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HS Code |
782073 |
| Cas Number | 537-57-1 |
| Molecular Formula | C12H7Br |
| Molar Mass | 231.09 g/mol |
| Appearance | Light brown to beige crystalline powder |
| Melting Point | 102-106 °C |
| Boiling Point | 380 °C (estimated) |
| Density | 1.61 g/cm³ |
| Purity | Typically ≥98% |
| Solubility In Water | Insoluble |
| Solubility In Organic Solvents | Soluble in chloroform, benzene, and ether |
| Refractive Index | 1.690 (estimated) |
| Synonyms | 5-Bromo-acenaphthene; Acenaphthene, 5-bromo- |
| Smiles | Brc1ccc2c(c1)CCc3ccccc23 |
| Inchi | InChI=1S/C12H7Br/c13-9-5-6-10-8(7-9)3-1-2-4-11(10)12-7-9/h1-6H,7-8H2 |
As an accredited 5-Bromoacenaphthene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | 5-Bromoacenaphthene, 25g, is supplied in a sealed amber glass bottle with a secure screw cap and hazard labeling. |
| Shipping | 5-Bromoacenaphthene is typically shipped in tightly sealed containers made of compatible materials, protected from light, moisture, and physical damage. The chemical is classified as hazardous, requiring appropriate labeling and documentation. Shipping must comply with international transport regulations, including UN and IATA guidelines. Handle with safety equipment to prevent exposure or spillages. |
| Storage | 5-Bromoacenaphthene should be stored in a cool, dry, well-ventilated area, away from incompatible substances such as strong oxidizing agents. Keep the container tightly closed and protected from light and moisture. Store in a chemical storage cabinet, preferably for organics or hazardous materials, and properly labeled. Avoid sources of ignition and always follow local regulations for chemical storage. |
Applications of 5-Bromoacenaphthene in Industrial ManufacturingAs a specialized manufacturer of aromatic brominated intermediates, we supply 5-Bromoacenaphthene for critical processes across several advanced industrial sectors. Below, we outline current application channels, real-world integration points, and industry-specific requirements for this material in large-scale downstream use. 1. Agrochemical Intermediate Synthesis5-Bromoacenaphthene serves as a key halogenated intermediate for the production of selective herbicide and fungicide actives in modern agricultural chemistry. Fine chemical processors incorporate this raw material as an aryl bromide building block during early-stage coupling reactions. Direct use enables straightforward access to acenaphthene-derived structures found in some widely registered agrochemical molecules. Typical downstream manufacturing includes Suzuki or Stille cross-coupling with boronic acids or organotin reagents for complex active ingredient assembly targeting cereal, oilseed, and specialty crop applications. Industry compliance standards
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2. Organic Semiconductor Materials DevelopmentElectronics material manufacturers utilize 5-Bromoacenaphthene in the controlled synthesis of polycyclic aromatic compounds for organic semiconductors. This aryl bromide feeds directly into Pd-catalyzed polymerizations and coupling reactions, fabricating π-conjugated molecular backbones with high charge carrier mobility. Its application appears most prominently in the research and scale-up of organic thin-film transistors (OTFTs), organic light-emitting diode (OLED) host matrices, and organic photovoltaic device layers, where structural precision and defect minimization are required for next-generation display and energy products. Industry compliance standards
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3. Pharmaceutical Chemical R&D (Advanced Building Block)Chemical research divisions and pharmaceutical pilot plants select 5-Bromoacenaphthene as an advanced aromatic halide for constructing polycyclic core scaffolds in small molecule drug candidates. The brominated structure supports both late-stage diversification and regioselective functionalization under palladium- or nickel-catalyzed conditions. Medicinal chemists rely on this intermediate to introduce specific functional groups or heteroaromatics onto the acenaphthene backbone, which can influence metabolic stability or modify pharmacokinetic properties in discovery-stage pharmaceuticals. Industry compliance standards
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4. Functional Dye and Pigment ManufacturingThe specialty dye and pigment sector utilizes 5-Bromoacenaphthene as a high-purity brominated aromatic for the synthesis of heat- and light-stable colorants. Manufacturers introduce this intermediate in the early bromination or coupling phase to anchor chromophore extension or introduce electron-rich substituents. The resulting pigments exhibit strong UV-vis absorption and are commonly used in technical printing inks, industrial coatings, and plastic coloration where long-term performance and color fidelity are critical. The material’s precise substitution pattern is essential for developing new dye shades and performance additives. Industry compliance standards
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5. Material Science Catalysis & Ligand SynthesisResearch and specialty chemical producers use 5-Bromoacenaphthene as a precursor in the design and synthesis of novel ligands and transition-metal complexes for catalysis research. The positional bromine enables regioselective Suzuki, Buchwald-Hartwig, or Negishi-type functionalization, generating custom acenaphthene-based ligands with unique chelating properties. These ligands facilitate high turnover or enantioselectivity in challenging transformations relevant to plastics, fine chemical, or pharmaceutical industries. Production facilities source this intermediate with high batch consistency to ensure reproducibility in catalyst preparation and subsequent scale-up trials. Industry compliance standards
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Competitive 5-Bromoacenaphthene prices that fit your budget—flexible terms and customized quotes for every order.
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Making 5-Bromoacenaphthene starts with a clear understanding of raw material quality and process control—two things we never delegate. Our team oversees every step, from purification of acenaphthene through the bromination process, checking not just batch yields but purity and real-world performance. Other suppliers may move product along a long chain, but in our plant we hear from the folks in blending and from clients in the lab, so we know failures early and design systems that address them before scaling up.
Each batch of 5-Bromoacenaphthene comes out as an off-white to light tan crystalline solid, and we routinely exceed the standard 99% HPLC purity. Over the last decade, we have invested in additional columns and custom filtration units to secure a tighter control over color and solid form, especially in applications where trace organics matter. On drying floors, quick quality checks pick up any hints of residual solvent or unusual odor, which we track through batch records and, more importantly, through conversations with chemists who expect consistent material.
As a manufacturer, we have watched years of minor changes in process pack a major punch in laboratory results down the line. In a polycyclic aromatic system like acenaphthene, halogenation can generate isomeric or over-reacted byproducts, which might pass a careless GC. That is why we continue to run purity and structure verifications at every scale, self-funding NMR and LC-MS screens even after verification by our external partners. End-users rely on this vigilance. We have documented how students and senior chemists alike have saved months sidestepping problem batches—for instance, the little surprises that show themselves as ghost peaks or slow-moving side-products in the synthesis of fine chemicals, or in pilot reactions for dyes. We engage directly with technical teams to customize particle sizing when needed, simply by shifting recrystallization protocols, sparing users the risk and hassle of micronization post-shipment.
5-Bromoacenaphthene has earned a crucial seat in advanced organic synthesis. End-users ask for it by grade because it forms the backbone for specialized intermediates, especially in pharmaceutical and agrochemical pipelines. Our biggest demand comes from teams using it for cross-coupling reactions—Suzuki, Stille, and Buchwald–Hartwig pathways spring to mind—where a stubborn impurity can derail ligation yield, clogging up workflow and inflating costs. Recently, one customer reported that with our material, product crystallized out of solution for the first time in half a decade. We gather these stories with pride because they speak to the heart of good manufacturing: knowing what your clients need and caring enough to change the process, not the narrative.
Unlike generic brominated aromatics, our 5-Bromoacenaphthene benefits from years of process tuning to reduce color body contamination and manage volatility. End-users working on luminophores and advanced materials rely on high shine and low fluorescence background, so trace dark impurities have to stay out. Our in-process TLC and melting point checks empower us to release only those batches meeting every requirement we've charted with our customers. This builds real trust—not just a list of technical claims.
Through years of batch work and direct dialogue with process chemists, we have seen why someone picks 5-Bromoacenaphthene over, say, 1-bromoacenaphthene, 1,5-dibromo, or halogenates on other polycyclic backbones. The monobromo at the five-position gives both steric and electronic control for downstream couplings, unlocking selectivity in C–C bond formation. Researchers working in electronics and pigment synthesis also tell us that monochlorinated or iodinated analogs cannot always deliver the same blend of reactivity, accessibility, and cost.
It is not just the position of halogen that matters. Other brominated aromatics sometimes show a tendency toward sensitivity under storage, as documented by several external studies and echoed in our own long-term shelf-life investigations. Our 5-Bromoacenaphthene, stored in ambient conditions and lined drums, shows negligible decomposition, even after eighteen months—something our partners in small- and large-scale synthesis appreciate. You need reproducible reactions and batch-to-batch sameness, especially if moving from search lab to scale-up pilot by the end of the quarter.
Quality is not a slogan for us; it is shaped by direct experience solving recurrent pain points. Several years ago, we noticed a particular transporter introduced a subtle moisture ingress issue during rainy season, spiking water content in a few exposed lots. Right away, we doubled the container liners, shortened outbound waiting times, and added dual-end humidity checks before dispatch—because if even one kilogram misses the mark and sets off hydrolysis, it means lost hours for someone downstream. These practical fixes came from talking to end-users, not just consultants or paper standards.
Technical staff check all product runs against a strict panel of tests. We retain samples and run periodic re-tests against aged material. Our reference spectra are constantly updated, and once a year, we double-investigate a set of historical samples alongside state-of-the-art standards. The controls don't stop at our doors—we encourage our customers to push us, requesting COAs and test results, and offer on-site visits for deeper technical audits. We find this dialog builds not only confidence, but delivers data that lets both sides win. Over the past two years, joint investigations with premium buyers improved our process, uncovering minor issues in early stage bromination and leading to protocol shifts that shortened reaction times and curbed minor impurity formation.
Safety in manufacture and handling governs everything we do. Brominated aromatics demand strict discipline, and our teams receive annual retraining on material handling, accident response, and disposal protocols. Every new staff member sees firsthand how improper transfer and moisture contact can create real hazards, so everyone works within a culture tuned to vigilance, not shortcuts. Rigorous engineering controls on air quality and spill prevention mean we have documented near-zero environmental incidents over the last decade.
As a chemical manufacturer, we know a lab manager’s headaches: delayed shipments, material mismatches, and hold-ups during scale-up. Some companies quote glossy timelines and let logistics drift. In our view, you have to treat each order as a real project—with hands-on weighing, batchwise documentation, and tracked transit. On larger scale, our tank and drum storage means we can secure supply even as worldwide bromine allocations tighten or freight costs spike, smoothing out some of the volatility faced by researchers and purchasing managers.
Smaller research groups reach out because they struggle sourcing authentic 5-Bromoacenaphthene in lot sizes under a kilogram—importing from traders who don’t maintain cold chain or check batch certificates. In response, we built a system where even a single flask draw comes with a tracked supply route and QA document, so no one works in the dark. Any complaint or oddity triggers a feedback call, not just a perfunctory email.
Our site team lives in the region, so we take responsibility for everything leaving our doors. Waste is tracked through closed-loop systems, and ongoing investment means our solvent recovery runs at over 90%, well ahead of most industry averages. We partner directly with clients whose requirements shift from batch to batch, and we keep feedback running both ways, so our bench chemists meet their scientists and talk details over raw data, not just paperwork.
Over time, we have observed the increasing presence of sustainability questions in technical discussions with R&D clients. Addressing these concerns has become part of our operations. By refining our bromination chemistry, swapping hazardous reagents for safer alternatives, and continually optimizing process energy use, we have gradually cut our emissions while keeping unit costs stable. These operational gains help everyone—cost savings, environmental benefits, and smoother handling for our team on the floor.
Working so closely with chemists in pharmaceutical and material science labs, we see how even small differences in intermediate quality ripple out—changing timelines, costs, and experimental outcomes. Manufacturing 5-Bromoacenaphthene has taught us that success is inseparable from an ongoing partnership with researchers on the front lines. One overlooked impurity, a missed drop in purity, or a delay creates much bigger problems than a lost order—so we keep our focus on the process, not shortcuts.
We support researchers who demand rigorous supply chains. Our team’s knowledge and background mean we can field questions about process upsets, analytical data, and even niche parameters like fluorescence background or solubility quirks. We get plenty of questions and scrutiny—sometimes even unscheduled visits or requests for mid-process samples—which we welcome, because transparent, verifiable production ensures we all get better at what we do.
Navigating the complex world of halogenated aromatics, real reliability starts inside the factory gates and grows through direct relationships with users. Seeing our product succeed in real synthetic applications, and hearing back on both wins and problems, shapes every procedural change we make.
Over the years, our clients have conducted their own apples-to-apples comparisons with imported lots and other sources. The differences turn up in subtle places: ease of weighing, batch-to-batch consistency, and in trouble-free scale-up from grams to kilos. A top laboratory once pointed out a sticking point where a previous supplier’s product caked in storage and forced a redissolution step before use. We shared their report with our operators, which prompted us to fine-tune our drying regime and revisit our packaging. Now, even larger drums arrive loose and easy to handle.
Another synthesis group reported a persistent issue with a faint background peak in their end-product, traced back to a co-eluting impurity in the commercial 5-Bromoacenaphthene they had been sourcing from an unnamed broker. Since shifting to our supply, their yield increased by four percent—small on paper, but huge across a year’s production cycle. These successes come not just from tweaking equipment, but from keeping channels open and paying close attention to what people need and notice.
In recent years, customers from regulated industries have brought detailed audit requirements and documentation needs. We have invested in keeping records that satisfy not only our own standards, but those of leading pharmaceutical partners. All release documentation traces back to original batch runs, and an internal database houses five years’ worth of archival spectra and analytical logs. For global buyers, this transparency avoids customs or QA snags, making for fewer operational headaches during product import or trial scale-up.
We work closely with compliance officers and regulatory teams, adapting to changing national and international controls. By anticipating what auditors and reviewers will look for, we support smooth, audit-ready processes for those working towards IND filings, patent submissions, or early-stage pilot campaigns. As rules get more stringent worldwide, we’re ready, having already built in documentation and process upgrades ahead of urgent need.
Our people take pride in craft and responsibility. All QC and blending staff have direct lines of communication with technical support and management, so issues rise fast and answers come from those closest to the source. The culture values questions and second opinions. If someone sees unexpected cloudiness, smells an odd solvent note, or reads a drift in melting point, the discussion starts right on the floor, before the batch ever gets boxed for dispatch.
This makes a difference over time. By treating every researcher’s request as a potential learning event, our team stays sharp and responsive, not just going through the motions. We see ourselves not as just a source of supply, but as reliable partners in the long chain of chemical innovation.
Making 5-Bromoacenaphthene is a continuous learning process, anchored in honest feedback, data-driven process improvement, and a respect for everyone who relies on this key intermediate. The path from raw material to finished drum takes precise technical know-how and a working knowledge of what researchers actually need, not just what a data sheet can show. By keeping our doors open for questions, audits, and ongoing collaboration, we shape a product line and a work ethic that serve not just the present, but the future needs of the research and manufacturing community.