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5-Methyl-1-Hexene

    • Product Name 5-Methyl-1-Hexene
    • Alias 5-Methylhex-1-ene
    • Einecs 211-234-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    888184

    Chemicalname 5-Methyl-1-Hexene
    Casnumber 763-29-1
    Molecularformula C7H14
    Molecularweight 98.19 g/mol
    Appearance Colorless liquid
    Boilingpoint 94-96 °C
    Density 0.707 g/mL at 25 °C
    Refractiveindex 1.409-1.411 at 20 °C
    Flashpoint -6 °C
    Solubilityinwater Insoluble
    Vaporpressure 84 mmHg (20 °C)
    Smiles CC(C)CCC=C
    Pubchemcid 12242

    As an accredited 5-Methyl-1-Hexene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 5-Methyl-1-Hexene is packaged in a 100 mL amber glass bottle, sealed with a screw cap, and labeled with hazard information.
    Shipping 5-Methyl-1-Hexene is shipped in tightly sealed containers, typically made of glass or compatible plastic, to prevent leaks and contamination. It should be transported under well-ventilated conditions, away from heat, open flames, and oxidizers. Appropriate labeling and adherence to hazardous materials regulations are required during handling and shipping.
    Storage 5-Methyl-1-hexene should be stored in a cool, well-ventilated area away from sources of ignition, heat, and direct sunlight. Keep the container tightly closed and protected from moisture. Store away from oxidizing agents and acids. Use with adequate ventilation and avoid breathing vapors. Store in a flammable liquid storage cabinet if possible, and keep container properly labeled at all times.
    Application of 5-Methyl-1-Hexene

    Applications of 5-Methyl-1-Hexene in Industrial Manufacturing

    5-Methyl-1-Hexene serves as a key specialty alkene in the synthesis of high-value chemicals and advanced polymer building blocks. As a direct manufacturer, we supply this material to several core industrial sectors where controlled reactivity, purity, and consistent batch quality are critical to end-product value. Below are the major application scenarios supported by detailed compliance, usage, process, and end-use insights.

    1. Polyolefin Co-Monomer Production

    Polyolefin manufacturers utilize 5-Methyl-1-Hexene as a co-monomer during the polymerization of specialty low and linear low-density polyethylenes (LDPE, LLDPE) for tuning mechanical properties such as flexibility, clarity, and stress cracking resistance. Its precise incorporation into the polymer matrix tailors material attributes to customer specification. Accurate dosing and continuous-feeding equipment manage the input stream, strictly controlled by in-line analysis.

    Industry compliance standards

    • ISO 19069-1:2015 (Polyolefins—PE for extrusion and molding)
    • ASTM D1238 (Melt flow rate test for thermoplastics)
    • REACH Annex XVII restrictions for use in polymer applications
    • Food Contact Notification (FCN) guidelines where applicable

    Typical usage ratio

    • Generally 0.5–3.0% by mole, adjusted to polymer density and comonomer reactivity ratio; final target defined by the desired mechanical profile of the end resin batch.

    Downstream process integration

    • Metered into high-pressure or gas-phase polymerization reactors in conjunction with ethylene/propylene feed, often via dedicated co-monomer dosing subsystems compatible with catalyst loading controls.

    Final product types

    • Specialty LLDPE films
    • Modified LDPE for wire/cable insulation
    • Flexible packaging resins
    • Injection-molded housewares

    2. Synthesis of Alkylated Aromatic Additives

    In lubricant and fuel additive manufacturing, formulators employ 5-Methyl-1-Hexene in Friedel–Crafts alkylation reactions to introduce branched alkyl chains onto aromatic bases. This modification increases solubility and pour-point depression in finished lubricant additives. Custom alkylation reactors and post-reaction purification ensure low residual unreacted olefin content as required by performance certificate protocols.

    Industry compliance standards

    • API SN/ILSAC GF-6 (Engine oil performance specs)
    • ASTM D4485 (Engine oil standards)
    • ISO 9001:2015 for additive production traceability
    • OECD chemical safety guidelines

    Typical usage ratio

    • Commonly 5–15% by weight in aromatic alkylation charge depending on chain length specification, optimized for cold flow improvement and oxidative durability.

    Downstream process integration

    • Loads directly into the alkylation reactor with aromatic base, catalyst selected depending on downstream compatibility (e.g., AlCl3 or zeolites), followed by distillation to separate alkylate product.

    Final product types

    • Pour point depressants for lubricating oils
    • Detergent additive intermediates
    • Fuel system cleaners
    • Industrial oil modifiers

    3. Pharmaceutical Intermediate Synthesis

    5-Methyl-1-Hexene provides a functionalized alkene raw material for the synthesis of branched intermediates essential to API production. Its use in transition metal-catalyzed hydroformylation or epoxidation can introduce branching specificity not achievable with linear alkenes. All processes run under strict GMP conditions with validated traceability.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice for Active Pharmaceutical Ingredients
    • USP/NF and EP monograph requirements for starting materials
    • 21 CFR Part 210/211 (FDA GMP regulations)
    • EMEA 3AQ7a Quality guideline

    Typical usage ratio

    • Generally 1.0–8.0% molar equivalent relative to pharmaceutical precursor conversion pathway; confirmed by batch-to-batch yield and impurity control trials.

    Downstream process integration

    • Fed into hydroformylation, epoxidation, or cross-coupling reactors as terminal alkene precursor, followed by multi-stage purification, monitored by in-process HPLC and GC analysis.

    Final product types

    • Active pharmaceutical intermediate compounds
    • Steroid alkyl side chains
    • Specialty pharma solvent building blocks
    • Research-scale fine chemicals

    4. Functional Silicone Modifier Synthesis

    Silicone resin and elastomer producers use 5-Methyl-1-Hexene in controlled hydrosilylation reactions to introduce alkyl side groups onto siloxane polymers. This improves flexibility, surface hydrophobicity, and processability of finished silicones. Purity and batch homogeneity must meet tight optical and mechanical tolerances demanded in electronics encapsulation and construction sealants.

    Industry compliance standards

    • ISO 9001:2015 for manufacturing traceability
    • ISO 14001:2015 for environmental controls
    • UL 94 (Flammability for silicone-based materials)
    • RoHS Directive for electronics applications

    Typical usage ratio

    • Typically 0.2–2.5% by total siloxane polymer mass; actual charge ratio set by required functionalization degree and catalyst activity profile.

    Downstream process integration

    • Introduced as a neat or dissolved alkene into the hydrosilylation reactor alongside poly(methylhydrosiloxane) and platinum catalyst, with online IR to monitor functional group uptake.

    Final product types

    • Modified silicone elastomers for automotive gaskets
    • Water-repellent architectural sealants
    • Flexible electronics encapsulants
    • Silicone-based adhesives with enhanced slip

    5. Flavors and Fragrance Chemical Manufacturing

    Producers in the flavors and fragrance sector apply 5-Methyl-1-Hexene in tailored alkylation and oxidation schemes to create complex, branched aroma molecules. Its use must comply with purity limits for potential sensory impurities and regulatory allergen control at each process step, especially during scale-up to food-grade specifications.

    Industry compliance standards

    • IFRA Standards and Codes of Practice
    • ISO 9235 (Natural flavouring substances definition but used for classification in synthetic manufacturing)
    • EU Regulation (EC) No 1334/2008 on flavorings
    • US FDA 21 CFR 172.515 (Synthetic flavoring substances and adjuvants)

    Typical usage ratio

    • Typically 2–7% by total mass of the reaction substrate; alteration subject to olfactory performance tests and regulatory content specifications in the EU and US markets.

    Downstream process integration

    • Enters alkylation/oxidation reactors for synthesis of branched aliphatic alcohols or aldehydes, followed by vacuum distillation and GC-olfactometry screening.

    Final product types

    • Branched aliphatic aldehydes for perfumery bases
    • Specialty flavoring esters
    • Aroma chemical intermediates for household and cosmetic fragrance blends
    • Process aids for natural product analogs
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    Certification & Compliance
    More Introduction

    5-Methyl-1-Hexene: A Closer Look from the Manufacturer’s Bench

    At our plant, chemistry is not only about equations; it is about turning years of experience into practical solutions for industry. 5-Methyl-1-Hexene still surprises people with how many things you can achieve with such a straightforward molecule. Produced consistently in our reactors, this compound stands out in the alkenes family. Its chemical structure—a six-carbon backbone with a methyl group on the fifth carbon and a double bond at the end—gives it distinct properties that place it into a unique, valuable spot. We have worked through every detail, from raw material sourcing to finished packaging, so we know exactly what goes into every shipment we send out.

    What 5-Methyl-1-Hexene Means for Downstream Manufacturing

    We see 5-Methyl-1-Hexene as more than just a feedstock, but as a pivotal player in upgrading chemical processes where a clean, reactive alkene is called for. Its main draw comes from that terminal double bond. Over the last decade, more and more customers have turned to us for alkenes that deliver consistent reactivity. Unlike internal alkenes, which sometimes behave unpredictably, the terminal double bond in 5-Methyl-1-Hexene reacts smoothly and predictably. This trait helps polymer engineers, specialty chemicals producers, and additive formulators cut down on side reactions and purification headaches.

    From our own floor, we know purity is a constant battle. Even a tiny off-spec fraction in the final distillation can translate into catalyst poison further down the line. We’ve refined both the synthesis and purification so that our standard purity levels for 5-Methyl-1-Hexene regularly exceed 98%. Years ago, hitting 99% would take enormous effort; now it’s routine thanks to better columns, better controls, and vigilance from our quality staff. That translates to fewer surprises for customers, which matters when even a small impurity can compromise an entire batch of specialty product.

    Why Choose 5-Methyl-1-Hexene?

    There’s a simple reason most of our clients stick with 5-Methyl-1-Hexene rather than reaching for similar molecules: it does exactly what it’s supposed to do. You get a molecule that doesn’t suffer from hindered reactivity or produce unpredictable side reactions. Some alternative alkenes have internal double bonds, which sound good on paper but behave erratically under real-world reaction conditions. We’ve encountered more than a few pilot customers trying to swap in less expensive feedstocks, only to circle back after discovering that product consistency suffered. In high-value polymer research, consistency beats cost cutting.

    We have extensive firsthand feedback from polymer chemists, especially those working in the adhesives sector. They turn to 5-Methyl-1-Hexene for grafting, which demands tight control over side chain length and placement. The methyl substitution presents unique opportunities: it allows the formation of branched polymers with predictable performance. That branching is tough to copy with straight-chain hexenes or pentenes. Over time, blends built from 5-Methyl-1-Hexene demonstrate better flexibility and lower crystallinity, which is crucial in hot-melt technology. Compare that to conventional 1-hexene, and the material properties are just not the same—either in processing or the final adhesive performance on customer assembly lines.

    Our Experience with Sourcing and Scalability

    One thing that doesn’t always get discussed in brochures is the practical reality of sourcing raw materials at steady quality. We’ve navigated periods where access to top-grade starting materials nearly shut down our reactor trains, so we learned to build redundancy into our supply. The starting alcohols and branching agents needed to build 5-Methyl-1-Hexene are notoriously touchy—one batch with slightly higher water content or oxygen levels, and everything gets redirected to waste management. Our team constantly audits supply partners, not just on price, but on consistency of what comes in by the drum. We’d rather halt a run than risk introducing a contaminant that our customers might find months later.

    Over the years, we invested in process improvements like closed-loop nitrogen blanketing and real-time monitoring for oxygen ingress during distillation. Experience taught us that it’s not just purity that matters; the batch-to-batch consistency allows customers to scale their processes without worrying about tweaks every time their shipment arrives. We know a kilo for early-stage R&D won’t behave the same as a full tanker destined for commercial manufacture unless every step along the way is reliable and repeatable. It is easier to promise this quality when you’ve hammered out the bugs yourself rather than leaving it to chance or a third-party trader who barely sees the inside of a plant.

    Specifications Shaped by the Realities of Production

    Every chemical producer knows that a product spec sheet tells only half the story. On the ground, we watched what small shifts in water content, oxygen scavengers, or reactor temperature did to both yield and final product purity. Over countless campaign runs, we optimized for a boiling point range that reliably excludes side products and other hexene isomers. Today, we fix our maximum water content by Karl Fischer at under 100 ppm. Peroxide numbers get checked every lot, protecting downstream users from inadvertent polymerization during transport or storage.

    It is common for us to receive special requests for extra-low moisture or custom inhibitor loads, especially from users in the elastomer and low-pressure polymerization industries. Instead of simply accepting these as “specials,” we routinely rerun purification or tweak inhibitor packages to make sure each drum meets not just our own internal spec, but also the trickier requirements that sometimes pop up from top-tier global customers. These tailored adjustments cost time, but making them keeps our relationships strong and customer complaints rare. This level of attentiveness only comes from years of experience standing by our reactors, seeing what works and what doesn’t, rather than ticking boxes.

    Comparing 5-Methyl-1-Hexene to Related Molecules

    For those not deeply involved in chemicals, 5-Methyl-1-Hexene can appear like “just another hexene.” From a synthetic chemistry angle, though, it fits in a different class. Take 1-Hexene, for example—it’s a classic comonomer in polyethylene, but it lacks the branched methyl group that gives distinct polymer properties. Products incorporating 5-Methyl-1-Hexene achieve greater flexibility due to the side-chain branching, and that small difference changes product performance in polymer applications like adhesives and specialty elastomers. In-house testing over the years repeatedly demonstrates better temperature stability and improved mechanical properties when 5-Methyl-1-Hexene replaces linear alternatives. These aren’t theoretical claims; our technical team has watched hundreds of pilot runs with client teams who backed up the results with extensive lab data.

    Other producers sometimes recommend 3-Methyl-1-Pentene or 2-Methyl-1-Pentene as “close equivalents.” From a chemical point of view, moving the methyl group changes everything about reactivity and polymer microstructure. The more central the branch, the more it disrupts crystallinity. For applications where a controlled, low-crystallinity polymer is crucial—tackifiers, sealants, certain medical grades—5-Methyl-1-Hexene earns its spot as the preferred choice. The chemistry is subtle, but customers who test alternatives in real processes come back because of fewer manufacturing surprises, more consistent speccing, and easier scale-up.

    Operator Safety, Handling, and Real-World Logistics

    Truly understanding a product like 5-Methyl-1-Hexene means handling drums of the stuff, not just passing paperwork. At the plant, its flammability and tendency to polymerize require the same respect as any other lower alkenes. We monitor inhibitor content—most often tert-butylcatechol—both at filling and upon shipping, because peroxide buildup is not some hypothetical problem: it can ruin expensive batches or, worse, put operators at risk. Our filling systems use inert atmospheres, not as a luxury but because accidental oxygen exposure already taught us hard lessons.

    5-Methyl-1-Hexene can’t be stored in the same shelters as simple hydrocarbons. Our real-world experience guides proper drum selection: stainless or coated steel, never simple unlined drums that invite contamination and corrosion. Temperature control makes a difference during extended warehousing, and we log storage times so that we never push shelf life limits. Some customers asked about larger isocontainers, but for this molecule, we recommend drums for better quality assurance. Temperature variations and longer transport times raise risks that only on-site safeguards can truly control.

    Major Applications Backed by Field Testing

    The most compelling stories come from our own customers, whose projects make genuine demands. In adhesives, using 5-Methyl-1-Hexene as a building block brings predictable branching in EVA copolymers—critical for hot-melt glue stick performance and packaging adhesives where flexibility and clarity matter. We’ve tracked entire programs where shifting to this material improved throughput. Customers saw smoother extruder performance, with fewer clogs and maintenance stoppages once the raw monomer delivered on its promises.

    In specialty lubricants and additives, engineers selected 5-Methyl-1-Hexene to introduce controlled branching at known positions, changing viscosity and pour points compared to straight-chain alkenes. Our own trials in blending with base oils led to new additive packages, which responded better in both light- and heavy-duty formulations. This isn’t guesswork: it’s direct observation coupled with laboratory data, yielded in-house and in collaboration with large-scale users. Some of our repeat buyers work in medical device polymers, where chain architecture limits extractables; they found that the consistency of our batches meant smoother regulatory approvals and fewer failed lots, which translates into real dollars and project momentum.

    Its role in producing specialty intermediates—like plasticizer precursors and fine chemicals—also can’t be overstated. We’ve worked with pilot chemists scaling from flask to reactor, helping them tweak conditions to maximize selectivity and lower byproduct formation. In these cases, the unmatched purity and low peroxide levels found in our 5-Methyl-1-Hexene drums gave process engineers confidence to push projects forward without needing to triple-check every inbound shipment. Every little gain in predictability saves labor and time once these multi-step syntheses reach full production.

    Quality Control: The Value of Repeated, Real-World Rigor

    Our approach to quality control reflects years of learning—sometimes the hard way. The first few runs of any new chemical rarely behave as the pipeline diagrams predict. 5-Methyl-1-Hexene batches must pass GC purity, color, water, and peroxide specs before they leave our facility. Each new process run yields a certificate, but our own labs also backstop tests with independent reference standards, not just automated results. We have caught off-brand compounds and early polymerization more than once because our operators do not rely solely on machinery. That level of scrutiny forms the foundation of every steady customer relationship we’ve kept over decades. Knowing that the product never once tripped a compliance deadline is worth all the extra hours spent in quality control.

    We have also dealt with freight hiccups where delayed containers risked exposure to heat, causing problems that looked minor on paper but derailed customer production lines. In response, our shipping procedures now include triggered temperature loggers and more streamlined customs paperwork, tailored to each market’s demands. We don’t consider these tweaks “added service”—they are definitive proof that deep, sustained experience results in more reliable shipments and fewer production halts downstream. Our focus is practical: help the customer avoid unpleasant surprises and keep their operations running at pace.

    Why We Stick with In-House Production

    We see a wide gulf between the batches produced firsthand and those sourced through bulk traders. The latter can appear cheaper, but missing just-in-time adjustments on moisture or oxidation leads to problems. We’ve revived more than one customer process that failed with an off-spec load from elsewhere. Customers visiting our site see the process in motion. They notice how facility inspections, operator training, and day-by-day equipment checks have more impact on reliability than any glossy technical sheet. Maintaining our own plants, with oversight at every stage, builds the feedback loop needed to improve quickly and keep ahead of shifting industry requirements.

    We never underestimate the value of detailed manufacturing records. These logs, written after every run, let us pinpoint changes needed for even modest shifts in feedstock or equipment. Projects targeting higher volume or custom specs benefit from this in-house memory. Each adjustment—whether in catalyst dose, reaction time, or distillation head height—gets recorded for real-world consequences rather than after-the-fact theorizing. This determined attention shapes every step of how we supply, troubleshoot, and keep promises for customers who can’t afford a single off day in their manufacturing schedule.

    Sustainability, Regulatory Considerations, and Industry Trends

    The conversation around industrial chemicals now centers on sustainability and compliance. It’s not just about regulatory checkboxes; it’s about the confidence that our 5-Methyl-1-Hexene batches consistently pass extensive compliance audits, both local and international. We have responded to environmental demands by building waste minimization and solvent recovery into every production run. We adopted these habits long before regulations required, simply because it protected our workers, supply chain, and the environment we work in each day. Over time, this commitment earned us preferencing among customers worried about sourcing without compliance risks.

    5-Methyl-1-Hexene does not present the same long-term storage or environmental hazards as some halogenated feedstocks, but it still requires careful stewardship. Spill response, run-off control, and routine training shape our plant routines. These real, on-the-ground disciplines make a material difference for workers and facility neighbors. As industry keeps tightening controls on all chemical production, the fact that we haven’t faced a compliance shutdown or recall gives our partners the confidence to build programs that last.

    A Product Built on Experience, Data, and Long-Term Accountability

    From our perspective, 5-Methyl-1-Hexene is not a mere commodity—it's the result of years of manufacturing discipline, iterative improvement, and a willingness to stand by every drum we ship. For those who want more than a minimum spec, but genuine, repeatedly tested results, working with a manufacturer who lives the process brings clear results. Chemical manufacturing does not reward shortcuts. The rigorous standards we apply to each batch reflect not only regulatory needs but the firsthand reality of our customers’ production floors.

    Every molecule leaving our plant carries the story of operators who watched the process unfold, managers who reviewed every logbook, and customers who put the product through its paces across adhesives, specialty polymers, and formulated chemicals. We know every drum will find its way into a line, a tank, or a pilot program with real financial and safety stakes. Through thousands of production hours and gallons shipped, that experience shapes not only what we do, but also why 5-Methyl-1-Hexene continues to earn its place as a backbone chemical for future-facing manufacturing.