts. On our own lines, we enforce nitrogen purging, sealed pumps, and closed transfer loops at every stage. From years of plant operation, we’ve seen that even a brief lapse—a stuck valve or cracked gasket—can mean ruined product or safety incidents. Returns and customer reports taught us to go further than regulations ask, tightening our filling and drum handling procedures at every turn.

    For downstream users, storing unopened drums under dry, inert conditions is not negotiable. Our technical service has walked more than one partner through proper facility upgrades to prevent moisture contamination—often catching problems before a full production run spoils hundreds of kilos of high-value silicones. Waste management practices also come from hands-on plant experience, with neutralization and offgas abatement developed for day-to-day reliability, not just to check a rulebook.

    Markets Trust Consistent Chemistry

    Sophisticated customers in electronic encapsulation, advanced polymers, and specialty surface treatments keep coming back to us not only for the product’s stated assay but also for its real-world reliability. Through repeated projects, the market confirmed that drop-in replacements from secondary suppliers rarely delivered identical results—batch stability, cloud point, or haze in final resins often flagged a hidden difference. We’ve run field trials side by side and seen how slight impurities cost performance, aging, and success at scale.

    From initial R&D through full-scale production, product lifetime and quality assurance depend on manufacturing controls rarely spelled out in public brochures. That’s why, behind every drum, there’s a record of not only analytical tests, but hands-on troubleshooting and continuous improvement, tuned over countless batches. The strongest claims about downstream performance—resin clarity, elastomer toughness, long-term dielectric strength—trace back to choices made inside the reactor.

    Looking Ahead: Supporting Innovation

    Sustainability targets and advanced electronics drive new demand for tailored organosilicon materials. Chlorodimethylphenylsilane sits at a crossroads of opportunity. Formulators exploring fire-resistant silicones, optically clear encapsulants, or next-generation medical-grade elastomers depend on a consistent and well-characterized supply of this intermediate. Our customers’ innovations, and ultimately their success, link directly to the stability and predictability of each delivery.

    Recently, we’ve worked alongside partners in automotive electronics, supplying batches for plasma-resistant silicone rubbers destined for critical gaskets and seals. Other collaborators use our chlorodimethylphenylsilane to fine-tune primer coatings for solar panels, improving both durability and transmittance under high-UV exposure. The differences compared to more generic chlorosilanes appear not just in spec sheets but in long-term reliability—fewer yellowing incidents, better weathering results, and tighter quality assurance at every shipment.

    Continuous Feedback and Product Evolution

    Staying relevant in specialty silicones means learning from every challenge. Over the last decade, process feedback from customers led us to redesign our distillation columns, add additional online monitoring, and swap in lower leaching elastomers for all contact seals. Each improvement reflected specific pain points shared from the field—from haze in optical applications to residue issues in large-scale casting systems.

    Collaboration with users revealed areas for further development: pushing assay even higher, increasing bulk pack flexibility, or developing specific blends for emerging uses in additive manufacturing. Every evolution traces back to real-world necessity, not a brochure promise. Even as end-uses change, the underlying priorities—predictability, robust processability, and fast-acting support—remain unchanged.

    A Manufacturer's Perspective

    No third party stands between us and the quality of chlorodimethylphenylsilane delivered to each customer. Year after year, this approach reduced rework, prevented surprises, and built a relationship of trust with those pushing the boundaries of advanced silicone chemistry. If your operations depend on the outcome, the advantages go beyond specification sheets: hands-on control, technical transparency, and dedication rooted in decades of craft. From each reactor to every drum shipped, our mission stays the same: supply a product that meets real-world expectations, batch after batch, project after project.