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4-Vinylbenzoic Acid

    • Product Name 4-Vinylbenzoic Acid
    • Alias 4-VBA
    • Einecs 208-947-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    582467

    Chemical Name 4-Vinylbenzoic Acid
    Cas Number 1076-79-1
    Molecular Formula C9H8O2
    Molecular Weight 148.16 g/mol
    Appearance White to light yellow crystalline powder
    Melting Point 141-144°C
    Boiling Point 315°C
    Density 1.192 g/cm3
    Solubility Slightly soluble in water, soluble in organic solvents
    Purity Typically >98%
    Synonyms p-Vinylbenzoic acid; 4-Ethenylbenzoic acid
    Smiles C=CC1=CC=C(C=C1)C(=O)O
    Inchi InChI=1S/C9H8O2/c1-2-7-3-5-8(6-4-7)9(10)11/h2-6H,1H2,(H,10,11)

    As an accredited 4-Vinylbenzoic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 4-Vinylbenzoic Acid, 100g, is sealed in an amber glass bottle with a white screw cap and tamper-evident label.
    Shipping 4-Vinylbenzoic acid is shipped in tightly sealed containers, protected from light, moisture, and incompatible materials. It is packaged according to chemical regulations, with hazard labeling as necessary. The shipment is conducted via ground or air, adhering to local and international transport guidelines for chemicals to ensure safe and compliant delivery.
    Storage 4-Vinylbenzoic Acid should be stored in a tightly sealed container in a cool, dry, and well-ventilated area. Keep away from sources of ignition, moisture, and incompatible materials such as strong oxidizing agents and bases. Protect from light and air to prevent polymerization and degradation. Proper labeling and safety precautions should be followed to ensure safe handling and storage.
    Application of 4-Vinylbenzoic Acid

    Applications of 4-Vinylbenzoic Acid in Industrial Manufacturing

    As a direct manufacturer of 4-vinylbenzoic acid, we support downstream partners in leveraging this specialty monomer across advanced industrial segments. Its well-defined functional group and polymerization properties enable differentiated product design and rigorous technical compliance. Below, we present real, industry-specific use cases with focused details on standards, formulation ratios, integration points, and end product categories.

    1. Performance Copolymers for Engineering Plastics

    Specialty resin producers incorporate 4-vinylbenzoic acid as a functional comonomer in the synthesis of advanced engineering plastics, including polyesters and copolymer blends. Its para-vinyl structure facilitates rigid chain incorporation and enhances molecular weight control, supporting the production of plastics with superior dimensional stability and thermal resistance for precision molding and demanding automotive or electronics applications.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • DIN EN ISO 1872-1 for polymerization-grade monomers
    • REACH Regulation (EC) No 1907/2006
    • UL 94 Flammability Standard (for plastics end use)

    Typical usage ratio

    • 0.5% – 5% by weight of the total monomer feed; dosage adjusted to optimize rigidity, surface polarity, and melt flow based on end-use specification.

    Downstream process integration

    • Charged in situ with primary monomers (e.g., ethylene terephthalate, styrene) during bulk or suspension polymerization; reacts via free-radical initiation under controlled temperature profiles.

    Final product types

    • Thermoplastic polyester copolymers (e.g., PBT blends)
    • High-performance injection-molded components
    • Flame-retardant and dielectric polymer housings
    • Automotive and electronics-grade structural plastics

    2. Functional Coatings and Crosslinkable Paint Resins

    Industrial coatings manufacturers use 4-vinylbenzoic acid as a modifier in acrylic or alkyd resin production, exploiting its aromatic carboxylic moiety for chemical crosslinking, adhesion enhancement, and improved solvent resistance. The monomer enables production of high-performance coatings with controlled surface polarity for substrates where strong interlayer bonding and long-term durability are mandatory, including heavy-duty metal protection and specialty can coatings.

    Industry compliance standards

    • ISO 12944 Corrosion Protection Standards
    • EN 927-5 Outdoor Coatings Weather Resistance
    • ASTM D3359 Adhesion Test for Coatings
    • Registration with ECHA for industrial use under REACH

    Typical usage ratio

    • 1% – 7% by mass in resin backbone; dosage tuned for desired crosslink density and film hardness as determined by application and substrate type.

    Downstream process integration

    • Added to the reactor with primary resin monomers; undergoes free-radical or step-growth polymerization prior to emulsification or solvent dispersion, followed by milling and filtration for particle size control.

    Final product types

    • Industrial anti-corrosion primers
    • Specialty metal coil coatings
    • High-durability can interior lacquer finishes
    • Architectural weatherproofing topcoats

    3. Ion-Exchange Membranes for Electrochemical Applications

    Membrane manufacturers integrate 4-vinylbenzoic acid in the fabrication of ion-exchange films for fuel cells, flow batteries, and advanced electrodialysis units. Its carboxylic acid group provides defined ionic sites that increase membrane selectivity and mechanical stability under harsh operational environments, particularly where temperature resistance and precise ion migration are critical for process efficiency.

    Industry compliance standards

    • IEC 62282-2 Fuel Cell Module Performance Testing
    • ISO 9001:2015 for membrane and separator manufacturing
    • RoHS Directive (2002/95/EC) for hazardous substance restriction
    • Customer-specific performance validation protocols

    Typical usage ratio

    • 3% – 12% by weight in copolymer blends; proportion determined by target ion-exchange capacity and mechanical requirements per application.

    Downstream process integration

    • Introduced during in situ copolymerization with styrene, divinylbenzene, or acrylonitrile; solution or emulsion casting yields membrane films, followed by post-sulfonation or neutralization steps depending on final ionic group requirements.

    Final product types

    • Proton exchange membrane fuel cells (PEMFCs)
    • Vanadium redox flow battery films
    • Electrodialysis desalination membranes
    • Chlor-alkali ion-selective barriers

    4. Photopolymer Materials for UV-Curable Systems

    Producers of photopolymerizable formulations employ 4-vinylbenzoic acid as a functional monomer in UV-curable coatings, inks, and adhesives. Its defined aromatic backbone promotes efficient photoinitiated polymerization, providing films with high scratch resistance and chemical stability. This application sees growing demand in electronics, printed circuit board conformal coatings, and precision optical component encapsulation.

    Industry compliance standards

    • IEC 61249-2-21 for electronic substrate materials
    • ISO 4582 for accelerated aging of plastics
    • EN 71-3 Safety of Toys (for indirect-contact protective layers)
    • RoHS 2011/65/EU for hazardous substances in electrical/electronic equipment

    Typical usage ratio

    • 2% – 8% by weight in total resin formulation; level set depending on cure speed requirements and final film property targets.

    Downstream process integration

    • Blended with acrylate or methacrylate oligomers, added to UV initiator system, and incorporated into the coating or ink batch prior to filtration and viscosity adjustment; applied by roll-coating, inkjet, or spray followed by UV lamp curing.

    Final product types

    • UV-cured conformal coatings for electronics
    • Scratch-resistant optical varnishes
    • LED device encapsulants
    • Digital printing inks and coatings

    5. Functional Polymer Supports in Catalytic Systems

    Chemical process engineers utilize 4-vinylbenzoic acid for manufacturing specialized polymer supports with pendant carboxylic groups. These supports anchor homogeneous and heterogeneous catalysts, facilitating high-activity, reusable catalytic beds for fine chemical synthesis and pharmaceutical manufacturing. The acid group density directly modulates ligand immobilization and metal coordination in continuous reactor environments.

    Industry compliance standards

    • GMP Guidelines for Pharmaceutical Active Substance Production (ICH Q7)
    • 21 CFR Part 211 for Finished Pharmaceuticals (if used in API production)
    • ISO 14001 for Environmental Management (waste minimization in catalyst recovery)
    • FDA-specific Drug Master File registration where applicable

    Typical usage ratio

    • 1% – 10% by polymer dry mass; precise ratio selected to optimize metal-binding density and swelling properties based on catalyst system.

    Downstream process integration

    • Enter the polymerization feed during bead or membrane preparation; post-polymerization functionalization then introduces target catalysts by ion-exchange or covalent linkage, finishing with washing and drying steps.

    Final product types

    • Immobilized transition metal catalysts for hydrogenation/oxidation
    • Enzyme-supporting polymer beads for biocatalysis
    • Continuous-flow reactor packing materials
    • API intermediate synthesis platforms

    6. Specialty Dispersants in Advanced Ceramic Processing

    Ceramic and composite material manufacturers implement 4-vinylbenzoic acid-based copolymers as dispersing agents in the formulation of high-purity ceramic slurries. The monomer’s carboxylic acid enables controlled surface adsorption on particle interfaces, providing effective stabilization and green body strength in processes requiring minimized aggregation and uniform feedstock viscosity for tape casting, extrusion, or additive manufacturing of technical ceramics.

    Industry compliance standards

    • ISO 20507:2014 (Fine ceramics—Terminology)
    • ASTM C1285 Standard Test Method for Leachability
    • Customer-specific purity criteria for functional ceramics
    • RoHS and REACH for supply chain transparency

    Typical usage ratio

    • 0.05% – 0.5% by slurry mass; added based on target viscosity, particle size, and sedimentation requirements of the ceramic system.

    Downstream process integration

    • Dosed during initial slurry mixing with ceramic powders, prior to milling or casting; aids in achieving stable colloidal suspensions, enabling precise molding or tape formation before binder removal and sintering.

    Final product types

    • Alumina and zirconia technical ceramics
    • High-purity ceramic substrates for electronics
    • Porous filtration media
    • Additively manufactured ceramic components
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    Certification & Compliance
    More Introduction

    4-Vinylbenzoic Acid: Practical Attributes and Real-World Performance

    Introducing Our 4-Vinylbenzoic Acid

    From a chemist’s standpoint, a lot of attention goes to the details behind every batch of 4-Vinylbenzoic Acid. Our daily experience in manufacturing teaches us that small process tweaks can change yield or purity in ways that impact end-user performance for months. As a plant-based producer, years of hands-on synthesis have shown that success with this monomer lies in careful control. Our own 4-Vinylbenzoic Acid arrives consistently as a white-to-off-white crystalline powder, readily soluble under alkaline conditions thanks to the carboxylic acid group, and designed to hold a defined melting range. That melting point sits around 148-150°C, a detail that matters during polymerization.

    Our team insists on keeping water content and trace impurities below specific limits, with acid number and vinyl purity measured batch-by-batch. It seems like a simple acid, but no two manufacturing runs turn out exactly alike unless the process is tightly managed—especially when keeping metal and organic byproducts under 100 ppm. These measures give people working downstream room to scale formulations without compensating for off-spec acid or haze caused by impurities.

    Why Industry Uses 4-Vinylbenzoic Acid

    Anybody involved in specialty polymers, adhesives, or resins will know how slight changes in a monomer structure affect strength, flexibility, or glass transition temperature. Adding a vinyl group to benzoic acid changes how it copolymerizes, which directly affects end-product performance. In our own pilot projects and feedback from longtime clients, this material stands out for introducing strong, rigid aromatic structure to the polymer backbone while also allowing further chemical modifications on the carboxyl group. This dual reactivity brings clear advantages compared to something like styrene, which lacks the acid handle, or benzoic acid, which lacks the vinyl double bond.

    Batches we produce see use everywhere from UV-cured coatings to high-performance plastics by customers who care about how the finished resin stands up to heat, solvents, or weather. Paint and coatings companies characterize test panels built around 4-Vinylbenzoic Acid-based copolymers for things like improved adhesion or scratch resistance—properties a basic acrylic acid or meta-vinylbenzoic acid cannot provide. Performance chemists working in aqueous formulations value the water solubilizing aspect of the acid, while those in organic systems rely on its compatibility with radical initiators. Years of customer trials consistently brought up these differentiating performance stories, and we built our batch controls around those insights.

    Key Differences from Related Products

    People sometimes ask why not just use styrene or acrylic acid, two cornerstones of commercial polymerization. In practice, 4-Vinylbenzoic Acid combines parts of both: a vinyl group ready for free radical copolymerization (like styrene), anchored onto a benzene ring with a carboxylic acid substituent (as with benzoic acid). This gives polymers unique performance properties. Styrene gives rigidity but lacks sites for crosslinking beyond the aromatic, while acrylic acid introduces hydrophilicity but can’t supply aromatic stability. Using 4-Vinylbenzoic Acid in a formulation directly affects molecular weight distribution, glass transition temperature, and polymer polarity.

    In-house polymer trials using different monomer combinations have shown how 4-Vinylbenzoic Acid delivers better solvent resistance than polyacrylates while offering more crosslinking options than polystyrene. The acid group enables the downstream addition of esters or amides, which chemists working on waterborne systems appreciate. Meta- and para-vinylbenzoic acid have slightly different reactivities; the para-isomer we manufacture often leads to more regular polymer structures because the substituents are positioned to reduce steric hindrance. Experience showed us that even minor contamination or isomeric mixing can shift polymer properties noticeably, so keeping positional isomer purity high remains a technical priority at our facility.

    Often in the past, customer research tried swapping 4-Vinylbenzoic Acid for cheaper vinyl aromatics, only to find that loss of thermal or chemical resistance ended up costing more in reformulation and warranty work. In copolymerizations with acrylates, this acid grants additional control over ionic character and reactivity, streamlining the development of dispersions and adhesives that need good wet adhesion and bond strength on metal or glass. Our process chemists have seen that carboxyl group at the para position act as both an anchor for crosslinking and as a stabilizer in formulas exposed to light and high humidity.

    Real-World Applications Backed by Manufacturing Insight

    Progress in polymer science almost always comes down to the properties delivered by the monomers at hand. The clients bringing the most repeat orders tend to work in specialty resins, high-performance adhesives, photopolymers, and coatings that cannot compromise on shelf life or physical properties. 4-Vinylbenzoic Acid appears in applications ranging from ion exchange resins—where acid handling counts—to industrial adhesives where high modulus and bond retention are the aim. Pilot batches at our site have gone into research projects that demand very low volatility in the finished product, taking advantage of the acid’s strong aromatic backbone.

    The difference this material makes in UV-cured or thermoset systems emerges in the details. Copolymers built from this acid resist yellowing and softening that hits some standard acrylate systems. For waterborne or powder coating chemistries, the acid group creates stable emulsions and helps disperse pigment, making shelf-stable formulations possible. Chemists working in semiconductor cleaning resins—where every trace of impurity can affect circuit yields—use our high-purity acid to keep particle counts low and solvent compatibility consistent between production runs.

    Plastics makers often choose this acid for specialty molding compounds because its aromatic structure enhances flame retardance and dimensional stability. Our staff has watched feedback from multiple molding plants on how downstream reactivity and melt flow can shift with every monomer tweak. Over the years, the most durable, well-aging compounds have combined 4-Vinylbenzoic Acid with acrylates, maleic anhydride, or styrene derivatives. This versatility comes back to the chemistry—something best understood by operators reaching into reactors, not spreadsheets.

    Supporting Customer Projects Through Reliable Supply

    Every batch going out the door comes with analytic data showing content, melting point, and residual solvents. This isn’t marketing—it’s the result of feedback from engineers frustrated by shipment-to-shipment variability from less vigilant suppliers. A vinyl acid like this is unforgiving to sloppy work, especially in pilot runs for new adhesives or resins where a clump of sodium, chloride, or halogen can upend a month of downstream QC. Process managers at our plant keep benchmarks tight for every parameter, holding volatility, water, and heavy metal levels to minimums that enable trouble-free scale-up.

    We get direct project feedback from production chemists, not just purchasing managers. Last year, one major user reported that an entire coating campaign crashed because they received inconsistent acid numbers from third-party packed drums. Since then, we’ve pushed for batch traceability and in-process HPLC validation, even on scale-ups beyond 100 kg. If a co-monomeric vinyl acid builds up color or haze in finished polymers, troubleshooting often traces back to impurities. Our on-site blending and crystallization stages reduce those headaches; the technicians running these reactors have seen what happens otherwise.

    Some clients ask about minimizing downtime during raw material changeovers. By maintaining consistent granulometry, particle size distribution, and low residual monomer content, we help polymerization operations avoid unplanned cleaning cycles or popcorning. People often underestimate how a tiny change in powder flow or dissolution rate can alter batch time by hours, leading to waste that end-users absorb. Our plant’s focus on these micro-details reflects a long cycle of conversation with R&D teams who prefer proof over glossy presentations.

    Looking Ahead: Improving Sustainability and Process Safety

    From the shop floor, process safety and sustainability aren’t just buzzwords. Workers at our site see firsthand how solvents, waste streams, or thermal runaways complicate life and hurt margins. Over years of making aromatic acids like this one, we’ve built closed-loop solvent recovery and energy monitoring into core workflows. Traditional production routes for 4-Vinylbenzoic Acid involved batchwise oxidation and precipitation, but modern lines at our site now use continuous crystallization and air-based oxidation, trimming energy costs and solvent loss.

    Customers in Europe and East Asia ask detailed questions about waste neutralization, not just cost. Our team uses catalytic recovery for unused starting materials and neutralizes spent acids for compliant disposal. Solvent vapor is scrubbed or recycled, with process data examined weekly to spot leaks or inefficiencies. These changes spring from years of legal, environmental, and customer pressure, not hypothetical discussions. People whose health and workflow depend on containment and clean operation drive our improvement cycles. Clients often benefit from cleaner product—lower color bodies, less ash, and more predictable copolymerization—all rooted in these behind-the-scenes upgrades.

    Meeting the Challenges of Future R&D

    Polymer chemists working on tomorrow’s resins care about more than legacy properties. We’ve seen a surge of requests from developers fine-tuning copolymers for medical devices and microelectronics. The demand for analytical purity, sub-ppm metals, and zero ionic contamination grows every quarter. Our response is to push process controls further, implementing new analytical tools and keeping a direct lab-to-plant feedback loop.

    Researchers at universities and corporate labs now bring new application questions every year: What about using 4-Vinylbenzoic Acid in copolymers for biomedicine, advanced filtration, or energy storage? We connect them with production runs to test ideas on real manufacturing scales, learning alongside them when process parameters must shift. Real progress usually follows from plant-level experimentation, not just lab synthesis. Teams with specialized application needs pilot blends with us, and relaying their successes or failures updates our own protocols. These test runs keep our manufacturing honest and responsive.

    Final Thoughts from the Production Floor

    Whether the job calls for scaling a new resin, troubleshooting batch variability, or meeting stringent purity targets, the operator’s perspective shapes every lot of 4-Vinylbenzoic Acid we release. Our staff has spent years recognizing how workflow habits and process adjustments determine real-world quality. Choices about feed temperature and crystallization time come from experience, not theory, and everybody in the supply chain—formulation scientist, plant manager, and line operator—benefits when that experience is built into the final product.

    Day-to-day effort in our plant shows up in the stability, purity, and performance of each 4-Vinylbenzoic Acid shipment. That’s why our production principles revolve around transparency, hands-on manufacturing, and active listening to end users. The difference for our partners isn’t found in abstract claims but in the repeatable ease and reliability after every shipment. Long-term users reward us by coming back, sharing their discoveries, and pushing us to keep each production run better than the last.