|
HS Code |
401880 |
| Chemical Name | 9-Bromo-9-Phenylfluorene |
| Cas Number | 116123-37-2 |
| Molecular Formula | C19H13Br |
| Molecular Weight | 321.21 g/mol |
| Appearance | White to off-white crystalline powder |
| Melting Point | 132-135°C |
| Boiling Point | Unknown |
| Solubility | Slightly soluble in organic solvents (e.g. dichloromethane, chloroform) |
| Density | 1.41 g/cm³ |
| Purity | Typically ≥98% |
| Smiles | Brc1c2ccccc2c(c2ccccc2)c2ccccc12 |
| Inchi | InChI=1S/C19H13Br/c20-19(15-9-3-1-4-10-15)16-11-5-7-13-8-6-12-17(14-13)18(16)19/h1-14H |
| Storage Conditions | Store at 2-8°C, protect from light and moisture |
| Synonyms | 9-Bromo-9-phenyl-9H-fluorene |
As an accredited 9-Bromo-9-Phenylfluorene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Amber glass bottle, 25g; white label with chemical name, CAS number, hazard symbols, lot number, and manufacturer’s details. |
| Shipping | 9-Bromo-9-Phenylfluorene is shipped in tightly sealed containers, protected from light and moisture. It is classified as a hazardous chemical and is transported according to relevant regulations, typically by ground or air with appropriate labeling. Use of secondary containment and protective packaging ensures safety during transit, minimizing the risk of leaks or spills. |
| Storage | Store 9-Bromo-9-Phenylfluorene in a tightly sealed container, in a cool, dry, and well-ventilated area away from moisture and incompatible substances, such as strong oxidizers. Protect from light and keep away from heat sources. Label the container clearly, and ensure it is kept in a designated chemical storage cabinet suitable for organic compounds. Handle using appropriate personal protective equipment. |
Applications of 9-Bromo-9-Phenylfluorene in Industrial ManufacturingAs a specialty manufacturer of 9-Bromo-9-Phenylfluorene, we support customers in advanced material sectors by enabling specific synthesis routes for high-value functional products. Our technical team works closely with partners to optimize use of this intermediate in precise downstream applications, where quality and regulatory adherence are critical to end-use performance. 1. Organic Light Emitting Diode (OLED) Materials Synthesis9-Bromo-9-Phenylfluorene serves as a key halogenated building block for the synthesis of functionalized fluorene derivatives, which form the backbone of high-performance OLED emitter, host, and transport layers. It is commonly used in Suzuki–Miyaura cross-coupling and similar reactions to introduce phenyl and aryl functionalities. These downstream organic semiconducting materials demand ultra-high purity and precise control over molecular structure to meet the luminous efficiency and color purity required in advanced display fabrication. Industry compliance standards
Typical usage ratio
Downstream process integration
Final product types
2. High-Performance Polymer ManufacturingAs a reactive monomer for the preparation of polyfluorene-based polymers, 9-Bromo-9-Phenylfluorene introduces rigidity and improved charge carrier properties in specialty plastics. Its use enables downstream producers to tailor polymer properties critical for optical, mechanical, and thermal performance in demanding environments such as optoelectronic components and advanced optical films. Industry compliance standards
Typical usage ratio
Downstream process integration
Final product types
3. Pharmaceutical Intermediate SynthesisIn pharmaceutical R&D and manufacturing settings, downstream users employ 9-Bromo-9-Phenylfluorene to construct complex heterocyclic frameworks and rigid polycyclic scaffolds relevant for drug candidates with specific receptor binding profiles. The brominated fluorene enables controlled C–C bond formation while minimizing process impurities and downstream risk in active pharmaceutical ingredient (API) development. Industry compliance standards
Typical usage ratio
Downstream process integration
Final product types
4. Fine Chemical & Specialty Ligand ProductionThe aryl bromide functionality in this compound provides downstream fine chemical producers and catalyst developers with a platform to create biphenyl and phenyl-substituted ligands for use in homogeneous catalysis and organometallic complex formation. Its role extends to the preparation of tailor-made ligands and molecular scaffolds with unique steric environments, directly impacting catalytic activity and selectivity in custom synthesis applications. Industry compliance standards
Typical usage ratio
Downstream process integration
Final product types
5. Functional Dye and Pigment SynthesisSpecialty dye manufacturers utilize the high reactivity of 9-Bromo-9-Phenylfluorene to construct rigid aromatic systems for organic dyes and high-performance pigments, particularly those requiring enhanced photostability and tunable electronic absorption characteristics. Its integration improves color intensity and long-term stability, which are essential for niche printing inks and security materials. Industry compliance standards
Typical usage ratio
Downstream process integration
Final product types
|
Competitive 9-Bromo-9-Phenylfluorene prices that fit your budget—flexible terms and customized quotes for every order.
For samples, pricing, or more information, please call us at +8615371019725 or mail to admin@sinochem-nanjing.com.
We will respond to you as soon as possible.
Tel: +8615371019725
Email: admin@sinochem-nanjing.com
Flexible payment, competitive price, premium service - Inquire now!
Today’s research labs and production floors demand genuine reliability from every intermediate. At our facility, we produce 9-Bromo-9-Phenylfluorene not as a commodity, but with the insight of chemists who understand the day-to-day impact material quality has on downstream results. The structure itself, merging a bromo group at the 9-position with a phenyl substitution on the fluorene core, opens doors for chemists pursuing facets of organic synthesis, materials development, and tailored functional molecules. Each lot reflects decisions shaped by years of hands-on practice and ongoing dialogue with researchers aiming for reproducibility.
Model variants revolve around purity percentages and granular differences in residual content. We understand those variations mean the difference between promising results and a project grind. We routinely supply 9-Bromo-9-Phenylfluorene at levels of 98% and above, with tested trace metal and halide specifications posted transparently. Our model numbering system captures minor changes in synthesis or post-purification, because we know a subtle trace impurity can rewrite the next stage of anyone’s synthesis. More than a catalog line, each model reflects improvement cycles grounded in real feedback from those who use our chemical in cross-coupling, Suzuki reactions, or the construction of extended π-conjugated materials. Quality here is not a slogan: it stems from repeatable procedures, operator skill, and calibrated equipment—variables that only direct manufacturers tackle minute-by-minute.
Demand for this intermediate comes from several fronts. In small-molecule R&D, the bromo group offers strategic access to a variety of coupling strategies—especially Suzuki or Negishi reactions. Academic and industrial chemists lean on this compound to craft custom fluorene-based ligands, organic semiconductors, and dyes. Polymer chemists working in the OLED and photovoltaic space trust 9-Bromo-9-Phenylfluorene as the backbone for their next synthesis, because the electronically active structure enables the custom tailoring of bandgaps. Over the years, contract projects have required us to adjust particle size for consistency, because we handle both the bottle of a few grams and multi-kilogram drums. Whether you run your reaction in a 20 mL Schlenk or scale it to kilos, performance holds steady; only a manufacturer controls parameters like drying protocols, packaging conditions, and route-to-purity to meet these expectations.
The road to a clean 9-Bromo-9-Phenylfluorene starts with reliable bromination of 9-phenylfluorene. As a producer, we see daily the effect of temperature, reaction time, and solvent quality—insights that don’t show up in technical marketing sheets. By operating reactors ourselves, not outsourcing steps, we catch early signs of byproduct formation, halide contamination, or sub-par lot color. Only those monitoring each batch from raw material acceptance through final packaging see off-odors or crystal polymorphism first-hand. Labeling a product “high-purity” is not enough for us; reproducibility and a visually clean product come up in our internal acceptance panels before any material ships. Feedback loops run between our plant chemists and R&D partners; when a product variant runs out of spec, it does not reach the shelf. This approach—making what we supply—means that downtimes, solubility adjustments, and handling requirements shape our own practices before yours. It’s the ethos of hands-on chemistry and direct accountability that resonates throughout the supply chain.
Not all 9-Bromo-9-Phenylfluorenes behave alike. Chemists focusing only on CAS numbers or purity metrics can miss practical differences playing out at the bench. Our process tunes not just the percent purity but control over microcontaminants—like trace iron, lithium, or residual palladium—since organometallic coupling stages are sensitive to these. While one batch may record 99% GC purity, we see subtle variation in how it dissolves or filters. That’s why our QC goes beyond published minimums, tracking how such differences carry through to your final yield or product hue. We’ve watched researchers troubleshoot sluggish reactions only to find a less-obvious culprit—a slightly higher water content, a few more ppm of alkali metals, or crystalline habitus that clogs their filters. Our feedback system exists because our own chemists need reliable predictions, so we don’t ship off “good-enough” lots that would stall another lab’s progress.
As a direct manufacturer, we do not buy intermediates from third-party vendors or rebrand from bulk suppliers. Each drum starts with in-house raw materials chosen for their known reactivity, followed by seasoned handling on our site. Distributors or resellers rarely trace a product from synthesis to container. We document every stage, right down to the blowing of dry nitrogen into packaging lines. This detail matters in real work: years back, we adjusted drying temperatures after a customer noted slight clumping during transfer under low humidity. It had never appeared in larger trading house stock, but at scale, it skewed dosing in automated feed systems. These lessons only stick when a team stands behind every molecule, not just an invoice slip.
9-Bromo-9-Phenylfluorene offers high chemical stability, but like many aromatic bromides, it demands respectful handling. Open a new bottle; you’ll see crystalline solid, pale off-white, and a faint aromatic odor—clean presentation is our hallmark. Batches stay dry and flowable under inert gas, and we pack materials double-bagged to resist moisture. Carryover moisture not only shifts weight but kicks off hydrolysis if a flask sits with damp residues. Over the years, direct customer feedback led us to pioneer smaller pack sizes, tighter seals, and inclusion of moisture indicator cards for high-sensitivity users. We see chemists probe trace halides in their reactions; it’s why we prioritize extremely low residual halogen content, so your catalytic cycles stay alive and you avoid spending days troubleshooting unknown deactivations or sketchy HPLC baselines.
Commitment to quality grows from our work overseeing whole life cycles of products, not just buying finished stock for resale. Each order draws from our on-site inventory, with a lot history chart stretching back through raw materials and operator entries. We talk daily with colleagues solving issues with catalyst deactivation, oily residues in product, or unexpected melting points. Tight control over specifications is not a checkbox but the result of habit—rechecking every batch for trusted markers that users have told us to watch. Only a direct maker has the authority to fix a persistent variance at the root. If a laboratory flags a shift in product flow during charging, we document agitation routines and probe container design, updating our filling machines to reduce static clumping. Every lot update is rooted in improvement; we take pride in transparent communication, sharing what we’ve learned along the way. These choices mean our material moves straight from reactor to package, no stops at speculative warehouses, no mixing with suspicious similar items.
Lab choice often boils down to trust, but every chemist can check a few quick flags for themselves. Authentic, high-purity 9-Bromo-9-Phenylfluorene stays crisp in texture and clean in color. Residue along the bottle wall means excess water content or poor drying—each batch leaving our doors has a measured water analysis certificate included. Our users note the difference: in polar solvents, our product gives a rapid, direct dissolution profile. Off-branded or shelf-worn intermediates can yield flakes or uneven crystallization, slowing filtration or giving haze to product solution. We developed improved glass ampule sealing as a direct response to heavy-use clients in OLED manufacture, who tracked microscopic variances in end-product response. Years of observing failures—stubborn reaction rates, batch-to-batch color shifts—trace back to a compound’s subtle failings, which are avoidable with accountable production. The hands guiding each batch are our own classmates, not a faceless third party; ultimately, we ship only what we’d put on our workbench as the starting reference.
Polymerization, cross-coupling, directed synthesis of new π-conjugated segments: most requests for 9-Bromo-9-Phenylfluorene start from these points. In OLED R&D, the unique substitution pattern supports homogenous stacking and desired electronic configurations. For metal-catalyzed coupling reactions, the stability and reactivity of the aryl bromide site provide consistent performance, particularly as users demand fewer side-products and higher purity downstream. Dyes, sensors, and advanced organic materials emerge from these reactions, powering everything from next-generation electronics to custom ligands for academic breakthroughs. We can adapt material—finer mesh, specific packaging, tighter controls on residual metals—because feedback drives our next improvement. This exchange with hands-on users shapes every iteration, replacing generic responses with direct explanations and fixes. We supply result-driven material because the next paper, patent, or pilot batch stands on reproducibility and visible progress at the bench.
Some years ago, a research partner reported irregularities during a scale-up using what appeared to be standard 9-Bromo-9-Phenylfluorene. Our technical team traced the issue to an unusual impurity left from a rushed crystallization process by a third-party supplier. Instead of clocking wasted time to “user error,” we contacted the researchers, sent an improved lot, and re-examined our crystallization technique for signs of similar problems. When purity is managed by those with no production oversight, these fixes take weeks, and communication falls flat. As a direct producer, our hands never leave the process—from mixing and monitoring to the last vial placed in logistics. These lessons echo through improvements in both equipment and standard operating procedures, ensuring others avoid the same pitfall. Our trust earns its place batch by batch, built on honest admissions of challenge and open exchange when users flag unexpected hurdles. We apply these experiences to bolster each production and support continual innovation at the user end.
Pharmaceutical development, functional materials for display systems, and basic academic study all rely on intermediates crafted with more than regulatory compliance—ongoing improvements serve the broader chemical community. We take specific feedback and requests from research teams, often updating synthesis markers, packaging methods, or analytical standards. The result is a library of knowledge that feeds back into our own technical team, closing the loop from factory floor to research publication. As more sectors adopt organic electronics and smart materials, 9-Bromo-9-Phenylfluorene stands out in its flexibility to serve as a robust precursor or building block. Our deep experience handling the full process gives us a vantage point unavailable to traders or redistributors: we share best practices for every step, from storage to precise addition, and follow through on next steps and project updates. This ecosystem of real improvement supports the users driving innovation—from pilot plants to graduate bench work.
Over decades, chemical synthesis and materials science have moved in cycles—each new technology demanding adaptations in supply and process. We see each trend ripple through orders and adapt material processing accordingly. Whether a customer needs 9-Bromo-9-Phenylfluorene for a fledgling OLED, a specialized ligand, or new photoactive polymers, we answer with a conversation, not a generic form letter. Our support staff handle recurring questions about filtration, sensitivity, packing, and upstream consequences of trace contaminants, and we update our SOPs based on this exchange. Improvements come not as mandates from anonymous standards departments but as responses to the lived reality of users. If a new class of cross-coupling catalysts emerges needing a tighter metals spec, we develop internal analytical protocols without delay. Our culture roots in those background exchanges shaping the direction of each production run, whether it means higher throughput, smaller batches with more targeted purity specs, or faster QC feedback loops to researchers in the field.
Reliability starts on the plant floor, where direct control over every reagent, filter, and vessel ensures the 9-Bromo-9-Phenylfluorene that reaches your bench performs without unexpected compromise. Our production is not faceless; each decision stems from conversation, observation, and decades spent in labs ourselves. Variants spring from real need, not marketer’s fantasies, and understanding user outcomes fuels each round of improvement. Whether your application is academic or industrial, reproducibility, traceability, and adaptable service signal the difference between us and repackagers. Transparency, quick feedback, and an open attitude set the bar. The result is a product you know and can trust, batch after batch, for synthetic consistency and dependable progress in the evolving world of advanced organic synthesis and material science.