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9,9-Bis(4-Hydroxyphenyl)Fluorene

    • Product Name 9,9-Bis(4-Hydroxyphenyl)Fluorene
    • Alias BHPF
    • Einecs 221-967-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    229066

    Chemicalname 9,9-Bis(4-Hydroxyphenyl)Fluorene
    Casnumber 3236-71-3
    Molecularformula C25H18O2
    Molecularweight 350.41 g/mol
    Appearance White to off-white powder
    Meltingpoint 229-233°C
    Solubility Insoluble in water; soluble in organic solvents
    Purity >98%
    Density 1.29 g/cm³
    Synonyms Bisphenol F fluorene; 9,9-bis(4-hydroxyphenyl)fluorene
    Structure Fluorene core with two 4-hydroxyphenyl groups at 9-position
    Smiles C1(C2=CC=CC=C2C3=CC=CC=C31)(C4=CC=C(C=C4)O)C5=CC=C(C=C5)O
    Inchikey AFNQZHHCUHCUJV-UHFFFAOYSA-N

    As an accredited 9,9-Bis(4-Hydroxyphenyl)Fluorene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 25g bottle of 9,9-Bis(4-Hydroxyphenyl)fluorene is sealed in an amber glass container with a secure screw cap, labeled clearly.
    Shipping 9,9-Bis(4-Hydroxyphenyl)fluorene is shipped in tightly sealed containers, protected from light and moisture. It should be handled as a chemical substance, with labeling in accordance with relevant transport regulations. Typically, shipments are classified as non-hazardous, but safety data sheets accompany all packages to ensure safe handling and compliance during transit.
    Storage Store **9,9-Bis(4-Hydroxyphenyl)fluorene** in a cool, dry, and well-ventilated area, away from direct sunlight and sources of ignition. Keep the container tightly closed and properly labeled. Avoid exposure to moisture and incompatible substances such as strong oxidizing agents. Use appropriate personal protective equipment when handling and ensure storage in accordance with local regulations and chemical safety guidelines.
    Application of 9,9-Bis(4-Hydroxyphenyl)Fluorene

    Applications of 9,9-Bis(4-Hydroxyphenyl)Fluorene in Industrial Manufacturing

    9,9-Bis(4-Hydroxyphenyl)Fluorene is a specialty bifunctional monomer prized in advanced polymer synthesis, enabling the production of high-performance and specialty plastics for demanding technology sectors. Our manufacturing integrates rigorous quality systems to support industrial customers in their formulation and process design, delivering purity and batch consistency that meet critical downstream requirements. Below, we detail its established application segments, technical formulation practice, and relevant finished product types driven by real-world industrial demand.

    1. Polycarbonate and Copolycarbonate Resins for Optical Data Storage

    Manufacturers value this monomer as a key component for producing high-glass transition temperature (Tg) polycarbonate materials, especially for optical-grade discs. It enables fabrication of resins featuring improved dimensional stability, high clarity, and superior hydrolytic stability, addressing the stringent performance needs of Blu-ray and DVD substrates as well as advanced data storage products that require long-term retention integrity.

    Industry compliance standards

    • ISO 10993-5 (biocompatibility standards for optical use)
    • IEC 60950-1 (safety requirements for IT equipment)
    • RoHS 2011/65/EU (Restriction of Hazardous Substances Directive in electronic components)
    • QC protocols for optical-grade base materials (media industry specifications)

    Typical usage ratio

    • 3–8% by mass as a co-monomer in phosgene or melt polycondensation, adjusted for balance between flow performance and heat resistance based on disc geometry and end-use longevity.

    Downstream process integration

    • Incorporation during co-monomer charge alongside bisphenol A and diphenyl carbonate or phosgene; controlled feeding into the reactor before chain-termination, followed by precision molding or extrusion to manufacture optical disc substrates.

    Final product types

    • Blu-ray discs
    • DVD substrates
    • Archival optical storage media
    • High-transparency data disks for professional recording

    2. High-Performance Polyetherketone and Polyethersulfone Engineering Plastics

    As a high-purity diol, 9,9-Bis(4-Hydroxyphenyl)Fluorene functions as a comonomer in nucleophilic aromatic substitution polymerizations to generate engineering thermoplastics with increased thermal resistance and superior dielectric properties. Downstream manufacturers employ these specialty resins in the electrical and aerospace sectors, where material reliability under thermal cycling and electrical field exposure is paramount.

    Industry compliance standards

    • UL 94 V-0 (flammability rating for plastics)
    • EN45545-2 (fire protection on railway vehicles)
    • ASTM D5207 (polyetherketone electrical testing methods)
    • IEC 60216 (thermal endurance for insulating materials)

    Typical usage ratio

    • 5–15 mol% as a partial bisphenol replacement, optimized according to targeted dielectric strength and Vicat softening point for advanced applications.

    Downstream process integration

    • Feeding into a stirred or continuous-flow reactor during polycondensation with aromatic dihalide monomers; polymer forms are then granulated and optionally stabilized before compounding and injection molding.

    Final product types

    • High-frequency circuit insulators
    • Connector housings for aerospace
    • Automotive sensor housings
    • Thermally stable fiber reinforcements

    3. Specialty Liquid Crystal Polymer (LCP) Synthesis for Display Components

    In the LCP field, the rigid fluorene structure provides exceptional planarity and enhances the thermal and oxidative stability of the polymers. Downstream industries use these materials to achieve ultra-thin, highly oriented films essential for high-resolution display technologies and flexible circuit substrates, satisfying advanced requirements for image definition and device miniaturization.

    Industry compliance standards

    • IEC 61249-2-21 (halogen-free requirements for electronic materials)
    • JEITA ET-7306 (Japanese industrial standards for display and film applications)
    • RoHS 2015/863/EU (updated restrictions on hazardous substances)
    • ISO 14616 (flexible film testing protocols)

    Typical usage ratio

    • 2–12 mol% in aromatic polyester LCP matrices, calibrated according to optical anisotropy and mechanical stretching targets for film processing.

    Downstream process integration

    • Copolymerization with hydroquinone or other diols via melt polymerization, followed by high-shear extrusion and orientation via casting or biaxial stretching under controlled temperature profiles.

    Final product types

    • LCP films for liquid crystal displays (LCDs, OLEDs)
    • Flexible printed circuit substrates
    • Microelectronic encapsulation membranes
    • Thin films for polarizers and reflector layers

    4. OLED and Advanced Photonic Polymer Materials

    Electronic device manufacturers incorporate this compound as a hole-transport unit or backbone modifier in the development of conjugated polymers, where chemical stability at elevated voltage and resistance to photodegradation drive the reliability of organic electronics. These uses directly support the commercial production of high-brightness OLED displays and lighting panels.

    Industry compliance standards

    • IEC 62341-5-1 (OLED display panel safety standards)
    • ANSI C78.377 (chromaticity standards for solid-state lighting)
    • RoHS 2011/65/EU (electronic hazard substance regulation)
    • IEC 62471 (photobiological safety evaluation)

    Typical usage ratio

    • 0.5–6 mol% within functional copolymers, precisely tailored per layer to balance quantum yield, hole-transport, and processing viscosity for thin film deposition.

    Downstream process integration

    • Solution co-polymerization with triarylamine or fluorene-based units, followed by purification and slot-die coating or spin coating onto ITO glass or flexible plastic substrates under cleanroom conditions.

    Final product types

    • OLED display panels for TVs and mobile devices
    • Organic lighting modules
    • High-efficiency organic photodiodes
    • Functional polymer layers in photonic ICs

    5. High-Purity Epoxy Resin Modifiers for Semiconductor Packaging

    Advanced semiconductor manufacturers leverage this building block as a molecular modifier in specialty epoxy formulations, targeting increased Tg and minimized dielectric loss for high-density electronic packaging. These modified epoxies deliver the reliability and warpage control necessary for contemporary microchip encapsulation and underfill techniques in device fabrication lines compliant with the latest international standards.

    Industry compliance standards

    • JEDEC JESD22 (device quality and reliability test methods)
    • IPC-4101B (specifications for base materials for printed boards)
    • IEC 60194 (PCB manufacturing standards)
    • IATF 16949 (automotive electronics quality system)

    Typical usage ratio

    • 1–5 wt% as a co-monomer in diglycidyl ether epoxy blends, adjusted to achieve target dielectric constant and cure profile as specified by end-user device qualification.

    Downstream process integration

    • Blending into epoxy resin base prior to hardener addition, then reacting under controlled temperature and vacuum; molded or dispensed into chip packages, PCB laminates, or underfill cavities.

    Final product types

    • Chip-scale semiconductor packages
    • IC encapsulation compounds
    • PCB laminating pre-pregs
    • Electronic underfill and adhesive solutions
    Free Quote

    Competitive 9,9-Bis(4-Hydroxyphenyl)Fluorene prices that fit your budget—flexible terms and customized quotes for every order.

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    Certification & Compliance
    More Introduction

    9,9-Bis(4-Hydroxyphenyl)Fluorene: Experience-Driven Excellence in Specialty Fluorene Compounds

    A Veteran Manufacturer’s Perspective

    Years on the production floor bring a certain perspective to specialty chemicals. Every batch of 9,9-Bis(4-Hydroxyphenyl)Fluorene we manufacture tells a story—one of material science refinement and the real demands our customers face in polymer and specialty resin applications. Over time, trends come and go, but the core requirements set by industry leaders endure: purity, stability, and predictable performance in the final product.

    Understanding What 9,9-Bis(4-Hydroxyphenyl)Fluorene Offers

    9,9-Bis(4-Hydroxyphenyl)Fluorene, often abbreviated as BHPF, carries the CAS number 3236-71-3. Chemically, it belongs to the family of bisphenols, yet reveals pronounced advantages compared to conventional bisphenol-based building blocks like Bisphenol A (BPA) or Bisphenol S (BPS) because of its rigid fluorene backbone. We see this structure as the catalyst behind BHPF’s thermal and oxidative endurance. High glass transition temperatures, exceptional transparency, and robust dimensional integrity arise from deliberate molecular engineering—benefits we have observed our customers rely on where lesser compounds falter.

    In practice, our facilities consistently meet industry benchmarks for moisture content, color, and assay. We track these parameters not just to satisfy paperwork, but to make sure our material consistently molds, mixes, and reacts as it should in downstream operations. When resin manufacturers run thousands of kilograms per month, a supplier’s inconsistency becomes everyone’s problem. So we drive out out-of-spec batches and eradicate any deviation—maintaining lot-to-lot performance so processors avoid unnecessary downtime.

    Specifications Backed by Manufacturing Experience

    Most customers rely on our BHPF in white, free-flowing crystalline powder form. We’ve honed our process to keep the color index low, typically keeping APHA or Hazen values under 20. Moisture checks out below 0.10%—anything higher spells trouble for high-temperature processing. By maintaining an assay above 99.0%, our team ensures that your end products, from specialty polycarbonates to engineered resins, hit physical property targets on spec sheet and in the real world alike.

    Year after year, requests for finer grind or tailored particle sizing remain rare. Most processors prefer the ease of handling that comes standard from our reactors. That said, our process allows for adjustments; large volume users occasionally order custom sieved fractions, and we have honed this side of operations for those needing seamless integration into their continuous compounding systems.

    What Sets BHPF Apart From Established Bisphenols

    On the surface, bisphenols all seem to fill a similar niche: forming the backbone in synthesis of high-performance plastics and resins. From our daily work, the differences become apparent closest to the machine—during reaction, curing, and even in final use cases. BHPF distinguishes itself through the rigid, fused ring fluorene core that outperforms BPA in resisting heat and oxidation. Parts made from BHPF-based resins hold clarity and shape where others yellow, warp, or crack.

    In our experience, end-users in optoelectronics and specialty display applications report a crucial drop in birefringence and color shift, attributes traceable to BHPF. For high-tech laminates requiring near-zero haze, this material provides a reliability that puts conventional bisphenols in the shade. Processors pushing the limits on thin-walled components or thermal stability keep coming back to this compound after lesser alternatives result in unacceptable rejection rates. Our warranty claims over the years for BHPF-based products remain virtually non-existent, a testament to the material’s resilience.

    Diverse Applications Backed by Daily Practice

    Every kilo of 9,9-Bis(4-Hydroxyphenyl)Fluorene shipped from our site typically supports high-value manufacturing, not bulk commodity goods. This material serves as a cornerstone in synthesizing specialty polycarbonate resins, often chosen for its ability to impart thermal, dimensional, and optical properties simply unattainable with more common bisphenol monomers.

    Some clients push for performance films or substrates in the electronics sector. Others utilize BHPF in specialty coatings where high temperature, clarity, and mechanical resilience must coexist. In particular, the stability of the fluorene structure proves essential in LED encapsulants, OLED displays, and various optical elements needing strength without clouding. From years spent supporting these fields, we know small differences in monomer selection escalate into massive gains—or losses—in yield, aging, and defect rates further down the line.

    Market pressures to eliminate BPA or certain halogenated compounds continue to mount. During process audits, we see BHPF step into roles previously reserved for riskier, less stable ingredients. Not every plant can run BPA-free without significant retooling, but incorporating BHPF has minimized those headaches for more than a few of our partners, whether they’re expanding into medical polymers or seeking certification for food contact applications.

    Reliability Across Scale: Batch Control and Traceability

    Fluctuations in feedstock purity or subtle process drift can undermine whole production runs in sensitive downstream operations. Over decades in chemical manufacturing, we’ve built our approach on tight process control. We oversee every aspect, from sourcing starting materials to reaction temperature regimes, drying curves, and controlled cooling. Our lab staff tracks every analytical checkpoint, from melting point validation to Karl Fischer moisture verification, and burn-in tests for oxidative durability.

    Lot traceability plays a critical role for our customers facing regulatory audits or high-liability end uses. Data archiving, process analytics, and physical retention of sample vials allow us to verify product history years down the road. Customers tapping into new geographic or regulatory markets frequently leverage our detailed batch data as proof of compliance. Our staff often walks clients through these documents—even arranging on-site audits for major volume buyers who want to inspect our protocols firsthand.

    Responding to Industry Shifts and Environmental Demands

    We’ve seen evolving legislation and stricter environmental requirements reshape how end-users select their raw materials. As scrutiny around BPA and similar legacy compounds intensifies, our facility noted a marked increase in queries about BHPF. Clients hope to meet new standards without sacrificing performance, and material designers prefer compounds with established track records both in safety assessments and processability.

    From a manufacturing standpoint, minimizing process waste and maximizing yield keeps costs manageable while meeting sustainability objectives. Over recent years, we’ve refined our recovery protocols for solvents and byproducts—combining incremental upgrades with employee training to prevent off-spec outputs. Keeping heavy-metal contaminants and residual organics well below international safety thresholds has become muscle memory for our team.

    Though no bisphenol offers a perfect solution for every regulatory framework around the globe, our experience indicates BHPF clears most common safety and performance hurdles in advanced material applications. We stay engaged with industry bodies and regulatory agencies, adapting documentation, validating through external labs, or supporting independent toxicological reviews where needed.

    Supporting Innovation with Practical Partnership

    We rarely meet customers who want “just another chemical.” Most are engaged in projects that demand reliability from their supply chain. BHPF’s strong performance profile lends itself to rapid prototyping, pilot-scale innovation, and large-volume rollout without the guesswork that comes with less understood specialty monomers. The fluency our technical staff builds working alongside R&D partners has proven every bit as important as the material in the bag. Whether optimizing reaction conditions or troubleshooting process upsets, we offer direct, on-site support as routine service for our largest-volume accounts.

    Over the years, our in-house experts have worked with teams developing flame-retardant resins for high-speed connectors, engineers seeking clarity for advanced optical films, and teams struggling with yellowing or warping in legacy blends. Drawing on plant-level experience, our chemists have set up custom pilot lots, suggested modified curing strategies, or provided analytical troubleshooting—all on the back of BHPF’s well-documented stability and handling profile.

    Long-Term Viability and Market Commitment

    Specialty raw materials face shifting supply chains, geopolitical uncertainties, and technology turnover. Direct manufacturing engagement makes a difference; traders or resellers can’t pivot production quickly or troubleshoot with direct process insight. Our long-standing investment in production infrastructure lets us turn around urgent orders quickly and adapt in response to customer growth or unforeseen supply chain interruptions.

    Our logistics staff coordinates seamless containerization and drum filling, keeping dust and moisture ingress away from the main product before it even leaves the loading bay. Over decades, repeat orders from blue-chip industrials and nimble market entrants have shaped our packaging, labeling, and documentary practices. Few things matter more to us than a production manager’s report of fault-free compounding or a new client’s successful scale-up using our latest batch.

    Since the early days, we have continuously updated our process automation, recipe fidelity, and post-reaction containment practices—never taking stability or compliance for granted. Each new region we supply brings new documentation requirements, which we see as an opportunity to sharpen our quality management rather than a paperwork burden.

    BHPF’s Role in the Next Generation of Engineered Materials

    Advanced electronics, displays, and structural materials demand monomers that can stand up to physical and thermal stresses for decades. Our experience shows that BHPF, when incorporated into next-generation polycarbonates and polyester-imide resins, consistently boosts dimensional stability without introducing optical distortion or mechanical brittleness. Customers pressing for lightweight, transparent, high-strength polymers in automotive, aerospace, and precision optics have anchored years of product lines on this compound.

    With sustainability pressures, BHPF offers advantages beyond simple regulatory avoidance. Our own life-cycle reviews support lower long-term process waste when compared to some legacy aromatic compounds, especially in continuous reactor operations running at scale. Our research partners continue to examine blends and copolymers involving BHPF to achieve even longer service life under challenging conditions—an endeavor we support with custom product grades for researchers and industrialists alike.

    Continuous Excellence Rooted in Direct Production Experience

    Plenty of suppliers offer chemicals—few bring the hands-on, plant-floor experience that comes from decades spent refining their process and supporting industry partners under real-world pressure. Every ton of 9,9-Bis(4-Hydroxyphenyl)Fluorene that leaves our facility carries behind it not just a specification, but the lived knowledge gained working side-by-side with materials scientists, plant operators, and quality control experts. Decisions about lot release, formulation adjustments, and analytic review are grounded in daily feedback from those who depend on the material for their business’s success.

    Whether it’s developing the next breakthrough polycarbonate blend, qualifying a transparent substrate for an aerospace program, or simply meeting ever-changing regulatory hurdles, BHPF serves as our contribution to real progress in materials engineering. Our legacy comes not from catalog listings but from the loyalty of long-term customers who put new ideas into practice using our materials, confident in every drum and every shipment.

    Staying Ahead in a Changing Industry

    Decades of navigating the ups and downs of the chemical markets have taught our operation that the ability to adapt outpaces even the most meticulous planning. From aligning with new electronic industry standards, to pivoting processes for emerging medical polymer requirements, our plant has grown in parallel with the world’s shifting priorities. We remain committed to the ongoing investment in plant capabilities, staff development, and environmental improvements needed to keep 9,9-Bis(4-Hydroxyphenyl)Fluorene a trusted pillar in your innovation toolkit.

    In every discussion with our partners, the message remains the same: we produce BHPF not as a commodity, but as a foundation for real advancements in specialty materials. That focus drives our continuous process improvement, our willingness to support custom analytical protocols, and our readiness to partner on your most demanding production challenges—today, tomorrow, and for years to come.