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4-Tert-Butylbenzoic Acid

    • Product Name 4-Tert-Butylbenzoic Acid
    • Alias p-Tert-Butylbenzoic Acid
    • Einecs 202-679-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    881988

    Chemical Name 4-Tert-Butylbenzoic Acid
    Cas Number 98-73-7
    Molecular Formula C11H14O2
    Molecular Weight 178.23 g/mol
    Appearance White crystalline powder
    Melting Point 165-169°C
    Boiling Point 316°C
    Solubility In Water Slightly soluble
    Density 1.07 g/cm³
    Purity Typically ≥98%
    Pka 4.88
    Smiles CC(C)(C)C1=CC=C(C=C1)C(=O)O
    Synonyms 4-(1,1-Dimethylethyl)benzoic acid
    Storage Conditions Store at room temperature, tightly closed, dry place
    Refractive Index 1.519

    As an accredited 4-Tert-Butylbenzoic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 4-Tert-Butylbenzoic Acid, 100g, supplied in a sealed amber glass bottle with a screw cap, labeled with hazard information.
    Shipping 4-Tert-Butylbenzoic Acid is shipped in tightly sealed containers, protected from moisture and sources of ignition. It should be packed according to local and international regulations, often in UN-approved packaging for chemicals. Ensure proper labeling, documentation, and use of secondary containment to prevent leaks during transit. Handle with appropriate safety measures.
    Storage 4-Tert-Butylbenzoic Acid should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area, away from sources of ignition, heat, and incompatible substances such as strong oxidizing agents. Protect it from moisture and direct sunlight. Label the container clearly and keep it away from food and drink. Follow all standard chemical storage protocols.
    Application of 4-Tert-Butylbenzoic Acid

    Applications of 4-Tert-Butylbenzoic Acid in Industrial Manufacturing

    4-Tert-Butylbenzoic Acid is a key aromatic carboxylic acid predominantly used as an intermediate in specialized chemical manufacturing sectors. The following sections present major downstream applications, highlighting integration specifics within each industry’s process chain.

    1. Synthetic Lubricant Additive Manufacturing

    Specialty lubricant manufacturers blend 4-Tert-Butylbenzoic Acid into ester-based synthetic lubricants to enhance oxidative stability and viscosity performance under elevated stress. It acts as a carboxylic acid precursor for the synthesis of specialized esters, most notably in the production of polyol ester (POE) oils for high-demand turbine and compressor lubricants. Process engineers incorporate the material in esterification with neopentyl polyols, improving fluid lifetime in extreme operating temperatures. QC teams closely monitor acid value adjustment during blending to meet precise formulation standards. The final esters undergo dehydration, filtration, and blending with performance additives before packaging for end users in aviation, refrigeration, and industrial fluid systems.

    Industry compliance standards

    • ISO 6743-3 (Lubricants, Industrial oils, Synthetic esters)
    • ASTM D7963 (Oxidation stability of lubricants)
    • REACH (EC) No 1907/2006 Registration
    • SAE AS5780 / MIL-PRF-23699 (Aviation lubricant specification)

    Typical usage ratio

    • Applied at 5%–25% by weight in ester synthesis, depending on base polyol and viscosity targets.
    • Proportion adjusted for viscosity range (ISO VG 15–100) and oxidation stability requirements.

    Downstream process integration

    • Direct esterification with neopentyl glycol, trimethylolpropane, or pentaerythritol.
    • Batch reactors for controlled condensation under vacuum.
    • In-line acid value monitoring and post-synthesis neutralization steps.
    • Blending with antiwear, antioxidant, and anti-foam additives prior to packaging.

    Final product types

    • Turbine compressor synthetic oils
    • PAG and POE refrigeration lubricants
    • High-temperature chain lubricants
    • Specialty greases for industrial machinery

    2. Alkyd Resin and Paint Binder Formulation

    Coatings manufacturers use 4-Tert-Butylbenzoic Acid as a reactive monomer in alkyd resin synthesis to regulate molecular weight distribution, enhance hardness, and increase resistance to yellowing. The bulky tert-butyl group supports cross-linking and improves hydrolytic stability in final resins. Integration takes place in autoclave reactors, where formulators balance the ratio of dibasic acid, polyol, phthalic anhydride, and modifiers such as this acid to achieve targeted film properties for OEM and refinish paints. The material helps minimize discoloration during curing and increases coating durability, which is key for automotive and industrial metal protection requirements.

    Industry compliance standards

    • EN ISO 12944 (Protective coatings for steel structures)
    • ASTM D3022 (Resistance of finishes to yellowing)
    • RoHS Directive 2011/65/EU (Restriction of hazardous substances)
    • GB/T 25251-2018 (Coating industry standard, China)

    Typical usage ratio

    • Used at 2%–8% by weight of total alkyd resin formulation.
    • Percentage set according to hardness and chemical resistance requirements.

    Downstream process integration

    • Introduction at the start of polycondensation with a specified polyol and oil ratio.
    • Stagewise heating under nitrogen atmosphere to reach target acid value.
    • Sampling for viscosity and solubility checks during process control.
    • Resin dilution and filtration prior to blend into end-use paint formulations.

    Final product types

    • Automotive enamels and primers
    • Industrial maintenance coatings
    • Appliance and furniture lacquers
    • Eco-friendly water-borne alkyd paints

    3. Corrosion Inhibitor Synthesis for Metalworking Fluids

    The acid serves as a key intermediate in the synthesis of corrosion inhibitors used in aqueous and semi-synthetic metalworking fluids. Its introduction produces hydrophobic benzoate salts, particularly for alkaline water-based systems, where they provide barrier protection to ferrous and non-ferrous metals during machining and storage. Downstream formulators react the raw acid with suitable amines or metal hydroxides in dedicated neutralization tanks, precisely tracking pH and solubility endpoints. Final concentrates undergo stabilization and performance testing to ensure long-term protection against oxidation and pitting under high-shear operational environments.

    Industry compliance standards

    • ASTM D4627 (Corrosion inhibition properties in emulsifiable fluids)
    • TRGS 611 (Germany, limit values for metalworking fluid additives)
    • REACH Annex XVII (Restricted Substances List)
    • GB/T 6144-2008 (Metalworking fluid performance test, China)

    Typical usage ratio

    • Typically neutralized for use at 0.2%–1.0% in final metalworking fluid concentrates.
    • Level fine-tuned based on fluid pH and metal type (ferrous/non-ferrous protection).

    Downstream process integration

    • Neutralization with monoethanolamine or sodium hydroxide in jacketed vessels.
    • Integration into concentrate blending with lubricity and emulsifier packages.
    • Shear/mixing equipment for uniform distribution.
    • Performance assessment in salt spray and immersion tests for release lots.

    Final product types

    • Ferrous and non-ferrous metalworking fluids
    • Corrosion inhibitor packages for coolants
    • Temporary protective coatings for metal parts
    • Storage preservative fluids

    4. Epoxy Curing Accelerator for Powder Coatings

    Powder coating compounders utilize this aromatic acid as a co-curing accelerator with dicyandiamide and epoxy resin systems to reduce curing temperatures and achieve faster throughput on coil and appliance coating lines. Its sterically hindered structure facilitates controlled imidization, which aids in precise TG and cross-link density regulation of the cured film. Engineers dose the acid directly in pre-mixers with resins and pigments to achieve uniform particle dispersion prior to extrusion and micronization. Cure profile validation ensures compatibility with standard application ovens and end substrate requirements.

    Industry compliance standards

    • EN 13438 (Performance of powder coatings on galvanized steel)
    • BS EN 12206-1 (Aluminium and powder coatings)
    • OEM Q-PL-03 (Powder Coating Specifications, Automotive)
    • RoHS Directive 2011/65/EU Compliance

    Typical usage ratio

    • Added at 0.5%–1.5% by weight of total powder coating mix.
    • Optimized based on type of epoxy resin and final bake schedule (160–200°C).

    Downstream process integration

    • Blending in high-speed mixers with epoxy and hardener pre-powders.
    • Extrusion and cooling, followed by grinding and sieving for particle size control.
    • Quality testing: gel time, gloss, adhesion, and TG/differential scanning calorimetry.
    • Batch coding for traceability in packaging and shipment.

    Final product types

    • Electrostatic powder coatings for appliances
    • Architectural metal coatings
    • Automotive underbody powder coatings
    • Functional industrial pipe and hardware coatings

    5. Specialty Plasticizer Production for Polymer Composites

    Plasticizer producers incorporate this aromatic acid as a reactive component in the manufacture of specialty esters used as plasticizers for engineered polymers such as PVC and polar polyolefin composites. The bulky tert-butyl structure imparts migration resistance and stabilizes mechanical properties under prolonged exposure to heat and solvents. Plants execute selective esterification with higher alcohols, utilizing batch-column distillation for purification, followed by rigorous residual acid analysis. Integration occurs upstream of compounding lines for wire and cable, flooring, and specialty molding applications, where real-time monitoring of viscosity and compatibility with resin grades is critical.

    Industry compliance standards

    • EN 71-3 (Toy Safety, Migration of certain elements)
    • REACH SVHC (Substances of Very High Concern listing)
    • IEC 60227 (PVC insulated cables, safety standard)
    • UL 94 (Flammability for polymeric materials)

    Typical usage ratio

    • Employed at 7%–18% by weight in target polymer resin blends.
    • Adjusted based on final flexibility, dielectric, and migration resistance goals.

    Downstream process integration

    • Esterification with 2-ethylhexanol or similar high-boiling alcohols in pressure reactors.
    • Purification via distillation and acid value/GC residual checks.
    • Inline addition into PVC compounding and twin-screw extruders.
    • Compatibility testing: tensile, elongation, and plasticizer migration assays.

    Final product types

    • Plasticized PVC sheets and profiles
    • Flexible wire and cable insulation
    • Technical flooring compounds
    • Precise molded parts for electrical and automotive sectors
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    Certification & Compliance
    More Introduction

    4-Tert-Butylbenzoic Acid: Practical Value Rooted in Real-World Manufacturing

    What Sets 4-Tert-Butylbenzoic Acid Apart in Our Lineup

    As a long-standing chemical manufacturer, our daily focus is on refining core aromatic acids to meet current industrial demands. Among these, 4-tert-Butylbenzoic Acid stands out, both in its distinct structure and its consistent utility across modern applications. Our route to production prioritizes batch reliability and traceable supply chains, which stem from years of hands-on improvements and steady demand from users who require consistency, whether for coatings, lubricants, or polymer processing. We produce 4-tert-butylbenzoic acid under controlled synthesis that avoids impurities typical in older methods, reducing the risk of inconsistent reactions in downstream processes.

    Physical Form and Handling: Insights From the Plant Floor

    Each batch emerges as a white, crystalline powder with minimal dust, produced under ventilation and low-moisture storage to fend off agglomeration or discoloration. The sharp melting point—around 164 to 168°C—remains one of our key quality markers. Most requests from our larger customers concern bulk packaging options and the material’s flow during mechanized transfer; it quickly became clear that modest tweaks in drying and screening equipment preserved its free-flowing nature, even in higher-humidity regions. For operators, minimized caking means less downtime, better process throughput, and safer handling.

    Beyond basic appearance, the stability of 4-tert-butylbenzoic acid at moderate temperature and humidity simplifies daily routines compared to some benzoic acid derivatives, which clump or degrade quickly. No one enjoys scooping out stratified material or running extra cleaning cycles on powder lines. By keeping the acid’s shelf life steady, we cut waste and streamline warehouse management, a simple gain that plays out over hundreds of tons each year.

    Understanding the Main Use Cases: From Lubricants to Polymer Additives

    It’s not always clear from literature—nor from suppliers who haven’t witnessed the shift firsthand—how much 4-tert-butylbenzoic acid’s market has grown in niche applications. Our team first saw steady uptick in its use as a lubricant additive, where it functions as a corrosion inhibitor and antioxidant. The tert-butyl group blocks unwanted reactivity, helping lubricants withstand higher operating temperatures and chemical stresses. Customers in the automotive and machinery sectors report fewer breakdowns and longer maintenance intervals. That kind of field feedback directs further product consistency efforts on our end, and shapes batch testing priorities.

    Coatings, resins, and adhesives account for another sizable share. Here, 4-tert-butylbenzoic acid acts as a modifier to control curing rates, gloss, and resistance to yellowing. Its molecular bulk translates to a distinctive set of physical properties—something we track closely through regular GC/HPLC checks. Those labs don’t just report numbers; they also flag outliers to staff on the line, ensuring that the acid’s incorporation leads to reliable performance in end-products.

    On the polymer side, processors add this acid to manage viscosity and processing temperature during extrusion or molding. The thermal stability and predictable solubility profile matter more than theoretical chemical descriptors. We’ve built up practical experience over the years helping customers resolve issues such as blockages and uneven dispersion in masterbatch systems—usually by fine-tuning the crystalline habit or milling parameters. Results from their production floors feed directly back to ours, shaping real-life improvements faster than any remote technical bulletin.

    Purity and Specifications Influenced by Real Manufacturing Needs

    Plenty of companies can recite purity percentages and identification numbers, but what often matters more is what lies just beneath the threshold. Our main production lines achieve a minimum purity exceeding 99 percent—by HPLC area—yet what makes the difference is controlling trace byproducts. For example, even tiny amounts of unreacted benzoic acid or isomeric impurities alter downstream polymerization or discolor lubrication systems. Each campaign of 4-tert-butylbenzoic acid undergoes tailored purification steps; this translates to less product loss and minimal recalibration for our regular clients.

    The acid’s structure, combining a bulky tert-butyl group with a carboxylic acid on the para position, sets its behavior apart from straightforward benzoic acid or ortho/iso variants. Observing production lines or quality issues over time, the side group’s sterics consistently ease blending in dense matrices and slow unwanted crosslinking. Lab analyses are practical tools here, confirming—via NMR and FTIR—that each lot displays the signature signals without off-notes. Years back, more than one polymerization customer flagged rare color streaking, traced to overlooked UV impurities in feedstock. We now filter and QC the luminance and color index of all outgoing batches, saving time lost to downstream complaint resolution.

    Comparison With Other Benzoic Acid Derivatives: More Than Structural Differences

    Having synthesized and packaged a range of aromatic carboxylic acids on site for decades, the differences aren’t only structural—they’re tangible in daily operations and in what customers request. Pure benzoic acid and para-substituted cousins—like p-chlorobenzoic or p-methylbenzoic acid—bring unique sets of solubility and reactivity, but the tert-butyl group punches above its weight by resisting oxidation and branching out the melting principal. This means in blends, tar build-up and yellowing decrease, and delivery lines need fewer chemical flushes per campaign. Long-term partners have moved to 4-tert-butylbenzoic acid to solve chronic issues in color and process robustness that couldn’t be tackled simply by changing suppliers or increasing filtration.

    Some polymer modifiers, such as p-hydroxybenzoic or p-aminobenzoic acids, serve different reaction routes or end functions, but their sensitivity to moisture or oxidation complicates shelf life and blending. Our teams have catalogued these behaviors side by side, logging incidents about batch separation, loss of reactivity, or poor flow. The tert-butyl derivative sits comfortably in the middle ground: structurally robust, yet chemically accessible for the desired reactions.

    We also field client questions on parallels with sodium and potassium benzoates, especially for salt-sensitive polymer systems. The simple answer is—those salts function well as preservatives but falter in non-polar settings needed for coatings, adhesives, or lubricants. By sticking with the acid form, our partners consistently achieve target physical and performance metrics without the need for extra additives, buffers, or re-designs.

    Traceability, Supply, and End-User Assurance

    Years ago, issues around supply chain transparency and raw material origin led to costly recall and requalification processes for several manufacturers—ours included. Since then, every batch of 4-tert-butylbenzoic acid tracks from incoming raw material bins through each reaction vessel, with digital logbooks containing timestamps, maintenance intervals, and operator initials. This system has caught potential mis-shipments early and allowed users to compare on-site test results against supplied certification data. For customers facing internal or regulatory audits, this has made passed inspections smoother and allowed their staff to focus more on performance than paperwork.

    Consistent review of global sourcing for key feedstocks limits disruptions that plagued early adopters of tert-butyl derivatives. By maintaining multiple procurement avenues for tert-butanol and specialty catalysts, we keep the acid flowing to both large production plants and smaller R&D teams. Production scheduling always accounts for regular demand cycles and emergency drawdowns; over time, this cuts the risk of empty stock warehouses and supply penalties that ripple through the customer’s economic planning. When environmental shifts or geopolitical blocks impact a particular route, we pivot out of established redundancy, steering production smoothly instead of passing on shortages.

    Sustainability and Environmental Impact

    As sustainability standards tighten, we routinely assess the process for 4-tert-butylbenzoic acid with both resource conservation and downstream end-of-life handling in mind. Our teams replaced legacy solvent streams with less toxic alternatives, and redesigned recovery skids to capture organics at over 90 percent efficiency. This slashes both process emissions and demands for fresh solvent loads. Chemical waste is separated at the source and sent into closed-loop reclamation, minimizing off-site disposal.

    Feedback from industrial clients signals that they value an upstream approach to greener chemistry. By providing a cleaner, purer starting acid, downstream emissions drop and decanting or venting steps run more efficiently. Storeroom managers report seeing fewer containers with residual caking or solvent haze, important not just for cost but for worker safety. Our environmental health staff conduct ongoing monitoring for trace VOCs in both the work environment and outgoing product. Regulatory reports regularly return clear; yet, even so, improvement targets remain front of mind for plant supervisors and front-line technicians alike.

    Our synthesis does not involve restricted precursors nor generate persistent byproducts that complicate local permits. That’s earned approval from a growing number of multinational customers seeking cradle-to-grave documentation for the chemicals they source. Ongoing dialogue with these partners spotlights opportunities for future innovation—shifts towards more biobased feedstocks, water-neutral processing, or energy-smart drying approaches. Those aren’t just slogans for our team; they tie directly to how our chemical output impacts not only user plants but surrounding communities.

    User Feedback and Problem-Solving From Real-World Installations

    Direct conversations with line engineers and process chemists shape our improvement plans. We learned early that coatings manufacturers struggled with residue and nozzle clogging when switching between acids, while polymer processors cited static buildup and poor powder flow. Tuning the grinding and drying steps, and swapping packaging liners, reduced both batch-to-batch variability and downtime without a major increase in cost.

    In lubrication, some customers encountered foaming or loss of clarity when substituting similar acids. We traced the issue to trace moisture and dust fines. More rigorous drying and in-line sieving yielded an immediately noticeable drop in customer complaints and field failures. It isn’t only about meeting a specification but enabling the product to work each time, under practical, often unpredictable, process environments.

    Feedback loops continue to drive incremental changes. Polymer companies now achieve tighter processing windows by customizing acid particle size, or by adding internal markers calibrated to their processing lines. For some, blending the acid with stabilizers or antioxidants tailored for particular end-use temperatures made the decisive difference between passing and failing a product launch. Our R&D center regularly hosts roundtables with customer tech teams, fixing application headaches that only become obvious after reaching real production scale.

    Why Consistency Is the True Benchmark

    In years of manufacturing, small deviations in purity, form, or moisture explain most downstream issues. We build in margin for variation, so users can focus on their recipe rather than troubleshooting a raw material. Investing in automated batch tracking, continuous in-line measurements, and dedicated delivery packaging leads to visible gains—fewer customer adjustments, less unscheduled maintenance, and cost savings up and down the value chain.

    Most of our volume goes to partners with strict standards set by end-user needs, not just by legal minimums. We routinely adapt processes to meet region-specific rules, whether for food contact, emissions, or batch certification; our plant teams draw on real-world experience to verify compliance and performance under these constraints.

    Continuous Improvement and Industry Trends

    We watch the evolution of lubricant, coating, and resin technology for new requirements. The recent rise in demands for low-VOC content materials prompted a fresh look at side-processes; as a result, we now reclaim more process streams and minimize organic solvent emission to meet air quality targets. New automation allows us to tune purity, particle size, and moisture to finer tolerances than ever, responding directly to feedback from our broad user base.

    Research teams regularly float possible changes—a push towards bio-based feedstocks, altered purifying agents, or next-gen green chemistry routes. Many of these ideas originate beyond traditional lab R&D, taking shape only after field operators and production staff spotlight wasted resources or cleaning headaches. By bringing all voices to the table, the future of our 4-tert-butylbenzoic acid production pivots not just on numbers, but on daily experience.

    Direct Experience Sets the Difference

    Trader and distributor descriptions rarely reflect the shop floor’s realities. Consistent 4-tert-butylbenzoic acid output comes from knowing how the product performs in complex, messy, high-pressure settings, not just in the lab. We address everyday challenges—dust, packing, batch recall, and residue—by sharing responsibility across synthesis, QA/QC, and logistics. Most problems come to light only with repeated handling, and we keep that feedback flowing both from large plants and small pilot lines. By building trust through transparent results and honest troubleshooting, we continue to grow with our partners and tailor our work to real-world needs.

    Future Prospects: Growing With Our Users

    As industries innovate, 4-tert-butylbenzoic acid plays a growing part in next-generation formulations—advanced lubricants, scratch-resistant coatings, custom polymers, and applications just emerging from pilot trials. Input from customers keeps stretching our manufacturing approach. Whether the shift comes from regulatory mandates, sustainability programs, or raw economic calculus, flexible production and quick response times make all the difference.

    We keep focus on real needs rather than chasing quick trends. Reliable specifications, steady improvement, and unbundled user support—these principles have brought our partners consistent results for decades. By providing a straightforward, stable, and effective 4-tert-butylbenzoic acid, we remain a part of their progress for years to come, adapting and responding, batch after batch.