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Antimony (IV) Oxide

    • Product Name Antimony (IV) Oxide
    • Alias Antimony tetroxide
    • Einecs 215-251-3
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    572412

    Chemical Name Antimony (IV) Oxide
    Formula SbO2
    Molar Mass 155.76 g/mol
    Appearance White to yellowish powder
    Density 5.67 g/cm3
    Solubility In Water Insoluble
    Oxidation State +4
    Cas Number 1332-81-6
    Pubchem Cid 166843
    Hazard Classification Harmful if inhaled or ingested
    Boiling Point Decomposes before boiling
    Crystal Structure Orthorhombic

    As an accredited Antimony (IV) Oxide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing White, sturdy HDPE bottle labeled “Antimony (IV) Oxide, 100g.” Features hazard symbols, chemical formula, and secure screw cap for safety.
    Shipping Antimony (IV) Oxide should be shipped in tightly sealed containers, away from incompatible substances and moisture. Transport must comply with local regulations for hazardous materials. Label containers clearly, ensure appropriate hazard communication, and use secondary containment to prevent spills. Handle with care to avoid dust generation during transit.
    Storage Antimony (IV) oxide should be stored in a tightly closed container, in a cool, dry, and well-ventilated area. Keep it away from incompatible substances such as strong acids and strong oxidizers. Protect from moisture and physical damage. Store in a designated chemical storage area with appropriate labeling and access restrictions to prevent unauthorized or untrained personnel from handling the chemical.
    Application of Antimony (IV) Oxide

    Applications of Antimony (IV) Oxide in Industrial Manufacturing

    Antimony (IV) Oxide serves critical roles in controlled downstream industrial processes across a diverse range of manufacturing sectors. As a direct-process manufacturer, we target application-specific grades and micron sizes to meet established technical and compliance benchmarks at each stage of customer production. Below, we outline the most prevalent end-use industries and detail the integration of this compound under real-world operating conditions.

    1. Flame Retardant Additives for Plastics

    Major thermoplastics such as polyethylene, polypropylene, and polyvinyl chloride utilize Antimony (IV) Oxide as a synergist, intensifying slow-burning characteristics in halogenated flame-retardant systems. Compounders add the oxide during initial resin formulation or in masterbatch blends, relying on close dose control to comply with industry fire safety standards. Process engineers tune dosage according to resin type, application exposure, and anticipated regulatory inspection, with quality checks for dispersion and particle size. This additive finds ultimate use in electronics housings, automotive interiors, and cable insulation requiring validated flame resistance performance.

    Industry compliance standards

    • UL 94 (Flammability of Plastic Materials for Parts in Devices and Appliances)
    • IEC 60695-11-10 (Fire hazard testing – Test flames)
    • REACH Annex XVII (Limits on restricted substances in plastics)
    • RoHS Directive 2011/65/EU (Lead, mercury, and other restricted substances in electronics)

    Typical usage ratio

    • 2% - 10% by weight in halogenated plastic resin compounds, adjusted based on polymer base, fire risk category, desired V-0/V-2 rating, and interaction with brominated or chlorinated agents.

    Downstream process integration

    • Direct addition to polymer melt compounding lines during high-shear mixing
    • Inclusion in color masterbatches before pelletization
    • Blending into extrusion, injection moulding, and film-casting feedstocks
    • Post-processing checks for uniform dispersion via FT-IR and TGA

    Final product types

    • Electrical and electronic equipment casings
    • Automotive dashboard and panel components
    • Insulation tapes and power cable jackets
    • Building insulation foam boards

    2. Flame Retardant Coatings for Textiles

    Textile manufacturers integrate Antimony (IV) Oxide into back-coating formulations for curtains, upholstery, and transportation fabrics. By combining the oxide with halogen donors, finishing lines achieve durable fire-resistant properties required by commercial and contract markets. Typical application involves aqueous or solvent-based formulations padded or sprayed onto textile backings during the final finishing stage, with robust fixation to withstand laundering and dry-cleaning. Quality control protocols include burn testing and confirmation of additive bonding at the fiber-matrix interface.

    Industry compliance standards

    • NFPA 701 (Standard Methods of Fire Tests for Flame Propagation of Textiles and Films)
    • BS 5852 (Methods of test for assessment of the ignitability of upholstered seating)
    • California TB 117 (Requirements for upholstered furniture flammability)
    • Oeko-Tex Standard 100 (Annexes for flame retardant chemical residues)

    Typical usage ratio

    • 7% - 15% by weight in flame retardant backing compounds, varying with base-fabric weight, fiber type, and regulatory fire barrier class.

    Downstream process integration

    • Dispersed in liquid back-coating formulations for padding or knife-coating application
    • Applied as a final layer during finishing, prior to drying and curing ovens
    • Monitored for application rate and penetration via inline gravimetric controls
    • Finished goods tested for flame spread and afterflame resistance per certification requirements

    Final product types

    • Aircraft and rail seat covers
    • Office chair fabrics
    • Hotel drapes and blackout curtains
    • Protective bedding and mattress barriers

    3. Glass and Enamel Opacifiers

    Producers of opal and colored glasses employ Antimony (IV) Oxide as a highly effective oxidizing agent and opacifier. The oxide adjusts the redox balance in the melt, assisting in the formation of stable white or blue opaque phases. It frequently enters the batch mix alongside arsenic compounds or other metal oxides, where precise dosage affects both the aesthetic opacity and the integrity of the glass microstructure. Industrial glassmakers audit batch-to-batch usage and particle size consistency for optimum light diffusion and minimal inclusion defects. Product focus covers domestic tableware, specialty glass tubing, and architectural glass panels requiring controlled translucency.

    Industry compliance standards

    • EN 1748 (Glass in building — Basic soda lime silicate glass products)
    • ASTM C162-05 (Standard Terminology of Glass and Glass Products)
    • ISO 14021 (Requirements on hazardous substances in glass container manufacturing)
    • FDA 21 CFR 175.300 (Resins and polymers in contact with food in glass coatings)

    Typical usage ratio

    • 0.1% - 1.0% by batch weight, tailored to the level of opacity, color type, glass chemistry, and melt oxidation needs.

    Downstream process integration

    • Introduced with other raw batch ingredients prior to furnace melting
    • Mixed under controlled agitation to enable uniform redox effects
    • Monitored during furnace operations for retention and fining behavior
    • Quality-checked in finished glass via spectrophotometric transmission tests

    Final product types

    • Opal dinnerware glass
    • Architectural panel glass
    • High-strength laboratory glassware
    • Colored beverage and cosmetic bottles

    4. Catalysts in Polyethylene Terephthalate (PET) Production

    Antimony (IV) Oxide acts as a crucial catalyst in the esterification and polycondensation steps of PET synthesis. It promotes rapid polymer chain growth and tailors molecular weight, directly influencing the physical properties required in beverage bottles and food packaging films. Resin manufacturers meter catalyst addition at defined points in the polycondensation reactor, tracking antimony residue levels to comply with food safety regulations. Ongoing process audits maintain batch repeatability, and downstream users analyze trace levels in finished PET to validate compliance with consumer safety expectations.

    Industry compliance standards

    • FDA 21 CFR 177.1630 (Polyethylene terephthalate polymers for food contact)
    • EU Regulation No. 10/2011 (Plastic materials and articles intended to come into contact with food)
    • GB 9685-2016 (Chinese National Food Safety Standard for Additives in food contact materials)
    • EFSA Scientific Opinion on the safety assessment of antimony migration

    Typical usage ratio

    • 150 - 350 ppm (0.015% - 0.035%) by weight of final polymer, dosed in relation to process speed, reaction temperature, and desired intrinsic viscosity.

    Downstream process integration

    • Injected into the polycondensation reactor after ester exchange
    • Continuously monitored via ICP or AAS for process contamination checks
    • Participates in final filtration steps to reduce catalyst carryover
    • Regulated removal of residual catalyst during downstream solid-state polymerization or pelletization stages

    Final product types

    • Beverage bottles (carbonated soft drinks, water, juices)
    • Food-grade PET film and sheet
    • Microwaveable and ovenable packaging trays
    • Pharmaceutical-grade PET containers

    5. Pigment Production for Ceramics

    Ceramic pigment suppliers use Antimony (IV) Oxide as a key component in yellow pigment production, particularly in reaction with lead and tin oxides to yield Naples yellow and other antimony-based shades. The oxide enters calcination or solid-state reaction processes, driving high-temperature colorant formation under strictly controlled stoichiometric ratios. Producers calibrate firing conditions and composition to fine-tune shade, opacity, and lightfastness, with end-use targeting tiles, sanitaryware glazes, and high-decorative ceramics. Finished pigments undergo rigorous aging, abrasion resistance, and migration testing before approval for integration into bulk ceramic formulations.

    Industry compliance standards

    • ISO 10545-15 (Ceramic tiles – Release of hazardous substances, including antimony)
    • ASTM C773-88 (Standard Test Method for Compressive Strength of Pigmented Ceramic Tiles)
    • EN 12875-1 (Dishwasher resistance in ceramic tableware and glazes)
    • National/international heavy metal content regulations for decorative ceramics

    Typical usage ratio

    • 20% - 40% by weight of pigment batch (Naples yellow), with ratio variation based on targeted pigment phase and thermal processing window.

    Downstream process integration

    • Reacted via solid-state synthesis at 900°C - 1100°C with tin, lead, and other metal oxides
    • Blended during pigment formation prior to wet or dry milling
    • Incorporated into overglaze or underglaze ceramic formulations during mixing
    • Quality controlled via particle size, colorimetry, and acid resistance tests

    Final product types

    • Architectural ceramic tiles
    • Tableware glazes
    • Sanitaryware coatings
    • Decorative ceramic figurines
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    Certification & Compliance
    More Introduction

    Antimony (IV) Oxide: A Chemical Manufacturer’s Insight

    Our Story with Antimony (IV) Oxide

    Producing Antimony (IV) Oxide over years inside our facility gives a real sense of how chemistry crosses into daily industry needs. Years ago, when our first batches ran through the reactors, there was limited recognition of the kind of stability and control this product introduces into production lines. We watched how raw material selection, reaction atmosphere, and temperature control each shaped the quality of what left our finishing bays. If you line up Antimony (IV) Oxide beside its family members like Antimony (III) Oxide or other heavy metal oxides, differences show up beyond the basic white powder appearance. Here, valence state touches everything from color to reactivity and compatibility.

    Understanding the Product: Model and Specifications

    Batch after batch, Antimony (IV) Oxide comes out as a fine, pale powder with a consistency that almost reminds you of powdered chalk—just finer. Our standard output falls within a narrow purity window, tested by X-ray diffraction and ICP-OES for trace metals and main elements, so users in electronics or flame retardants don’t run into unexpected corrosion or compatibility issues. Grain size matters—ours averages under ten microns. This range brings maximum surface area but avoids the clumping that can slow down integration into polymers or ceramics. In our experience, lowering residual chloride and sulfate content takes repeated purification; we cut off every batch with moisture below 0.5%, knowing how hydrated oxides can throw reactions out of balance.

    One key detail—antimony in the oxidation state here stands at IV, not the more common III. This subtle difference changes not only its chemical reactions but influences how the finished material works in the end application. The ease of redox transitions in Antimony (IV) Oxide opens possible catalytic benefits that Antimony (III) simply doesn't provide as dependably. In-house, we see clear patterns: IV shows less tendency to degrade in oxidative or high-heat settings, making it more reliable for certain high-performance uses.

    Comparison: Not All Oxides Are Built the Same

    Watching customers test out different antimony oxides in their labs and then coming back with hands-on feedback, we’ve heard one recurring point. Antimony (IV) Oxide, compared with Antimony (III) Oxide, introduces a new layer of oxidation resistance. Those working with high-temperature glass or ceramic processes see better long-term performance—the IV oxide handles thermal cycling and repeated exposure to air without shifting color or composition. Where some oxides darken or break down, IV oxide stays stable. We’ve pulled samples from glass-melting experiments and, under microscope, the IV oxide-integrated sections show fewer cracks or discolored spots after multiple furnace runs.

    In flame retardancy, the story shifts a bit. Traditional Antimony (III) Oxide finds its place in synergistic mixes with halogenated compounds, producing antimony halides that douse flames by interrupting radical cycles. Our Antimony (IV) Oxide, though, leans toward applications where customers really worry about the corrosive side effects of halide release. Sometimes, shifting to IV makes a measurable difference—less equipment damage over time, and a cleaner product for downstream users in confined or high-purity settings.

    We hear frequent questions about toxicity and regulatory compliance. Antimony as a whole draws close monitoring, but Antimony (IV) Oxide’s more stable oxidation state stands out. Less volatile and less prone to reduce and leach under end-use conditions, it fits more comfortably within tight environmental limits. Our quality assurance process controls particle size not just for performance, but also to minimize inhalation or dispersion risks. We run bulk and dust density checks every shift, recalling how a single over-aerated drum once turned an entire shipping bay into a white cloud disaster—a lesson never repeated.

    Day-to-Day Applications: Real-World Feedback

    Over the years, we’ve watched Antimony (IV) Oxide get picked up by customers in wildly different industries. One group tested it as a dopant in specialty ceramics for electronics—capacitors, varistors, or spark gap arrestors. Their feedback echoed what our lab trials hinted: the IV oxide adds stability during repeated charge/discharge cycles. Where lower-level oxides broke down or shifted conductivity, ours maintained specs longer, leading to fewer rejected runs at their site.

    Another team, manufacturers of flame-retardant coatings for textiles, tried out the oxide to replace antimony salts that tended to bloom and discolor pale fabrics. By adjusting our drying and milling procedure, we doubled filter throughput, eliminating clogging which brought down their maintenance costs. They showed us fabric samples after accelerated weathering—the new formula kept original color, something they couldn’t pull off using other metal oxides.

    We’ve seen Antimony (IV) Oxide serve chemical synthesis as a catalyst, especially in oxidative coupling or selective oxidation of hydrocarbons. The oxide’s unique valence gives a more robust catalytic surface, resisting reduction much longer than Antimony (III) Oxide. In a few pilot projects with fine chemical suppliers, reaction rates and selectivity both ticked up, cutting batch times and increasing raw material yield. Here, the real advantage comes from the molecule’s ability to stay ‘active’ for longer seasons of production before needing reactor cleaning or catalyst replacement.

    Environmental and Safety Challenges in Manufacture

    Manufacturing Antimony (IV) Oxide is no walk-through. Handling the raw antimony metal requires rigorous operator training. Most of our processing lines run closed-loop scrubbers to trap any released antimony vapor or dust before exhaust leaves our plant. Our oldest employees still tell stories of plant upgrades after realizing dust migrates much farther than anyone thought. Now, all workers wear fitted filtration masks and a robust hygiene schedule cuts down on take-home contamination. Medical monitoring became non-negotiable after a single elevated blood antimony case turned into tighter community expectations.

    We learned quickly that wastewater can build up antimony levels, so we invested in ion-exchange polishing plants well ahead of regulatory deadlines. Now our discharge metrics land well below legal thresholds. In solid waste, spent filter cakes still contain some product value. Instead of sending these off-site, we created a reprocessing loop that burns off organic residues and returns antimony back to the oxidation cycle—a small win that paid off both in saved raw costs and landfill diversion.

    Transport has evolved, too. Our Antimony (IV) Oxide goes into sealed, double-lined bags. We switched from fiber drums to metal containers after moisture pick-up during a summer shipment nearly ruined an entire freight load. The smallest details—choice of liner, humidity during loading, even the route and truck ventilation—now get built into our shipping checklist. Clients downstream rely on every step to arrive predictable, so these fixes came out of real world mishaps and the drive to never repeat them.

    Working With End Users: Customization and New Demands

    Not all users need the same grade or form. Some want extra-fine powder for coatings, others ask for larger, granulated material to blend into plastics without dusting issues. Market trends push toward ever lower trace metal content—especially lead, arsenic, and mercury—so we respond with enhanced refining and continuous spectrometric checkpoints. A single out-of-spec drum used to trigger days of rework, delayed customer launches, and hard-earned market credibility losses. Over time, we set up real-time screening along the belt, stopping off-spec material before packing instead of sorting out mistakes after the fact. That improvement was more about dignity and pride in production than just margins.

    A few years back, a major electronics manufacturer visiting our site asked for Antimony (IV) Oxide within a certain median particle diameter, tighter than our current specification. Together, we adjusted hammer milling speed and classifier airflow until repeat runs consistently produced powder within their target. Their manufacturing yield rose, and that success story made it through their supply chain. It reminded us that technical demands keep shifting—so investment in flexible equipment and cross-trained operators translates into real market advantage, even if it takes months before the return shows up.

    Smaller customers from the research sector push us to provide precise documentation—full traceability batch by batch, certificates not only for antimony content but for every element above ppm ranges. Our analytics team expanded, and we started archiving every test result digitally for instant recall. Some researchers even ask to tour our line, observing each process step before signing off on a purchase. Their trust comes from seeing how we manage the chemistry day in and day out, not just from data on paper.

    Ongoing Innovation Driven by Regulations and Sustainability

    Regulatory pressure doesn’t let up. Antimony and its compounds show up on many government lists with limited threshold values in final goods. We keep up by monitoring global rules—European REACH, US EPA, Asian regional standards—so every tweak in a limit gets filtered down to manufacturing and QC. Some years, tighter thresholds mean buying newer testing instruments or tightening raw input acceptance. In other cases, we redesign our reactors or emissions capture. These choices add costs, but skipping them means excluded markets and lost long-term customers. The environmental sustainability push climbs every year, and buyers now ask about not just content but our carbon footprint, recycling practices, and energy consumption per ton of oxide produced.

    Recent upgrades include switching to renewable electricity in finishing lines and introducing cogeneration for process heat. On the waste side, we now work with utility partners to trial the use of spent antimony oxide as a binder in stabilized hazardous waste forms. Some experiments failed, but certain trials showed improved stability over traditionally used additives. Sharing these results, not hiding failed attempts, builds long-term trust with clients worried about waste stewardship.

    We also support downstream partners to identify safer or greener flame-retardant blends, testing Antimony (IV) Oxide in low-halogen plastics and rubber systems. Through these collaborations, we’ve found that the oxide provides flame resistance with less toxic fume evolution than similar antimony salts, opening up new options for consumer and building products looking for green labels without sacrificing fire safety.

    Market Outlook and Industry Trends

    The demand curve for Antimony (IV) Oxide has shifted. Old uses in fire retardants and glass pigmentation remain steady, but the riskiest applications gave way to those asking for purity and environmental reliability. Some ceramics producers now rely on our oxide for electrical stability in spark-resistant tiles and substrates. The electronics market keeps pushing toward ‘cleaner’ oxides, which keep semiconductors and capacitors running within narrow loss margins.

    Global antimony metal supply chains remain unpredictable; prices of raw input metals vary with mining output, geopolitical changes, and export quotas. We keep buffer stocks, source from reliable partners, and hedge supply risk through multi-year contracts. Those efforts mean users see fewer price spikes and shortages—a small advantage in a volatile field.

    Companies using antimony compounds now report up the chain, publishing material use for global brands or regulatory filings. Documentation, audit trails, and transparent sourcing matter more than before. Our guarantee on Antimony (IV) Oxide now involves site audits, process videos, and published environmental disclosures. Big customers want to link their ESG claims with supplier practices, and manufacturer transparency shapes our reputation as much as the powder’s technical merit.

    Challenges Moving Forward

    The industry faces questions about the long-term place of antimony-based flame retardants and additives. NGOs, consumer groups, and some regulators raise concerns about antimony leaching, exposure from end-use products, or the impact of mining on local communities. We collaborate with industry consortia to back research on the health and environmental fate of Antimony (IV) Oxide—encouraging peer-reviewed studies, not just internal tests.

    Both in our factory and our customers’ finished goods, risk management means tighter controls. Investments go into dust extraction, sealed transfer systems, spill response drills, and quarterly air monitoring. Inside our plant fences, we make a point of discussing risks openly with staff and local community groups, updating them on improvements and incident learnings. Their trust comes partly from our willingness to show what could go wrong, not just the ‘success story’ side.

    Attempts to find direct substitutes haven’t fully replaced Antimony (IV) Oxide yet. Several metal oxide alternatives underperform for flame retardancy or lack thermal tolerance in high-end electronics. The search continues—meanwhile, we focus on continuous incremental improvements: cleaner processing, safer handling, tighter quality, and measurable environmental leadership.

    Commitment Beyond the Sale

    Every drum of Antimony (IV) Oxide shipped carries more than product value—it represents the learning curve of factory staff, painstaking quality control, environmental investment, and a dialogue with every customer or inspector crossing our loading docks. Our goal means not just hitting a spec sheet, but adapting as users’ needs shift and new regulations set higher bars. We believe in sharing what goes right—and what sometimes goes wrong—so clients, regulators, and neighbors keep confidence both in us and the products that leave our gates.

    Now, as industries look for both fire safety and environmental responsibility, Antimony (IV) Oxide stands at an intersection: traditional utility joined with strict stewardship. We match material science progress with responsible action, so tomorrow’s users can trust what we build today.